Download or read book Orthometallated Acetophenone Imines as Ligands for Transition and Main Group Metals written by John Frederick Beck and published by . This book was released on 2011 with total page 171 pages. Available in PDF, EPUB and Kindle. Book excerpt: Orthometallated aryl imines have been used extensively as ligands for late transition metals such as palladium and iridium. Due to the lack of a direct synthetic pathway from the imine to the orthometallated imine, there are few examples of early metals utilizing orthometallated aryl imines as ligands. Early transition metals like titanium and zirconium are unable to undergo the necessary C-H activation step to form the orthometallated complex. In order to synthesize early metal complexes utilizing orthometallated imines, a new method was developed which activates the ortho-proton, via a regiospecific lithiation, prior to metal complexation. The inclusion of a methylenedioxy moiety directs the lithiation and stabilizes the product. A series of early transition metal complexes with orthometallated imines were produced and structurally characterized, using small molecule X-ray diffraction. Multiple metal complexes were synthesized by reacting a ortholithiated imine with early transition and main group metal synthons such as Ti(NtBu)Cl2py3, CpTi(NtBu)Clpy, HfCl4, EtMgBr, AlCl3, CuI, ZnCl2,and nBu3SnCl. The synthesis of alicyclic 3-iminophosphine ligands was extended to include a new framework incorporating a cyclopentenyl backbone with a di-tert-butyl phosphine functionality (3IPtBu). The palladium complex [(3IPtBu)Pd(allyl)]OTf displayed excellent catalytic activity in the hydroamination of 3-methyl-1,2-butadiene(1,1-dimethylallene) with primary aryl amines anilines), selectively producing the branched allylic amine product (kinetic product) in high conversion at ambient temperature for non-halogenated substrates. Hydroamination using halogenated anilines was successful at 70 °C, providing moderate yields, with the formation of little or no linear product (thermodynamic product). Additionally, a subsequent aromatic amino Claisen rearrangement of selected allylic amine products, employing catalytic triflic acid, proved to be an effective atom-economical method for the production of ortho-allylic anilines in a high yielding two-step, one-pot synthesis.
Download or read book Synthesis of Group IV Metal Complexes Employing a Newly Developed Orthometallated Imine Ligand System written by Tamam Issa Baiz and published by . This book was released on 2007 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Main Group and Transition metal Complexes of Oxygen containing Ligands written by Mauricio Roldan Urbano and published by . This book was released on 1976 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Main Group and Transition metal Complexes of Oxygen containing Ligands written by Mauricio Roldan Urbano and published by . This book was released on 1976 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inorganic Syntheses Volume 35 written by and published by John Wiley & Sons. This book was released on 2010-08-13 with total page 221 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. Includes complete, up-to-date procedures involving important inorganic substances Contains subject, contributor, and formula indexes
Download or read book Palladacycles written by Jairton Dupont and published by John Wiley & Sons. This book was released on 2008-10-13 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: From synthesis to applications in catalysis, material science and biology this much-needed book is the first to comprehensively present everything you need to know about palladacycles. Renowned international authors guarantee high-quality content, making this a must-have for everyone working in the field.
Download or read book Gold Chemistry written by Fabian Mohr and published by John Wiley & Sons. This book was released on 2009-04-20 with total page 425 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by world-class authors, this most recent major book on the topic highlights new and current trends as well as future directions. It is comprehensive in its scope, covering all aspects of gold chemistry -- from homogeneous to heterogeneous catalysis, from supramolecular assemblies to sensors and medicinal applications. The result is an invaluable work for both organic and inorganic chemists working in universities and industry, as well as material scientists.
Download or read book The Chemistry of Pincer Compounds written by David Morales-Morales and published by Elsevier. This book was released on 2011-08-11 with total page 467 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties.The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds* Covers the areas in which pincer complexes have had an impact* Includes information on more recent and interesting pincer compounds not just those that are well-known
Download or read book Pincer and Pincer Type Complexes written by Kálmán J. Szabó and published by John Wiley & Sons. This book was released on 2014-06-10 with total page 389 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.
Download or read book Fundamentals of Molecular Catalysis written by and published by Elsevier. This book was released on 2003-04-02 with total page 537 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all contemporary organic synthesis involve transition metal complexes as catalysts or particular reagents. The aim of this book is to provide the reader with detailed accounts of elementary processes within molecular catalysis to allow its development and as an aid in designing novel catalytic systems. The book comprises authoritative reviews on elementary processes from experts working at the forefront of organometallic chemistry. · This is the first book that focuses on elementary processes in transition metal complexes for understanding catalytic mechanisms· Provides detailed description of elementary processes involved in catalytic cycles by experts in the field· Provides an overview of the mechanisms of various homogeneous catalyses
Download or read book The Privileged Pincer Metal Platform Coordination Chemistry Applications written by Gerard van Koten and published by Springer. This book was released on 2015-08-27 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Download or read book Applications of Organometallic Compounds written by Iwao Omae and published by John Wiley & Sons. This book was released on 1998-05-08 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: Applications of Organometallic Compounds Iwao Omae Omae Research Laboratories, Japan Applications of Organometallic Compounds is a comprehensive and in-depth survey of all recent developments in organometallic chemistry. Chapter by chapter, the author discusses 20 of the most common elements used in organometallic chemistry. Each chapter describes the synthesis of the organometallic compounds of the element, their structure and their importance in organic transformations. Applications of Organometallic Compounds: * Combines a full background to the topic with comprehensive organic syntheses. * Contains a historical overview of organometallic chemistry. * Discusses the possible side reactions that are caused by impurities in each organometallic reagent. * Includes the basic coordination chemistry of organometallics. * Contains hundreds of reaction examples and extensive referencing. The book is intended to be an introduction to organometallic chemistry for research chemists in organic, natural product and pharmaceutical synthetic chemistry.
Download or read book Organometallics written by Christoph Elschenbroich and published by Wiley-VCH. This book was released on 1992-02-17 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: From reviews of the first English edition: 'The selection of material and the order of its presentation is first class ... Students and their instructors will find this book extraordinarily easy to use and extraordinarily useful.' Chemistry in Britain 'Elschenbroich and Salzer have written the textbook of choice for graduate or senior-level courses that place an equal emphasis on main group element and transition metal organometallic chemistry. ... this book can be unequivocally recommended to any teacher or student of organometallic chemistry.' Angewandte Chemie International Edition 'The breadth and depth of coverage are outstanding, and the excitement of synthetic organometallic chemistry comes across very strongly.' Journal of the American Chemical Society
Download or read book Aqueous Phase Organometallic Catalysis written by Boy Cornils and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 780 pages. Available in PDF, EPUB and Kindle. Book excerpt: Now in its second completely revised and expanded edition. Written by the renowned editors B. Cornils and W. A. Herrmann, this book presents every important aspect of aqueous-phase organometallic catalysis, a method which saves time, waste and money. The large-scale application of this "green" technology in chemical industry clearly underlines its practical use outside of academia. New chapters (for example "Organic Chemistry in Water"), 20% more content and fully updated contributions from a plethora of international authors make this book a "must-have" for everyone working in this field. From the reviews of the first edition: "This overview will be extremely useful for everyone active in this field [...]" Angewandte Chemie "This book is an essential in any chemical research library and I strongly recommend it to all synthetic research and teaching chemists. [...]" The Alchemist "The editors are to be congratulated on assembling such a wide range of contributors who have described the industrial as well as the academic aspects of the subject." [...] Journal of Organometallic Chemistry
Download or read book Basic Organometallic Chemistry written by Ionel Haiduc and published by Walter de Gruyter. This book was released on 2011-06-01 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Cyclometalation Reactions written by Iwao Omae and published by Springer Science & Business Media. This book was released on 2014-01-23 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.
Download or read book Modern Inorganic Synthetic Chemistry written by Ruren Xu and published by Elsevier. This book was released on 2017-02-11 with total page 810 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modern Inorganic Synthetic Chemistry, Second Edition captures, in five distinct sections, the latest advancements in inorganic synthetic chemistry, providing materials chemists, chemical engineers, and materials scientists with a valuable reference source to help them advance their research efforts and achieve breakthroughs. Section one includes six chapters centering on synthetic chemistry under specific conditions, such as high-temperature, low-temperature and cryogenic, hydrothermal and solvothermal, high-pressure, photochemical and fusion conditions. Section two focuses on the synthesis and related chemistry problems of highly distinct categories of inorganic compounds, including superheavy elements, coordination compounds and coordination polymers, cluster compounds, organometallic compounds, inorganic polymers, and nonstoichiometric compounds. Section three elaborates on the synthetic chemistry of five important classes of inorganic functional materials, namely, ordered porous materials, carbon materials, advanced ceramic materials, host-guest materials, and hierarchically structured materials. Section four consists of four chapters where the synthesis of functional inorganic aggregates is discussed, giving special attention to the growth of single crystals, assembly of nanomaterials, and preparation of amorphous materials and membranes. The new edition’s biggest highlight is Section five where the frontier in inorganic synthetic chemistry is reviewed by focusing on biomimetic synthesis and rationally designed synthesis. Focuses on the chemistry of inorganic synthesis, assembly, and organization of wide-ranging inorganic systems Covers all major methodologies of inorganic synthesis Provides state-of-the-art synthetic methods Includes real examples in the organization of complex inorganic functional materials Contains more than 4000 references that are all highly reflective of the latest advancement in inorganic synthetic chemistry Presents a comprehensive coverage of the key issues involved in modern inorganic synthetic chemistry as written by experts in the field
