Download or read book Organotitanium Reagents in Organic Synthesis written by Manfred T. Reetz and published by Springer. This book was released on 1986 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organotitanium Reagents in Organic Synthesis written by Manfred Reetz and published by . This book was released on 2014-01-15 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organotitanium Reagents in Organic Synthesis written by Manfred T. Reetz and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: Titanium has been used to perform many kinds of reactions in organic and inorganic chemistry. The present book is concerned primarily with a new development in titanium chemistry which is useful in organic synthesis. In 1979/80 it was discovered that the titanation of classical carbanions using C1TiX leads to species with reduced basicity and reactivity. This increases 3 chemo-, regio-and stereo selectivity in reactions with organic compounds such as aldehydes, ketones and alkyl halides. Many new examples have been reported in recent times. Since the nature of the ligand X at titanium can be widely varied, the electronic and steric nature of the reagents is easily controlled. This helps in predicting the stereochemical outcome of many of the C-C bond forming reactions, but the trial and error method is still necessary in other cases. One of the ultimate objectives of chemistry is to understand correlations between structure and reactivity. Although this goal has not been reached in the area of organotitanium chemistry, appreciable progress has been made. A great deal of physical and computational data of organotitanium compounds described in the current and older literature (e. g. , Ziegler-Natta type catalysts) has been reported by polymer, inorganic and theoretical chemists. It is summarized in Chapter 2 of this book, because some aspects are useful in understanding reactivity and selectivity of organo titanium compounds in organic synthesis as described in the chapters which follow.
Download or read book Organotitanium Reagents in Organic Chemistry written by Manfred T. Reetz and published by . This book was released on 1992 with total page 824 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organometallic Chemistry of Titanium Zirconium and Hafnium written by P.C. Wailes and published by Elsevier. This book was released on 2012-12-02 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Chemistry of Titanium, Zirconium, and Hafnium covers the chemistry of organic complexes of titanium, zirconium, and hafnium having metal-to-carbon linkage. This book is organized into eight chapters that consider the significant developments in delineating the chemistry of these metal derivatives. This book starts with a description of the stability and bonding in cyclopentadienyl derivatives of the metals, based on the thermodynamic and spectroscopic evidence. The remaining chapters discuss the preparation and reactions of titanium-, zirconium-, and hafnium-bonded organic compounds. These chapters also look into the synthetic difficulties encountered from the reactions and preparation of these compounds. The stabilization and adduct formation of these metal complexes are also explored. Organic chemists and organic chemistry researchers and students will find this book invaluable.
Download or read book Utilization of Organotitanium Compounds in Organic Synthesis written by Walter Keung and published by . This book was released on 2000 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Titanium and Zirconium in Organic Synthesis written by Ilan Marek and published by Wiley-VCH Verlag GmbH. This book was released on 2002-01-01 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last years, the role of titanium and zirconium in organic synthesis has dramatically increased and nowadays, no synthetic chemist can afford to be without a sound knowledge of this fascinating organometal chemistry. This unique book, edited by Ilan Marek, thus summarizes the numerous applications and developments of these two group 4 early transition metal complexes. A plethora of internationally renowned experts and leading scientists in this field cover all the significant aspects of this increasingly important part of organic chemistry and bring the reader up to date. A particularly attractive and useful feature is the inclusion of typical experimental procedures, chosen for broad utility and application. This comprehensive demonstrates the diversity and the applications of these important compounds and is a must-have for all chemists working in organometallic or synthetic organic chemistry.
Download or read book Organometallics in Process Chemistry written by Ahmed F. Abdel-Magid and published by Springer Science & Business Media. This book was released on 2004-06-15 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: The design of efficient syntheses of medicinal agents is one of the prime goals of the process chemist in the pharmaceutical industry. The expanding list of metal-mediated reactions has had a major impact on this endeavor over the last two decades. This volume will highlight some of the areas of organometallic chemistry that have played a particularly important role in development. The chapters are written by chemists who work in the process groups of major pharmaceutical companies and fine chemical manufacturers. Having demonstrated the power of organometallics in their processes the authors herein expand upon their experiences with examples from the literature as reported by process groups within the industry. The chapters are organized either by the application of a particular metal or reaction class. Removal of the residual metal(s) from the isolated active pharmaceutical ingredient (API) is key to the release of the material for human consumption, and hence, is reviewed here as well. This volume of Topics in Organometallic Chemistry is presented to offer a representative cross section of organometallic applications in the pharmaceutical industry as well as to give an appreciation for the creativity possible in process chemistry.
Download or read book Organo di Metallic Compounds or Reagents written by Zhenfeng Xi and published by Springer. This book was released on 2016-09-22 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Download or read book The Organic Chemistry of Titanium written by Raoul Feld and published by . This book was released on 1965 with total page 213 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organic Chemistry of Titanium written by Raoul Feld and published by . This book was released on 1995-12-31 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organometallics in Synthesis written by Manfred Schlosser and published by Wiley. This book was released on 1996-11-27 with total page 614 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a practical introduction into the organic syntheses using organometallic reagents and catalysts. Addressing the most important issues, it restricts itself to the derivatives of less than a dozen metals, focusing on those which are most versatile and frequently used. Provides practical advice on how to choose the best methods and conditions and how to carry out and work up organometallic reactions. Details the fundamental facts and the mechanistic background needed to fully understand why a reaction follows a given course.
Download or read book Organometallic Chemistry of Titanium Zirconium and Hafnium written by P. C. Wailes and published by . This book was released on 1974-01-01 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Chemistry of Titanium, Zirconium, and Hafnium...
Download or read book Transition Metal Reagents and Catalysts written by Jiro Tsuji and published by John Wiley & Sons. This book was released on 2002-08-16 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
Download or read book Modern Organic Synthesis written by George S. Zweifel and published by John Wiley & Sons. This book was released on 2017-03-13 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book bridges the gap between sophomore and advanced / graduate level organic chemistry courses, providing students with a necessary background to begin research in either an industry or academic environment. • Covers key concepts that include retrosynthesis, conformational analysis, and functional group transformations as well as presents the latest developments in organometallic chemistry and C–C bond formation • Uses a concise and easy-to-read style, with many illustrated examples • Updates material, examples, and references from the first edition • Adds coverage of organocatalysts and organometallic reagents
Download or read book Tin in Organic Synthesis written by Michel Pereyre and published by Butterworth-Heinemann. This book was released on 1987 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tin in Organic Synthesis is a systematic presentation of the organic chemistry of tin. This book discusses the significant advances that have been made with regard to the applications of organotin compounds as reagents or intermediates in organic synthesis and points out directions for future developments. This monograph is comprised of 17 chapters divided into four sections. Following a brief introduction to organotin chemistry, the production of the organotin reagents, which are most usually employed in organic synthesis, is described. Special emphasis is placed on the creation of a fresh ti ...
Download or read book Organometallic Chemistry of Five Membered Heterocycles written by Alexander Sadimenko and published by . This book was released on 2019-10-25 with total page 792 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Chemistry of Five-Membered Heterocycles is a comprehensive source of information on the synthesis, coordination modes and reactivity of coordinated five-membered monoheterocycles and the organometallic complexes of their numerous derivatives, including chelating ligands, oligomers and macrocycles. Applications in modern materials chemistry are examined, including optical materials, catalysts, fuels, and more. An ideal reference for researchers working in organometallic, heterocyclic, materials chemistry, organic chemistry and catalysis, readers will find this book a comprehensive overview on the modern synthetic methods, possible coordination situations, trends in reactivity of the coordinated heteroaromatic ligands, and methods for construction of modern materials. Includes synthesis, structural features and coordination modes of five-membered heterocycles Features a comparative analysis of reactivity of uncoordinated and coordinated ligands Offers coverage of derivatives of fundamental ligands and examines trends in materials applications
