Download or read book Organosilicon Reactions Catalysed by Organotin Compounds written by Gordon Cecil Butler and published by . This book was released on 1973 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Reactions of Organosilicon and Organotin Compounds with Platinum and Palladium Complexes written by H. Azizian-Balaneji and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organosilicon Chemistry written by Tamejiro Hiyama and published by John Wiley & Sons. This book was released on 2020-02-18 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a unique summary of important catalytic reactions in the presence of silicon A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals. In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules. -The first book about this topic in decades, covering a broad range of reactions -Covers new approaches and novel catalyst systems that have been developed in recent years -Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry.
Download or read book Organosilicon Compounds written by Vladimir Ya Lee and published by Academic Press. This book was released on 2017-08-22 with total page 758 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology
Download or read book Reactions of Organotin and Organosilicon Compounds with Complexes of Platinum and Related Metals written by N. M. Shuaib and published by . This book was released on 1984 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Progress in Organosilicon Chemistry written by Bogdan Marciniec and published by Taylor & Francis. This book was released on 1995 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Organosilicon Chemistry comprises more than thirty papers presented by many of the world's most eminent organosilicon specialists at the Tenth International Symposium on Organosilicon Chemistry held in Poznan, Poland in August 1993. The conference marked the fiftieth anniversary of the discovery and exploration of "direct synthesis." As much attention today is directed beyond silicon polymers, chemists have become involved with the use of elementary silicon and its applications, including ultrapure silicon in transistors and computers, silicon precursors of polymers, and other silicon-based materials as well as fine chemicals. This book provides an overview of organosilicon chemistry, including organic and inorganic chemistry of silicon, silicon polymers and oligomers; theoretical and structural chemistry of silicon; silicon-based materials and their applications; silicon in organic synthesis; mechanistic organosilicon chemistry; and bio- and environmental organosilicon chemistry. This diverse range of topics makes the book a valuable reference for chemists working in both applied and theoretical chemistry.
Download or read book Organosilicon Chemistry written by Stephan Pawlenko and published by Walter de Gruyter. This book was released on 2011-06-01 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organotin and Organosilicon Computers in Cross coupling Aromatic Nucleophilis Substitution and Addition Reactions written by I. P. Beletskaya and published by . This book was released on 1989 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactions of organotin compounds with organic halides and acid halides catalyzed by Pd complexes without phosphine ligands have been carried out under very mild conditions. These reactions afford biaryls, tolans, sytrenes, dienes and unsymmetrical ketones with various substituents. Synthesis of organotin compounds may be realized by the reactions of organic halides with hexaaryldistannanes catalyzed by Pd and Ni complexes. Pd-catalyzed carbonylation of organic halides in the present of organotin compounds of the series Alk3SnNu (Nu=R, MeO, PhS, Et2N, SnAlk3) proves to be a convenient methods for the synthesis of ketones, derivatives of aromatic acids and -diketones.
Download or read book Organosilicon Compounds Two volume set written by Vladimir Ya Lee and published by Academic Press. This book was released on 2017-10-01 with total page 1436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Compounds provides readers with the state-of-the-art status of organosilicon chemistry, including its theoretical, synthetic, physico-chemical and applied aspects. By including high quality content in a key strategic signing area, this work is a strong addition to chemistry offerings in organic, main group and organometallic research. Organosilicon chemistry deals with compounds containing carbon–silicon bonds, an essential part of organic and organometallic chemistry. This book presents the many milestone in the field that have been discovered during the last few years, also detailing its usage in commercial products, such as sealants, adhesives and coatings. Features valuable contributions from prominent experts who cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects Covers important breakthroughs in the field, along with historically significant achievements Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) working in organometallic, organosilicon, main group element, transition metal, industrial silicon chemistry, and more
Download or read book Cross Coupling Reactions written by Norio Miyaura and published by Springer. This book was released on 2003-07-01 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,Zn,In,Sn, and Hg compounds. These reactions provided an indispensable and simple methodology for preparative organic chemists. Due to the simplicity and rel- bility in the carbon-carbon, carbon-heteroatom, and carbon-metalloid bo- formations,as well as high efficiency of the catalytic process,the reactions have been widely employed by organic chemists in various fields. Application of the protocol ranges from various syntheses of complex natural products to the preparation of biologically relevant molecules including drugs, and of sup- molecules, and to functional materials. The reactions on solid surfaces allow robot synthesis and combinatorial synthesis. Now, many organic chemists do not hesitate to use transition metal complexes for the transformation of org- ic molecules. Indeed, innumerable organic syntheses have been realized by the catalyzed reactions of transition metal complexes that are not achievable by t- ditional synthetic methods. Among these, the metal-catalyzed cross-coupling reactions have undoubtedly contributed greatly to the development of such a new area of “metal-catalyzed organic syntheses”. An excellent monograph for the cross-coupling reactions and other met- catalyzed C-C bond-forming reactions recently appeared in Metal-catalyzed Cross-coupling Reactions (Wiley-VCH,1998).
Download or read book Exchange Reactions of Organotin and Organosilicon Compounds with Mild Fluorinating Agents written by and published by . This book was released on 1992 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: A diverse group of compounds bearing labile fluorine atoms have been found to undergo similar exchange reactions with various organosilanes and stannanes. For example, methylphosphonic difluoride, boron trifluoride etherate, and perfluoroisobutene all react with both organosilicon and organotin alkoxides to give products resulting from the exchange of fluoride for an alkoxide group. In contrast to reactions involving the use of protic nucleophiles that may yield these products, hydrogen fluoride is not formed as a byproduct in these systems. Organotin compounds have been found to be more reactive than their silicon based analogs. Mechanisms are proposed to account for the products and the reactivity differences observed in these systems. These reactions have proven useful for the routine synthesis of various compounds.
Download or read book Synthesis and Structural Chemistry of Organotin and Organosilicon Compounds written by Jean Frances Vollano and published by . This book was released on 1983 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organosilicon Chemistry 2 written by Sam Stuart and published by Elsevier. This book was released on 2013-09-03 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Chemistry: 2 provides information pertinent to the fundamental aspects of organosilicon chemistry. This book discusses the organosilicon substituents in anionic rearrangements as well as examines the production of tetrakis allene from a large number of aliphatic and aromatic polyhalogenated compounds. Organized into 14 chapters, this book begins with an overview of the use of organosilyl groups as migrating substituents. This text then examines the development in the chemistry of organosilicon cyclic compounds. Other chapters consider the evidence supporting the intermediacy of silylenes and the general picture of the chemistry of organosilylenes. This book discusses as well the two major approaches for the silylation of polyhalogenated compounds, including the direct reaction of polyhalogenated compounds and the metalation or halogen-metal exchange between the halogenated aromatic compounds and organolithium reagents. The final chapter deals with the importance of hydrosilation. This book is a valuable resource for chemists, scientists, and research workers.
Download or read book Organosilicon Chemistry III written by Norbert Auner and published by Wiley-VCH. This book was released on 1998-02-11 with total page 754 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Chemistry III From Molecules to Materials Edited by N. Auner and J. Weis Organosilicon Chemistry at its best... Like its two hugely successful predecessors, the third volume again presents the latest developments in a rapidly expanding field of industrial and academic research. The contributions from approx, 80 internationally renowned experts and researchers in this fascinating part of the rapidly growing field of main group chemistry describe current trends in organosilicon chemistry and provide summaries of the latest (1997!) knowledge in this area. To facilitate access to the ongoing research this volume is split into two parts, each with a comprehensive introduction: Part 1: Fascinating Organosilicon Compounds Part 2: Silicon-based Materials
Download or read book Organometallic Chemistry Reviews written by R. Bruce King and published by Elsevier Science & Technology. This book was released on 1984 with total page 554 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Reaction Pathways in the Thermolysis of Organotin Compounds written by P. G. Harrison and published by . This book was released on 1989 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: These reactions are interpreted mechanistically in terms of surface-triggered gas-phase free-radical reactions. Organosilicon compounds behave in a broadly similar fashion although at significantly higher temperatures.
Download or read book Ionic and Organometallic Catalyzed Organosilane Reductions written by Gerald L. Larson and published by Wiley. This book was released on 2009-11-19 with total page 816 pages. Available in PDF, EPUB and Kindle. Book excerpt: An essential reference book for all synthetic organic chemists The exceptionally useful chemical-reducing properties of organosilicon hydrides have been known for more than half a century. Since the early discovery of these properties, interest in the use of organosilicon hydrides for the reduction of organic functional groups has increased steadily and has led to the development of many techniques for their deployment in chemo-, regio-, and stereoselective transformations in organic synthesis. Ionic and Organometallic-Catalyzed Organosilane Reductions provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis. Both ionic and catalyst-mediated reaction types are included, with appropriate reference to reaction mechanisms where they have been elucidated. A wide variety of organic functional group reductions by organosilicon hydrides receive critical comments and evaluation, especially with respect to scope and limitations. A substantial discussion of asymmetric reductions is also included in this book. The contents of the book are taken from the comprehensive review of the topic contained in the Organic Reactions series and cover the reduction of all organic groups. All known examples are compiled in thirty-four easily scanned, comprehensive tables compiled from 809 original articles. Updated lists comprising 256 additional references for the tables are provided that bring the coverage up to March 2009. The authors have been, and continue to be, involved in the applications of organosilanes to organic synthesis. Consistent with the goal of Organic Reactions, the content and presentation of this text emphasize the preparative aspects of the reductions focusing on the scope and limitations of the individual transformations along with detailed experimental procedures. Ionic and Organometallic-Catalyzed Organosilane Reductions is an essential reference book for all synthetic organic chemists working in academic and industrial laboratories.
