Download or read book Organic electronic materials for hydrogen peroxide production written by Maciej Gryszel and published by Linköping University Electronic Press. This book was released on 2020-02-25 with total page 92 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen peroxide (H2O2) is an important oxidant, used in various fields of industry, such as paper manufacturing, production of polymers, detergents, and cosmetics. Considering that the molecule degrades only to H2O and O2, it is regarded as a green chemical. Unfortunately, the incumbent method of H2O2 synthesis, based on anthraquinone oxidation, although efficient, is not environmentally friendly, as it requires fossil fuels and significant energy input. Therefore, there are efforts underway to reduce the ecological impact of hydrogen peroxide production. Some of the most promising approaches involve catalytic reduction of O2 to H2O2 in an aqueous environment. This can be coupled with water oxidation. As the required energy could be delivered in different ways, hydrogen peroxide synthesis can be achieved by electrocatalysis, photoelectrocatalysis, or photocatalysis. This thesis explores the possibility of using organic electronic materials as catalysts for H2O2 evolution in oxygenated water solutions. Organic electronics is a field of materials science focused on conducting and semiconducting organic molecules. These materials offer many possible advantages, related to low cost, flexibility, and good optoelectronic properties. Huge progress in the field over the last years led to their commercial applications in e.g. organic light emitting diodes and photovoltaics. Only very recently have organic electronics begun to be considered from the point of view of catalysis. In the first two papers, we investigate electrocatalytic activity of an organic pigment (PTCDI) and a conducting polymer (PEDOT) towards oxygen reduction to hydrogen peroxide. Both types of catalysts are chemically stable and able to operate in a wide pH range. In paper 3, we demonstrate that H2O2-evolving photocathodes can be based on an organic PN heterojunction, giving devices of a record-breaking performance. In the first part of paper 4, the same concept was tested for a naturally-occurring semiconductor, eumelanin, leading to a first report of photoelectrocatalytic properties of this material. In the second part of paper 4, as well as in papers 5 and 6, we explore, respectively, photochemical hydrogen peroxide synthesis with eumelanin, organic semiconductors, and organic dyes. We show that the photostability of catalysts is higher for materials with low-lying HOMO level and it can be increased by an addition of a reducing agent to the reaction system. Our findings prove that already existing organic electronic materials can be successfully applied in H2O2 evolution for environmentally friendly chemical synthesis, suggesting their use in harvesting of solar energy and in situ generation of hydrogen peroxide for biomedical applications. Väteperoxid (H2O2) är en viktig oxidant som används inom olika industrier, såsom papperstillverkning och produktion av polymerer, tvättmedel och kosmetika. Med tanke på att molekylen bryts ner till vatten (H2O) och syre (O2) betraktas den som en grön kemikalie. Tyvärr är den befintliga metoden för framställning av H2O2 baserad på oxidation av en antrakinon, en metod som är effektiv, men inte miljövänlig eftersom den kräver fossila bränslen och betydande energitillförsel. Det pågår därför ansträngningar för att minska den ekologiska effekten av väteperoxidproduktionen. Några av de mest lovande metoderna involverar katalytisk O2 till H2O2-reduktion i vattenlösning, kombinerat med vattenoxidation. Eftersom den nödvändiga energin kan levereras på olika sätt kan väteperoxidsyntesen uppnås genom elektrokatalys, fotoelektrokatalys eller fotokatalys. Denna avhandling undersöker möjligheten att använda organiska elektroniska material som katalysatorer för framställning av H2O2i syresatta vattenlösningar. Organisk elektronik är ett område inom materialvetenskap med fokus på ledande och halvledande organiska molekyler. Dessa material erbjuder många fördelar, såsom låg kostnad, flexibilitet och goda optoelektroniska egenskaper. Enorma framsteg på området har under de senaste åren lett till deras kommersiella tillämpningar i till exempel organiska ljusemitterande dioder och fotovoltaik. Nyligen har också organisk elektronik börjat övervägas ur katalysens synvinkel. I de två första artiklarna undersöker vi en elektrokatalytisk aktivitet av ett organiskt pigment (PTCDI) och en ledande polymer (PEDOT) i respekt till syrereduktion och väteperoxidproduktion. Båda typerna av katalysatorer är kemiskt stabila och kan arbeta inom ett brett pH-område. I artikel 3 visar vi att H2O2-producerande fotokatoder kan baseras på en organisk PN-gränsyta, vilket ger enheter med en rekordbrytande kapacitet. I den första delen av artikel 4 testades samma koncept för en naturligt förekommande halvledare, eumelanin, vilket ledde till en första rapport om fotoelektrokatalytiska egenskaper hos detta material. I den andra delen av artikel 4, samt i artikel 5 och 6, undersöker vi fotokemisk väteperoxidsyntes med eumelanin, organiska halvledare och organiska färgämnen. Vi visar att fotostabiliteten hos katalysatorer är högre för material med lågt liggande HOMO-nivå och att den kan ökas genom en tillsats av ett reduktionsmedel till reaktionssystemet. Våra fynd visar att redan befintliga organiska elektroniska material framgångsrikt kan tillämpas i H2O2-utvecklingen för miljövänlig kemisk syntes, vilket antyder att de kan användas för att ta tillvara på solenergi och för produktion av väteperoxid inom biomedicin.
Download or read book Electrochemical Membrane Technology written by Adewale Giwa and published by Elsevier. This book was released on 2024-01-23 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical Membrane Technology will have a strong impact on electrochemical and membrane separation research in the future and will contribute significantly to academic training and the well-being of human society. This book will include a comprehensive discussion of SWOT analysis of each electrochemical membrane technology, and the discussion of energy production from electrochemical membrane technologies in a separate chapter. This will be based theoretical and experimental studies on electrochemical membrane technologies and applications. Written for chemical and environmental engineers, professors and other university teachers, research scientists, graduate students, water treatment managers, research institutions, and Research and Development departments of industries involved in sustainable water treatment and coproduction of valuable products from water treatment technologies. Provides comparative analysis of energy production from electrochemical membrane technologies and a comprehensive analysis of the recent advances in these technologies Discusses the strengths, weaknesses, opportunities, and threats/challenges (SWOT) of each electrochemical membrane technology Addresses the importance energy co-production
Download or read book Environmental Issues with Materials and Processes for the Electronics and Semiconductor Industries written by Laura Mendicino and published by The Electrochemical Society. This book was released on 2001 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advanced Technologies for Solid Liquid and Gas Waste Treatment written by Saleh Al Arni and published by CRC Press. This book was released on 2023-04-05 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Technologies for Solid, Liquid, and Gas Waste Treatment presents the potential of using advanced and emerging technologies to effectively treat waste. This book uniquely addresses treatment techniques for waste in all three phases, solid, liquid, and gas, with the goals of mitigating negative impacts of waste and producing valued-added products, such as biogas and fertilizer, as well as the use of artificial intelligence in the field. • Covers a wide range of advanced and emerging treatment technologies such as photocatalysis processing, adsorptive membranes, pyrolysis, advanced oxidation process, electrocoagulation, composting technologies, etc. • Addresses issues associated with wastes in different phases. • Discusses the pros and cons of treatment technologies for handling different wastes produced by different industrial processes, such as agricultural biomass, industrial/domestic solid wastes, wastewater, and hazardous gas. • Includes application of artificial intelligence in treatment of electronic waste. This book will appeal to chemical, civil, and environmental engineers working on waste treatment, waste valorization, and pollution control.
Download or read book Electrochemical Hydrogen Peroxide Production from Molecular Oxygen on Functionalized Carbon Materials written by Yanyan Sun and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Minerals Yearbook written by United States. Bureau of Mines and published by . This book was released on 1996 with total page 998 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Electrochemical Oxygen Reduction written by Pei Kang Shen and published by Springer Nature. This book was released on 2021-01-16 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses systematically the theoretical research and the applications of electrochemical oxygen reduction. Oxygen reduction reaction is a common issue in electrochemistry, but is also an important process involved in the field of energy, cryogenic fuel cells, metal–air cells, oxygen sensors and hydrogen peroxide preparation. This book is divided into 6 chapters; it starts with a description of dynamic mechanisms, followed by a detailed introduction on the related experimental methods and related catalyst preparation technology. By providing the basic methods and testing techniques, and by demonstrating their applications, it helps readers gain a better understanding of oxygen reduction reactions, making it a valuable resource for the industrialization of scientific research achievements. Accordingly, the book appeals to a broad readership, particularly graduate students, those working at universities and research organizations, and industrial researchers.
Download or read book Organic Flexible Electronics written by Piero Cosseddu and published by Woodhead Publishing. This book was released on 2020-09-29 with total page 666 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Electronics is a novel field of electronics that has gained an incredible attention over the past few decades. New materials, device architectures and applications have been continuously introduced by the academic and also industrial communities, and novel topics have raised strong interest in such communities, as molecular doping, thermoelectrics, bioelectronics and many others.Organic Flexible Electronics is mainly divided into three sections. The first part is focused on the fundamentals of organic electronics, such as charge transport models in these systems and new approaches for the design and synthesis of novel molecules. The first section addresses the main challenges that are still open in this field, including the important role of interfaces for achieving high-performing devices or the novel approaches employed for improving reliability issues.The second part discusses the most innovative devices which have been developed in recent years, such as devices for energy harvesting, flexible batteries, high frequency circuits, and flexible devices for tattoo electronics and bioelectronics.Finally the book reviews the most important applications moving from more standard flexible back panels to wearable and textile electronics and more futuristic applications like ingestible systems. Reviews the fundamental properties and methods for optimizing organic electronic materials including chemical doping and techniques to address stability issues Discusses the most promising organic electronic devices for energy, electronics, and biomedical applications Addresses key applications of organic electronic devices in imagers, wearable electronics, bioelectronics
Download or read book Catalytic Process Development for Renewable Materials written by Pieter Imhof and published by John Wiley & Sons. This book was released on 2013-02-28 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Green, clean and renewable are the hottest keywords for catalysis and industry. This handbook and ready reference is the first to combine the fields of advanced experimentation and catalytic process development for biobased materials in industry. It describes the entire workflow from idea, approach, research, and process development, right up to commercialization. A large part of the book is devoted to the use of advanced technologies and methodologies like high throughput experimentation, as well as reactor and process design models, with a wide selection of real-life examples included at each stage. The contributions are from authors at leading companies and institutes, providing firsthand information and knowledge that is hard to find elsewhere. This work is aimed at decision makers, engineers and chemists in industry, chemists and engineers working with/on renewables, chemists in the field of catalysis, and chemical engineers.
Download or read book Encyclopedic Dictionary of Industrial Technology written by David F. Tver and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume has been prepared as a reference guide for all engineering, industrial and technical management personnel who are in any way involved in the manufacturing process, in product design, or in converting of raw materials to finished products. This Encyclopedic Dictionary covers a wide range of subjects from industrial materials, minerals, metals, plastics and synthetic fibers to machine tools, computers, lasers, robots and other production equipment as well as manufacturing processes. Some of the materials reviewed are brass, steel, nickel, copper, bronze, cast iron, cements, clay, coal, coke, petroleum and petrochemicals, glass, limestone, rubber, paper, metal alloys, chemicals, synthetic fibers, textiles, plastics, resins, lubricants, and thermoplastics. Various processes are reviewed such as metal casting, forming, machining, anneal ing, extrusion, heat treating, injection molding, papermaking and steel processing. In heat treating such areas as martempering, annealing, spheroidizing, tempering and austempering are included. Different types of equipment related to the products are defined. In plastics such pro ducts are covered as nylons, polyesters, rayons, Teflon, Vinyon, Saran, acetates and acrylics. Many of the manufacturing processes and equipment involved in the conversion of material to finished products are described along with products and their ultimate uses. Also, important associated manufacturing activities such as inspection, handling, and control are included to make the references as complete as is practicable.
Download or read book Energy efficient anodic reactions for sustainable hydrogen production via water electrolysis written by Wenxian Liu and published by OAE Publishing Inc.. This book was released on 2023-10-13 with total page 31 pages. Available in PDF, EPUB and Kindle. Book excerpt: Overall water splitting is considered as an effective technique for hydrogen (H2) production; however, it usually requires large operating voltage mainly due to the high equilibrium potential of the anodic oxygen evolution reaction (OER). Replacing OER with energy-saving anode reactions not only reduces the operating voltage for H2 production but also generates high-value-added chemicals or purifies wastewater. This review article provides an overview of the fundamental reaction principles of overall water splitting and typical energy-saving alternative anode reactions, including methanol oxidation, hydrazine oxidation, and urea oxidation reactions. Then, the preparation methods, regulation strategies, and composition/structure-performance relations of advanced catalysts for these energy-efficient H2 generation technologies are discussed. Finally, we propose the underlying challenges and perspectives for this promising field.
Download or read book Innovations in Environmental Biotechnology written by Sudipti Arora and published by Springer Nature. This book was released on 2022-05-16 with total page 959 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book has 2 sections; Section A focuses on Environmental Sustainability and Green Technology and Section B covers Emerging Technologies in Environmental Biotechnology. The book introduces Environmental biotechnology as a tool to progress towards sustainable development goals and covers green technologies such as Bio-plastics, Third generation hybrid technology for algal biomass production, wastewater treatment and greenhouse gas mitigation, Green vaccination, Bio-fuels, Microbial enzymes, Bioelectrical systems, eco-friendly handmade paper production, nature based sanitation solutions, and greener ways to tackle air pollution along with the application of GIS to monitor & manage COVDI19 pandemic. The Section B covers emerging & innovative technologies such as vermifiltration, Small scale PVA gel based innovative solution for wastewater treatment, Cyclic technology based sequencing batch reactors (SBR) and role of Role of Bio-selectors in Performing Simultaneous Nitrification and Denitrification in SBR’s. It holistically covers essential information on Enzymatic Biotransformation and Biopolymer based nanocomposites for dye waste treatment, Arbuscular Mycorrhizal Fungi assisted Bioremediation of heavy metals, Coir Retting and Duckweeds: The Tiny Creatures for Resolving the Major Environmental Issues. It is a promising book for researchers, academicians, teachers, students, industrial enterprises, policy makers, public health officials and general users. The book is closely aligned to curricula of post graduate courses in biotechnology, microbiology, environmental biotechnology and environmental science.
Download or read book U S Government Research Reports written by and published by . This book was released on 1963 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book New Horizons in Electrochemical Science and Technology written by National Research Council and published by National Academies Press. This book was released on 1987-02-01 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modern technology depends heavily on advances in the electrochemical field, but this field may not be receiving the research attention and funding it needs. This new book addresses this issue. It reviews the status of current electrochemical knowledge, recommends areas of future research and development, identifies new technological opportunities in electrochemistry, delineates opportunities for interdisciplinary research, and outlines the socioeconomic impact of electrochemical advances.
Download or read book Chemistry and Chemists in Florence written by Marco Fontani and published by Springer. This book was released on 2016-04-15 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt: This brief offers a novel vision of the city of Florence, tracing the development of chemistry via the biographies of its most illustrious chemists. It documents not only important scientific research that came from the hands of Galileo Galilei and the physicists who followed in his footsteps, but also the growth of new disciplines such as chemistry, pharmaceutical chemistry, and biochemistry. It recounts how, in the Middle Ages, chemistry began as an applied science that served to bolster the Florentine economy, particularly in the textile dyeing industry. Later, important scientific collections founded by the ruling Medici family served as the basis of renowned museums that now house priceless artifacts and instruments. Also described in this text are the chemists such as Hugo Schiff, Angelo Angeli, and Luigi Rolla, who were active over the course of the following century and a quarter. The authors tell the story of the evolution of the Royal University of Florence, which ultimately became the University of Florence. Of interest to historians and chemists, this tale is told through the lives and work of the principal actors in the university’s department of chemistry.
Download or read book Organic Building Blocks of the Chemical Industry written by Harry H. Szmant and published by John Wiley & Sons. This book was released on 1989-11-09 with total page 744 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive survey of industrial organic chemicals, their useful properties, and the economic rationale for the dominant synthetic pathways. This practical guide explains where these organic building blocks of the chemical industry come from, how to make them on a commercial scale, how to price them, and how to analyze trends in demand and production of any given material. Coverage ranges from how and why different processes originated to the latest developments in high-value-added specialty chemicals.
Download or read book Photochemistry Volume 51 written by Stefano Crespi and published by Royal Society of Chemistry. This book was released on 2023-12-20 with total page 614 pages. Available in PDF, EPUB and Kindle. Book excerpt:
