Download or read book Organic Chemistry of Sulfur written by S. Oae and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 714 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.
Download or read book Organic Sulfur Chemistry written by Shigeru Oae and published by CRC Press. This book was released on 2018-05-04 with total page 441 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains fundamental knowledge regarding the structure and mechanisms of organic sulfur chemistry. Topics include sulfur bondings, effects of sulfur groups, stereochemistry around sulfur, substitution, ligand coupling within s-sulfurane, oxidation, reduction and rearrangement. References in this work total over 2,300. Anyone with an interest in organic sulfur chemistry will find this book to be fascinating reading.
Download or read book Organic Sulfur Compounds written by N. Kharasch and published by Elsevier. This book was released on 2013-10-22 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.
Download or read book Organic Sulfur Chemistry written by F. Bernardi and published by Elsevier Science & Technology. This book was released on 1985 with total page 760 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Chemistry of Organic Sulfur Compounds written by and published by . This book was released on 1961 with total page 662 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organic Chemistry of Sulfur written by 3Island Press and published by . This book was released on 1977-06-01 with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Organic Chemistry of Sulfur Tetracovalent Sulfur Compounds written by Chester Merle Suter and published by . This book was released on 1944 with total page 858 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Chemistry of Organic Sulfur Compounds written by Norman Kharasch and published by Elsevier. This book was released on 2013-10-22 with total page 475 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Organic Sulfur Compounds deals with the chemistry of organic sulfur compounds such as thiocyanates, 1-alkynyl thioethers, thiols, and olefins. Topics covered range from the mechanisms of Raney nickel desulfuration to olefin sulfide chemistry, desulfonylation reactions, and alkaline decomposition of aliphatic disulfides. The reaction of cyanide with cystine and cystine peptides is also discussed. This volume is comprised of 15 chapters and begins with an introduction to electron correlation and bond properties in some selected sulfur compounds including thionyl and sulfuryl fluoride. The following chapters explore the mechanisms of Raney nickel desulfuration; isomerization of organic thiocyanates; polyfluoroalkyl derivatives of sulfur; anionic oxidation of thiols and co-oxidation of thiols with olefins; and the chemistry of the 1,2-sithiole ring. Thiohydantoins, thiophosgene, and the alkaline decomposition of aliphatic disulfides are also considered. The final chapter is devoted to oxidation of disulfides, with special reference to cystine. This book will be a useful resource for organic chemists.
Download or read book Organic Sulfur Chemistry written by Shigeru Oae and published by CRC Press. This book was released on 1992-06-15 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: his volume provides an organic chemical perspective on the biochemistry of sulfur compounds. The authors have applied the principles of various biochemical processes to a general theory of the biochemical phenomena of sulfur compounds. These processes include metabolisms of inorganic sulfur compounds and metalloenzymes, mechanisms of thiolesterase actions, functions of disulfides in proteins, and biochemical redox reactions. Organic Sulfur Chemistry: Biochemical Aspects is an ideal reference for students and researchers in both biochemistry and organic chemistry.
Download or read book The Organic Chemistry of Sulfur written by C.M. Suter and published by . This book was released on 1969 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Versatile Organic Chemistry of Sulfur IV written by Vincent Porte and published by American Chemical Society. This book was released on 2024-02-09 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the vast landscape of organic chemistry, sulfur-containing compounds play a pivotal role in pharmaceuticals, industrial processes, and a wide range of chemical transformations, where they often enable selective and otherwise challenging functionalization reactions. This primer aims not only to elucidate the fundamental characteristics of sulfoxides and sulfur ylides but also to address key challenges encountered in their chemistry. By examining the influence of molecular structure on reactivity, the authors uncover valuable insights that underpin the utilization of these compounds. The Versatile Organic Chemistry of Sulfur(IV) is conceived as a precursor to our more extensive review, tailored to provide foundational knowledge for readers seeking entry into the more specialized material presented therein. The authors‘ goal for this primer is to equip both novices and seasoned practitioners with an understanding that transcends theoretical concepts, fostering an environment ripe for exploration and innovation.
Download or read book Reactions of Organosulfur Compounds written by Eric Block and published by Academic Press. This book was released on 2013-10-22 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, Volume 37: Reactions of Organosulfur Compounds covers the basics of organosulfur chemistry and the characteristics of organically bound sulfur, with an emphasis on reactions, particularly those of synthetic utility. The book discusses the preparation, nature, stereochemical aspects, reactions, and the kinetic and thermodynamic assessment of the stability of sulfur-containing carbanions; the preparation and reactions of sulfur ylides; and the preparation, assessment of stability, and reactions of sulfur-containing carbocations. The text also describes preparation, assessment of stability, nature, and reactions of sulfur-containing radicals, organosulfur carbenes, and carbenoids; as well as the the pericyclic reactions of organosulfur compounds. Chemists, biochemists, and students taking related courses will find the book useful.
Download or read book An Introduction to Organosulfur Chemistry written by R. J. Cremlyn and published by John Wiley & Sons. This book was released on 1996-12-23 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sulfur chemistry is becoming increasingly important as the role of this element is explored in both biological and environmental fields. After the initial chapters have discussed the synthesis, reactivity, and properties of the compounds in general, each of the next nine chapters takes a specific sulfur containing functional group and expands the discussion on synthetic procedures. The final chapter looks at the major uses of organo-sulfur compounds and their impact on biological and environmental areas.
Download or read book Sulfur Reagents in Organic Synthesis written by Patrick Metzner and published by Elsevier. This book was released on 2013-10-22 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: Designed for the practising organic chemist, this book details over a hundred experimental procedures using sulfer compounds in organic synthesis. Many of these methods are new to the literature, having been published since 1991, and illustrate the striking versatility of the use of sulfur reagents. Examples are simple to perform and extremely useful, and as such this book will be an invaluable aid to all involved in synthetic organic chemistry, whether in academic or industrial laboratories.
Download or read book Sulfur Dioxide Insertion Reactions for Organic Synthesis written by Danqing Zheng and published by . This book was released on 2017 with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Developments in the Organic Chemistry of Sulfur written by Carl Th Pedersen and published by Routledge. This book was released on 1989 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Sulfur in Organic and Inorganic Chemistry written by Alexander Senning and published by . This book was released on 1971 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt:
