Download or read book Orbitals written by Charles S McCaw and published by World Scientific Publishing Company. This book was released on 2015-03-30 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes atomic orbitals at a level suitable for undergraduates in chemistry. The mathematical treatment is brought to life by many illustrations rendered from mathematical functions (no artists' impressions), including three-dimensional plots of angular functions, showing orbital phase, and contour plots of the wavefunctions that result from orbital hybridisation. Orbitals extends the key fundamental quantum properties to many-electron atoms, linear combinations of atomic orbitals, simple molecules, delocalised systems and atomic spectroscopy. By focusing on simple model systems, use of analogies and avoiding group theory the results are obtained from initial postulates without the need for sophisticated mathematics.
Download or read book Orbitals With Applications In Atomic Spectra Revised Edition written by Charles Stuart Mccaw and published by World Scientific. This book was released on 2020-04-15 with total page 279 pages. Available in PDF, EPUB and Kindle. Book excerpt: 'Without being an explicitly philosophical treatise Chas McCaw's book delves into some of the deepest and most difficult aspects of atomic physics and chemistry and its underlying quantum mechanical account … One of the many strengths of the book under review is that it takes a rigorous and unflinching look at the necessary mathematical details. In addition, the author, who is the Head of Science at Winchester College in the UK, provides as many as 107 exercises which are interspersed throughout the main text. The detailed solutions are given at the end of the book, over a sequence of about 50 pages.'Foundations of ChemistryOrbitals: With Applications in Atomic Spectra describes atomic orbitals at a level suitable for undergraduates in chemistry. The mathematical treatment is brought to life by many illustrations rendered from mathematical functions (no artists' impressions), including three-dimensional plots of angular functions, showing orbital phase, and contour plots of the wavefunctions that result from orbital hybridisation.This revised edition includes new discussion of the origins of the colour of gold and the 'accidental degeneracy' of the hydrogen atom subshells, a new figure, a new exercise and worked solution, as well as several new references. It also contains current and accurate updates to the old edition.Orbitals extends the key fundamental quantum properties to many-electron atoms, linear combinations of atomic orbitals, simple molecules, delocalised systems and atomic spectroscopy. By focusing on simple model systems, use of analogies and avoiding group theory, results are obtained from initial postulates without the need for sophisticated mathematics. The book explains topics from first principles and guides the reader carefully through the necessary mathematics, supplemented by worked solutions to problems.
Download or read book Atomic Spectra and Radiative Transitions written by I.I. Sobelman and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: My previous book on the theory of atomic spectra was published in Russian about fifteen years ago. Besides the traditional problems usually included in a book on atomic spectroscopy, some other problems arising in various applications of spectroscopic methods were also discussed in the book. These include, for example, continuous spectrum radiation, excitation of atoms, and spectral line broadening. Extensive revisions were made in the English version of the book published by the Pergamon Press in 1972, especially in the chapter devoted to the problem of excitation of atoms. This book is intended as the first part of a two-volume presentation of the theory of atomic spectra, atomic radiative transitions, excitation of atoms, and spectral line broadening. The aim in preparing these new books has been to stress the problems connected with the most interesting applications of atomic spectroscopy to plasma diagnostics, astrophysics, laser physics, and other fields, which have been developed very intensively in recent years. The content of this first volume, devoted to the systematics of atomic spectra and radiative transitions, is similar to that of Chapters 1-6, 8 and 9 of the old book, but considerable revision has been made. Some sections, such as those on the Hartree-Fock method, the Dirac equation, and relativistic corrections, have been deleted. At the same time, more attention is paid to radiative transitions. More extensive tables of oscillator strengths, prob abilities, and effective cross sections of radiative transitions in discrete and continuous spectra are given.
Download or read book Atomic And Molecular Spectroscopy written by Mool Chand Gupta and published by New Age International. This book was released on 2007 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Comprehensive Text Clearly Explains Quantum Theory, Wave Mechanics, Structure Of Atoms And Molecules And Spectroscopy.The Book Is In Three Parts, Namely, Wave Mechanics; Structure Of Atoms And Molecules; And Spectroscopy And Resonance Techniques.In A Simple And Systematic Manner, The Book Explains The Quantum Mechanical Approach To Structure, Along With The Basic Principles And Application Of Spectroscopic Methods For Molecular Structure Determination.The Book Also Incorporates The Electric And Magnetic Properties Of Matter, The Symmetry, Group Theory And Its Applications.Each Chapter Includes Many Solved Examples And Problems For A Better Understanding Of The Subject.With Its Exhaustive Coverage And Systematic Approach, This Is An Invaluable Text For B.Sc. (Hons.) And M.Sc. Chemistry Students.
Download or read book Springer Handbook of Atomic Molecular and Optical Physics written by Gordon W. F. Drake and published by Springer Nature. This book was released on 2023-02-09 with total page 1436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprises a comprehensive reference source that unifies the entire fields of atomic molecular and optical (AMO) physics, assembling the principal ideas, techniques and results of the field. 92 chapters written by about 120 authors present the principal ideas, techniques and results of the field, together with a guide to the primary research literature (carefully edited to ensure a uniform coverage and style, with extensive cross-references). Along with a summary of key ideas, techniques, and results, many chapters offer diagrams of apparatus, graphs, and tables of data. From atomic spectroscopy to applications in comets, one finds contributions from over 100 authors, all leaders in their respective disciplines. Substantially updated and expanded since the original 1996 edition, it now contains several entirely new chapters covering current areas of great research interest that barely existed in 1996, such as Bose-Einstein condensation, quantum information, and cosmological variations of the fundamental constants. A fully-searchable CD- ROM version of the contents accompanies the handbook.
Download or read book The Theory of Atomic Structure and Spectra written by Robert D. Cowan and published by Univ of California Press. This book was released on 2023-11-15 with total page 764 pages. Available in PDF, EPUB and Kindle. Book excerpt: Both the interpretation of atomic spectra and the application of atomic spectroscopy to current problems in astrophysics, laser physics, and thermonuclear plasmas require a thorough knowledge of the Slater-Condon theory of atomic structure and spectra. This book gathers together aspects of the theory that are widely scattered in the literature and augments them to produce a coherent set of closed-form equations suitable both for computer calculations on cases of arbitrary complexity and for hand calculations for very simple cases.
Download or read book Theoretical Atomic Spectroscopy written by Zenonas Rudzikas and published by . This book was released on 2007-07-26 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph presents a complete guide to the theory of modern spectroscopy of atoms. Atomic spectroscopy continues to be one of the most important subjects of contemporary physics. The book describes the contemporary state of the theory of many-electron atoms and ions, the peculiarities of their structure and spectra, the processes of their interaction with radiation, and some of the applications of atomic spectroscopy. It contains a large number of new results, which have been published mainly in Russian and are therefore almost unknown to western scientists. Primarily a reference for researchers and graduate students in atomic physics and physical chemistry, this work will also be of value to physicists and chemists in other areas who use spectroscopy in their work.
Download or read book Spectra of Atoms and Molecules written by Peter F. Bernath and published by Oxford University Press. This book was released on 2015-11-16 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: This third edition of Peter Bernath's successful Spectra of Atoms and Molecules is designed to provide advanced undergraduates and graduate students a working knowledge of the vast field of spectroscopy. Also of interest to chemists, physicists, astronomers, atmospheric scientists, and engineers, this volume emphasizes the fundamental principles of spectroscopy with the primary goal of teaching the interpretation of spectra. Features include a presentation of group theory needed to understand spectroscopy, detailed worked examples and a large number of excellent problems at the end of each chapter. Prof. Bernath provides a large number of diagrams and spectra which have been specifically recorded for this book. Molecular symmetry, matrix representation of groups, quantum mechanics, and group theory are among the topics covered; atomic, rotational, vibrational, electronic and Raman spectra are analyzed. Bernath's clear treatment of the confusing topic of line strengths as needed for quantitative applications is featured. This much-needed new edition has been updated to include the 2010 CODATA revision of physical constants, and a large number of corrections and clarifications. Responding to student requests, the main new feature is the addition of detailed worked examples in each chapter. Spectra of Atoms and Molecules, 3e will help demystify spectroscopy by showing readers the necessary steps in a derivation, as well as the final result.
Download or read book Atomic Spectra written by Tim P. Softley and published by Oxford University Press, USA. This book was released on 1994 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt: This primer provides a systematic introduction to the spectra and electronic structure of atoms, beginning with the hydrogen atom, and following a logical progression through the alkali metals and the helium atom, to atoms with many unpaired electrons.
Download or read book Atomic Spectra written by W. R. Hindmarsh and published by Elsevier. This book was released on 2013-10-22 with total page 379 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomic Spectra compiles papers on the highlighted developments in the atomic spectra. This book discusses regularities in spectra emitted by monatomic gases that lead to an understanding of the structure of atoms and discovery of the principles that govern the behavior of matter on the atomic scale. This compilation includes Rydberg's famous account of the series of spectral lines; Weisskopf and Wigner’s papers on natural line-width; and Bethe’s study on the Lamb shift of energy levels. Papers dealing with the spectra of atoms with more than two electrons in the valence shell and continuous spectra of atoms are not included. This publication is useful to students intending to gain knowledge on the atomic spectra.
Download or read book Atomic Spectra and Atomic Structure written by Gerhard Herzberg and published by . This book was released on 1972 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Excitation of Atoms and Broadening of Spectral Lines written by Igor I. Sobel'man and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: A survey of elementary processes and mechanisms, presenting useful and relatively simple methods of approximation for calculating the effective cross sections, giving a number of approximate formulas. Extensive tables list cross sections and rate coefficients for various atoms and elementary processes. For this second edition several sections and formulas have been substantially revised, the tables recalculated using the updated version of ATOM and recent progress in the field has been added.
Download or read book ATOM LASER AND SPECTROSCOPY written by S. N. THAKUR and published by PHI Learning Pvt. Ltd.. This book was released on 2013-08-21 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Experimental spectroscopic techniques, especially those involving lasers, have wide-ranging applications in the fields of physics, medicine, electronics, and chemistry. Keeping in mind the importance of spectroscopic detection and characterization of atomic and molecular species, this book, now in its Second Edition, is updated. It deals with both the conventional and modern experimental techniques related to atoms, spectroscopy and lasers. It discusses the recent innovations, types and operating principles of lasers and laser systems. A section on Fiber Laser has been added in the new edition of the book. Recent developments in planetary detection of atoms and molecules by Laser Induced Breakdown Spectroscopy (LIBS) has prompted the inclusion of a section on LIBS on planet Mars along with its applications. Primarily intended as a text for undergraduate and postgraduate students of Physics in various Indian universities, this uptodate book would be immensely useful also for both undergraduate and postgraduate students in Chemistry, Astrophysics, Metallurgy and Material Science, and Geology and Mining. Key Features Coverage is quite extensive to cater to students of most Indian universities—with detailed discussions on atoms, spectroscopy and lasers. Gives special emphasis on modern aspects of spectroscopy such as laser cooling of atoms. Contains more than 140 diagrams to illustrate the concepts better.
Download or read book Shattered Symmetry written by Pieter Thyssen and published by Oxford University Press. This book was released on 2017-01-02 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: The standard model of subatomic particles and the periodic table of the atoms have the common goal to bring order in the bewildering chaos of the constituents of matter. Their success relies on the presence of fundamental symmetries in their core. The purpose of the book is to share the admiration for the power and the beauty of these symmetries. The reader is taken on a journey from the basic geometric symmetry group of a circle to the sublime dynamic symmetries that govern the motions of the particles. The trail follows the lines of parentage linking groups upstream to the unitary symmetry of the eightfold way of quarks, and to the four-dimensional symmetry of the hydrogen atom. Along the way the theory of symmetry groups is gradually introduced with special emphasis on graphical representations. The final challenge is to open up the structure of Mendeleev's table which goes beyond the symmetry of the hydrogen atom. Breaking this symmetry to accommodate the multi-electron atoms requires to leave the common ground of linear algebras and explore the potential of non-linearity.
Download or read book Basic Physical Chemistry written by E Brian Smith and published by World Scientific Publishing Company. This book was released on 2013-06-03 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: This elegant book provides a student-friendly introduction to the subject of physical chemistry. It is by the author of the very successful Basic Chemical Thermodynamics and is written in the same well-received popular style. It is concise and more compact than standard textbooks on the subject and emphasises the two important topics underpinning the subject: quantum mechanics and the second law of thermodynamics. Both topics are challenging to students because they focus on uncertainty and probability. The book explains these fundamental concepts clearly and shows how they offer the key to understanding a wide range of chemical phenomena including atomic and molecular spectra, the structure and properties of solids, liquids and gases, chemical equilibrium and the rates of chemical reactions. This revised edition has enabled improvements and corrections to be made.
Download or read book Group Theory written by Eugene P. Wigner and published by Elsevier. This book was released on 2013-09-03 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: Group Theory and its Application to the Quantum Mechanics of Atomic Spectra describes the applications of group theoretical methods to problems of quantum mechanics with particular reference to atomic spectra. The manuscript first takes a look at vectors and matrices, generalizations, and principal axis transformation. Topics include principal axis transformation for unitary and Hermitian matrices; unitary matrices and the scalar product; linear independence of vectors; and real orthogonal and symmetric matrices. The publication also ponders on the elements of quantum mechanics, perturbation theory, and transformation theory and the bases for the statistical interpretation of quantum mechanics. The book discusses abstract group theory and invariant subgroups, including theorems of finite groups, factor group, and isomorphism and homomorphism. The text also reviews the algebra of representation theory, rotation groups, three-dimensional pure rotation group, and characteristics of atomic spectra. Discussions focus on eigenvalues and quantum numbers, spherical harmonics, and representations of the unitary group. The manuscript is a valuable reference for readers interested in the applications of group theoretical methods.
Download or read book Fundamentals of Quantum Chemistry written by James E. House and published by Elsevier. This book was released on 2003-10-14 with total page 309 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fundamentals of Quantum Chemistry is an introduction to the principles of quantum mechanics needed in physical chemistry. Mathematical tools are presented and developed as needed and only basic calculus, chemistry, and physics is assumed. Applications include atomic and molecular structure, spectroscopy, alpha decay, tunneling, and superconductivity. New edition includes sections on perturbation theory, orbital symmetry of diatomic molecules, the Huckel MO method and Woodward/Hoffman rules as well as a new chapter on SCF and Hartree-Fock methods. This revised text clearly presents basic quantum mechanics for students in chemistry Separate sections treat needed mathematical techniques. Presents complete mathematical details of derivations Contains applications of quantum mechanics to a broad range of problems in spectroscopy and molecular structure New in this Edition: A new chapter on molecular orbital calculations (extended Hückel and self-consistent field) A significant number of additional figures and improvements to existing figures New exercises, plus answers for selected problems Now includes the photoelectric effect, the perturbation treatment of the helium atom, orbital symmetry and chemical reactions, and molecular term symbols Careful and extensive edits throughout the text improve clarity and correct minor errors
