Download or read book Oil in water Emulsion Technique Enhancement for Viscous Crude Oil Flow in Pipelines written by Muhammad Fawwaz Abdul Wahab and published by . This book was released on 2015 with total page 77 pages. Available in PDF, EPUB and Kindle. Book excerpt: The production of heavy crude oil is limited due to its high viscosity. It is expected to increase in the future as low viscosity crudes are depleted. The high viscosity lead to the increasing of pump energy as it creates high pressure drop. In order to reduce the viscosity of the heavy crude, it is suggested to mix it with water and optimum emulsifiers to create a lower viscous fluid, oil-in-water (O/W) emulsions. In this study, both chemical and physical properties of O/W emulsion that is prepared by using cocoamide DEA (non-ionic and biodegradable surfactant that synthesis from coconut oil) and two types of conventional chemical emulsifiers (Span 80 and Triton X-100) were investigated. O/W emulsions with three different ratios (50 - 50% and 65 - 35% and 80 - 20%) were prepared at a mixing speed of 2000 rpm with the concentrations of (1.0 wt%, 1.5 wt% and 2.0 wt%) of each emulsifier. These emulsions were tested for relative rates of water separation (stability test), viscosity, shear stress and shear rate at room temperature and stirring speed of Brookfield viscometer. While the droplet size was carried out by using Carl Zeiss Research Microscope and its software. Result shows that Span 80 at 1.0 wt% mixed at each ratio of 50 - 50%, 65 - 35% and 80 - 20% O/W with 2000 rpm mixing speed obtained the most stable emulsions for transportation compared to the other emulsifiers. Demulsification is the process of separation of water from crude oil. Crude oil needs to be separated efficiently and quickly from the water to allow further treatment. This is to ensure the crude oil value can be maximized and the operating cost can be minimized. Demulsifiers (Hexylamine, Cocamide MEA and Dioctylamine) with different concentrations (1.0 wt%, 1.5% and 2.0 wt%) were used for demulsification. The relative rates of water separation were characterized via beaker test.
Download or read book Enhancement of Flow in Pipeline Transportation for Crude Oil Emulsion written by Sue Ann Khoo and published by . This book was released on 2012 with total page 87 pages. Available in PDF, EPUB and Kindle. Book excerpt: This study presents the flow enhancement of crude oil in pipeline transportation using emulsion. High viscosity and low pour point of crude oil often hinder transportation from processing wells to the enhanced oil recovery reservoir. Therefore, a stable oil-in-water emulsion is desired, by comparing different types of surfactant. Demulsification process too is necessary to separate the oil in water. Emulsion was prepared using Span 80, Span 83, and Triton X-100 each respectively in a ratio of 70-30% o/w and 50-50% o/w. Parameters include varying mixing speed in emulsion preparation, temperature and rheological properties of the emulsion were studied by carrying out stability tests. Interfacial properties such as surface tension and interfacial tension of the emulsion were also measured. The effect of droplet diameter with surfactant concentration in the emulsion was also studied. The most stable emulsion was used for transportation in a 3meter pipeline. Rheological data on the emulsion was used to correlate to the laminar flow during transportation. Three demulsifiers: dioctylamine, cocoamine, hexylamine were used to compare for their effectiveness in demulsification. The study reveals that the stability of o/w emulsion increases when an anionic surfactant, Span 83, was used. By increasing the oil content, the speed and mixing temperature resulted in an increased emulsion stability, and a reduced droplet diameter. Dioctylamine proved to be the best demulsifier among cocoamine and hexylamine.
Download or read book Oil in water Emulsion Enhancement for Viscious Crude Oil Flow in Pipeline written by Liyana Nadhirah Mat Suli and published by . This book was released on 2014 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Optimized Heavy Oil in water Emulsions for Flow in Pipelines written by Nabijan Nizamidin and published by . This book was released on 2016 with total page 714 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oilfield operations such as drilling, reservoir management, and production require the injection and/or production of complex fluids to improve the extraction of crude oils. Some of these complex fluids such as drilling muds, fracking fluids, foams, emulsions, surfactants, and polymers, fall under the classification of colloidal suspensions which is one substance of microscopically dispersed insoluble particles suspended throughout another substance. These colloidal suspensions show complex rheological properties that are dependent on the suspension properties, flow conditions, and flow conduit dimensions. Rheology of colloidal suspensions is a complex subject that is still being investigated. The focus of this study is on heavy oil-in-water emulsions. Heavy oil and bitumen resources account for approximately 70% of the remaining oil discovered to date in the world. Heavy crude oils are costly to produce, transport, and refine compared to light crude oils due to the high viscosity of heavy crude oils. To improve the economic viability of producing heavy oils, especially in a time with low crude oil prices, operational expenses must be reduced. One of the main areas to improve is the cost associated with transporting produced heavy oils from production wells to refineries. Currently, heavy oils are diluted with low viscosity diluents such as condensates and light crude oils to lower the mixture viscosity below 350 cSt before heavy oils can be transported through pipelines. The diluted mixtures require up to 50% (vol.) diluents to lower the heavy oil viscosity. High demand and low supply of condensates and constrained pipeline capacities have resulted in pipeline transportation costs of up to $22/bbl of diluted heavy oil from Canada to refineries in the U.S. An alternative method of transporting heavy oils is to transport heavy oils in an emulsified form, heavy oil-in-water emulsions, which can show orders of magnitude lower viscosities compared to the viscosity of heavy oils. In this study, a simple, one-step method of preparing heavy oil-in-water emulsions was developed. The physical properties of heavy oil-in-water emulsions are controlled and modified by optimizing the chemical formulation used to prepare emulsions. Stable heavy oil-in-water emulsions can be prepared with chemical formulations that are tailored to the type of heavy oils and available water sources which can range from freshwater to softened seawater. The rheology of heavy oil-in-water emulsions has been characterized with a rotational viscometer. Heavy oil-in-water emulsions, especially concentrated emulsions, showed complex rheological properties such as shear thinning behavior, two-step yield stresses, two-step wall slips, and rheopexy. A rheological equation and a wall slip equation have been developed to model the rheology of heavy oil-in-water emulsions over a range of shear rates and flow conduit dimensions. Heavy oil-in-water emulsions characterized with capillary tube viscometers showed drastically different viscosity measurements compared to the viscosity measurements obtained with a rotational viscometer. This is important because the flow of emulsions in pipelines are similar to the flow of emulsions in capillary tube viscometers, not rotational viscometers. The lower viscosities measured with capillary tube viscometers are attributed to oil droplet migration away from the tube walls due to the shear heterogeneity observed in Poiseuille (tube) flow. A scaling equation was proposed to relate the viscosity measurements of emulsions with a rotation viscometer to the viscosity measurements of emulsions with capillary tube viscometers. The rheological measurements of heavy oil-in-water emulsions are used to estimate the flow of emulsions in crude oil pipelines with various radii. Viscosity measurements of optimized heavy oil-in-water emulsions with a rotational viscometer showed that heavy oil-in-water emulsions with up to 75% dispersed heavy oil can be successfully transported in crude oil pipelines. Adding the effect of oil droplet migration measured with capillary tube viscometers, heavy oil-in-water emulsions with up to 85-90% dispersed heavy oil can be successfully transported in crude oil pipelines. The cost of chemicals used to prepare 85% heavy oil-in-water emulsion is approximately $1-3/bbl of emulsion. Heavy oil-in-water emulsions also showed drag reduction properties which can significantly increase the maximum flow capacity of crude oil pipelines. Transporting heavy oils as concentrated heavy oil-in-water emulsions appeared to be a competitive if not a better method of lowering heavy oil viscosity compared to the diluent method in terms of cost and flow performance in pipelines.
Download or read book Pipe line Transportation of Heavy Oil in water Emulsion written by Vickneswaran Nagaratnam and published by . This book was released on 2010 with total page 53 pages. Available in PDF, EPUB and Kindle. Book excerpt: The diverse factors affecting the viscosity of a viscous crude oil-in-water emulsion for pipeline transportation were studied. The factors that are taken into account is effect of oil content, type and concentration of the surfactant, and speed of mixing, Agent in water method is used in the preparation of oil in water emulsions. The oil content ratio used in this study is 50-50, 70-30, and 90-10 by volume. Different surfactants, namely Triton X-100, Span 80 and Tween 80 are used to determine the best surfactant to emulsify heavy oil. The speed of mixing used in this study is 1000rpm, 1500rpm and 2000rpm. This study is conducted in room temperature. Amine functional group demulsifier are used to study the destabilization of heavy oil in water emulsions. The demulsifier used in this study is hexylamine and dioctylamine. The viscosity of the oil in water emulsion was found to decrease as the oil content of the emulsion decreased, and the speed of mixing decreased. The stability of the crude oil-in-water emulsions increases as the oil content of the emulsions increases, the surfactant concentration increases, and the speed of mixing increases. Hexylamine remove more water over time in the destabilization process. Hence, hexylamine is a better demulsifier than dioctlamine. From this research it can be concluded that oil in water emulsion method can reduce the viscosity of heavy crude oil greatly.
Download or read book Pipeline Transportation for Heavy Crude Oil Via Oil in Water Emulsions written by Abdurahman Nour and published by LAP Lambert Academic Publishing. This book was released on 2011 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: With the combination of an increase in world energy demand and the decline of conventional oils, heavy crude oils have been presented as a relevant hydrocarbons resource for use in the future. Hydrocarbon resources are very important given that they account for approximately 65% of the world's overall energy resources. Currently, there are three general approaches for transportation of heavy and extra heavy oil: viscosity reduction, drag minimization and in-situ oil upgrading. This book introduces Another promising pipeline technique is the transport of viscous crudes as concentrated oil-in-water (O/W) emulsions.
Download or read book Processing of Heavy Crude Oils written by Ramasamy Marappa Gounder and published by . This book was released on 2019-12-18 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Flow Enhancement in Pipeline Transportation for Heavy Crude Oil Emulsion written by Nurul Hafiza Norden and published by . This book was released on 2014 with total page 76 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Practices and Methods of Preventing and Treating Crude oil Emulsions written by Gerald Bernard Shea and published by . This book was released on 1939 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Pipelines written by M. Rafiqul Islam and published by Gulf Professional Publishing. This book was released on 2023-07-03 with total page 929 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pipelines: Emerging Technologies and Design Criteria, the latest release in the Sustainable Oil and Gas Development series, delivers the tools needed to understand more environmentally-friendly design, construction and maintenance of oil and gas pipelines. Designed to introduce ideal solutions and current state-of-the-art practices, the reference includes guidelines on environmental impact assessment and sustainable route design as well as the sustainability of additives and power systems. Material selection, real-time processing of smart well data and remote sensing are also discussed. Rounded out with inspection tools and emerging technology such as novel corrosion protection, this book gives pipeline engineers a guide on safer alternatives and upcoming guidelines in the race to reduce emissions. - Provides insights to more environmentally-friendly protocols for material selection, construction and integrity - Helps readers determine more accurate protection plans and learn the latest techniques, including nanotechnology and sustainable hydrate and wax mitigation - Presents valuable insights from a well-known author with extensive experience in both academia and industry
Download or read book The Formation of Oil field Emulsions written by D. B. Dow and published by . This book was released on 1925 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Petroleum Engineering Handbook written by Larry W. Lake and published by . This book was released on 2006 with total page 930 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Petroleum Engineering Handbook has long been recognized as a valuable comprehensive reference book that offers practical day-to-day applications for students and experienced engineering professionals alike. Available now in 7 Volumes, Volume 1 covers General Engineering topics including chapters on mathematics, fluid properties (fluid sampling techniques; properties and correlations of oil, gas, condensate, and water; hydrocarbon phase behavior and phase diagrams for hydrocarbon systems; the phase behavior of water/hydrocarbon systems; and the properties of waxes, asphaltenes, and crude oil emulsions), rock properties (bulk rock properties, permeability, relative permeability, and capillary pressure), the economic and regulatory environment, and the role of fossil energy in the 21st century energy mix.
Download or read book Pipeline Flow Behavior of Water in oil Emulsions written by Ali Omer Abulkasim Omer and published by . This book was released on 2009 with total page 169 pages. Available in PDF, EPUB and Kindle. Book excerpt: Water-in-oil (W/O) emulsions consist of water droplets dispersed in continuous oil phase. They are encountered at various stages of oil production. The oil produced from an oil-well usually carries a significant amount of water in the form of droplets. In enhanced oil recovery techniques involving the injection of polymer solution, the aqueous phase of the water-in-oil emulsions produced from the oil well consists of polymeric additive. A good understanding of the flow behavior of emulsions in pipelines is essential for the design and operation of oil production-gathering facilities and emulsion pipelines. A number of studies have been reported on simultaneous flow of oil and water in pipelines. However, the studies reported in the literature are mainly focused on either oil-water flow patterns and separated flows (annular and stratified flow of oil and water phases) or oil-in-water (O/W) emulsion flows. The pipeline flow of water-in-oil (W/O) emulsions has received less attention. Also, little work has been carried out on the effect of additives such as polymer. In this study, new experimental results are presented on the pipeline flow behavior of water-in-oil (W/O) emulsions, with and without the presence of polymeric additive in the aqueous phase. The emulsions were prepared from three different oils, namely EDM-244, EDM-Monarch, and Shell Pella of different viscosities (2.5 mPa.s for EDM-244, 6 mPa.s for EDM-Monarch, and 5.4 mPa.s for Shell Pella, at 25 0C). The water-in-oil emulsions prepared from EDM-244 and EDM-Monarch (without any polymeric additive in the dispersed aqueous phase) exhibited drag reduction behavior in turbulent flow. The turbulent friction factor data of the emulsions fell well below the standard Blasius equation for smooth pipes. The water-in-oil emulsions prepared from EDM-244 exhibited stronger drag reduction as compared with the EDM-Monarch emulsions. The Shell Pella emulsions (w/o type) did not exhibit any drag reduction in turbulent flow; the friction factor data followed the Blasius equation. The Shell Pella emulsions were more stable than the EDM-244 and EDM-Monarch emulsions. When left unstirred, the EDM-244 and EDM-Monarch emulsions quickly coalesced into separate oil and water phases whereas the Shell Pella emulsions took significantly longer time to separate into oil and water phases. The Shell Pella oil emulsions were also milkier than the EDM emulsions. The addition of polymer to the dispersed aqueous phase of water-in-oil emulsions had a significant effect on the turbulent drag reduction behavior. Emulsions were less drag reducing when polymer was present in the aqueous droplets. The effect of surfactant on the pipeline flow behavior of water/oil emulsions was also investigated. The surfactant-stabilized water-in-oil emulsions followed the single phase flow behavior. The presence of surfactant in the emulsions caused the dispersed droplets to become significantly smaller. It is believed that the droplets were smaller than the scale of turbulence when surfactant was present and consequently no drag reduction was observed.
Download or read book Encyclopedic Handbook of Emulsion Technology written by Johan Sjoblom and published by CRC Press. This book was released on 2001-03-16 with total page 766 pages. Available in PDF, EPUB and Kindle. Book excerpt: A discussion of fundamental characteristics, theories and applications for liquid-liquid colloidal dispersions. It profiles experimental and traditional measurement techniques in a variety of emulsified systems, including rheology, nuclear magnetic resonance, dielectric spectroscopy, microcalorimetry, video enhanced microscopy, and conductivity.
Download or read book Polymer Flooding written by W. Littmann and published by Elsevier. This book was released on 1988-09-01 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers all aspects of polymer flooding, an enhanced oil recovery method using water soluble polymers to increase the viscosity of flood water, for the displacement of crude oil from porous reservoir rocks. Although this method is becoming increasingly important, there is very little literature available for the engineer wishing to embark on such a project. In the past, polymer flooding was mainly the subject of research. The results of this research are spread over a vast number of single publications, making it difficult for someone who has not kept up-to-date with developments during the last 10 to 15 years to judge the suitability of polymer flooding to a particular field case. This book tries to fill that gap. The basic mechanisms of the process are described and criteria given where it may be employed. Basic elements of the chemistry of EOR-polymers are provided. The fundamentals of polymer physics, such as rheology, flow in porous media and adsorption, are derived. Practical hints on mixing and testing of polymers in the laboratory are given, as well as instructions for their application in the oil field. Polymer flooding is illustrated by some case histories and the economics of the methods are examined. For the essential subjects, example calculations are added. An indispensable book for reservoir engineers, production engineers and laboratory technicians within the petroleum industry.
Download or read book Pipeline Transportation of Heavy Crude Oil in water Emulsion written by Liyana Nadirah Mat Suli and published by . This book was released on 2010 with total page 79 pages. Available in PDF, EPUB and Kindle. Book excerpt: The increasing world energy demand, heavy crude oils represent a significant energy supply that will play an important role. However these petroleum products are known to present technical challengers in all phase operation which is reservoir, transportation, and refining. The crude oil has high viscosity that would be challenge and difficult to transport via pipeline. This researched focus on two parts, first factors that effect stability of crude oil in water during transportation part. Second part is breaking oil in water emulsions. These investigations used 4 different types of surfactant to study stability part, and two types of demulsifiers for breaking the emulsion. The result showed increasing of oil content, the speed and temperature mixing of the emulsion resulted in increased emulsion stability. Span 80 is the most stable emulsifier for emulsion stability compared to the other surfactant. The graph plot between shear rate and shear stress shows the behavior of the crude oil. Demulsification of the stable crude oil in water emulsion was achieved by using hexylamine with 2% concentration which is the best demusifier.
Download or read book Characterization Demulsification and Transportation of Heavy Crude Oil written by Abdurahman H. Nour and published by LAP Lambert Academic Publishing. This book was released on 2012-02 with total page 168 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stable concentrated oil-in-water (O/W) emulsions were prepared and their application for heavy oil pipeline transportation was investigated using very viscous Malaysian heavy crude oil. Two Malaysian heavy crude oil samples, Tapis and a blend of Tapis and Masilla, were used to produce heavy crude oil-in-water emulsions. The diverse factors affecting the properties and stability of emulsions were investigated. There was a restricted limit of 68 vol. % and 72 vol. % for crude oil content in the emulsions, and beyond that limit, the emulsion underwent phase inversion. The study revealed that the stability of the oil-in-water emulsion stabilized by Triton X-100 increases as the surfactant concentration increases, with a subsequent decrease in the crude oil-water interfacial tension (IFT). Increasing the oil content, the speed and duration of mixing, the salt concentration and the pH of the aqueous phase of the emulsion; resulted in increased emulsion stability, while increases in the temperature of the homogenization process substantially reduced the viscosity of the prepared emulsions.
