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Book Non equilibrium Thermodynamics Of Heterogeneous Systems

Download or read book Non equilibrium Thermodynamics Of Heterogeneous Systems written by Signe Kjelstrup and published by World Scientific. This book was released on 2008-02-22 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.

Book Non equilibrium Thermodynamics Of Heterogeneous Systems  Second Edition

Download or read book Non equilibrium Thermodynamics Of Heterogeneous Systems Second Edition written by Signe Kjelstrup and published by World Scientific. This book was released on 2020-08-27 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book utilizes non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. There are large coupling effects between transport of heat, mass, charge and chemical reactions at surfaces, and it is important to know how one should properly integrate across systems where different phases are in contact. There is no other book available today that gives a prescription of how to set up flux equations for transports across heterogeneous systems.

Book Nonequilibrium Thermodynamics

Download or read book Nonequilibrium Thermodynamics written by Yasar Demirel and published by Newnes. This book was released on 2013-12-16 with total page 787 pages. Available in PDF, EPUB and Kindle. Book excerpt: Natural phenomena consist of simultaneously occurring transport processes and chemical reactions. These processes may interact with each other and may lead to self-organized structures, fluctuations, instabilities, and evolutionary systems. Nonequilibrium Thermodynamics, Third Edition emphasizes the unifying role of thermodynamics in analyzing the natural phenomena. This third edition updates and expands on the first and second editions by focusing on the general balance equations for coupled processes of physical, chemical, and biological systems. The new edition contains a new chapter on stochastic approaches to include the statistical thermodynamics, mesoscopic nonequilibrium thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems in thermodynamic analysis. This new addition also comes with more examples and practice problems. - Informs and updates on all the latest developments in the field - Contributions from leading authorities and industry experts - A useful text for seniors and graduate students from diverse engineering and science programs to analyze some nonequilibrium, coupled, evolutionary, stochastic, and dissipative processes - Highlights fundamentals of equilibrium thermodynamics, transport processes and chemical reactions - Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical, and biological systems - Presents a unified analysis for transport and rate processes in various time and space scales - Discusses stochastic approaches in thermodynamic analysis including fluctuation and information theories - Has 198 fully solved examples and 287 practice problems - An Instructor Resource containing the Solution Manual can be obtained from the author: [email protected]

Book Understanding Non equilibrium Thermodynamics

Download or read book Understanding Non equilibrium Thermodynamics written by Georgy Lebon and published by Springer Science & Business Media. This book was released on 2008-01-12 with total page 331 pages. Available in PDF, EPUB and Kindle. Book excerpt: Discover the many facets of non-equilibrium thermodynamics. The first part of this book describes the current thermodynamic formalism recognized as the classical theory. The second part focuses on different approaches. Throughout the presentation, the emphasis is on problem-solving applications. To help build your understanding, some problems have been analyzed using several formalisms to underscore their differences and their similarities.

Book Non Equilibrium Thermodynamics

Download or read book Non Equilibrium Thermodynamics written by S. R. De Groot and published by Courier Corporation. This book was released on 2013-01-23 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.

Book Nonequilibrium Thermodynamics

Download or read book Nonequilibrium Thermodynamics written by Yasar Demirel and published by Elsevier. This book was released on 2018-11-24 with total page 882 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nonequilibrium Thermodynamics: Transport and Rate Processes in Physical, Chemical and Biological Systems, Fourth Edition emphasizes the unifying role of thermodynamics in analyzing natural phenomena. This updated edition expands on the third edition by focusing on the general balance equations for coupled processes of physical, chemical and biological systems. Updates include stochastic approaches, self-organization criticality, ecosystems, mesoscopic thermodynamics, constructual law, quantum thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems. The book also emphasizes nonequilibrium thermodynamics tools, such as fluctuation theories, mesoscopic thermodynamic analysis, information theories, and quantum thermodynamics in describing and designing small scale systems. - Provides a useful text for seniors and graduate students from diverse engineering and science programs - Highlights the fundamentals of equilibrium thermodynamics, transport processes and chemical reactions - Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical and biological systems - Presents a unified analysis for transport and rate processes in various time and space scales - Discusses stochastic approaches in thermodynamic analysis, including fluctuation and information theories, mesoscopic nonequilibrium thermodynamics, constructal law and quantum thermodynamics

Book Experimental Thermodynamics Volume X

Download or read book Experimental Thermodynamics Volume X written by Dick Bedeaux and published by Royal Society of Chemistry. This book was released on 2016 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering recent developments in the theory of non-equilibrium thermodynamics and its applications, this title is aimed at a predominantly, but not exclusively, academic audience of practitioners of thermodynamics and energy conversion.

Book Non equilibrium Thermodynamics and Statistical Mechanics

Download or read book Non equilibrium Thermodynamics and Statistical Mechanics written by Phil Attard and published by OUP Oxford. This book was released on 2012-10-04 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: `Non-equilibrium Thermodynamics and Statistical Mechanics: Foundations and Applications' builds from basic principles to advanced techniques, and covers the major phenomena, methods, and results of time-dependent systems. It is a pedagogic introduction, a comprehensive reference manual, and an original research monograph. Uniquely, the book treats time-dependent systems by close analogy with their static counterparts, with most of the familiar results of equilibrium thermodynamics and statistical mechanics being generalized and applied to the non-equilibrium case. The book is notable for its unified treatment of thermodynamics, hydrodynamics, stochastic processes, and statistical mechanics, for its self-contained, coherent derivation of a variety of non-equilibrium theorems, and for its quantitative tests against experimental measurements and computer simulations. Systems that evolve in time are more common than static systems, and yet until recently they lacked any over-arching theory. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is unique in its unified presentation of the theory of non-equilibrium systems, which has now reached the stage of quantitative experimental and computational verification. The novel perspective and deep understanding that this book brings offers the opportunity for new direction and growth in the study of time-dependent phenomena. 'Non-equilibrium Thermodynamics and Statistical Mechanics' is an invaluable reference manual for experts already working in the field. Research scientists from different disciplines will find the overview of time-dependent systems stimulating and thought-provoking. Lecturers in physics and chemistry will be excited by many fresh ideas and topics, insightful explanations, and new approaches. Graduate students will benefit from its lucid reasoning and its coherent approach, as well as from the chem12physof mathematical techniques, derivations, and computer algorithms.

Book Beyond the Second Law

Download or read book Beyond the Second Law written by Roderick C. Dewar and published by Springer. This book was released on 2013-12-02 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Second Law, a cornerstone of thermodynamics, governs the average direction of dissipative, non-equilibrium processes. But it says nothing about their actual rates or the probability of fluctuations about the average. This interdisciplinary book, written and peer-reviewed by international experts, presents recent advances in the search for new non-equilibrium principles beyond the Second Law, and their applications to a wide range of systems across physics, chemistry and biology. Beyond The Second Law brings together traditionally isolated areas of non-equilibrium research and highlights potentially fruitful connections between them, with entropy production playing the unifying role. Key theoretical concepts include the Maximum Entropy Production principle, the Fluctuation Theorem, and the Maximum Entropy method of statistical inference. Applications of these principles are illustrated in such diverse fields as climatology, cosmology, crystal growth morphology, Earth system science, environmental physics, evolutionary biology and technology, fluid turbulence, microbial biogeochemistry, plasma physics, and radiative transport, using a wide variety of analytical and experimental techniques. Beyond The Second Law will appeal to students and researchers wishing to gain an understanding of entropy production and its central place in the science of non-equilibrium systems – both in detail and in terms of the bigger picture.

Book Non equilibrium Thermodynamics For Engineers  Second Edition

Download or read book Non equilibrium Thermodynamics For Engineers Second Edition written by Signe Kjelstrup and published by World Scientific Publishing Company. This book was released on 2017-02-15 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kjelstrup, Bedeaux, Johannessen, and Gross describe what non-equilibrium thermodynamics is in a simple and practical way and how it can add to engineering design. They explain how to describe proper equations of transport that are more precise than those used so far, and how to use them to understand the waste of energy resources in central process units in the industry. The authors introduce the entropy balance as an additional equation to use in engineering; to create consistent thermodynamic models, and to systematically minimize energy losses that are connected with the transport of heat, mass, charge and momentum.Non-equilibrium Thermodynamics for Engineers teaches the essence of non-equilibrium thermodynamics and its applications at a level comprehensible to engineering students, practitioner engineers, and scientists working on industrial problems. The book may be used as a textbook in basic engineering curricula or graduate courses.

Book Non equilibrium thermodynamics and physical kinetics

Download or read book Non equilibrium thermodynamics and physical kinetics written by Halid Bikkin and published by Walter de Gruyter GmbH & Co KG. This book was released on 2014-08-22 with total page 425 pages. Available in PDF, EPUB and Kindle. Book excerpt: This graduate textbook covers contemporary directions of non-equilibrium statistical mechanics as well as classical methods of kinetics. Starting from phenomenological non-equilibrium thermodynamics, the kinetic equation method discussed and demonstrated with electrons and phonons in conducting crystals. Linear response theory as well as the non-equilibrium statistical operator and the master equation approach are discussed in the course of the book. With one of the main propositions being to avoid terms such as "obviously" and "it is easy to show", this treatise is an easy-to-read introduction into this traditional, yet vibrant field. Problems and their well-documented solutions included at appropriate points of the narrative allow the reader to actively develop essential parts of the theory himself. From the content: Phenomenological thermodynamics of irreversible processes Brownian motion Kinetic equations in non-equilibrium thermodynamics Kinetic equation for electrons and phonons in conducting crystals Theory of non-linear response to an external mechanical pertubation Non-equilibrium statistical operator method Response of a highly non-equilibrium system to a weakly measuring field Master equation approach

Book Nonequilibrium Thermodynamics

Download or read book Nonequilibrium Thermodynamics written by Yasar Demirel and published by Elsevier. This book was released on 2002-11-22 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book begins with a brief review of equilibrium systems and transport and rate processes, then covers the following areas: theory of nonequilibrium thermodynamics; dissipation function; entropy and exergy; analysis and case studies on using the second law of thermodynamics; economic impact of the nonequilibrium thermodynamics theory; analysis of transport and rate processes; membrane transport; dissipative structures and biological systems; and other thermodynamic approaches and extended nonequilibrium thermodynamics. Summarizes new applications of thermodynamics as tools for design and optimisation Covers second law and exergy analysis for sustainable development Promotes understanding of the coupled phenomena of natural processes

Book Non equilibrium Thermodynamics of Heterogeneous Systems

Download or read book Non equilibrium Thermodynamics of Heterogeneous Systems written by Signe Kjelstrup and published by World Scientific. This book was released on 2008 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.

Book Aspects of Non equilibrium Thermodynamics

Download or read book Aspects of Non equilibrium Thermodynamics written by Wolfgang Muschik and published by World Scientific. This book was released on 1990 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: In six lectures aspects of modern non-equilibrium thermodynamics of discrete systems as well as continuum theoretical concepts are represented. Starting out with survey and introduction, state spaces are defined, the existence of internal energy is investigated, and Clausius inequality including negative absolute temperature is derived by diagram technique. Non-equilibrium contact quantities, such as contact temperature ? the dynamic analogue of thermostatic temperature ? and chemical potentials are phenomenologically defined and quantumstatistically founded. Using Clausius inequality the existence of non-negative entropy production is proved which allows to formulate a dissipation inequality in continuum thermodynamics. The transition between thermodynamics of discrete systems and continuum thermodynamics with respect to contact quantities is considered. Different possibilities of exploiting the dissipation inequality for getting constraints for constitutive equations are discussed. Finally hyperbolic heat conduction in non-extended thermodynamics is treated.

Book Extended Irreversible Thermodynamics

Download or read book Extended Irreversible Thermodynamics written by David Jou and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Classical irreversible thermodynamics, as developed by Onsager, Prigogine and many other authors, is based on the local-equilibrium hypothesis. Out of equilibrium, any system is assumed to depend locally on the same set of variables as when it is in eqUilibrium. This leads to a formal thermody namic structure identical to that of eqUilibrium: intensive parameters such as temperature, pressure and chemical potentials are well-defined quantities keeping their usual meaning, thermodynamic potentials are derived as Leg endre transformations and all equilibrium thermodynamic relations retain their validity. The theory based on this hypothesis has turned out to be very useful and has achieved a number of successes in many practical situations. of interest in going However, the recent decade has witnessed a surge beyond the classical formulation. There are several reasons for this. One of them is the development of experimental methods able to deal with the response of systems to high-frequency and short-wavelength perturbations, such as ultrasound propagation and light and neutron scattering. The ob served results have led to generalizations of the classical hydrodynamical theories, by including memory functions or generalized transport coefficients depending on the frequency and the wavevector. This field has generated impressive progress in non-equilibrium statistical mechanics, but for the moment it has not brought about a parallel development in non-equilibrium thermodynamics. An extension of thermodynamics compatible with gener alized hydrodynamics therefore appears to be a natural subject of research.

Book Non equilibrium Thermodynamics For Engineering Applications

Download or read book Non equilibrium Thermodynamics For Engineering Applications written by Signe Kjelstrup and published by World Scientific. This book was released on 2024-07-23 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the theory of non-equilibrium thermodynamics in a pedagogical and practical way that targets engineering applications. In it, tools to take advantage of the second as well as the first law of thermodynamics are provided.The book starts by explaining how the entropy production is the cornerstone of non-equilibrium thermodynamics — the basis to describe coupled transport phenomena, which are highly relevant for several renewable energy technologies. The book also uses entropy production as the foundation for a systematic methodology to analyze and improve energy efficiency, and shows how entropy production can be used to test the consistency of transport models. The link between transport theory and energy efficiency is also shown, and the relationship to exergy analysis is demonstrated. The theory is applied using examples from practical cases like evaporation, heat exchange, reactor optimization, distillation and more.Non-Equilibrium Thermodynamics for Engineering Applications may be used as a textbook for undergraduate and graduate university curricula containing thermodynamics or energy conversion issues at large, chemical and mechanical engineering, applied chemistry and applied physics.

Book Nonequilibrium Statistical Thermodynamics

Download or read book Nonequilibrium Statistical Thermodynamics written by Bernard H. Lavenda and published by Courier Dover Publications. This book was released on 2019-04-17 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book develops in detail the statistical foundations of nonequilibrium thermodynamics, based on the mathematical theory of Brownian motion. Author Bernard H. Lavenda demonstrates that thermodynamic criteria emerge in the limit of small thermal fluctuations and in the Gaussian limit where means and modes of the distribution coincide. His treatment assumes the theory of Brownian motion to be a general and practical model of irreversible processes that are inevitably influenced by random thermal fluctuations. This unifying approach permits the extraction of widely applicable principles from the analysis of specific models. Arranged by argument rather than theory, the text is based on the premises that random thermal fluctuations play a decisive role in governing the evolution of nonequilibrium thermodynamic processes and that they can be viewed as a dynamic superposition of many random events. Intended for nonmathematicians working in the areas of nonequilibrium thermodynamics and statistical mechanics, this book will also be of interest to chemical physicists, condensed matter physicists, and readers in the area of nonlinear optics.