Download or read book The Nitrate Radical written by Richard P. Wayne and published by . This book was released on 1991 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Processes in Atmospheric Oxidation written by Georges Le Bras and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation and removal of atmospheric constituents involve complex sequences of reactions which can lead to the production of photo-oxidants such as ozone. In order to understand and model these complex reaction sequences, it is necessary to have a comprehensive understanding of reaction mechanisms and accurate estimates of kinetic parameters for relevant gas-phase atmospheric reactions. This book presents recent advances in the field and includes the following topics: e.g. the oxidation of simple organic compounds, NOx kinetics and mechanisms, OH radical production and rate constants for the OH attack on more complex organic compounds, peroxy and alkoxy radical reactions, photo-oxidation of aromatic and biogenic compounds, and the interaction between radical species.
Download or read book The Chemistry of Nitrate Radical NO3 and Dinitrogen Pentoxide N2O5 in Beijing written by Haichao Wang and published by Springer Nature. This book was released on 2020-10-31 with total page 129 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book systematically describes the instrument setup for the measurement of nitrate radical (NO3) and dinitrogen pentoxide (N2O5), as well as the mixing ratio, chemical behaviors, and atmospheric impacts of NO3 and N2O5 in Beijing, China. It also discusses the instrument design and data analysis method in detail. Based on several field measurements of NO3 and N2O5 in Beijing, it shows the variation in concentration and the budget of NO3 and N2O5. The N2O5 heterogeneous uptake coefficient was determined using various methods, and the relationship between the N2O5 uptake coefficient and the particle properties was demonstrated, as well as the impact of NO3–N2O5 chemistry to the atmospheric oxidation and the formation of particulate nitrate. These results increase our understanding of nighttime chemistry and provide insights into the role of NO3–N2O5 chemistry in other polluted regions.
Download or read book Nitrate Radical Atmospheric Reactions written by Edward J. Dlugokencky and published by . This book was released on 1987 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Mechanisms of Reactions Influencing Atmospheric Ozone written by Jack George Calvert and published by . This book was released on 2015 with total page 609 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ozone, an important trace component, is critical to life on Earth and to atmospheric chemistry. The presence of ozone profoundly impacts the physical structure of the atmosphere and meteorology. Ozone is also an important photolytic source for HO radicals, the driving force for most of the chemistry that occurs in the lower atmosphere, is essential to shielding biota, and is the only molecule in the atmosphere that provides protection from UV radiation in the 250-300 nm region. However, recent concerns regarding environmental issues have inspired a need for a greater understanding of ozone, and the effects that it has on the Earth's atmosphere. The Mechanisms of Reactions Influencing Atmospheric Ozone provides an overview of the chemical processes associated with the formation and loss of ozone in the atmosphere, meeting the need for a greater body of knowledge regarding atmospheric chemistry. Renowned atmospheric researcher Jack Calvert and his coauthors discuss the various chemical and physical properties of the earth's atmosphere, the ways in which ozone is formed and destroyed, and the mechanisms of various ozone chemical reactions in the different spheres of the atmosphere. The volume is rich with valuable knowledge and useful descriptions, and will appeal to environmental scientists and engineers alike. A thorough analysis of the processes related to tropospheric ozone, The Mechanisms of Reactions Influencing Atmospheric Ozone is an essential resource for those hoping to combat the continuing and future environmental problems, particularly issues that require a deeper understanding of atmospheric chemistry.
Download or read book The Nitrate Radical Physics Chemistry and the Atmosphere written by and published by . This book was released on 1991 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Volatile Organic Compounds in the Atmosphere written by Ralf Koppmann and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: Every day, large quantities of volatile organic compounds (VOCs) are emitted into the atmosphere from both anthropogenic and natural sources. The formation of gaseous and particulate secondary products caused by oxidation of VOCs is one of the largest unknowns in the quantitative prediction of the earth’s climate on a regional and global scale, and on the understanding of local air quality. To be able to model and control their impact, it is essential to understand the sources of VOCs, their distribution in the atmosphere and the chemical transformations which remove these compounds from the atmosphere. In recent years techniques for the analysis of organic compounds in the atmosphere have been developed to increase the spectrum of detectable compounds and their detection limits. New methods have been introduced to increase the time resolution of those measurements and to resolve more complex mixtures of organic compounds. Volatile Organic Compounds in the Atmosphere describes the current state of knowledge of the chemistry of VOCs as well as the methods and techniques to analyse gaseous and particulate organic compounds in the atmosphere. The aim is to provide an authoritative review to address the needs of both graduate students and active researchers in the field of atmospheric chemistry research.
Download or read book Introduction to Atmospheric Chemistry written by Daniel J. Jacob and published by Princeton University Press. This book was released on 1999 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric chemistry is one of the fastest growing fields in the earth sciences. Until now, however, there has been no book designed to help students capture the essence of the subject in a brief course of study. Daniel Jacob, a leading researcher and teacher in the field, addresses that problem by presenting the first textbook on atmospheric chemistry for a one-semester course. Based on the approach he developed in his class at Harvard, Jacob introduces students in clear and concise chapters to the fundamentals as well as the latest ideas and findings in the field. Jacob's aim is to show students how to use basic principles of physics and chemistry to describe a complex system such as the atmosphere. He also seeks to give students an overview of the current state of research and the work that led to this point. Jacob begins with atmospheric structure, design of simple models, atmospheric transport, and the continuity equation, and continues with geochemical cycles, the greenhouse effect, aerosols, stratospheric ozone, the oxidizing power of the atmosphere, smog, and acid rain. Each chapter concludes with a problem set based on recent scientific literature. This is a novel approach to problem-set writing, and one that successfully introduces students to the prevailing issues. This is a major contribution to a growing area of study and will be welcomed enthusiastically by students and teachers alike.
Download or read book Atmospheric Chemistry written by Barbara J. Finlayson-Pitts and published by Wiley-Interscience. This book was released on 1986 with total page 1164 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides comprehensive coverage of the new and emerging discipline of atmospheric chemistry. Starting with the fundamentals of kinetics and photochemistry, it shows how the experimental techniques in these areas are applied to the study and control of chemical reactions in the troposphere. Gives detailed analysis of such major societal issues as smog, acid rain and volatile toxic organics, and treats the seven criteria pollutants considered by the U.S. Environmental Protection Agency to be hazardous, as well as a variety of trace non-criteria pollutants, such as those cited in the Clean Air Act of 1977. Also included is a comprehensive bibliography and over 340 illustrations.
Download or read book Atmospheric Degradation of Organic Substances written by Walter Klöpffer and published by John Wiley & Sons. This book was released on 2008-01-08 with total page 258 pages. Available in PDF, EPUB and Kindle. Book excerpt: This compilation on the degradation of 1,100 commercially important chemical products is the first publication to make this knowledge publicly accessible in one book. The data and annotations have been painstakingly assembled over a 10-year period in a collaboration between academia and regulatory authorities. The work explains in detail the methods, including computational ones, for the environmental assessment of volatile and semi-volatile substances, and is rounded off with data tables of degradation rates. A key resource for manufacturers and regulators of such substances.
Download or read book Laboratory Studies of Reactions of Nitrate Radicals with Species of Atmospheric Importance written by Mark Flugge and published by . This book was released on 2004 with total page 758 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Modeling of Atmospheric Chemistry written by Guy P. Brasseur and published by Cambridge University Press. This book was released on 2017-06-19 with total page 631 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mathematical modeling of atmospheric composition is a formidable scientific and computational challenge. This comprehensive presentation of the modeling methods used in atmospheric chemistry focuses on both theory and practice, from the fundamental principles behind models, through to their applications in interpreting observations. An encyclopaedic coverage of methods used in atmospheric modeling, including their advantages and disadvantages, makes this a one-stop resource with a large scope. Particular emphasis is given to the mathematical formulation of chemical, radiative, and aerosol processes; advection and turbulent transport; emission and deposition processes; as well as major chapters on model evaluation and inverse modeling. The modeling of atmospheric chemistry is an intrinsically interdisciplinary endeavour, bringing together meteorology, radiative transfer, physical chemistry and biogeochemistry, making the book of value to a broad readership. Introductory chapters and a review of the relevant mathematics make this book instantly accessible to graduate students and researchers in the atmospheric sciences.
Download or read book Progress and Problems in Atmospheric Chemistry written by John Roger Barker and published by World Scientific. This book was released on 1995 with total page 960 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric chemistry is central to understanding global changes ? ozone depletion, appearance of the polar ozone holes, and compositional changes which worsen the greenhouse effect. Because of its importance, work is progressing on many fronts.This volume emphasizes the troposhere and stratosphere and has chapters on gas phase, condensed phase, and heterogeneous chemistry. Present progress is emphasized, and important future directions are also described.This book fills a need not satisfied by any others and will be popular for some years to come. It informs students and newcomers to the field of the many facets of atmospheric chemistry and can be used as a text for advanced students. It is also a valuable desk reference summarizing activities by quite a number of the most active research groups.Chapter 18 by Kolb et al. on heterogeneous chemistry is especially noteworthy because it represents a unique joint effort by several groups working on a very timely subject; they describe a conceptual framework and establish conventions which will be standard in future papers on this subject.
Download or read book The Role of Air Sea Exchange in Geochemical Cycling written by Patrick Buat-Ménard and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 555 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book arises from a NATO-sponsored Advanced Study Institute on 'The Role of Air-Sea Exchange in Geochemical Cycling' held at Bombann@§. near Bordeaux, France. from 16 to 27 September 1985. The chapters of the book are the written versions of the lectures given at the Institute. The aim of the book is to give a comprehensive up-to-date coverage of the subject. presented in a teaching mode. The chapters contain much recent research material and attempt to give the reader an understanding of how the role of air-sea exchange in geochemical cycling can be quantitatively assessed. In the last decade, major advances in the fields of marine and atmospheric chemistry have underlined the role of physical, chemical and biological processes at and near the air-sea interface in a number of geochemical cycles (C. S, N, metals etc ... ). Further, there is strong concern over the anthropogenic perturbation of these cycles on both regional and global scales. The first part of the book (Chapters 1 to 8) provides a review of topics fundamental to such studies. These topics include concepts in geochemical modelling, assessment of atmospheric transport from sources to the oceans. description of mixing and transport processes within the ocean for both dissolved and particulate materials, quantification of air-sea fluxes for both gases and particles, photochemical transformations in the atmospheric and oceanic boundary layers.
Download or read book Nitrate Radicals in the Atmosphere written by Christian Pfrang and published by . This book was released on 2006 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Application of Cavity Ring down Spectroscopy to Determine Nitrate Radical Concentrations in the Atmosphere written by Eric Michael Dick and published by . This book was released on 2002 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The nitrate radical, NO3, is a potent atmospheric oxidant. Current NO3 measurement methods average NO3 concentrations over several kilometer pathlengths. Recent modeling studies predict that NO3's distribution is vertically inhomogenous, causing previous NO3 observations to not be representative of its atmospheric chemistry. In-situ measurements offer a test of these modeling predictions and a better understanding of NO3 chemistry. In this thesis, we describe construction of an instrument capable of detecting NO3 in-situ. This sensor is based upon cavity ring-down spectroscopy. Our initial work demonstrated that CRDS could sensitively detect NO3. We then built and tested a field prototype during June 2001, successfully detecting NO3 in the field. CRDS observations were compared to path averaged NO3 observations. Similar time behavior of both signals indicated that the techniques were observing NO3. A consistent difference in signal levels indicated that the two techniques were not sampling a homogeneous air mass"--Leaf iii.
Download or read book Mechanisms of Atmospheric Oxidation of the Oxygenates written by Jack Calvert and published by OUP USA. This book was released on 2011-09-29 with total page 1634 pages. Available in PDF, EPUB and Kindle. Book excerpt: Prepared by an international team of eminent atmospheric scientists, Mechanisms of Atmospheric Oxidation of the Oxygenates is an authoritative source of information on the role of oxygenates in the chemistry of the atmosphere. The oxygenates, including the many different alcohols, ethers, aldehydes, ketones, acids, esters, and nitrogen-atom containing oxygenates, are of special interest today due to their increased use as alternative fuels and fuel additives. This book describes the physical properties of oxygenates, as well as the chemical and photochemical parameters that determine their reaction pathways in the atmosphere. Quantitative descriptions of the pathways of the oxygenates from release or formation in the atmosphere to final products are provided, as is a comprehensive review and evaluation of the extensive kinetic literature on the atmospheric chemistry of the different oxygenates and their many halogen-atom substituted analogues. This book will be of interest to modelers of atmospheric chemistry, environmental scientists and engineers, and air quality planning agencies as a useful input for development of realistic modules designed to simulate the atmospheric chemistry of the oxygenates, their major oxidation products, and their influence on ozone and other trace gases within the troposhere.
