Download or read book Morphology and Physical Properties of Polyurethane Block Polymers written by Dong-soo Huh and published by . This book was released on 1971 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Polyurethane Polymers Blends and Interpenetrating Polymer Networks written by Sabu Thomas and published by Elsevier. This book was released on 2017-08-15 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyurethane Polymers: Blends and Interpenetrating Networks deals with almost all aspects of blends and IPNs formed by polyurethane, including the thermal, mechanical, morphological, and viscoelastic properties of each blend presented in the book. In addition, major applications related to these blends and IPNs are mentioned. - Provides an elaborate coverage of the chemistry of polyurethane, including its synthesis and properties - Includes available characterization techniques - Relates types of polyurethanes to their potential properties - Discusses blends options

Download or read book Properties of Some Thermoplastic Polyurethane Block Copolymers in Relation to Their Structure and Morphology written by Krisda Suchiva and published by . This book was released on 1978 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: POLYURETHANE COPOLYMERS, ELASTOMERS, CHEMICAL STRUCTURE, POLYMER MORPHOLOGY, THERMAL PROPERTIES, MECHANICAL PROPERTIES, ELECTRON MICROSCOPY, ALIPHATIC POLYESTERS, CRYSTAL STRUCTURE.

Download or read book Morphology and Fatigue Properties of Polyurethane Thermoplastic Elastomers written by Craig Wayne Stephen Myers and published by . This book was released on 1993 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyurethane thermoplastic elastomers are segmented block polymers consisting of rubbery "soft" blocks and glassy or semi-crystalline "hard" blocks. Thermodynamic incompatibility between the soft and hard blocks causes the formation of a microdomain morphology which imparts elastomeric properties to the material. Despite their commercial importance, the response of these materials to repeated cyclic loading (fatigue) has not been well studied. This work is devoted to achieving a more detailed understanding of the chemical and morphological factors which govern fatigue behavior in polyurethane thermoplastic elastomers.

Download or read book The Effects of Segmental Incompatibility and the Degree of Phase Separation on the Morphology and Properties of Polyurethane Block Copolymers written by Thomas Arthur Speckhard and published by . This book was released on 1985 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Block Polymers written by S. L. Aggarwal and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: Block polymers represent another milestone in the preparation of polymers of controlled structure. Catalysts and polymerization methods that allowed the preparation of polymers in which the stereo- and geometric isomerism of the monomer units could be con trolled have indeed been among the major developments in polymer science during the last decade. The synthesis of block polymers, in which the sequence length of the comonomer units can be con trolled, portends equally important developments in the science and technology of polymers. The papers collected in this volume cover primarily the pro ceedings of the most recent symposium on block polymers, sponsored by the Division of Polymer Chemistry of the American Chemical Society. It was held in New York City during the Society's 158th National Meeting in September, 1969. Additional contributions from selected authors were invited especially for this book to achieve the most up-to-date account of the advances that have been made since the development of the thermoplastic elastomers that first brought into focus this important area of research. The first two papers in this volume draw attention to the various problems that should be considered in the preparation of block polymers of precisely defined structure from styrene and butadiene or isoprene by anionic polymerization. Characterization of block polymers presents many problems and there is a paucity of systematic work in this area. Attention has been given to the di lute solution properties of block polymers,however, in one of the papers in this volume.

Download or read book Processing Structure and Properties of Block Copolymers written by M.J. Folkes and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: Block copolymers represent an important class of multi-phase material, which have received very widespread attention, particularly since their successful commercial development in the mid-1960s. Much of the interest in these polymers has arisen because of their rather remarkable micro phase morphology and, hence, they have been the subject of extensive microstructural examination. In many respects, the quest for a comprehensive interpretation of their structure, both theoretically and experimentally, has not been generally matched by a corresponding enthusiasm for developing structure/property relationships in the context of their commercial application. Indeed, it has been left largely to the industrial companies involved in the development and utilization of these materials to fulfil this latter role. While it is generally disappointing that a much greater synergism does not exist between science and technology, it is especially sad in the case of block copolymers. Thus these materials offer an almost unique opportunity for the application of fundamental structural and property data to the interpretation of the properties of generally processed artefacts. Accordingly, in this book, the editor has drawn together an eminent group of research workers, with the specific intention of highlighting some of those aspects of the science and technology of block copolymers that are potentially important if further advances are to be made either in material formulation or utilization. For example, special consideration is given to the relationship between the flow properties of block copo lymers and their microstructure.

Download or read book The Effects of Structure and Morphology on the Physical Properties of End Crystallizable Block Copolymers and Polymer Blends written by Wei-Yuan Lin and published by . This book was released on 1983 with total page 538 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Shape Memory Polymers written by Hemjyoti Kalita and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-03-19 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: The basic principles and mechanism of shape memory polymers, classification of shape memory polymers, and related characterization techniques are illustrated. Furthermore, an overview of the broad spectrum of applications in various fields for shape memory polymer is presented. Special focus will be given to hyperbranched, blended, interpenetrating and bio-based shape memory polymers, as well as shape memory polymer nanocomposites.

Download or read book Recent Advances in Polymer Blends Grafts and Blocks written by L. Sperling and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer blends, grafts, and blocks, broadly defined, encompass all of the ways in which two or more kinds of poly mer molecules can be mixed and/or joined. Because these mate rials exhibit non-linear and often synergistic properties, they have found increasing application in our technology. Their multifarious uses have, in turn, spurred new research efforts, to find yet different ways of joining two kinds of polymer molecules, with novel physical and/or mechanical behavior patterns. In August, 1973, the Polymer Division of the American Chemical Society sponsored a symposium at its meeting in Chi cago on Polymer Blends, Grafts, and Blocks. This book collects the papers presented at that symposium. Yet, it is more than just a collection of papers, for we here display the thinking and efforts of a number of top-ranking American and foreign scientists in one of the world's more active research areas. The symposium emphasized the interrelationships among synthetic detail, morphology, and physical and mechanical properties. Several novel syntheses were presented. These include oxidation resistant thermoplastic elastomers (Holden), a graft copolymer based thermoplastic elastomer (Kennedy and Smith), a cationic graft copolymer (Kennedy, Charles, and Davidson), an AB crosslinked copolymer (Bamford and Eastmond), an interpenetrating polymer network (Donatelli, Thomas, and Sperling), and simultaneous interpenetrating networks (Frisch, Klempner, Frisch, and Ghiradella). Most polymer blends, grafts, and blocks exhibit two phases. The theory of microdomain structure was discussed (Helfand). The different ways that the two molecules can be joined together was examined (Kenney), and their topology was explored (Sperling).

Download or read book Synthesis and Physical Properties of Poly Perfluoroalkylether Urethanes written by and published by . This book was released on 1989 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyurethane block copolymers were synthesized containing 33 and 50 wt% soft segment, and hard segment based on 4,4-diphenylmethane dissocyanate (MDI) chain extender. The soft segments were mixtures of poly(tetramethylene oxide) (PTMO) and poly(perfluoroalkylether) (PFEG) glycols (Mn=1000 and 1900, respectively), ranging from 4 to 100wt% PFEG. The PMTO polyol in one sample was substituted with a PMTO/ethylene oxide polyol (75:25 mole ratio) (Mn=1140). The MDEA-extended polymer was ionized using 1,3-propane sultone. The morphology, bulk, and surface properties of these polymers were evaluated by a variety of techniques. Differential scanning calorimetry and dynamic mechanical analysis showed that the incorporation of PFEG into the soft segment phase slightly enhanced the degree of phase separation. Polyurethanes; Poly(perfluoroalkylether); Mixed soft segment; Polymers; Organic chemistry.

Download or read book Polyurethane Polymers Composites and Nanocomposites written by Sabu Thomas and published by Elsevier. This book was released on 2017-08-17 with total page 635 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyurethane Polymers: Composites and Nanocomposites concentrates on the composites and nanocomposites of polyurethane based materials. Polyurethane composites are a very important class of materials widely used in the biomedical and industrial field that offer numerous potential applications in many areas. This book discusses current research and identifies future research needs in the area. - Provides an elaborate coverage of the chemistry of polyurethane, its synthesis, and properties - Includes available characterization techniques - Relates types of polyurethanes to their potential properties - Discusses composites, nanocomposites options, and PU recycling

Download or read book Morphology of Segmented Polyurethanes as Probed by Electron Microscopy Small angle X ray Scattering and Gas Transport Measurement written by Chi Li and published by . This book was released on 1988 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Controlling the Morphology of Polymers written by Geoffrey R. Mitchell and published by Springer. This book was released on 2016-09-06 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on controlling morphology of different scales for polymers. The authors explain the need for successful control of morphology to yield target macroscopic physical properties in the application of polymers to diverse areas such as engineering materials, nanodielectrics and photonic crystals. The book combines specialized chapters with an introduction to the morphology of polymers and the range of experimental techniques available to evaluate it.

Download or read book Polymer Blends and Composites written by John A. Manson and published by Springer Science & Business Media. This book was released on 1976 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. Homopolymer Structure and Behavior.- 1.1. High Polymers.- 1.2. Molecular Size and Shape.- 1.2.1. Chain Conformation.- 1.2.2. Chain Entanglement.- 1.3. Molecular Structure.- 1.3.1. Configurations of Polymer Chains.- 1.3.2. Stereo and Geometrical Isomerism.- 1.3.3. Random Branching.- 1.3.4. Nonrandom Branching.- 1.3.5. Crosslinking.- 1.4. Crystallinity and Order.- 1.4.1. Fringed Micelle Model.- 1.4.2. Folded-Chain Single Crystals.- 1.4.3. Extended-Chain Crystals.- 1.4.4.Spherulites.- 1.5. Mechanical Response: Elasticity and Viscoelasticity.- 1.5.1. Molecular and Segmental Motion.- 1.5.2. Modulus-Temperature Behavior.- 1.5.3. Five Regions of Viscoelastic Behavior.- 1.5.4. Rubberlike Elasticity.- 1.5.5. Dynamic Mechanical Spectroscopy.- 1.5.6. Stress-Relaxation and Creep Behavior.- 1.5.7. Time-Temperature Relationship.- 1.6. Energetics and Mechanics of Fracture.- 1.6.1. General Approach to Fracture.- 1.6.2. Energy Balance in Fracture.- 1.6.3. Viscoelastic Rupture of Elastomers.- 1.7. Mechanical Testing of Polymers.- 1.7.1. Stress-Strain and Fracture Behavior.- 1.7.2. Impact Strength.- 1.7.3. Fatigue.- Appendix A. Polymer Synthesis.- Appendix B. Basic Mechanical Properties and Relationships.- Bibliography of Polymer Books and Journals.- 2. General Behavior of Polymer Mixtures.- 2.1. Methods of Mixing Polymer Pairs.- 2.1.1. Polymer Blends.- 2.1.2. Graft Copolymers.- 2.1.3. Block Copolymers.- 2.1.4. Interpenetrating Polymer Networks (IPN's).- 2.2. Interdiffusion.- 2.3. Nomenclature.- 2.4. Electron Microscopy.- 2.5. The Incompatibility Problem.- 2.5.1. Thermodynamics of Mixing.- 2.5.2. Polymer-Polymer Phase Diagrams.- 2.6. Bulk Behavior of Two-Phase Polymeric Materials.- 2.6.1. Glass Transitions.- 2.6.2. Modulus-Temperature Behavior of Model Polyblends.- 2.6.3. Stress-Relaxation Behavior.- 2.6.4. The Takayanagi Models.- 2.6.5. Free Volume Model.- 2.6.6. Other Models.- 2.6.7. Morphology-Modulus Interrelationships.- 2.7. Analogy between Polymer Blends and Crystalline Homopolymers.- 2.8. Polymer Blend Chronology.- Appendix A. Counterpart Phase Separation Characteristics of Metallic Alloys and Inorganic Glasses.- Bibliography of Polymer Blend Symposia.- 3. Rubber-Toughened Plastics.- 3.1. Synthesis and Morphology.- 3.1.1. Impact-Resistant Polystyrene.- 3.1.1.1. Solution-Type Graft Copolymers.- 3.1.1.2. Phase Inversion.- 3.1.1.3. Grafting vs. Mechanical Entrapment.- 3.1.2. ABS Resins.- 3.1.2.1. Emulsion Polymerization.- 3.1.2.2. Structure of the Latex Grafts.- 3.1.3. Origin of the Cell Structure.- 3.1.4. Poly(vinyl chloride) Blends.- 3.1.5. Mixed Latex Blends.- 3.2. Physical and Mechanical Behavior of Polyblends.- 3.2.1. The Effect of Compatibility on Transition Behavior.- 3.2.2. Impact Resistance and Deformation.- 3.2.2.1. Impact Behavior.- 3.2.2.2. Tensile and Creep Behavior.- 3.2.2.3. Fatigue Behavior.- 3.2.3. Toughening Mechanisms.- 3.2.3.1. Crazing and Shear Phenomena.- 3.2.3.2. Characteristics of the Rubber.- 3.3. Optical Properties of Polyblends.- 3.4. Oxidation and Weathering of Polyblends.- 4. Diblock and Triblock Copolymers.- 4.1. Synthesis.- 4.1.1. Dilithium Initiators.- 4.1.2. Mechanochemical Methods.- 4.2. Solution Behavior of Block Copolymers.- 4.3. Plastic Compositions.- 4.4. Thermoplastic Elastomers.- 4.5. Long-Range Domain Order.- 4.6. Thermodynamics of Domain Characteristics.- 4.7. Thermodynamic Criteria for Phase Separation.- 4.7.1. Zeroth Approximation.- 4.7.2. Dilute Solution Approach.- 4.7.3. Diffusion Equation Approach.- 4.8. Effect of Solvent Casting on Morphology.- 4.9. Effect of Deformation on Morphology.- 4.10. Mixtures of A-B Blocks with A and B Mechanical Blends.- 4.11. Rheological Behavior of Block Copolymers.- 5. Multiblock Copolymers, Including Ionomers.- 5.1. Segmented Polyurethane Elastomers.- 5.1.1. Modulus and Swelling Behavior.- 5.1.2. Stress-Strain Behavior.- 5.1.3. Stress-Optical Behavior.- 5.1.4. Tensile Strength and Abrasion Resistance.- 5.1.5. Some Generalizations.- 5.2. Carboxylic Rubbers an...

Download or read book Advances in Shape Memory Polymers written by Jinlian Hu and published by Elsevier. This book was released on 2013-04-16 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: Shape memory materials are immensely useful because of their capability to recover their original shapes upon exposure to an external stimulus such as heat, moisture, light or a magnetic field. This book reviews key recent research in shape memory polymers, their properties and applications. Topics include the relationship between morphological structures and shape memory properties; high performance Tg and Tm type shape memory polymers; structures of shape memory polymers with supramolecular switches; and the thermally-active and moisture-active shape memory effect of supermolecular shape memory polymers.Advances in shape memory polymers is an essential reference for polymer and textile material students, scientists, designers, engineers and manufacturers. It is also an invaluable guide for professionals in the biomedical, electronics and engineering industries. - Reviews key recent research in shape-memory polymers, their properties and applications - Opening chapters address the relationship between morphological structures and shape memory properties and high performance Tg and Tm type shape memory polymers - Chapters cover thermally-active and moisture-active shape memory effect of supermolecular shape memory polymers, among other topics

Download or read book Multicomponent Polymers written by Guojian Wang and published by Walter de Gruyter GmbH & Co KG. This book was released on 2020-10-26 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book introduces fundamental principles, phase structure, mechanism, mechanical properties, and different types of multicomponent polymers. Rheological properties, graft copolymers, block copolymers and interpenetrating polymer networks are discussed in detail as well. With abundant illustrations, it is an essential reference for polymer chemists, material scientists and graduate students.