Download or read book Modern Aspects of Electrochemistry 30 written by Ralph E. White and published by Springer. This book was released on 1996-12-31 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 30 of this authoritative series provides detailed information about current advances in both fundamental and applied electrochemical research.

Download or read book Modern Electrochemistry 2A written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 2001-01-31 with total page 820 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.

Download or read book Modern Aspects of Electrochemistry written by Ralph E. White and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume of Modern Aspects contains seven chapters. The major topics covered in the first six chapters of this volume include fundamentals of solid state electrochemistry; kinetics of electrochemical hydrogen entry into metals and alloys; oxidation of organics; fuel cells; electrode kinetics of trace-anion catalysis; nano structural analysis. The last chapter is a corrected version of chapter four from Volume 35. Faisal M. AI-faqeer and Howard W. Pickering begin the first chapter by going back to 1864 and Cailletet who found that some hydrogen evolved and was absorbed by iron when it was immersed in dilute sulfuric acid. The absorption of hydrogen into metals and alloys can lead to catastrophic failures of structures. They discuss the kinetics of electrochemical hydrogen entry into metals and alloys. In chapter three, Clyde L. Briant reviews the electrochemistry, corrosion and hydrogen embrittlement of unalloyed titanium. He begins by reviewing the basic electrochemistry and general corrosion of titanium. He also discusses pitting and galvanostatic corrosion followed by a review of hydrogen embrittlement emphasizing the formation of hydrides and the effect of these on titanium's mechanical properties. Christos Comninellis and Gy6rgy F6ti discuss the oxidative electrochemical processes of organics in chapter three. They begin by defining direct and indirect electrochemical oxidation of organics. They introduce a model that allows them to distinguish between active (strong) and non-active (weak) anodes. Different classes of organic compounds are used for kinetic models of organic oxidation at active and non-active type anodes.

Download or read book Modern Aspects of Electrochemistry 42 written by Constantinos G. Vayenas and published by Springer Science & Business Media. This book was released on 2008-03-08 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.

Download or read book Progress in Corrosion Science and Engineering I written by Su-Il Pyun and published by Springer Science & Business Media. This book was released on 2009-09-18 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume of Modern Aspects of Electrochemistry is composed of four chapters covering topics having relevance both in corrosion science and materials engineering. All of the chapters provide comprehensive coverage of recent advances in corrosion science. The first chapter, by Maurice and Marcus, provides a comprehensive review on the structural aspects and anti-corrosion properties of passive films on metals and alloys. These authors look at recent experimental data collected by in-situ microscopic techniques coupled with electrochemical methods. A detailed description is given of the nucleation and growth of 2-dimensional passive films at earlier stages, their effect on the corrosion properties of metal surfaces, and the nanostructures of- dimensional passive films. On the basis of the experimental data reviewed, the authors present a model for passivity breakdown and pit initiation, which takes into account the preferential role of grain boundaries. In Chapter 2, Takahashi and his co-workers give a specialized account on the electrochemical and structural properties of anodic oxide films formed on aluminum. In addition to the electrochemical corrosion-related problems of anodic oxide films, the chapter reviews state-of-the-art research of nano-/mic- fabrications based on anodizing treatments combined with chemical/mechanical processes such as laser irradiation, atomic force micro-probe processing and thin film deposition techniques.

Download or read book Modern Aspects of Electrochemistry written by Brian E. Conway and published by Springer Science & Business Media. This book was released on 2005-11-21 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recognized experts present incisive analysis of both fundamental and applied problems in this continuation of a highly acclaimed series. Topics discussed include: A thorough and mathematical treatment of periodic phenomena, with consideration of new theories about the transition between `order' and `chaos'; Impedance spectroscopy as applied to the study of kinetics and mechanisms of electrode processes; The use of stoichiometric numbers in mechanism analysis; The electro-osmotic dewatering of clays with important implications for the processing of industrial waste and geotechnical; stabilization; Magnetic effects in electrolytic processes and the electrolytic Hall effect; and The computer analysis and modeling of mass transfer and fluid flow. These authoritative studies will be invaluable for researchers in engineering, electrochemistry, analytical chemistry, materials science, physical chemistry, and corrosion science.

Download or read book Modern Aspects of Electrochemistry written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 2006-04-18 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: Prof. Jerzy Sobkowski starts off this 31st volume of Modern Aspects of Electrochemistry with a far-ranging discussion of experimental results from the past 10 years of interfacial studies. It forms a good background for the two succeeding chapters. The second chapter is by S. U. M. Khan on quantum mechanical treatment of electrode processes. Dr. Khan’s experience in this area is a good basis for this chapter, the contents of which will surprise some, but which as been well refereed. Molecular dynamic simulation is now a much-used technique in physical electrochemistry and in the third chapter Ilan Benjamin has written an account that brings together information from many recent publications, sometimes confirming earlier modeling approaches and sometimes breaking new territory. In Chapter 4, Akiko Aramata’s experience in researching single crystals is put to good advantage in her authoritative article on under- tential deposition. Finally, in Chapter 5, the applied side of electrochemistry is served by Bech-Neilsen et al. in the review of recent techniques for automated measurement of corrosion. J. O’M. Bockris, Texas A&M University B. E. Conway, University of Ottawa R. E. White, University of South Carolina Contents Chapter 1 METAL/SOLUTION INTERFACE: AN EXPERIMENTAL APPROACH Jerzy Sobkowski and Maria Jurkiewicz-Herbich I. Introduction.............................................. 1 II. Molecular Approach to the Metal/Solution Interface............. 3 1. Double-Layer Structure: General Considerations .......... 3 2. Solid Metal/Electrolyte Interface.......................... 8 3. Methods Used to Study Properties ofthe Metal/Solution Interface: Role of the Solvent and the Metal............. 15 The Thermodynamic Approach to the Metal/Solution Interface 35 III.

Download or read book Modern Aspects of Electrochemistry 40 written by Ralph E. White and published by Springer Science & Business Media. This book was released on 2010-04-28 with total page 367 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume in the acclaimed series Modern Aspects of Electrochemistry starts with a dedication to the late Professor Brian Conway who for 50 years helped to guide this series to its current prominence. The remainder of the volume is then devoted to the following topics: PEM fuel cells; the use of graphs in electrochemical reaction newtworks; nanomaterials in Lithium-ion batteries; direct methanolf fuel cells (two chapters); fuel cell catalyst layers. The book is for electrochemists, electrochemical engineers, fuel cell workers and energy generation workers.

Download or read book Modern Aspects of Electrochemistry written by B. E. Conway and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the subject of electrochemistry moves into the final quarter of the century, a number of developed areas can be assessed in depth while some new areas provide quantitatively and qualitatively novel data and results. The first chapter, by Kebarle, deals with an example of the latter type of field in which new information of the energetics and equilibria of reactions between ions and solvent molecules is studied in the gas phase and provides interesting basic information for treatments of ions in solution, i.e., ionic solvation. Chapter 2, by Hamann, discusses the behavior of electrolyte solutions under high pressures, a matter of intrinsic interest in relation to ion-solvent interaction and the structural aspects of the properties of ionic solutions, especially in water. This topic is also of current interest with regard to the physical chemistry of the marine environment, especially at great depths. In the article by Bloom and Snook (Chapter 3), models for treatments of molten salt systems are examined quantitatively in relation to the structure of molten ionic liquids and to the statistical mechanical approaches that can be meaningfully made to interpret their properties and electrochemical behavior.

Download or read book Modern Aspects of Electrochemistry No 6 written by J. O'M. Bockris and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decade, the evolution of electrochemistry away from concern with the physical chemistry of solutions to its more fruitful goal in the study of the widespread consequences of the transfer of electric charges across interphases has come to fruition. The turning of technology away from an onward rush, regardless, to progress which takes into account repercussions of techno logical activity on the environment, and the consequent need for a reduction and then termination of the injection of CO into 2 the atmosphere (greenhouse effect), together with a reckoning with air and water pollution in general, ensures a long-term need for advances in a basic knowledge of electrochemical systems, an increased technological use of which seems to arise from the environmental necessities. But a mighty change in attitude needs to spread among electro chemists (indeed, among all surface chemists) concerning the terms and level in which their field is discussed. The treatment of charge transfer reactions has often been made too vaguely, in terms, it seemed, of atom transfer, with the electron-transfer step, the essence of electrochemistry, an implied accompaniment to the transfer of ions across electrical double layers. The treatment has been in terms of classical mechanics, only tenable while inadequate questions were asked concerning the behavior of the electron in the interfacial transfer. No process demands a more exclusively quantal discussion than does electron transfer.

Download or read book Modern Aspects of Electrochemistry written by J. O'M. Bockris and published by . This book was released on 1986 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Modern Aspects of Electrochemistry written by J. O'M Bockris and published by . This book was released on 2014-09-01 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Modern Aspects of Electrochemistry written by John Bockris and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 674 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains eight chapters covering a wide range of topics: ultrasonic vibration potentials, impedance measurements, photo electrochemical kinetics, chlorine production, electrochemical behavior of titanium, structural properties of membranes, bioelec troche mistry, and small-particle effects for electrocatalysis. Chapter 1, contributed by Zana and Yeager, discusses the little used but potentially important area of ultrasonic vibration potentials. The authors review the historical literature and the associated theoretical equations. They continue by discussing various aspects of the experimental technique and close with a review of the existing studies. They conclude by noting that vibra tion potentials may be useful for determining the effects of various agents on colloidal suspensions found in such important industries as paper production. Chapter 2 is a review of impedance techniques, written by Macdonald and McKubre. The authors include not only derivations of various impedance functions for electrochemical systems but also particularly useful discussions of instrumental methods. The authors close with an interesting claim: "the distribution of current and potential within a porous battery or fuel-cell electrode and within 'flow-through' electrodes is best analyzed in terms of the frequency dispersion of the impedance." Chapter 3, by Khan and Bockris, is a timely review of photo electrochemical kinetics and related devices. Their work begins by reviewing critically important papers on photoelectrochemical kinetics. They continue by presenting detailed discussions concern ing the conceptual ideas of the semiconductor-solution interface.

Download or read book Applications of Electrochemistry in Medicine written by Mordechay Schlesinger and published by Springer Science & Business Media. This book was released on 2013-03-02 with total page 457 pages. Available in PDF, EPUB and Kindle. Book excerpt: Medical Applications of Electrochemistry, a volume of the series Modern Aspects of Electrochemistry, illustrates the interdisciplinary nature of modern science by indicating the many current issues in medicine that are susceptible to solution by electrochemical methods. This book also suggests how personalized medicine can develop.

Download or read book Electrochemical Production of Metal Powders written by Stojan S. Djokić and published by Springer Science & Business Media. This book was released on 2012-03-24 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new volume of Modern Aspects of Electrochemistry reviews different methods for the production of metal powders including mechanical, chemical and electrochemical powders. Electrochemically produced metal powders are of high purity and they are extremely active during sintering. These powders find a wide-range of applications in automotive, aerospace, energy device and electronics industries.

Download or read book Modern Electrochemistry written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 1973-10-31 with total page 876 pages. Available in PDF, EPUB and Kindle. Book excerpt: 7 The Electrified Interface.- 7.1 Electrification of an Interface.- 7.1.1 The Electrode-Electrolyte Interface: The Basis of Electrodics.- 7.1.2 New Forces at the Boundary of an Electrolyte.- 7.1.3 The Interphase Region Has New Properties and New Structures.- 7.1.4 An Electrode Is Like a Giant Central Ion.- 7.1.5 The Consequences of Compromise Arrangements: The Electrolyte Side of the Boundary Acquires a Charge.- 7.1.6 Both Sides of the Interface Become Electrified: The So-Called "Electrical Double Layer"--7.1.7 Double Layers Are Characteristic of All Phase Boundaries.- 7.1.8 A Look into an El.

Download or read book Modern Aspects of Electrochemistry 37 written by Ralph E. White and published by . This book was released on 2014-01-15 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: