Download or read book Modeling the Dissolution and Transport of a Multicomponent NAPL written by Ellen Anja Blackburn and published by . This book was released on 1998 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Coupled Multicomponent NAPL Dissolution and Transport in the Subsurface Analytic Solutions and Forensic Aspects written by Scott Kalev Hansen and published by . This book was released on 2012 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissolving multicomponent NAPL as a source of contamination in subsurface water is considered. In particular, two processes are analyzed with regard to how they alter inter-species concentration ratios at remote monitoring locations relative to inter-species molar ratios in the NAPL: nonlinear dissolution governed by Raoult's Law and differential sorption during subsurface transport. An analytic solution for Raoult's Law-governed dissolution is presented. Separately, it is shown how a variety of 1D analytic transport models for simple boundary conditions may be adapted to use arbitrary time-varying concentrations by use of some properties of Laguerre series. This is combined with the analytic solution so that Raoult's Law-governed multicomponent NAPL dissolution may be employed as the boundary condition for analytic transport models. A new computer model implementing this technique in an environment of discrete, parallel fractures is presented, and its accuracy verified for specific conditions against an existing code. The new code is applied to a parametric study on the plume separation of PAH and phenolic compounds from the dissolution of creosote. Narrow fracture spacing as well as significant values of matrix organic carbon are seen as particularly conducive to separation of these types of plumes, which in some circumstances may be entirely disjoint. Concentration ratios downgradient are shown largely unrelated to concentration ratios at the source. Finally, a study of PCB speciation is undertaken in fractured rock with known parameters, for which a rigorous, least squares speciation approach is developed. Even at distances of 5 m from the source, given perfect information about the subsurface, it is found not possible to chemically fingerprint a source PCB mixture from a list of three absent a model of the weathering of the NAPL. Both the PCB and creosote studies demonstrate that forensic inference of source compositions from field data is unreliable and the need for coupled dissolution and transport models like the one developed here.
Download or read book Fate and Transport of Subsurface Pollutants written by Pankaj Kumar Gupta and published by Springer Nature. This book was released on 2020-10-20 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume offers detailed information on the behaviour of various water pollutants, and on the principles and concepts of groundwater flow and transport. It will help readers to understand and execute the planning, supervision, and review of solute transport and groundwater modeling projects. The book also discusses the role and fate of elements that have been identified as major contaminants in surface and subsurface waters, and their adverse effects on ecology and human health. The book explores this theme throughout four sections – a. Understanding Soil-Water Systems, b. Fate and Transport of Pollutants, c. Physico-Chemical Treatment of Wastewater and d. Microbial Techniques Used to Decontaminate Soil-Water Systems. Introducing readers to a range of recent advances concerning the fundamentals of subsurface water treatment, it offers a valuable guide for teachers, researchers, policymakers, and undergraduate and graduate students of hydrology, environmental microbiology, biotechnology and the environmental sciences. It also provides field engineers and industrial practitioners with essential support in the effective remediation and management of polluted sites.
Download or read book Characterization Dissolution and Enhanced Solubilization of Multicomponent Nonaqueous Phase Liquid in Porous Media written by Kenneth Cooper Carroll and published by . This book was released on 2007 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt: Multicomponent nonaqueous phase liquids (NAPL) contaminating the subsurface can significantly inhibit remediation. One method of enhancing the rate of remediation of NAPL constituents, compared to pump-and-treat, involves source zone treatment with enhanced solubilization agents (ESAs) including cyclodextrins. Equilibrium cyclodextrin enhanced solubilization of simple 1, 2, and 3 component NAPL mixtures was examined to evaluate the applicability of Raoult's Law. The results suggest that Raoult's Law may be used to estimate equilibrium and early-time dynamic concentrations in contact with ideal NAPL mixtures, and Raoult's Law may be used to estimate cyclodextrin enhanced groundwater concentrations for ideal NAPL mixtures. Solubility enhancement of NAPL compounds was dependent on the cyclodextrin concentration and independent of NAPL composition. Column experiments and numerical modeling were used to evaluate the dissolution behavior of the NAPL mixtures in water and a cyclodextrin solution to estimate mass transfer rates. The aqueous multicomponent dissolution followed Raoult's Law, and the model-estimated lumped rate coefficients were independent of the NAPL composition. Addition of the cyclodextrin enhanced the dissolution and removal of compounds from residual NAPL due to an increase in the driving force (i.e. concentration gradient) and the mass transfer coefficient. The model results suggest that Raoult's Law is applicable for ideal NAPL mixture dissolution in water, but potential nonideality was observed and caused the model simulation to deviate from the dissolution behavior for NAPL mixture cyclodextrin experiments. The cyclodextrin dissolution experiments were less rate-limited than aqueous dissolution, and the mass transfer coefficients were quantified with the model. The results of the model suggest that NAPL mixture nonideality and intra-NAPL diffusion may also impact enhanced dissolution behavior. Additionally, the importance of NAPL mixture characterization was illustrated by evaluation of a mixture of PCE (tetrachloroethene) and diesel fuel collected from a site in Tucson, Arizona. A sample from the site was used to create mixtures with increasing PCE in the NAPL. Chemical evaluation of the complex NAPL was conducted, and physical property and phase partitioning testing was performed, which demonstrated the effect of NAPL composition on its distribution, interphase mass transfer, and potential mobilization.
Download or read book Numerical Modeling of Multiphase Transport of Multicomponent Organic Contaminants and Heat in the Subsurface written by Adeyinka Emmanuel Adenekan and published by . This book was released on 1992 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Soil and Groundwater Contamination written by Alex S. Mayer and published by American Geophysical Union. This book was released on 2005-01-14 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: Accompanying CD-ROM ... "contains spreadsheets used in many of the example calculations, color versions of some of the illustrations, and movies illustrating the NAPL migration."--Page vi.
Download or read book Groundwater in Fractured Bedrock Environments Managing Catchment and Subsurface Resources written by U. Ofterdinger and published by Geological Society of London. This book was released on 2019-07-19 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fractured bedrock aquifers have traditionally been regarded as low-productivity aquifers, with only limited relevance to regional groundwater resources. It is now being increasingly recognised that these complex bedrock aquifers can play an important role in catchment management and subsurface energy systems. At shallow to intermediate depth, fractured bedrock aquifers help to sustain surface water baseflows and groundwater dependent ecosystems, provide local groundwater supplies and impact on contaminant transfers on a catchment scale. At greater depths, understanding the properties and groundwater flow regimes of these complex aquifers can be crucial for the successful installation of subsurface energy and storage systems, such as deep geothermal or Aquifer Thermal Energy Storage systems and natural gas or CO2 storage facilities as well as the exploration of natural resources such as conventional/unconventional oil and gas. In many scenarios, a robust understanding of fractured bedrock aquifers is required to assess the nature and extent of connectivity between such engineered subsurface systems at depth and overlying receptors in the shallow subsurface.
Download or read book Environmental Impact Assessment of Recycled Wastes on Surface and Ground Waters written by Tarek A. Kassim and published by Springer Science & Business Media. This book was released on 2005-07-20 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 3: Engineering Modeling and Sustainability. This 3-volume reference presents the latest findings in impact assessment of recycled hazardous waste materials on surface and ground waters. Topics covered include chemodynamics, toxicology, modeling and information systems. The book serves as a practical guide for the monitoring, design, management, or conduct of environmental impact assessment. Each volume contains the table of contents of all volumes.
Download or read book Natural Attenuation of Fuels and Chlorinated Solvents in the Subsurface written by Todd H. Wiedemeier and published by John Wiley & Sons. This book was released on 1999-03-08 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive guide to one of today's most innovative approaches to environmental contamination Natural attenuation is gaining increasing attention as a nonintrusive, cost-effective alternative to standard remediation techniques for environmental contamination. This landmark work presents the first in-depth examination of the theory, mechanisms, and application of natural attenuation. Written by four internationally recognized leaders in this approach, the book describes both biotic and abiotic natural attenuation processes, focusing on two of the environmental contaminants most frequently encountered in groundwater--fuels and chlorinated solvents. The authors draw on a wealth of combined experience to detail successful techniques for simulating natural attenuation processes and predicting their effectiveness in the field. They also show how natural attenuation works in the real world, using numerous examples and case studies from a wide range of leading-edge projects nationwide involving fuel hydrocarbons and chlorinated solvents. Finally, they discuss the evaluation and assessment of natural attenuation and explore the design of long-term monitoring programs. An indispensable reference for anyone working in environmental remediation, Natural Attenuation of Fuels and Chlorinated Solvents in the Subsurface is essential reading for scientists and engineers in a range of industries, as well as state and federal environmental regulators, and professors and graduate students in environmental or chemical engineering.
Download or read book Dissolution from Multicomponent Nonaqueous Phase Liquids NAPLs written by Priti P. Brahma and published by . This book was released on 2000 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Soil Sciences Two Volume Set written by Pan Ming Huang and published by CRC Press. This book was released on 2018-10-03 with total page 2249 pages. Available in PDF, EPUB and Kindle. Book excerpt: An evolving, living organic/inorganic covering, soil is in dynamic equilibrium with the atmosphere above, the biosphere within, and the geology below. It acts as an anchor for roots, a purveyor of water and nutrients, a residence for a vast community of microorganisms and animals, a sanitizer of the environment, and a source of raw materials for co
Download or read book Hazardous and Industrial Waste Proceedings 32nd Mid Atlantic Conference written by James E. Kilduff and published by CRC Press. This book was released on 2000-06-26 with total page 944 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chlorinated Solvent Source Zone Remediation written by Bernard H. Kueper and published by Springer Science & Business. This book was released on 2014-04-22 with total page 759 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to help engineers and scientists better understand dense nonaqueous phase liquid (DNAPL) contamination of groundwater and the methods and technology used for characterization and remediation. Remediation of DNAPL source zones is very difficult and controversial and must be based on state-of-the-art knowledge of the behavior (transport and fate) of nonaqueous phase liquids in the subsurface and site specific geology, chemistry and hydrology. This volume is focused on the characterization and remediation of nonaqueous phase chlorinated solvents and it is hoped that mid-level engineers and scientists will find this book helpful in understanding the current state-of-practice of DNAPL source zone management and remediation.
Download or read book Spring Meeting written by American Geophysical Union. Meeting and published by . This book was released on 2001 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Handbook of Groundwater Engineering Third Edition written by John H. Cushman and published by CRC Press. This book was released on 2016-11-25 with total page 1726 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new edition adds several new chapters and is thoroughly updated to include data on new topics such as hydraulic fracturing, CO2 sequestration, sustainable groundwater management, and more. Providing a complete treatment of the theory and practice of groundwater engineering, this new handbook also presents a current and detailed review of how to model the flow of water and the transport of contaminants both in the unsaturated and saturated zones, covers the protection of groundwater, and the remediation of contaminated groundwater.
Download or read book The Handbook of Groundwater Engineering written by Jacques W. Delleur and published by CRC Press. This book was released on 2006-11-16 with total page 1342 pages. Available in PDF, EPUB and Kindle. Book excerpt: A complete treatment of the theory and practice of groundwater engineering, The Handbook of Groundwater Engineering, Second Edition provides a current and detailed review of how to model the flow of water and the transport of contaminants both in the unsaturated and saturated zones, covers the production of groundwater and the remediation of contaminated groundwater.
Download or read book Issues in Environmental Economics Engineering and Technology 2013 Edition written by and published by ScholarlyEditions. This book was released on 2013-05-01 with total page 1099 pages. Available in PDF, EPUB and Kindle. Book excerpt: Issues in Environmental Economics, Engineering, and Technology: 2013 Edition is a ScholarlyEditions™ book that delivers timely, authoritative, and comprehensive information about Environmental Economics. The editors have built Issues in Environmental Economics, Engineering, and Technology: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Environmental Economics in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Issues in Environmental Economics, Engineering, and Technology: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
