Download or read book Modeling Lithium ion Capacity Fade by Lithium Plating and Set Formation written by and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Capacity fade models effectively study the aging behavior of a battery cell after long term cycling, and allow for better understanding of the theory of degradation, thereby slowing down the capacity fade rate and improving battery safety issues. Solid electrolyte interface (SEI) growth and lithium plating are two key reasons why capacity fade occurs. In this study, a physics-based lithium-ion cell model including capacity fade and thermal effects is developed and used to predict the cell cycle life under different operating conditions. The model is validated using the experimental data. Under low temperatures or high C-rates, lithium plating seems to be the dominating factor of cell capacity fade; under high temperatures or low C-rates, the SEI film is the dominating factor of cell capacity fade. As evidenced by this study, the cell capacity fade is more sensitive to the operating temperature than the charging rate under the normal operating and charging conditions. 1 C and 25 °C is found to be the optimal operating condition. The thermal analysis results show that the cell temperature increases with cycle number, which is attributed to the high ohmic losses from the resistance of anode. The model presented in this research will be useful for charging strategy design in order to minimize the lithium plating and provide insight for the cell thermal management.

Download or read book Electrochemical Systems written by John Newman and published by John Wiley & Sons. This book was released on 2012-11-27 with total page 671 pages. Available in PDF, EPUB and Kindle. Book excerpt: The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basicsof thermodynamics and electrode kinetics to transport phenomena inelectrolytes, metals, and semiconductors. Newly updated andexpanded, the Third Edition covers important new treatments, ideas,and technologies while also increasing the book's accessibility forreaders in related fields. Rigorous and complete presentation of the fundamentalconcepts In-depth examples applying the concepts to real-life designproblems Homework problems ranging from the reinforcing to the highlythought-provoking Extensive bibliography giving both the historical developmentof the field and references for the practicing electrochemist.

Download or read book Lithium Batteries written by Bruno Scrosati and published by John Wiley & Sons. This book was released on 2013-06-18 with total page 495 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explains the current state of the science and points the way to technological advances First developed in the late 1980s, lithium-ion batteries now power everything from tablet computers to power tools to electric cars. Despite tremendous progress in the last two decades in the engineering and manufacturing of lithium-ion batteries, they are currently unable to meet the energy and power demands of many new and emerging devices. This book sets the stage for the development of a new generation of higher-energy density, rechargeable lithium-ion batteries by advancing battery chemistry and identifying new electrode and electrolyte materials. The first chapter of Lithium Batteries sets the foundation for the rest of the book with a brief account of the history of lithium-ion battery development. Next, the book covers such topics as: Advanced organic and ionic liquid electrolytes for battery applications Advanced cathode materials for lithium-ion batteries Metal fluorosulphates capable of doubling the energy density of lithium-ion batteries Efforts to develop lithium-air batteries Alternative anode rechargeable batteries such as magnesium and sodium anode systems Each of the sixteen chapters has been contributed by one or more leading experts in electrochemistry and lithium battery technology. Their contributions are based on the latest published findings as well as their own firsthand laboratory experience. Figures throughout the book help readers understand the concepts underlying the latest efforts to advance the science of batteries and develop new materials. Readers will also find a bibliography at the end of each chapter to facilitate further research into individual topics. Lithium Batteries provides electrochemistry students and researchers with a snapshot of current efforts to improve battery performance as well as the tools needed to advance their own research efforts.

Download or read book Review of Capacity Fade Models for Lithium ion Batteries Effect of Mechanisms on Numerical Implementation written by Mengdi Fan and published by . This book was released on 2018 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium-ion battery applications, such as EVs and PHEVs, require long battery life. However, capacity fade always occurs due to unwanted side reactions including electrolyte oxidation at the positive electrode, lithium deposition at the negative electrode, electrolyte decomposition processes, and the formation of the Solid-Electrolyte Interphase (SEI) layer[1]. To simulate the capacity fade, different models have been proposed in the literature[2-4]. In this work, we model the capacity fade by assuming the SEI layer formation to be the dominant mechanism. Even among SEI layer models, several different expressions have been used in many papers[5-8]. In most cases, the solid particles are assumed to be spherical, and the intercalation process is modeled using Fick’s law of diffusion in the radial direction. In this work, the SEI-forming side reaction based on the Single Particle Model (SPM) is studied. Three models are compared with different charging rates cycling study. For solving the solid-phase diffusion in the radial-dimension, many efficient mathematical algorithms of reformulation and simulation have been proposed in the past[9-12]. We address how those different SEI layer growth expressions affect the numerical implementation stability. The partial differential equations of the SPM are discretized using the finite difference method in the radial direction and solved in time using the numerical method of lines approaches.

Download or read book Detection and characterization of Lithium plating written by Long, Julian and published by Universitätsverlag der TU Berlin. This book was released on 2023-05-31 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium plating is not only the most severe ageing mechanism in lithium-ion batteries (LIBs) but also becoming more and more important due the increasing presence of electric vehicles (EVs). In EVs the extreme conditions causing lithium plating, like very high charging currents and low environment temperatures, are much more prevalent than in consumer electronics. Due to the high number of factors that influence the plating process, ranging from the cell geometry to the chemical composition of the electrolyte, a deeper understanding of the plating process is still lacking. Without this knowledge it is hard to design cells in a plating resistant way, or to operate cells under the ideal conditions to minimize plating. This thesis aims at showing different methods to investigate the plating process on three different levels. The first method is on the cell level, investigating the behaviour of the whole cell during plating. It contains the analysis of the voltage and current profiles that show an atypical behaviour during plating. The focus of the analysis is on the current profile of the constant voltage (CV) phase during charging under low temperature conditions leading to plating. This current profile can be fitted with the Johnson-Mehl-Avrami-Kolmogorov (JMAK) function that describes the electrochemical deposition process of a metallic species on a surface. The resulting fitting parameters can be utilized to characterize the plating behaviour of the cell as well as better estimate the amount of plated lithium than commonly used methods. It can also potentially predict the future safety risk due to dendrite formation. In the second part the chemical composition of the surface electrolyte interface (SEI) is investigated using X-ray photoelectron spectroscopy (XPS). The composition as well as the mechanical properties of the SEI are strongly influencing the plating process and preliminary work has shown that plating is also changing the morphology of the SEI and increasing its thickness drastically. Cells under different conditions (plated, charged and discharged) as well as cells of different manufacturers have been probed using XPS. During the measurements an unwanted side effect of the experimental setup was discovered that lead to a migration of lithium to the surface of the sample and was distorting the measurement results. Regardless of the effect, it was possible to see that the SEI can have a very different composition in cells of different manufacturers and that plating not only changes the morphology but also the composition of the SEI. The unwanted side effect could furthermore be utilized to identify samples that were plated recently and could be used in further more controlled experiments to localize lithium depositions on plated samples. In the last part the particle structure of the anode surface of cells of different manufacturers was investigated using a watershed particle detection algorithm on laser scanning microscopy (LSM) images of the anode surfaces. The distributions of the particle sizes have then been compared to the capacity loss in plated cells. It was shown that the capacity loss correlates with parameters extracted from the particle size distributions. It is however necessary to create more data to verify this correlation. In summary this thesis utilized new methods to detect or characterize plating on different levels of magnification, from the cell level to the chemical composition. New approaches were found to predict a cells future plating behaviour, spatially localize plated areas on the anode and design cells in a plating resistant way. Lithium Plating ist nicht nur der Alterungsmechanismus in Lithium-Ionen-Batterien mit dem größten Kapazitätsverlust, sondern wird auch im Zuge der voranschreitenden Elektrifizierung des Personenverkehrs immer wichtiger. In Elektrofahrzeugen finden sich die extremen Zustände, wie niedrige Ladetemperaturen und hohe Ladestrome, unter denen Plating auftritt, deutlich häufiger als in Unterhaltungstechnik. Durch die Vielzahl von Parametern, von der Zellgeometrie bis hin zur Elektrolyzusammensetzung, die Plating beeinflussen, fehlt immer noch ein tieferes Verständnis des Plating-Prozesses. Ohne dieses Wissen ist es schwer, Zellen zu designen, die resistent gegen Plating sind oder Zellen unter optimalen Bedingungen zu betreiben um Plating zu minimieren. Das Ziel dieser Arbeit ist es, verschiedene Methoden aufzuzeigen, die die Untersuchung von Plating auf drei verschiedenen Ebenen ermöglichen. Die erste Methode untersucht das Gesamtverhalten der Zelle auf Zellebene. Hierbei wird das atypische Verhalten der Strom- und Spannunsprofile wahrend des Plating-Vorgangs analysiert. Der Fokus liegt dabei auf der Untersuchung der Konstantstrom-Phase bei niedrigen Temperaturen während der Ladung. Das Stromprofil dieser Phase kann mit der JMAK-Funktion gefittet werden, welche die elektrochemische Abscheidung eines Metalls auf einer Oberfläche beschreibt. Die resultierenden Fitting-Parameter können genutzt werden, um das Plating-Verhalten vorherzusagen und sind gleichzeitig eine bessere Abschätzung fur die Menge an geplatetem Lithium im Vergleich zu gängigen Methoden. Die Ergebnisse konnten außerdem helfen das Sicherheitsrisiko der Zelle bei Dendritenbildung vorherzusagen. Im zweiten Teil wird die chemische Zusammensetzung der SEI mittels XPS untersucht. Die Zusammensetzung, wie auch die mechanischen Eigenschaften der SEI, beeinflussen den Plating-Prozess stark und es wurde in vorhergehenden Arbeiten gezeigt, dass Plating auch die Morphologie und Dicke der SEI drastisch verändern kann. Zellen in verschiedenen Zuständen (geplatet, geladen, entladen), sowie Zellen verschiedener Hersteller wurden mit XPS untersucht. Während der Messungen wurde ein ungewollter Nebeneffekt des Messaufbaus entdeckt, der zu einer Migration von Lithium an die Oberflache der Proben geführt und die Messergebnisse verfälscht hat. Unabhängig von diesem Effekt war es dennoch möglich, zu zeigen, dass die SEI in Zellen verschiedener Hersteller stark unterschiedliche Zusammensetzungen haben kann und dass Plating nicht nur die Morphologie der SEI beeinflusst, sondern auch die chemische Zusammensetzung. Weiterhin konnte der ungewollte Nebeneffekt verwendet werden, um Proben zu identifizieren, die vor kurzem geplatet wurden und konnte in zukünftigen Arbeiten verwendet werden, um lokalisiert Lithium-Ablagerungen auf geplateten Proben zu identifizieren. Im letzten Teil wurde die Partikelstruktur der Anoden von Zellen verschiedener Zellhersteller mit Hilfe einer watershed-Partikeldetektion an LSM-Bildern untersucht. Die Verteilung der Partikelgrößen wurde mit dem Kapazitätsverlust gleicher Zelle durch Plating verglichen. Es wurde gezeigt, dass der Kapazitätsverlust mit Parametern, die aus den Partikelverteilungen extrahiert wurden, korreliert. Ein größerer Datensatz ist jedoch notwendig, um diese Ergebnisse zu validieren. Zusammenfassend hat diese Arbeit verschiedene neue Methoden aufgezeigt, um Plating auf verschiedenen Vergrößerungsebenen zu detektieren und zu charakterisieren. Neue Ansätze wurden gefunden, um das Platingverhalten von Zellen vorherzusagen, lokalisiertes Lithium auf der Oberfläche zu detektieren und Zellen platingresistenter designen zu können.

Download or read book Modeling of Lithium Plating in Lithium ion batteries written by and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Simulating Controlling and Understanding Lithium ion Battery Models written by Marc Dylan Berliner and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Novel operating modes (such as constant temperature and lithium plating overpotential) are efficiently simulated using DAEs in PET and other simpler models without deriving analytical solutions. Next, this methodology is applied to PET coupled with an empirical degradation model to simulate long-term cycling behavior using physics-based operating modes. These approaches move beyond conventional constant current- constant voltage (CC-CV) charging protocols and show that degradation-aware protocols using physics-based operating modes such as constant temperature, constant solid-electrolyte interface (SEI) growth rate, and constant State of Health (SOH) rate of decay can charge batteries more quickly than CC-CV while generating equal levels of degradation at similar computational costs. The third and final Part of this thesis applies nonlinear identifiability analyses to the PET model, describing what can and cannot be learned from a combination of model, data, and unknown parameters. The first step theoretically investigates the uniqueness of five diffusion and transport coefficients for a synthetic discharge curve generated from a LiCoO2 battery. Markov chain Monte Carlo (MCMC) shows that only a single parameter, the anodic solid diffusion coefficient, can be uniquely estimated within a 95% confidence interval, signifying that the resistance to lithium flow in the anode is also meaningful and measurable from this model-data combination. Parameter unidentifiabilities can be resolved by incorporating new and different measurements of the system. Next, this methodology is applied to 7776 discharge curves spanning the lifetime of 95 nickel cobalt aluminum oxide (NCA) cells with Si-doped graphite anodes. With PETLION, 1 billion PET simulations for the MCMC analysis can be efficiently computed in about one week. Parameter identifiability trends are observed to change as cells become more degraded. While the anodic solid diffusion coefficient began as the only identifiable parameter for pristine cells, the cathodic solid diffusion coefficient and anodic rate constant (and their resistances) became identifiable as the cells degrade. Simple fitted relationships for the parameters are proposed as a function of discharge capacity which may be implemented in hybridized battery models to simulate capacity fade.

Download or read book Modeling of Lithium Plating in Lithium ion batteries written by Smon Hein and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Mathematical Modeling of Lithium Ion Batteries and Cells written by V. Subramanian and published by The Electrochemical Society. This book was released on 2012 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Capacity Fade Analysis and Model Based Optimization of Lithium ion Batteries written by Venkatasailanathan Ramadesigan and published by . This book was released on 2013 with total page 153 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical power sources have had significant improvements in design, economy, and operating range and are expected to play a vital role in the future in a wide range of applications. The lithium-ion battery is an ideal candidate for a wide variety of applications due to its high energy/power density and operating voltage. Some limitations of existing lithium-ion battery technology include underutilization, stress-induced material damage, capacity fade, and the potential for thermal runaway. This dissertation contributes to the efforts in the modeling, simulation and optimization of lithium-ion batteries and their use in the design of better batteries for the future. While physics-based models have been widely developed and studied for these systems, the rigorous models have not been employed for parameter estimation or dynamic optimization of operating conditions. The first chapter discusses a systems engineering based approach to illustrate different critical issues possible ways to overcome them using modeling, simulation and optimization of lithium-ion batteries. The chapters 2-5, explain some of these ways to facilitate (i) capacity fade analysis of Li-ion batteries using different approaches for modeling capacity fade in lithium-ion batteries, (ii) model based optimal design in Li-ion batteries and (iii) optimum operating conditions (current profile) for lithium-ion batteries based on dynamic optimization techniques. The major outcomes of this thesis will be, (i) comparison of different types of modeling efforts that will help predict and understand capacity fade in lithium-ion batteries that will help design better batteries for the future, (ii) a methodology for the optimal design of next-generation porous electrodes for lithium-ion batteries, with spatially graded porosity distributions with improved energy efficiency and battery lifetime and (iii) optimized operating conditions of batteries for high energy and utilization efficiency, safer operation without thermal runaway and longer life.

Download or read book Lithium ion Batteries written by Perla B. Balbuena and published by World Scientific. This book was released on 2004 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electromechanical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.

Download or read book Physical Multiscale Modeling and Numerical Simulation of Electrochemical Devices for Energy Conversion and Storage written by Alejandro A. Franco and published by Springer. This book was released on 2015-11-12 with total page 253 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to review innovative physical multiscale modeling methods which numerically simulate the structure and properties of electrochemical devices for energy storage and conversion. Written by world-class experts in the field, it revisits concepts, methodologies and approaches connecting ab initio with micro-, meso- and macro-scale modeling of components and cells. It also discusses the major scientific challenges of this field, such as that of lithium-ion batteries. This book demonstrates how fuel cells and batteries can be brought together to take advantage of well-established multi-scale physical modeling methodologies to advance research in this area. This book also highlights promising capabilities of such approaches for inexpensive virtual experimentation. In recent years, electrochemical systems such as polymer electrolyte membrane fuel cells, solid oxide fuel cells, water electrolyzers, lithium-ion batteries and supercapacitors have attracted much attention due to their potential for clean energy conversion and as storage devices. This has resulted in tremendous technological progress, such as the development of new electrolytes and new engineering designs of electrode structures. However, these technologies do not yet possess all the necessary characteristics, especially in terms of cost and durability, to compete within the most attractive markets. Physical multiscale modeling approaches bridge the gap between materials’ atomistic and structural properties and the macroscopic behavior of a device. They play a crucial role in optimizing the materials and operation in real-life conditions, thereby enabling enhanced cell performance and durability at a reduced cost. This book provides a valuable resource for researchers, engineers and students interested in physical modelling, numerical simulation, electrochemistry and theoretical chemistry.

Download or read book Enabling Fast Charging in Lithium ion Batteries written by Srishti Mittal and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis presents a novel method for onboard detection of lithium plating in lithium-ion batteries by combining machine learning (ML) techniques with differential pressure sensing. The study aims to address the challenge of lithium plating, which can lead to capacity fade and cell failure, particularly during fast charging. By measuring the pressure changes during charging and discharging, differential pressure (dP/dQ) can serve as a binary classifier for lithium plating detection. While such detection methods are limited by their invasiveness or specialized equipment requirements, we can overcome these limitations through the proposed approach that utilizes ML models to predict the differential pressure (dP/dQ) signal associated with lithium plating. The best regression model achieved an accuracy of 97.75% on the test set, providing an accurate means of calculating dP/dQ without the need for load cells or external pressure sensors. The study also analyzes the feature importance of the model, revealing key factors influencing the prediction, such as cycling protocol, phase transitions, and battery health. Although further refinement is needed, this research offers a promising avenue for real-time lithium plating detection in LIBs, facilitating safer and more efficient battery management.

Download or read book The Handbook of Lithium Ion Battery Pack Design written by John T. Warner and published by Elsevier. This book was released on 2024-05-14 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Lithium-Ion Battery Pack Design: Chemistry, Components, Types and Terminology,?Second Edition provides a clear and concise explanation of EV and Li-ion batteries for readers that are new to the field. The second edition expands and updates all topics covered in the original book, adding more details to all existing chapters and including major updates to align with all of the rapid changes the industry has experienced over the past few years. This handbook offers a layman's explanation of the history of vehicle electrification and battery technology, describing the various terminology and acronyms and explaining how to do simple calculations that can be used in determining basic battery sizing, capacity, voltage, and energy. By the end of this book the reader will have a solid understanding of the terminology around Li-ion batteries and be able to undertake simple battery calculations. The book is immensely useful to beginning and experienced engineers alike who are moving into the battery field. Li-ion batteries are one of the most unique systems in automobiles today in that they combine multiple engineering disciplines, yet most engineering programs focus on only a single engineering field. This book provides the reader with a reference to the history, terminology and design criteria needed to understand the Li-ion battery and to successfully lay out a new battery concept. Whether you are an electrical engineer, a mechanical engineer or a chemist, this book will help you better appreciate the inter-relationships between the various battery engineering fields that are required to understand the battery as an Energy Storage System. It gives great insights for readers ranging from engineers to sales, marketing, management, leadership, investors, and government officials. - Adds a brief history of battery technology and its evolution to current technologies? - Expands and updates the chemistry to include the latest types - Discusses thermal runaway and cascading failure mitigation technologies? - Expands and updates the descriptions of the battery module and pack components and systems?? - Adds description of the manufacturing processes for cells, modules, and packs? - Introduces and discusses new topics such as battery-as-a-service, cell to pack and cell to chassis designs, and wireless BMS?

Download or read book Advances in Lithium Ion Batteries written by Walter van Schalkwijk and published by Springer Science & Business Media. This book was released on 2007-05-08 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the decade since the introduction of the first commercial lithium-ion battery research and development on virtually every aspect of the chemistry and engineering of these systems has proceeded at unprecedented levels. This book is a snapshot of the state-of-the-art and where the work is going in the near future. The book is intended not only for researchers, but also for engineers and users of lithium-ion batteries which are found in virtually every type of portable electronic product.

Download or read book Battery Management Systems written by Gregory L. Plett and published by Artech House Publishers. This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: State-Of-The-Art applications of equivalent-circuit methods as they pertain to solving problems in battery management and control.

Download or read book Batteries for Sustainability written by Ralph J. Brodd and published by Springer Science & Business Media. This book was released on 2012-12-12 with total page 513 pages. Available in PDF, EPUB and Kindle. Book excerpt: Batteries that can store electricity from solar and wind generation farms are a key component of a sustainable energy strategy. Featuring 15 peer-reviewed entries from the Encyclopedia of Sustainability Science and Technology, this book presents a wide range of battery types and components, from nanocarbons for supercapacitors to lead acid battery systems and technology. Worldwide experts provides a snapshot-in-time of the state-of-the art in battery-related R&D, with a particular focus on rechargeable batteries. Such batteries can store electrical energy generated by renewable energy sources such as solar, wind, and hydropower installations with high efficiency and release it on demand. They are efficient, non-polluting, self-contained devices, and their components can be recovered and used to recreate battery systems. Coverage also highlights the significant efforts currently underway to adapt battery technology to power cars, trucks and buses in order to eliminate pollution from petroleum combustion. Written for an audience of undergraduate and graduate students, researchers, and industry experts, Batteries for Sustainability is an invaluable one-stop reference to this essential area of energy technology.