Download or read book Modeling Carbon Dioxide Capture by Monoethanolamine Solvent with ASPEN Plus written by Tianyi Luo and published by . This book was released on 2010 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt: On the other hand, the cost of CO2 capture (and sequestration) could be reduced by limiting size of the Absorber column and operating pressure.

Download or read book CO2 Capture by Reactive Absorption Stripping written by Claudio Madeddu and published by Springer. This book was released on 2018-12-15 with total page 93 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on modelling issues and their implications for the correct design of reactive absorption–desorption systems. In addition, it addresses the case of carbon dioxide (CO2) post-combustion capture in detail. The book proposes a new perspective on these systems, and provides technological solutions with comparisons to previous treatments of the subject. The model that is proposed is subsequently validated using experimental data. In addition, the book features graphs to guide readers with immediate visualizations of the benefits of the methodology proposed. It shows a systematic procedure for the steady-state model-based design of a CO2 post-combustion capture plant that employs reactive absorption-stripping, using monoethanolamine as the solvent. It also discusses the minimization of energy consumption, both through the modification of the plant flowsheet and the set-up of the operating parameters. The book offers a unique source of information for researchers and practitioners alike, as it also includes an economic analysis of the complete plant. Further, it will be of interest to all academics and students whose work involves reactive absorption-stripping design and the modelling of reactive absorption-stripping systems.

Download or read book Process Intensification written by David Reay and published by Butterworth-Heinemann. This book was released on 2013-06-05 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: Process Intensification: Engineering for Efficiency, Sustainability and Flexibility is the first book to provide a practical working guide to understanding process intensification (PI) and developing successful PI solutions and applications in chemical process, civil, environmental, energy, pharmaceutical, biological, and biochemical systems. Process intensification is a chemical and process design approach that leads to substantially smaller, cleaner, safer, and more energy efficient process technology. It improves process flexibility, product quality, speed to market and inherent safety, with a reduced environmental footprint. This book represents a valuable resource for engineers working with leading-edge process technologies, and those involved research and development of chemical, process, environmental, pharmaceutical, and bioscience systems. - No other reference covers both the technology and application of PI, addressing fundamentals, industry applications, and including a development and implementation guide - Covers hot and high growth topics, including emission prevention, sustainable design, and pinch analysis - World-class authors: Colin Ramshaw pioneered PI at ICI and is widely credited as the father of the technology

Download or read book Carbon Dioxide Capture by Chemical Absorption written by Anusha Kothandaraman and published by . This book was released on 2010 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the light of increasing fears about climate change, greenhouse gas mitigation technologies have assumed growing importance. In the United States, energy related CO2 emissions accounted for 98% of the total emissions in 2007 with electricity generation accounting for 40% of the total'. Carbon capture and sequestration (CCS) is one of the options that can enable the utilization of fossil fuels with lower CO2 emissions. Of the different technologies for CO2 capture, capture of CO2 by chemical absorption is the technology that is closest to commercialization. While a number of different solvents for use in chemical absorption of CO2 have been proposed, a systematic comparison of performance of different solvents has not been performed and claims on the performance of different solvents vary widely. This thesis focuses on developing a consistent framework for an objective comparison of the performance of different solvents. This framework has been applied to evaluate the performance of three different solvents - monoethanolamine, potassium carbonate and chilled ammonia. In this thesis, comprehensive flow-sheet models have been built for each of the solvent systems, using ASPEN Plus as the modeling tool. In order to ensure an objective and consistent comparison of the performance of different solvent systems, the representation of physical properties, thermodynamics and kinetics had to be verified and corrected as required in ASPEN Plus. The ASPEN RateSep module was used to facilitate the computation of mass transfer characteristics of the system for sizing calculations. For each solvent system, many parametric simulations were performed to identify the effect on energy consumption in the system. The overall energy consumption in the CO2 capture and compression system was calculated and an evaluation of the required equipment size for critical equipment in the system was performed. The degradation characteristics and environmental impact of the solvents were also investigated. In addition, different flow-sheet configurations were explored to optimize the energy recuperation for each system. Monoethanolamine (MEA) was evaluated as the base case system in this thesis. Simulations showed the energy penalty for CO2 capture from flue gas from coal-fired power plants to be 0.01572 kWh/gmol CO2 . The energy penalty from CO2 regeneration accounted for 60% of the energy penalty while the compression work accounted for 30%. The process flexibility in the MEA system was limited by degradation reactions. It was found that different flow-sheet configurations for energy recuperation in the MEA system did not improve energy efficiency significantly. Chilled ammonia was explored as an alternative to MEA for use in new coal-fired power plants as well as for retrofitting existing power plants. The overall energy penalty for CO2 capture in chilled ammonia was found to be higher than in the MEA system, though energy requirements for CO2 regeneration were found to be lower. The energy penalty for 85% capture of CO2 in the chilled ammonia system was estimated to be 0.021 kWh/gmol CO2. As compared to the MEA system, the breakdown of the energy requirements was different with refrigeration in the absorber accounting for 44% of the energy penalty. This illustrates the need to perform a systemwide comparison of different solvents in order to evaluate the performance of various solvent systems. The use of potassium carbonate as a solvent for CO2 capture was evaluated for use in Integrated Reforming Combined Cycle (IRCC) system. With potassium carbonate, a high partial pressure of CO2 in the flue gas is required. Different schemes for energy recuperation in the system were investigated and the energy consumption was reduced by 22% over the base case. An optimized version of the potassium carbonate flowsheet was developed for an IRCC application with a reboiler duty of 1980 kJ/kg. In conclusion, a framework for the comparison of the performance of different solvents for CO2 capture has been developed and the performance of monoethanolamine, chilled ammonia and potassium carbonate has been compared. From the standpoint of energy consumption, for existing power plants the use of MEA is found to be the best choice while for future design of power plants, potassium carbonate appears to be an attractive alternative. An economic analysis based on the technical findings in this thesis will help in identifying the optimal choices for various large, stationary sources of CO2.

Download or read book Carbon Capture and Storage written by Mai Bui and published by Royal Society of Chemistry. This book was released on 2019-11-29 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book will provide the latest global perspective on the role and value of carbon capture and storage (CCS) in delivering temperature targets and reducing the impact of global warming. As well as providing a comprehensive, up-to-date overview of the major sources of carbon dioxide emission and negative emissions technologies, the book also discusses technical, economic and political issues associated with CCS along with strategies to enable commercialisation.

Download or read book Modeling of Carbon Dioxide Absorption Using Aqueous Monoethanolamine Piperazine and Promoted Potassium Carbonate written by Jorge Mario Plaza and published by . This book was released on 2012 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rigorous CO2 absorption models were developed for aqueous 4.5 m K+/4.5 m PZ, monoethanolamine (7m - 9m), and piperazine (8m) in Aspen Plus® RateSepTM. The 4.5 m K+/4.5 m PZ model uses the Hilliard thermodynamic representation and kinetics based on work by Chen. The MEA (Phoenix) and PZ (5deMayo) models incorporate new data for partial pressure of CO2 vs. loading and kinetics from wetted wall column data. They use reduced reaction sets based on the more relevant species present at the expected operating loading. Kinetics were regressed to match reported carbon dioxide flux data using a wetted wall column (WWC). Density and viscosity were satisfactorily regressed to match newly obtained experimental data. The activity coefficient of CO2 was also regressed to include newly obtained CO2 solvent solubility data. The models were reconciled and validated using pilot plant data obtained from five campaigns conducted at the Pickle Research Center. Performance was matched within 10% of NTU for most runs. Temperature profiles are adequately represented in all campaigns. The calculated temperature profiles showed the effect of the L/G on the location and magnitude of the temperature bulge. As the L/G is increased the temperature bulge moves from near the top of the column towards the bottom and its magnitude decreases. Performance improvement due to intercooling was validated across the campaigns that evaluated this process option. Absorber intercooling was studied using various solvent rates (Lmin, 1.1 Lmin and 1.2 Lmin). It is most effective at the critical L/G where the temperature bulge without intercooling is in the middle of the column. In this case it will allow for higher absorption by reducing the magnitude of the bulge temperature. The volume of packing to get 90% removal with L/Lmin =1.1 at the critical L/G is reduced by 30% for 8m PZ. For MEA and a solvent flow rate of 1.1 Lmin packing volume is increased with intercooling at constant L/G. This increase is compensated by higher solvent loadings that suggest lower stripping energy requirements. The critical L/G is 4.3 for 8m PZ, 6.9 for 9m MEA and 4.1 for K+/PZ.

Download or read book Packed Tower Design and Applications written by Ralph F. Strigle and published by Butterworth-Heinemann. This book was released on 1994 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Energy Efficient Solvents for CO2 Capture by Gas Liquid Absorption written by Wojciech M. Budzianowski and published by Springer. This book was released on 2016-12-01 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.

Download or read book 23rd European Symposium on Computer Aided Process Engineering written by and published by Elsevier. This book was released on 2013-06-10 with total page 1085 pages. Available in PDF, EPUB and Kindle. Book excerpt: Computer-aided process engineering (CAPE) plays a key design and operations role in the process industries, from the molecular scale through managing complex manufacturing sites. The research interests cover a wide range of interdisciplinary problems related to the current needs of society and industry. ESCAPE 23 brings together researchers and practitioners of computer-aided process engineering interested in modeling, simulation and optimization, synthesis and design, automation and control, and education. The proceedings present and evaluate emerging as well as established research methods and concepts, as well as industrial case studies. - Contributions from the international community using computer-based methods in process engineering - Reviews the latest developments in process systems engineering - Emphasis on industrial and societal challenges

Download or read book Gas Purification written by Arthur L. Kohl and published by Butterworth-Heinemann. This book was released on 1985 with total page 918 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book ASPEN Plus Simulation of CO2 Recovery Process written by and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: ASPEN Plus simulations have been created for a CO2 capture process based on adsorption by monoethanolamine (MEA). Three separate simulations were developed, one each for the flue gas scrubbing, recovery, and purification sections of the process. Although intended to work together, each simulation can be used and executed independently. The simulations were designed as template simulations to be added as a component to other more complex simulations. Applications involving simple cycle or hybrid power production processes were targeted. The default block parameters were developed based on a feed stream of raw flue gas of approximately 14 volume percent CO2 with a 90% recovery of the CO2 as liquid. This report presents detailed descriptions of the process sections as well as technical documentation for the ASPEN simulations including the design basis, models employed, key assumptions, design parameters, convergence algorithms, and calculated outputs.

Download or read book Greenhouse Gas Control Technologies written by B. Eliasson and published by Elsevier. This book was released on 1999-05-20 with total page 1225 pages. Available in PDF, EPUB and Kindle. Book excerpt: These proceedings contain 270 papers outlining ideas and contributions to the new scientific, technical and political discipline of Greenhouse Gas (GHG) Control. The contributions were presented at the 4th International Conference on Greenhouse Gas Control Technologies (GHGT-4). It was the largest gathering of experts active in this new and fast-developing field.GHGT-4 was different from its predecessors in that it included all greenhouse gases, not only CO2, and all issues which could contribute to the mitigation of the greenhouse problem - technical, economic and political. The main focus was on practical solutions and real demonstrations of mitigation technology being planned and implemented today. It also addressed ways to increase the efficiency of power production and utilisation, and looked at proposals to encourage the development of renewable energy sources.During the Opening Session, 10 keynote addresses were heard from prominent personalities in government, industry and academia. To tackle this very inter-disciplinary problem and to achieve acceptable solutions, it is essential for industry and government to initiate intense dialogue and cooperation. Conferences like this can provide the opportunity for a meeting of minds between engineers and politicians in the face of global challenge. The primary attributes of this global challenge are manifold: the problem is global and international; it is inter-disciplinary, both in substance and approach; it covers technical, political and economic issues and involves government, science, industry and academia; it is complex and non-linear; and it will take the efforts of all parties involved to solve the problem.These proceedings contain ideas for starting demonstration projects and for making better use of the power and flexibility of market measures. They also show it is a problem we can influence and that there is a wealth of ideas. The challenge now is to find the right partners to put these ideas into action.

Download or read book Absorption Based Post Combustion Capture of Carbon Dioxide written by Paul Feron and published by Woodhead Publishing. This book was released on 2016-05-27 with total page 816 pages. Available in PDF, EPUB and Kindle. Book excerpt: Absorption-Based Post-Combustion Capture of Carbon Dioxide provides a comprehensive and authoritative review of the use of absorbents for post-combustion capture of carbon dioxide. As fossil fuel-based power generation technologies are likely to remain key in the future, at least in the short- and medium-term, carbon capture and storage will be a critical greenhouse gas reduction technique. Post-combustion capture involves the removal of carbon dioxide from flue gases after fuel combustion, meaning that carbon dioxide can then be compressed and cooled to form a safely transportable liquid that can be stored underground. - Provides researchers in academia and industry with an authoritative overview of the amine-based methods for carbon dioxide capture from flue gases and related processes - Editors and contributors are well known experts in the field - Presents the first book on this specific topic

Download or read book Advanced CO2 Capture Technologies written by Shin-ichi Nakao and published by Springer. This book was released on 2019-05-07 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarises the advanced CO2 capture technologies that can be used to reduce greenhouse gas emissions, especially those from large-scale sources, such as power-generation and steel-making plants. Focusing on the fundamental chemistry and chemical processes, as well as advanced technologies, including absorption and adsorption, it also discusses other aspects of the major CO2 capture methods: membrane separation; the basic chemistry and process for CO2 capture; the development of materials and processes; and practical applications, based on the authors’ R&D experience. This book serves as a valuable reference resource for researchers, teachers and students interested in CO2 problems, providing essential information on how to capture CO2 from various types of gases efficiently. It is also of interest to practitioners and academics, as it discusses the performance of the latest technologies applied in large-scale emission sources.

Download or read book Process Systems and Materials for CO2 Capture written by Athanasios I. Papadopoulos and published by John Wiley & Sons. This book was released on 2017-05-01 with total page 686 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive volume brings together an extensive collection of systematic computer-aided tools and methods developed in recent years for CO2 capture applications, and presents a structured and organized account of works from internationally acknowledged scientists and engineers, through: Modeling of materials and processes based on chemical and physical principles Design of materials and processes based on systematic optimization methods Utilization of advanced control and integration methods in process and plant-wide operations The tools and methods described are illustrated through case studies on materials such as solvents, adsorbents, and membranes, and on processes such as absorption / desorption, pressure and vacuum swing adsorption, membranes, oxycombustion, solid looping, etc. Process Systems and Materials for CO2 Capture: Modelling, Design, Control and Integration should become the essential introductory resource for researchers and industrial practitioners in the field of CO2 capture technology who wish to explore developments in computer-aided tools and methods. In addition, it aims to introduce CO2 capture technologies to process systems engineers working in the development of general computational tools and methods by highlighting opportunities for new developments to address the needs and challenges in CO2 capture technologies.

Download or read book Pilot Plant Study of Carbon Dioxide Capture by Aqueous Monoethanolamine written by Ross Edward Dugas and published by . This book was released on 2006 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work serves as a baseline for CO2 capture using monoethanolamine (MEA). MEA is an appropriate choice for a baseline study since it is the most mature and common solvent for CO2 capture from coal fired power plants. This work serves as a comparison to the piperazine/potassium carbonate solvent currently being tested by the Rochelle research group, as well as any future solvents that may be tested. A close-looped absorption/stripping pilot plant with 42.7 cm ID columns was used to capture CO2 using an 32.5 wt% aqueous MEA solution. Both the absorber and stripper contained 20 ft of packing. The pilot plant campaign consisted of 48 runs at 24 operating conditions over a period of about one month. Various packings, lean CO2 loadings, gas and liquid rates, and stripper pressures were tested. The CO2 material and heat balances converged within 6.5 and 6.9%, respectively. The temperature bulge for the absorber ranged from 2-45°C. The bulge was located at the top of the absorber with L/G less than 5 kg/kg and at the bottom of the absorber with L/G greater than 6 kg/kg. Flexipac 1Y, a structured metal packing, achieved approximately 1.5-2 times more mass transfer than IMTP #40, a random metal packing, due an increased wetted area. The calculated K[subscript G] for Flexipac 1Y and IMTP #40 matched values showed similar trends to data previously in a wetted wall column. The MEA/Flexipac 1Y data had mass transfer coefficients similar to those obtained using Flexipac 1Y with the potassium carbonate/piperazine, but operated at significantly lower partial pressures. Measured heat duties for the pilot plant ranged from 369 to 1690 MJ/hr. These reboiler duties were especially high due to a lack of adequate preheat before the stripper. Vacuum stripping at 69 kPa was performed successfully without operational difficulties. Some of the pilot plant data was modeled in Aspen Plus using a RateFrac model previously created by Freguia (2002). Both absorber and stripper conditions were simulated. Results from absorber conditions using IMTP #40 were fairly close to the actual pilot plant. Absorber conditions with Flexipac 1Y predicted higher required packing heights to obtain the measured results. Stripper simulations were ineffective due to the limitations of the model. Reactions in the stripper are calculated as instantaneous reactions contrary to the rate based reactions in the absorber

Download or read book Recent Advances in Carbon Capture and Storage written by Yongseung Yun and published by BoD – Books on Demand. This book was released on 2017-03-08 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon capture and storage (CCS) has been considered as a practical way in sequestering the huge anthropogenic CO2 amount with a reasonable cost until a more pragmatic solution appears. The CCS can work as a bridge before fulfilling the no-CO2 era of the future by applying to large-scale CO2 emitting facilities. But CCS appears to lose some passion by the lack of progress in technical developments and in commercial success stories other than EOR. This is the time to go back to basics, starting from finding a solution in small steps. The CCS technology desperately needs far newer ideas and breakthroughs that can overcome earlier attempts through improving, modifying, and switching the known principles. This book tries to give some insight into developing an urgently needed technical breakthrough through the recent advances in CCS research, in addition to the available small steps like soil carbon sequestration. This book provides the fundamental and practical information for researchers and graduate students who want to review the current technical status and to bring in new ideas to the conventional CCS technologies.