Download or read book Model Cellulosic Surfaces written by Maren Roman and published by OUP USA. This book was released on 2010-04-08 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an overview of the different methods of model cellulosic surface preparation and presents recent studies on the properties of these surfaces. The topics covered are considered relatively new and would serve as the launch pad for further research in this area.

Download or read book Novel Oil Resistant Cellulosic Materials written by Christian Aulin and published by . This book was released on 2009 with total page 55 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this study has been to prepare and characterise oil resistant cellulosic materials, ranging from model surfaces to papers and aerogels. The cellulosic materials were made oil resistant by chemical and topographic modifications, based on surface energy, surface roughness and barrier approaches. Detailed wetting studies of the prepared cellulosic materials were made using contact angle measurements and standardised penetration tests with different alkanes and oil mixtures. A significant part of the activities were devoted to the development of model cellulosic surfaces with different degrees of crystalline ordering for the wetting studies. Crystalline cellulose I, II and amorphous cellulose surfaces were prepared by spin-coating of cellulose nanocrystal or microfibrillated cellulose (MFC) dispersions, with Langmuir-Schaefer (LS) films or by a layer-by-layer (LbL) deposition technique. The formation of multilayers consisting of polyethyleneimine (PEI)/anionic MFC or cationic MFC/anionic MFC was further studied and optimized in terms of total layer thickness and adsorbed amount by combining Dual Polarization Interferometry (DPI) or Stagnation Point Adsorption Reflectrometry (SPAR) with a Quartz Crystal Microbalance with Dissipation (QCM-D). The smooth cellulosic surfaces prepared had different molecular and mesostructure properties and different surface energies as shown by X-ray diffraction, Atomic Force Microscopy (AFM) imaging, ellipsometry measurements and contact angle measurements. The cellulose model surfaces were found to be ideal for detailed wetting studies, and after the surface has been coated or covalently modified with various amounts of fluorosurfactants, the fluorinated cellulose films were used to follow the spreading mechanisms of different oil mixtures. The viscosity and surface tension of the oil mixtures, as we ll as the dispersive surface energy of the cellulose surfaces, were found to be essential parameters governing the spreading kinetics. A strong correlation was found between the surface concentration of fluorine, the dispersive surface energy and the measured contact angle of the oil mixtures. Silicon surfaces possessing structural porous characteristics were fabricated by a plasma etching process. The structured silicon surfaces were coated with sulfate-stabilized cellulose I nanocrystals using the LbL technique. These artificial intrinsically oleophilic cellulose surfaces were made highly oleophobic when coated with a thin layer of fluorinated silanes. By comparison with flat cellulose surfaces, which are oleophilic, it is demonstrated that the surface energy and the surface texture are essential factors preventing oil from spreading on the surface and, thus, inducing the observed macroscopic oleophobic properties. The use of the MFC for surface coating on base papers demonstrated very promising characteristics as packaging materials. Environmental-Scanning Electron Microscopy (E-SEM) micrographs indicated that the MFC layer reduced the sheet porosity, i.e. the dense structure formed by the nanofibers resulted in superior oil barrier properties. Attempts were made to link the procedure for preparation of the MFC dispersions to the resulting microstructure of the coatings, and film porosity and the film moisture content to the resulting permeability properties. Finally, MFC aerogels were successfully prepared by freeze-drying. The surface texture of the porous aerogels was carefully controlled by adjusting the concentration of the MFC dispersion used for the freeze-drying. The different scales of roughness of the MFC aerogels were utilised, together with the very low surface energy created by fluorination of the aerogel, to induce highly oleophobic properties.

Download or read book Interactions of Cellulose and Model Surfaces written by Johanna Stiernstedt and published by . This book was released on 2006 with total page 58 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Surface Chemistry of Cellulose written by Eero Jaakko Kontturi and published by . This book was released on 2005 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Cellulose Model Surfaces Studied by Femtosecond Sum Frequency Spectroscopy written by Li Lei and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Cellulose Derivatives written by Thomas Heinze and published by Springer. This book was released on 2018-02-12 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarizes recent progress in cellulose chemistry. The last 10 years have witnessed important developments, because sustainability is a major concern. Biodegradable cellulose derivatives, in particular esters and ethers, are employed on a large scale. The recent developments in cellulose chemistry include unconventional methods for the synthesis of derivatives, introduction of novel solvents, e.g. ionic liquids, novel approaches to regioselective derivatization of cellulose, preparation of nano-particles and nano-composites for specific applications. These new developments are discussed comprehensively. This book is aimed at researchers and professionals working on cellulose and its derivatives. It fills an important gap in teaching, because most organic chemistry textbooks concentrate on the relatively simple chemistry of mono- and disaccharides. The chemistry and, more importantly, the applications of cellulose are only concisely mentioned.

Download or read book Tailoring Adhesion and Wetting Properties of Cellulose Fibers and Model Surfaces written by Emil Gustafsson and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The layer-by-layer (LbL) technique was used to modify the surface of cellulose fibers by consecutive adsorption of poly(allylamine hydrochloride) (PAH) and poly(acrylic acid) (PAA) followed by a final adsorbed layer of anionic paraffin wax colloids. Paper hand sheets made from the modified fibers were found to be highly hydrophobic with a contact angle of 150°. In addition to the significantly increased hydrophobicity, the sheets showed improved mechanical properties, such as a higher tensile strength. Heat treatment of the prepared sheets further enhanced both the mechanical properties and the hydrophobicity. These results demonstrate the flexibility and robustness of the LbL technique, which allows us to combine the known adhesive effect of PAH/PAA LbL films with the functionality of wax nanoparticles, creating a stronger and highly hydrophobic paper.It was further observed that LbL modified sheets without wax also displayed increased hydrophobicity when heat treated. The mechanism was studied through model experiments where LbL films of PAH/PAA were assembled on flat non-porous model cellulose surfaces. Contact angle measurements showed the same trend due to heat treatment of the model films, although, the absolute value of the contact angles were smaller. Analysis using the highly interfacial sensitive vibrational sum frequency spectroscopy technique showed an enrichment of CH3 groups (from the polymer chain ends) at the solid/air interface. These results indicate that during the heat treatment, a reorientation of polymer chains occurs to minimize the surface energy of the LbL film.In the second part of this work, the adhesive interactions between the main constituents of wood fibers were studied using high-resolution measuring techniques and well-defined model films of cellulose, hemicellulose and lignin. Successful surface modification of polydimethylsiloxane (PDMS) caps, needed in the Johnson-Kendall-Roberts (JKR) measuring methodology, by LbL deposition of nanofibrillated cellulose (NFC) and poly(ethylene imine) (PEI) allowed for the first known all-wood biopolymer JKR measurements of the adhesion between cellulose/cellulose, cellulose/lignin and the cellulose/glucomannan surfaces. The work of adhesion on loading and the adhesion hysteresis were similar for all three systems, suggesting that adhesion between the different wood biopolymers does not differ greatly.

Download or read book Cellulosic Pulps Fibres and Materials written by J F Kennedy and published by Elsevier. This book was released on 2001-10-31 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on the proceedings of the 10th international Cellucon Conference held in Turku/Abo, Finland, this book offers a comprehensive overview of research undertaken in all aspects of cellulosic pulps, fibes and materials including the production and processing of pulp and paper fibre.

Download or read book Cellulose Science and Technology written by Thomas Rosenau and published by John Wiley & Sons. This book was released on 2018-11-30 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses both classic concepts and state-of-the-art technologies surrounding cellulose science and technology. Integrating nanoscience and applications in materials, energy, biotechnology, and more, the book appeals broadly to students and researchers in chemistry, materials, energy, and environmental science. • Includes contributions from leading cellulose scientists worldwide, with five Anselm Payen Cellulose Award winners and two Hayashi Jisuke Cellulose Award winners • Deals with a highly applicable and timely topic, considering the current activities in the fields of bioeconomies, biorefineries, and biomass utilization • Maximizes readership by combining fundamental science and application development

Download or read book Cellulose Chemistry and Properties Fibers Nanocelluloses and Advanced Materials written by Orlando J. Rojas and published by Springer. This book was released on 2016-02-25 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vincent Bulone et al.: Cellulose sources and new understanding of synthesis in plants Thomas Heinze et al.:Cellulose structure and properties Thomas Rosenau, Antje Potthast, Ute Henniges et al.: Recent developments in cellulose aging (degradation / yellowing / chromophore formation) Sunkyu Park et al.:Cellulose crystallinity Lina Zhang et al.:Gelation and dissolution behavior of cellulose Yoshiyuki Nishio et al.:Cellulose and derivatives in liquid crystals Alessandro Gandini, Naceur Belgacem et al.:The surface and in-depth modification of cellulose fibers Emily D. Cranston et al.:Interfacial properties of cellulose Herbert Sixta, Michael Hummel et al.Cellulose Fibers Regenerated from Cellulose Solutions in Ionic Liquids Qi Zhou et al.:Cellulose-based biocomposites Orlando Rojas et al.:Films of cellulose nanocrystals and nanofibrils Pedro Fardim et al.:Functional cellulose particles Wadood Hamad et al.:Cellulose Composites

Download or read book A Study of Flame Spread Over Cellulosic Surfaces written by James Boothroyd Stott and published by . This book was released on 1949 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Nanomaterials and Nanocomposites written by Visakh P. M. and published by John Wiley & Sons. This book was released on 2016-06-27 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials are defined as materials in which at least one length dimension is below 100 nanometers. In this size regime, these materials exhibit particular - and tunable - optical, electrical or mechanical properties that are not present at the macro-scale. This opens up the possibility for a plethora of applications at the interface of materials, chemistry, physics and biology, many of which have already entered the commercial realm. When nanomaterials are blended with other materials not necessarily in the nanometer regime, the resulting nanocomposites can exhibit dramatically different properties than the bulk material alone, leading to an enhanced performance in terms of, for example, increased thermal and mechanical stability. This book presents the synthesis, characterization and applications of nanomaterials and nanocomposites, covering zero-dimensional, elemental nanoparticles, one-dimensional materials such as nanorods and nanowhiskers, two-dimensional materials such as graphene and boron nitride as well as three-dimensional materials such as fullerenes, polyhedral oligomers and zeolites, complemented by bio-based nanomaterials, e.g., cellulose, chitin, starch and proteins. Introductory chapters on the state-of-the-art of nanomaterial research and the chemistry and physics in nanoscience and nanotechnology round off the book.

Download or read book Superhydrophobic Cellulose Surfaces written by Oskar Werner and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Production and Applications of Cellulose Nanomaterials written by Robert J. Moon and published by . This book was released on 2013 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book National Research Initiative Competitive Grants Program written by and published by . This book was released on 1995 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Multifunctional Polymeric Nanocomposites Based on Cellulosic Reinforcements written by Debora Puglia and published by William Andrew. This book was released on 2016-07-11 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: Multifunctional Polymeric Nanocomposites Based on Cellulosic Reinforcements introduces the innovative applications of polymeric materials based on nanocellulose, and covers extraction methods, functionalization approaches, and assembly methods to enable these applications. The book presents the state-of-the-art of this novel nano-filler and how it enables new applications in many different sectors, beyond existing products. With a focus on application of nano-cellulose based polymers with multifunctional activity, the book explains the methodology of nano-cellulose extraction and production and shows the potential performance benefits of these particular nanostructured polymers, for applications across different sectors, including food active packaging, energy-photovoltaics, biomedical, and filtration. The book describes how the different methodologies, functionalization, and organization at the nano-scale level could contribute to the design of required properties at macro level. The book studies the interactions between the main nano-filler with other active systems and how this interaction enables multi-functionality in the produced materials. The book is an indispensable resource for the growing number of scientists and engineers interested in the preparation and novel applications of nano-cellulose, and for industrial scientists active in formulation and fabrication of polymer products based on renewable resources. Provides insight into nanostructure formation science, and processing of polymeric materials and their characterization Offers a strong analysis of real industry needs for designing the materials Provides a well-balanced structure, including a light introduction of basic knowledge on extraction methods, functionalization approaches, and assembling focused to applications Describes how different methodologies, functionalization, and organization at the nano-scale level could contribute to the design of required properties at macro level

Download or read book Surface Properties of Non conventional Cellulose Fibres written by Majda Sfiligoj Smole and published by Springer. This book was released on 2019-02-15 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors describe how sustainable textile fibers from crops such as quinoa, grass, hops, corn and wheat stems, etc. have recently begun to generate great interest. The structure-property relationships of such non-conventional cellulose fibers are studied in this brief, as are their sorption and surface properties which are of primary importance. A systematic review of each fiber's properties is given, the emphasis is placed on the water sorption capacity, the fiber's surface potential, and fibrillation properties.