Download or read book Mo Organische Verbindungen Organomolybdenum Compounds 5 written by SPRINGER VERLAG and published by Springer. This book was released on 1992-12-08 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume deals with mononuclear organomolybdenum compounds with organic ligands bonded by one to four carbon atoms to molybdenum with and without additional CO groups. These compounds can contain neutral donor ligands (e.g. amines, phosphanes, or nitriles) or ionic ligands (e.g. halides or pyrazolyl derivatives). The combination of these ligands leads to a great number of different types of compounds. The first sections describe compounds with isocyanide, carbene, carbyne, and acetylide ligands, e.g. compounds of the types (CO3)Mo(CNR)N2C10H8, RC(O)C(R')=MO(CO)5, RChMo(CO)4X, or K3 Ä(RChC)3Mo(CO=)3Ü. The following sections deal with compounds having alkene, alkyne, and allyl derivatives as ligands. The volume concludes with a description of compounds with ligands forming four Mo-C bonds. Most of these ligands are dienes. Compounds with trimethylene methane ligands, e.g. (CH2)3CMo(CO)4, are included. Among the many types of reactions described displacement of the diene ligand is the most common one. In particular, the norbarnadiene complex, C7H8Mo(CO)4, is the most widely used for the preparation of tetracarbonylmolybdenum compounds. An empirical formula and ligand index completes the volume.
Download or read book Mo Organomolybdenum Compounds written by Hans Schumann and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 409 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume 8 is the fourth in a series dealing with organomolybdenum compounds. An Empirical Formula Index and a Ligand Formula Index provide ready access to the compounds covered. Volume 5 describes mononuclear organomolybdenum compounds with isocyanide, 3 4 carbene, carbyne, alkynyl, alkene, alkyne, L, and L ligands with and without additional CO groups. Volume 6 starts the description of mononuclear organomolybdenum compounds with 5 one L Ligand, a Ligand bonded to molybdenum by five carbon atoms. The compounds contain either zero or one CO group bonded to the molybdenum atom. Volume 7 continues the 5 description of L-molybdenum compounds containing two CO groups, but no additional nl 5 ligands. This volume describes L-molybdenum compounds with two CO groups and additional 1 4 L to L ligands. Following the nomenclature used in this series of organomolybdenum com pounds, nl is an organic Ligand bonded by n C atoms to molybdenum, and mo is an electron 2 donor Ligand with m donor electrons. Thus 0 denotes a Ligand such as PR . 3 Many of the data, particular those in tables, are given in an abbreviated form without units; for explanations see p. X. Additional information, if necessary, is given before the individual table. Frankfurt am Main Manfred Winter November 1992 Wolfgang Petz X Remarks on Abbreviations and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, the dimensions are omitted for the sake of conciseness. This necessitates the following clarifications.
Download or read book Mo Organische Verbindungen Organomolybdenum Compounds 13 written by Leopold Gmelin and published by Springer. This book was released on 1996-12-19 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume contains all available information on mononuclear organomolybdenum compounds with one 6L ligand, an additional nD electron donor, and up to three 1L ligands. The main part of the volume deals with the numerous complexes where 6L is benzene or a substituted benzene. The properties, including the spectroscopy, and the reactivity of these complexes are described in detail. A large number of compounds is known where the Mo(CO)3 moiety is bonded to 6L ligands such as cycloheptatriene, cyclooctatriene, cyclooctatetraene, higher carbocycles, or more or less complicated polycyclic carbocycles. C7H8Mo(CO)3 is a versatile starting material for the synthesis of a considerable number of Mo complexes, and these reactions are summarized.
Download or read book Gmelin Handbook of Inorganic and Organometallic Chemistry System Number 53 written by Leopold Gmelin and published by . This book was released on 1994-01-01 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mo Organomolybdenum Compounds written by Hans Schumann and published by Springer. This book was released on 2013-10-03 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume 8 is the fourth in a series dealing with organomolybdenum compounds. An Empirical Formula Index and a Ligand Formula Index provide ready access to the compounds covered. Volume 5 describes mononuclear organomolybdenum compounds with isocyanide, 3 4 carbene, carbyne, alkynyl, alkene, alkyne, L, and L ligands with and without additional CO groups. Volume 6 starts the description of mononuclear organomolybdenum compounds with 5 one L Ligand, a Ligand bonded to molybdenum by five carbon atoms. The compounds contain either zero or one CO group bonded to the molybdenum atom. Volume 7 continues the 5 description of L-molybdenum compounds containing two CO groups, but no additional nl 5 ligands. This volume describes L-molybdenum compounds with two CO groups and additional 1 4 L to L ligands. Following the nomenclature used in this series of organomolybdenum com pounds, nl is an organic Ligand bonded by n C atoms to molybdenum, and mo is an electron 2 donor Ligand with m donor electrons. Thus 0 denotes a Ligand such as PR . 3 Many of the data, particular those in tables, are given in an abbreviated form without units; for explanations see p. X. Additional information, if necessary, is given before the individual table. Frankfurt am Main Manfred Winter November 1992 Wolfgang Petz X Remarks on Abbreviations and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, the dimensions are omitted for the sake of conciseness. This necessitates the following clarifications.
Download or read book Mo Organische Verbindungen Organomolybdenum Compounds 10 written by Lutz Dahlenburg and published by Springer. This book was released on 1995-11-17 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Gmelin Handbook of Inorganic and Organometallic Chemistry written by Leopold Gmelin and published by Springer-Verlag. This book was released on 1996 with total page 395 pages. Available in PDF, EPUB and Kindle. Book excerpt: The C5H5Mo(CO)3 unit is among the most ubiquitous fragments in organometallic chemistry. The present volume first describes neutal compounds of the type C5H5Mo(CO)31L (1L = alkyl, vinyl, aryl, and alkynyl) and the C5H5Mo(CO)3=CR2 + cations. Many of the C5H5Mo(CO)31L compounds are important precursors in organometallic synthesis. Typical reactions are the insertion of electrophiles into the Mo-1L bond, e.g., the insertion of SO2 with the formation of sulfinato derivatives. The kind of products formed in substitution reactions of the CO groups by nucleophiles depends strongly on the 1L ligand. The second part of the volume deals with compounds with one 5LMo(CO)3 fragment (5L is a general organic ligand bonded by five carbon atoms to the metal, e.g., substituted cyclopentadienyl or open-chain pentadienyl derivatives).
Download or read book Mo Organomolybdenum Compounds written by Lutz Dahlenburg and published by . This book was released on 1995 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mo Organische Verbindungen Organomolybdenum Compounds 5 written by Leopold Gmelin and published by Springer. This book was released on 1992-11-06 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume deals with mononuclear organomolybdenum compounds with organic ligands bonded by one to four carbon atoms to molybdenum with and without additional CO groups. These compounds can contain neutral donor ligands (e.g. amines, phosphanes, or nitriles) or ionic ligands (e.g. halides or pyrazolyl derivatives). The combination of these ligands leads to a great number of different types of compounds. The first sections describe compounds with isocyanide, carbene, carbyne, and acetylide ligands, e.g. compounds of the types (CO3)Mo(CNR)N2C10H8, RC(O)C(R')=MO(CO)5, RChMo(CO)4X, or K3 Ä(RChC)3Mo(CO=)3Ü. The following sections deal with compounds having alkene, alkyne, and allyl derivatives as ligands. The volume concludes with a description of compounds with ligands forming four Mo-C bonds. Most of these ligands are dienes. Compounds with trimethylene methane ligands, e.g. (CH2)3CMo(CO)4, are included. Among the many types of reactions described displacement of the diene ligand is the most common one. In particular, the norbarnadiene complex, C7H8Mo(CO)4, is the most widely used for the preparation of tetracarbonylmolybdenum compounds. An empirical formula and ligand index completes the volume.
Download or read book Ni Organonickel Compounds written by Peter W. Jolly and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume starts the updating of the information on organonickel chemistry, one of the most active areas of modern organometallic chemistry. It covers all mononuclear compounds containing one nickel-to-carbon bond. The main part is devoted to the family of planar NiII compounds, RNi(D)2X, which within 20 years has increased from about 250 to more than 1000 members. This research interest has been stimulated by the fact that many compounds insert various unsaturated species into the Ni-C bond to create new organonickel species. Moreover, these compounds are important as intermediates in many catalytic processes involving organic halides. Compounds containing h*2-bonded heteroalkene molecules including the C1 fragments CO2 and CS2, and related metallocyclic compounds are also emphasized in this volume. These types of compounds play an important role in a number of nickel-catalyzed co-oligomerization reactions involving unsaturated organic compounds. Most of the compounds are well-characterized by modern spectroscopic techniques. The various types of compounds are in most cases confirmed by X-ray diffraction. The author of these volumes, a member of the M lheim group, has made many contributions of his own and is eminently qualified to critically review this area of research.
Download or read book Os Organoosmium Compounds written by Kerstin Behrends and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume, "Organoosmium Compounds" 8 6, systematically covers the litera ture through 1992, including many later references. This volume is the first published of Series 8. This series is devoted to compounds containing two or more osmium atoms. The volume forms a unit with" Organoosmium Compounds" 8 5 (in preparation). 80th volumes deal with trinuclear compounds with ligands other than CO which are bonded to Os by one carbon atom ("1L ligands "), regardless of whether the ligand is additionally coordinated to Os by heteroatoms. Generally CO groups are additional ligands. As is usual in the organometallic Gmelin series, the term "trinuclear" means three osmium atoms in the molecule without regard to any additional metals that may be present. The content and the subdivision of both volumes are described on p. 1. Volume 85 will deal with homometallic compounds in which the bonding C atom of the leading 1L ligand is bonded to Os by one non-bridging Os-C bond. The first part of the present volume, 86, is devoted to homometallic compounds in which the bonding C atom of the 1L ligand bridges two or three Os atoms. A second part deals with all heterometallic compounds with 1L ligands other than CO. An Empirical Formula Index and a Ligand Formula Index for both volumes 8 5 and 86 will be included in volume 8 5. For abbreviations and dimensions used throughout this volume, see p. X.
Download or read book Molybdenum Mononuclear compounds written by Irene Kersting and published by . This book was released on 1996 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ge Organogermanium Compounds written by John E. Drake and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume in the organogermanium series describes mononuclear compounds containing only germanium-carbon and germanium-hydrogen bonds (Chapter 1.3). Germanium hydrides with other additional non-carbon ligands, such as halogen or oxygen bonded groups, appear in later chapters according to the Gmelin principle of the last posi tion. Compounds with Ge-H and Ge-O bonds have already been described in Volume 5, Section 1.5.1.4, pp. 50/62. The present volume covers the literature to the end of 1992 and includes many references up to 1994. The nomenclature recommended by IUPAC has been generally adhered to. However, compound names were largely avoided, as most of the compounds are presented in tables and are only identified by their formulas. Many of the data in the tables appear in abbreviated form without units; general explanations are given on pp. X/XI. The volume contains an empirical formula index (p. 327) and a ligand formula index (p.341). The editor wishes to express his gratitude to the former author, Professor J. E. Drake, and to Professor J. Satge for his kind advice and fruitful collaboration. Thanks are due also to Dr. A. R. Pebler for editing the English text and to Mr. H.-G. Karrenberg for drawing the numerous formulas and molecular structures.
Download or read book Mo Organomolybdenum Compounds written by and published by . This book was released on 1992 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Os Organoosmium Compounds written by Karin Greiner and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Molybdenum Mononuclear compounds written by Irene Kersting and published by . This book was released on 1993 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book In Organoindium Compounds written by Johann Weidlein and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume contains all compounds in which at least one indium-carbon bonding interaction can be assumed. The compilation starts with the simplest compound of trivalent indium, In(CHh, and ends with studies about the interaction of indium with carbon monoxide 3 in an argon matrix. Literature coverage is intended to be complete to spring 1991 with various examples up to September 1991. The arrangement is closely related to that of the organogallium volume and documents the similarities between the two elements. Following the indium triorganyls and their adducts with Lewis bases in Section 1, the broad field of compounds of the general type R ln- n 3 n (n = 1, 2) is treated in sections 2 to 9; X represents a ligand bonded with a non-carbon atom to the indium atom. The arrangement of the various ligands follows the order group 17, 16, 15, etc. elements, with few compounds having direct indium-transition metal bonds. Ionic species, predominantly [R lnX -n]-compounds (n = 1 to 4), close the series of trivalent n 4 organoindium compounds and are collected in Section 11. Compounds of formally low valent indium (In", Ini, and Ino), with one R 1nlnR species having an In-In bond, form Section 12; 2 2 an extended chapter therein is dedicated to the young area of Cp*ln compounds in which i formalln is coordinated in an T] 5 manner.
