Download or read book Mixed Metal Complexes Containing a Novel Chelating Sulfur Ligand written by Robert John Dell and published by . This book was released on 1971 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Complexes of Sulfur Containing Ligands written by Shailey Singhal and published by LAP Lambert Academic Publishing. This book was released on 2014-02 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt: Present book provides an insight to the synthesis, characterization and structural analysis of compounds containing nitrogen and sulfur containing chelating agents. Keeping in mind the biological, medicinal, industrial and chelating importance of sulfur (alone) and nitrogen containing donor ligands, two important chelating agents, viz Potassium-2-trithiocarbonatoethyl xanthate (PTEX) and 2-amino-4-benzamido thiosemicarbazide (ABTSC) have been discussed in details w.r.t. their synthesis, characterization and metals complexes. All the possible techniques have been dealt in order to elucidate the structures of the complexes generated.
Download or read book Synthesis and Characterization of Metal Complexes with Sulfur and Nitrogen containing Ligands written by Claire MacLeod Ohman and published by . This book was released on 2001 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Molybdenum and Molybdenum Containing Enzymes written by Michael P. Coughlan and published by Elsevier. This book was released on 2014-06-28 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molybdenum and Molybdenum-Containing Enzymes is a collection of papers that deals with the various concerns with molybdenum-containing enzymes. The text first covers the organometallic chemistry of molybdenum, and then proceeds to tackling molybdenum-containing enzymes, such as xanthine oxidase, aldehyde oxidase, and sulphite oxidase. The text also discusses the advancement in the understanding of molybdenum-containing enzymes. The remaining chapters deal with the genetics of molybdoenzymes and the nutritional aspects of molybdenum. The book will be of great use to students, researchers, and practitioners of biochemistry.
Download or read book Metal Complexes of Chelate Ligands Containing Nitrogen and Sulphur as Donor Atoms written by Peter See Kien Chia and published by . This book was released on 1966 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal complexes of sulfur containing ligands iii written by I. Savago and published by . This book was released on 1980 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis and Reactions of Group VIII Metal Complexes Containing Sulfur Selenium Phosphorus and Oxygen Ligands written by William B. Beaulieu and published by . This book was released on 1978 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Complexes Containing Sulphur nitrogen Ligands written by John Derek Woollins and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis and Study of Metal Complexes with Sulphur Containing Ligands written by and published by . This book was released on 1967 with total page 205 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Syntheses Structures and Reactivity of the Group 6 and 7 Metal Complexes Containing Chelating Nitrogen Donor Ligands and Metal Ligand Multiple Bonds written by 李富華 and published by Open Dissertation Press. This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Syntheses, Structures and Reactivity of the Group 6 and 7 Metal Complexes Containing Chelating Nitrogen Donor Ligands and Metal-ligand Multiple Bonds" by 李富華, Fu-wa, Lee, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled "SYNTHESES, STRUCTURES AND REACTIVITY OF THE GROUP 6 AND 7 METAL COMPLEXES CONTAINING CHELATING NITROGEN DONOR LIGANDS AND METAL-LIGAND MULTIPLE BONDS" submitted by Lee Fu Wa for the degree of Doctor of Philosophy at the University of Hong Kong in September, 1997. ____________________________________________________________________ [Cr(CRMe )Cl ] (CRMe =meso-2,3,7,11,12-pentamethyl-3,7,11,17- 3 2 3 2+ tetraazabicyclo[11.3.1]-heptadeca-1(17),13,15-triene), [Cr(CRMe )Cl(H O)], 3 2 2+ + [Cr(CRMe )Cl(CH CN)] and [Cr(CRMe )(N )(OH)] are prepared. Upon addition 3 3 3 3 2+ 2+ of PhI=O to solutions of [Cr(CRMe )Cl(CH CN)] and [Cr(CRMe )Cl(H O)] 3 3 3 2 respectively in CH CN, the UV-visible absorption spectra of the two mixtures show similar isosbestic spectral changes attributed to the formation of V 2+ [Cr (CRMe )Cl(O)] . Addition of PhP causes the immediate recovery of 3 3 2+ [Cr(CRMe )Cl(CH CN)] as the isosbestic changes are reversed. Irradiation of 3 3 [Cr(CRMe )(N )(OH)] in acetonitrile with UV-visible light gives an azide-free 3 3 product, the FAB-MS of which shows a molecular ion peak indicative of V + + ([Cr (CRMe )(N)]ClO ). The UV-visible spectra of [Cr(CRMe )Cl ], 3 4 3 2 2+ 2+ [Cr(CRMe )Cl(H O)] and [Cr(CRMe )Cl(CH CN)] measured in water are 3 2 3 3 3+ similar to that of [Cr(CRMe )(H O) ] . Results from the conductivity measurement 3 2 2 + 2+ show that in water, [Cr(CRMe )Cl ], [Cr(CRMe )Cl(H O)] and 3 2 3 2 2+ [Cr(CRMe )Cl(CH CN)] behave as 3:1 electrolytes. The species which exists in 3 3 3+ water is likely to be the di-aquo complex [Cr(CRMe )(H O) ] . 3 2 2 2+ 2+ [Cr(CRMe )Cl(H O)] and [Cr(CRMe )Cl(CH CN)] are both found to give a 3 2 3 3 reversible oxidation couple at +1.11 V vs. SCE in aqueous solutions at pH=1 which is assigned to Cr(III)/(IV). iii t + The bis(imido) complexes [(TACN)M(N Bu) Cl] (M=Cr, Mo; TACN=1,4,7-triazacyclononane) and their 1,4,7-trimethyl derivatives are prepared, the crystal structures of which reveal the trans influence of the imido group. These 0 +/0 d species display a quasi-reversible couple at potentials 0.86 - 1.20 V vs. Cp Fe in acetonitrile assignable to a imido ligand-centred oxidation. (Me TACN)Mo(CO), 1,4,7-Tri((S)-2-methylbutyl)-1,4,7-triazacyclononane 3 3 * * * (L ) and L Mo(CO) are synthesized. (Me TACN)Mo(CO) and L Mo(CO) show 3 3 3 3 +/0 reversible oxidation couples at -0.26 V and -0.24 V vs. Cp Fe in CH CN 2 3 I/0 respectively which are assigned to Mo . The comparable electronic effect of * Me TACN and L in this system is therefore implied. 2+ [(Me TACN) Mn (μ-O)(μ-OCOCH ) ] is prepared and found to mediate 3 2 2 3 2 aziridination of styrene, methylstyrene, cis- and trans-stilbene, 1,1-diphenylethene and norbornene by PhI=NTs in CH Cl at 25 C. The nitrene transfer to cis- and 2 2 trans-stilbene is found to be stereoselective to exclusively give the trans-aziridine product. + + [(Me TACN)(CO) M CPh] (M=Mo, W) and [(TACN)(CO) Mo CPh] 3 2 2 are prepared. [(Me TACN)(CO) M CPh] (M=Mo, W) exhibit a reversible 3 2 +/0 reduction couple at -2.15 V vs Fe Cp and an irreversible wave at 0.77 V vs +/0 Fe Cp, which are ascribed to a reduction centred at the phenyl ring and oxidation of the terminal CO respectively. Treatment of Cl(
Download or read book Metal Complexes of Sulphur and Nitrogen Containing Ligands written by Stephen Gill and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book s Block Metal Complexes written by Matthias Westerhausen and published by MDPI. This book was released on 2018-06-27 with total page 155 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a printed edition of the Special Issue "s-Block Metal Complexes" that was published in Inorganics
Download or read book Characterization and Reactions of Sulfur Ligand Metal Complexes written by William C. Seidel and published by . This book was released on 1969 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Principles and Applications of Metal Chelation written by Colin Frank Bell and published by Oxford University Press, USA. This book was released on 1977 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chelating Agents and Metal Chelates written by Francis P. J. Dwyer and published by . This book was released on 1964 with total page 610 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Complexes Containing Sulphur Ligands and the Catalytic Homogeneous Hydrogenation of Alkenes and Arenes written by Michael John Hayling Russell and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Some Stereochemical Studies on Metal Complexes Containing Sulphur Ligands written by Lawrence Robin Gahan and published by . This book was released on 1975 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
