Download or read book Microbial and Photochemical Degradation of Allochthonous Dissolved Organic Matter Within River Systems and Watersheds written by Tracy Nicole Wiegner and published by . This book was released on 2002 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Microbial and Photochemical Degradation of Dissolved Organic Matter in Aquatic Ecosystems written by Rainer Maria Wolfgang Amon and published by . This book was released on 1995 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Photochemical and Microbial Degradation of Dissolved Organic Matter in the Lake Superior Watershed written by Megan J. Macdonald and published by . This book was released on 2012 with total page 72 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Microbial and Photochemical Cycling of Dissolved Organic Matter in Boreal Headwater Streams written by Doreen Franke and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissolved organic matter (DOM) is a key global energy source and carbon reservoir that links terrestrial and aquatic biogeochemical cycling. Allochthonous organic matter is abundant in boreal headwater streams, and environmental changes such as variation in nutrient availability and changes to watershed landscape composition have great potential for altering the DOM source, its composition and cycling. This dissertation focuses on two of the main drivers of aquatic carbon and nutrient cycling: the photochemical and the microbial processing of DOM in boreal headwater streams; specifically (i) how the photochemical lability of DOM varies between reaches within headwater streams, among headwater streams and an associated large river reach, (ii) how stream biofilm mineralization may be regulated by watershed organic matter source and composition, increased labile carbon, nitrogen, and phosphorus availability, and (iii) whether algal carbon sources are important to supporting stream biofilms and if such sources influence the use of allochthonous DOM in nutrient-enriched streams. The results suggest changes in landscape and nutrient availability have the potential to alter the photochemical and biogeochemical cycling of DOM. DOM photolability was increased upstream relative to downstream and the river DOM. This may be due to differences in DOM source and composition, and suggests losses in photolabile DOM downstream and in the lower reaches of the watershed. The phototransformation of DOM into low molecular weight compounds and nutrients such as ammonium is likely relevant to the carbon and nutrient cycling in boreal watersheds. Results here further suggest that boreal stream biofilm mineralization of DOM is regulated by watershed DOM source and composition. Labile carbon sources, such as algal inputs, may also play an important role in regulating DOM mineralization and the processing of nutrients by these biofilms. In nutrient-impacted streams, where primary production is high relative to nutrientpoor streams, biofilms may be stimulated to incorporate algal carbon sources. Yet in the boreal streams studied here, added labile carbon rarely enhanced the mineralization of extant stream DOM suggesting autotrophic-heterotrophic interactions represent a more important priming effect relative to changing DOM source in boreal streams.

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2002 with total page 756 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Aquatic Organic Matter Fluorescence written by Paula G. Coble and published by Cambridge University Press. This book was released on 2014-07-14 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: A core text on principles, laboratory/field methodologies, and data interpretation for fluorescence applications in aquatic science, for advanced students and researchers.

Download or read book Interaction of photochemical and microbial processes in the degradation of refractory dissolved organic matter from a coastal marine environment written by W.L. MILLER and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book High Resolution Molecular Characterization of Photochemical and Microbial Transformation of Dissolved Organic Matter in Temperate Streams of Different Watershed Land Use written by Xiaping Li and published by . This book was released on 2014 with total page 73 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of the present study was to provide better understanding of the effects of watershed land use on molecular composition of streamwater DOM and molecular transformations associated with photochemical and microbial processing of DOM. We compared DOM from headwater streams draining forest-dominated watersheds (FW) and pasture-dominated watersheds (PW) in the lower Chesapeake Bay region (Virginia, USA). Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry analysis was conducted on streamwater DOM prior to and after laboratory incubations: 1) bacteria-only incubations; 2) light-only incubations; and 3) combined light+bacterial incubations. Results showed that DOM in FW streams and PW streams differed in molecular characteristics--the former was characterized by greater structural complexity and aromaticity, higher proportions of condensed aromatic molecules and black carbon-like components, while the latter was higher in the proportions of lipid-like components, protein-like components and aliphatic compounds. Relative to DOM from FW streams, DOM from PW streams was more reactive to bacterial transformation. Protein-like components, lipid-like components and unsaturated hydrocarbon-like components are primarily responsible for the changes associated with bacterial transformation of DOM. However, similar behavior was also observed for DOM in FW streams and PW streams under the influence of bacterial and photochemical processes. Bacterial transformation reduced the proportions of lipid-like components but increased the proportions of lignin-like components and carboxyl-rich alicyclic molecule-like components, indicating that lipid-like components was a bioreactive class while lignin-like components and carboxyl-rich alicyclic were resistant to bacterial processing. Photochemical processes, alone or combined with microbial alterations, increased the proportions of protein-like components, which may be due to the light stimulation of autochthonous production of protein-like components, and increased the relative abundance of carboxyl-rich alicyclic molecule-like components, which indicates the refractory nature of these molecules. Photochemical processes also significantly reduced the amount of dissolved black carbon-like components, which suggests dissolved black carbon was a photoreactive class, countering the conventional view that black carbon was an inter group in carbon cycle. Collectively, these findings suggest that human land use in upstream watersheds may lead to alterations to the molecular composition of streamwater DOM as well as to its behavior to photochemical and microbial processing.

Download or read book Dissolved Organic Matter in the Anthropogenically Impacted Grand River and Natural Burnt River Watersheds written by Ryan H. S. Hutchins and published by . This book was released on 2011 with total page 99 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissolved organic carbon (DOM) is one of the largest cycled organic carbon pools on Earth and an important biogeochemical factor in aquatic systems. DOM can act as an energy source for microorganisms, alter the depth of the photic zone for photosynthesis, absorb harmful ultraviolet radiation, as well as alter the transport and toxicity of contaminants. The purpose of this research project was to characterize DOM in the Grand River watershed in Ontario, Canada using a wide range of qualitative and quantitative techniques and determine the impact of anthropogenic activities as well as seasonal and longitudinal changes on DOM processes. To reach the study objectives, historical data was analyzed to determine the seasonal cycle in the Grand River watershed. Intensive longitudinal sampling surveys were undertaken to evaluate the DOM characteristics and processes in the Grand River. Surveys of the less impacted Burnt River watershed were used as a comparison watershed to the Grand River to evaluate allochthonous and autochthonous indicators of DOM source and human impacts on DOM processes. Drinking water surveillance data was used to evaluate the effect of DOM in the Grand River on formation of disinfection by-products (DBPs). Different trends were seen in the Grand River in terms of longitudinal area and season. The headwaters of the river showed more autochthonous DOM in the spring and winter compared to the fall and summer. The lower-central river peaked in autochthonous DOM in the summer and was more allochthonous in the winter. DOM generally became more autochthonous downstream in the Grand River and was most autochthonous below the large sewage treatment plants (STPs) in the central portion. Protein content, measured as protein-like fluorescence normalized to DOC concentration, was strongly related to [delta]15N of DON; both are associated with autochthonous DOM in the Grand River and show the effects of the major STPs. The increase in autochthonous DOM below the STPs is likely associated with nutrient enrichment stimulating primary production and macrophyte growth. Based on the comparison of the Burnt River with the more impacted Grand River, the effect of lakes and photodegradation can make discrimination of autochthonous and allochthonous DOM more difficult. The ratio of DOC/DON and protein-like fluorescence proved to be robust indicators despite photodegradation. Human impacts on the Grand River watershed result in a greater seasonal cycle, high primary production in the summer and a downstream trend of increasing autochthonous DOM compared to the Burnt River. Based on drinking water surveillance data and literature review, autochthonous DOM caused greater DBPs in the drinking waters fed by the Grand River. This is currently a threat to human health and DBPs in sewage treatment plant effluent may be a threat to ecosystem health.

Download or read book Interactions of the Major Biogeochemical Cycles written by Jerry M. Melillo and published by . This book was released on 2003 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Table of contents

Download or read book Photobiogeochemistry of Organic Matter written by Khan M.G. Mostofa and published by Springer Science & Business Media. This book was released on 2012-12-15 with total page 919 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photoinduced processes, caused by natural sunlight, are key functions for sustaining all living organisms through production and transformation of organic matter (OM) in the biosphere. Production of hydrogen peroxide (H2O2) from OM is a primary step of photoinduced processes, because H2O2 acts as strong reductant and oxidant. It is potentially important in many aquatic reactions, also in association with photosynthesis. Allochthonous and autochthonous dissolved organic matter (DOM) can be involved into several photoinduced or biological processes. DOM subsequently undergoes several physical, chemical, photoinduced and biological processes, which can be affected by global warming. This book is uniquely structured to overview some vital issues, such as: DOM; H2O2 and ROOH; HO•; Degradation of DOM; CDOM, FDOM; Photosynthesis; Chlorophyll; Metal complexation, and Global warming, as well as their mutual interrelationships, based on updated scientific results.

Download or read book Solar Radiation enhanced Dissolution photodissolution of Particulate Organic Matter in Texas Estuaries written by Qiyuan Liu and published by . This book was released on 2013 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissolved organic matter (DOM) is crucial to carbon and nutrient biogeochemical cycling in the marine environment because it helps fuel heterotrophic microbial activity by providing substrates for degradation and remineralization. This study shows that substantial production of DOM in Texas estuaries can result from the solar radiation-enhanced dissolution (photodissolution) of particulate organic matter (POM). Experimental results showed that 0.4-6.6 mg C L−1gsed−1 of dissolved organic carbon (DOC) and 0.03-0.93 mg N L−1gsed−1 of total dissolved nitrogen (TDN) can be produced from irradiated sediment suspensions within 24 hours, and further that photodissolution may augment DOC and TDN loads in Texas estuarine waters by as much as 3-85% and 4-75%, respectively. Photodissolution can also enhance the optical thickness of the water column via the release of chromophoric dissolved organic matter (CDOM), which may subsequently further enhance photochemical processes in surrounding waters. Photoproduced CDOM appears to be of relatively high molecular weight and dominantly exhibits humic-like fluorescence, suggesting that photodissolution primarily occurs for humic moieties. Photodissolution was also observed for sterilized sediment suspensions, indicating that photochemical degradation of POM is the primary pathway of DOM production during photodissolution, as opposed to microbial mediated degradation or stimulation of benthic primary production by benthic phytoplankton or algae. Environmental and mechanistic factors controlling the extent of photodissolution in Texas estuaries may include sediment desiccation, water organic content, and sediment characteristics (organic content and lability of POM). Desiccated-rewetted sediments suspended in artificial seawater under solar irradiation produced ~40% more DOC and TDN than wet sediments, indicating the sediment dry-wet cycle may alter the 3-D structure of sediment grain matrices and thus might be a major controlling factor of photodissolution in salt marsh systems. The organic content of water used in sediment suspensions did not significantly influence DOC or TDN photoproduction by itself, but the combined influence of water organic content and sediment dry-rewet event played a substantial role in controlling the extent of photodissolution. In contrast to the results in artificial seawater, wet sediments produced slightly more DOC ([Delta]DOC=0.10 mg C gsed−1) and substantially more TDN ([Delta]TDN=0.14 mg N gsed−1) than dry-rewetted sediments in organic-rich Nueces Marsh water during 24 hours of photoincubation. Photodissolution dominantly produced humic-like DOM even though biologically labile organic matter was available in sediments, indicating that photochemical reactions preferentially occur with humic-like rather than protein-like organic matter. DOC and TDN production during photodissolution was strongly proportional to the amount of POC in sediment suspensions. On average, 69.2 ± 11.0 mg C of DOC and 9 ± 3.1 mg N of TDN was produced from 1 g of organic carbon in sediment suspensions after 24 hours of photodissolution.

Download or read book Dissolved Organic Matter in Arctic Watersheds and Coastal Waters written by Craig Thomas Connolly and published by . This book was released on 2019 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Arctic warming is already affecting the movement of freshwater and dissolved organic matter (DOM) from watersheds to the coastal ocean in the Arctic. Improved understanding of DOM in freshwater sources and linkages to DOM characteristics in Arctic coastal waters is needed to assess responses to and feedbacks with climate change. This work focuses on DOM characteristics that couple watershed and coastal systems in the Arctic, with specific considerations of river and groundwater inputs to lagoon ecosystems along the eastern Alaska Beaufort Sea coast. We found that spring and summer river-borne concentrations of dissolved organic carbon and nitrogen (DOC and DON) are strongly linked to variations in watershed slope and soil organic matter coverage across space and scale in the Arctic. The quantities and composition of DOM in lagoons of the eastern Alaska Beaufort Sea coast vary markedly between seasons. Specifically, lagoons experience a shift from high to low DOC and DON concentrations between the late spring sea ice break-up and winter ice-covered periods, but these concentrations are more variable during the summer open water period. Distinct seasonal transitions in ice coverage, runoff from land, and water exchange with the Beaufort Sea strongly influence the availability of lagoon DOM. During the summer, concentrations of DOC and DON in supra-permafrost groundwater (SPGW) inputs to lagoons are much higher than those found in local rivers and lagoons. Late-summer fluxes of SPGW DOM to the northern Alaska coastline are substantial and may be the principal source of DOM to lagoons without river inputs. This SPGW DOM is sourced from readily leachable organic matter in surface soils and deeper soil horizons that likely extend into thawing permafrost. SPGW DOM contains aromatic carbon compounds that are largely resistant to microbial degradation on the order of days to months. While nearby river and lagoon water DOM has a similar composition and degradability, SPGW contains a portion of bioavailable and reactive DOM that is not present in river and lagoon waters. Inputs of SPGW DOM provide a potentially important source of energy for lagoon food webs along the Alaskan Beaufort Sea coast during the late summer

Download or read book The Role of Dissolved Organic Matter in Structuring Microbial Community Composition written by Rachel Elizabeth Sipler and published by . This book was released on 2009 with total page 179 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissolved organic matter (DOM) is an important source of nutrients in aquatic systems contributing to the growth of phytoplankton and bacteria. The overall response appears to be driven by the phytoplankton and bacteria species present as well as the composition of DOM provided. This dissertation explores the bioavailability of allochthonous and autochthonous DOM sources to, and its affect on, the growth of marine phytoplankton and bacterial community abundance and composition. This research utilizes advanced chemical (electrospray ionization mass spectrometry (ESI-MS)) and molecular (terminal restriction fragment length polymorphism (TRFLP)) techniques to characterize the DOM and microbial community. To investigate the role of allochthonous DOM in phytoplankton growth, DOM from two different riverine sources from watersheds with different land use practices, was supplied to a natural cyanobacteria population. The bioavailability of autochthonous DOM was investigated by supplying DOM produced by a single culture of cyanobacteria to a natural dinoflagellate bloom community. The potential negative effect of an individual autochthonous DOM compound was investigated through the addition of marine toxin, brevetoxin, to three different natural bacterial communities. This dissertation resulted in the first ESI-MS characterization spectra of the DOM associated with three different natural phytoplankton blooms, a culture of cyanobacteria, and two different South Florida rivers. It was also the first study to identify previously uncharacterized allochthonous and autochthonous DOM masses bioavailable to natural marine phytoplankton communities. Bulk level analyses within these experiments quantified lower limits for the bioavailability of allochthonous and autochthonous DOM sources and the relative community response to each of these sources. This dissertation also represents the first molecular evaluation of the bacteria associated with a bloom and the first investigation of the allelopathic properties of brevetoxin. It has discussed and applied the use of ESI-MS to investigate the bioavailability of complex DOM, identified and quantified potential nutrient sources and linked marine toxin production to changes in bacterial community composition.

Download or read book Photochemistry of Effluent and Natural Organic Matter and Photochemical Degradation of Micropollutants written by Laleen Chanaka Bodhipaksha and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The photoreactivity of treated wastewater effluent organic matter (EfOM) has received recent attention because it is an important fraction of the dissolved organic matter (DOM) pool in wastewater-receiving rivers. Dissolved organic matter contains chromophore moieties that absorb energy from sunlight and, in turn, produce reactive intermediates through secondary reactions of these excited-state moieties. Photochemically produced reactive intermediates (PPRIs) include excited state triplet organic matter (3DOM*), singlet oxygen (1O2), hydroxyl radicals (OH•) and others. Apparent quantum yields of production of PPRIs appear to be higher for EfOM than for natural organic materials (NOM), which implied that contributions of EfOM may enhance the photoproduction of reactive intermediates in EfOM-receiving rivers. Our evaluations with EfOM and NOM mixtures showed higher photoreactivity in mixtures having more than 25% (v/v) of EfOM; however, evidence of 3DOM* and 1O2 quenching in organic matter mixtures was found when measured yields were compared to theoretical yields. These results suggest that effluent contributions of greater than 25% to rivers have a lower than expected contribution to photochemical production of 3DOM* and 1O2 because of quenching of 3DOM* by DOM. To examine how trends of reactive species productions translate to indirect photodegradation of micropollutants, we studied photodegradation of organic compounds in wastewater effluent, river water and mixtures thereof. The compounds were selected considering their photodegradation pathways. Greater contributions of oxidants in the degradation of compounds were observed in EfOM compared to NOM. Comparisons of measured rate constants with model calculations based on end member reaction rate constants showed model overestimations of photodegradation in the case of 3DOM* and 1O2 pathways, and conserved mixing behavior in the case of OH• reaction pathways. Finally, we found that amino acids in EfOM involve in quenching of triplets.

Download or read book Acid Rain Deposition to Recovery written by Peter Brimblecombe and published by Springer Science & Business Media. This book was released on 2007-12-11 with total page 405 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book looks at the sources and composition of the atmosphere and rainfall, with particular attention on acidifying components and those that affect ecosystems. It further widens the subject to look at trace metals. It includes papers on the impact of deposition on soils and forests and the recovery of the natural environment. Work on critical loads makes a contribution to understanding the degree to which deposition must be reduced to limit its impact.

Download or read book How Does Availability of Allochthonous Dissolved Organic Matter DOM Influence Bacterial Community Composition in Clear Water and Humic Lakes written by Kristine Michelle L. Hutalle-Schmelzer and published by . This book was released on 2009 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: