Download or read book Mechanism of Pitting Corrosion Prevention by Nitrite in Carbon Steel Exposed to Dilute Salt Solutions written by and published by . This book was released on 2002 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall goal of this project was to develop a detailed understanding of the role of nitrite in preventing the breakdown of protective oxide on steel and on the onset of pitting, by considering the interactions of the oxidation and reduction reactions that may occur in alkaline salt solutions.
Download or read book Mechanism of Pitting Corrosion Prevention by Nitrite in Carbon Steel Exposed to Dilute Salt Solutions 1998 Annual Progress Report written by and published by . This book was released on 1998 with total page 3 pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall goal of this project is to develop a fundamental understanding of the role of nitrite in preventing the breakdown of protective oxide(s) on carbon steel and the onset of pitting. Pitting corrosion of carbon steel exposed to dilute alkaline salt solutions can be induced by nitrate, sulfate, and chloride ions and is prevented by sufficient concentration of nitrite. A significant example of this material/electrolyte system is the storage and processing of DOE''s high-level radioactive liquid waste in carbon steel tanks. Added nitrite in the waste has a considerable downstream impact on the immobilization of the waste in a stable glass form. Waste tank integrity and glass production efficiency may benefit from the fundamental understanding of nitrite''s role in preventing pitting. This report summarizes progress after approximately six months of effort in this three-year EMSP project. Initial experimental and theoretical work has focused on the electrochemical behavior of carbon steel in simplified non-radioactive solutions that simulate complex dilute radioactive waste solutions. These solutions contain corrosion-inducing species such as nitrate and chloride and the corrosion-inhibiting nitrite at moderately alkaline pHs. The electrochemical behavior of interest here is that of the open-circuit potential of the steel specimen at equilibrium in the experimental electrolyte and the measures of the steel''s passivity and passivity breakdown.
Download or read book Energy Materials Coordinating Committe EMaCC Fiscal Year 1999 Annual Technical Report written by and published by DIANE Publishing. This book was released on with total page 221 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Materials Coordinating Committe EMaCC Fiscal Year 2000 Annual Technical Report written by and published by DIANE Publishing. This book was released on with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Materials Coordinating Committe EMaCC Fiscal Year 1997 Annual Technical Report written by and published by DIANE Publishing. This book was released on with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inhibiting Pitting Corrosion in Carbon Steel Exposed to Dilute Radioactive Waste Slurries written by and published by . This book was released on 1991 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dilute caustic high-level radioactive waste slurries can induce pitting corrosion in carbon steel. Cyclic potentiodynamic polarization tests were conducted in simulated and actual waste solutions to determine minimum concentrations of sodium nitrate which inhibit pitting in ASTM A537 class 1 steel exposed to these solutions. Susceptibility to pitting was assessed through microscopic inspection of specimens and inspection of polarization scans. Long-term coupon immersion tests were conducted to verify the nitrite concentrations established by the cyclic potentiodynamic polarization tests. The minimum effective nitrite concentration is expressed as a function of the waste nitrate concentration and temperature.
Download or read book Energy Materials Coordinating Committe EMaCC Fiscal Year 1998 Annual Technical Report written by and published by DIANE Publishing. This book was released on with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Meeting Abstracts written by Electrochemical Society. Meeting and published by . This book was released on 1998 with total page 1492 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Pitting Growth Rate in Carbon Steel Exposed to Simulated Radioactive Waste written by and published by . This book was released on 1995 with total page 15 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dilute high-level radioactive waste slurries can induce pitting corrosion in carbon steel tanks in which such waste is stored and processed. The waste is normally maintained with closely monitored nitrite and hydroxide concentrations known to prevent the initiation of pitting. Coupon immersion are being conducted in laboratory simulants of waste to determine the probability and growth rate of pitting in steel in the event of below-limits nitrite concentrations. Sets of about 36 carbon steel coupons have been immersed in known corrosive conditions (nitrite
Download or read book Electrochemical Studies of Nitrate Induced Pitting in Carbon Steel written by and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The phenomenon of pitting in carbon steel exposed to alkaline solutions of nitrate and chloride was studied with the cyclic potentiodynamic polarization technique. Open-circuit and pitting potentials were measured on specimens of ASTM A537 carbon steel in pH 9.73 salt solutions at 40 degrees Celsius, with and without the inhibiting nitrite ion present. Nitrate is not so aggressive a pitting agent as is chloride. Both nitrate and chloride did induce passive breakdown and pitting in nitrite-free solutions, but the carbon steel retained passivity in solutions with 0.11-M nitrite even at a nitrate concentration of 2.2 M.
Download or read book Directory of Graduate Research written by and published by . This book was released on 2001 with total page 1850 pages. Available in PDF, EPUB and Kindle. Book excerpt: Faculties, publications and doctoral theses in departments or divisions of chemistry, chemical engineering, biochemistry and pharmaceutical and/or medicinal chemistry at universities in the United States and Canada.
Download or read book Green Corrosion Inhibitors written by V. S. Sastri and published by John Wiley & Sons. This book was released on 2012-02-14 with total page 267 pages. Available in PDF, EPUB and Kindle. Book excerpt: A book to cover developments in corrosion inhibitors is long overdue. This has been addressed by Dr Sastri in a book which presents fundamental aspects of corrosion inhibition, historical developments and the industrial applications of inhibitors. The book deals with the electrochemical principles and chemical aspects of corrosion inhibition, such as stability of metal complexes, the Hammett equation, hard and soft acid and base principle, quantum chemical aspects and Hansch' s model and also with the various surface analysis techniques, e.g. XPS, Auger, SIMS and Raman spectroscopy, that are used in industry for corrosion inhibition. The applications of corrosion inhibition are wide ranging. Examples given in this book include: oil and gas wells, petrochemical plants, steel reinforced cement, water cooling systems, and many more. The final chapters discuss economic and environmental considerations which are now of prime importance. The book is written for researchers in academia and industry, practicing corrosion engineers and students of materials science, engineering and applied chemistry.
Download or read book Metals Abstracts written by and published by . This book was released on 1996 with total page 1628 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Corrosion Science and Technology written by David E.J. Talbot and published by CRC Press. This book was released on 2018-01-29 with total page 699 pages. Available in PDF, EPUB and Kindle. Book excerpt: Twenty years after its first publication, Corrosion Science and Technology continues to be a relevant practical guide for students and professionals interested in material science. This Third Edition thoroughly covers the basic principles of corrosion science in the same reader-friendly manner that made the previous edition invaluable, and enlarges the scope of the content with expanded chapters on processes for various metals and new technologies for limiting costs and metal degradation in a variety of commercial enterprises not explored in previous editions. This book also presents expertly developed methods of corrosion testing and prediction.
Download or read book Metals Abstracts Index written by and published by . This book was released on 1996 with total page 1622 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Corrosion Abstracts written by and published by . This book was released on 1967 with total page 904 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metals Handbook Corrosion written by ASM International. Handbook Committee and published by . This book was released on 1978 with total page 1440 pages. Available in PDF, EPUB and Kindle. Book excerpt:
