Download or read book Isotopic Exchange Reactions of Cobalt Complexes written by Ningondappa Shenkreppa Biradar and published by . This book was released on 1960 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Isotopic Exchange Reactions written by Milton Kahn and published by . This book was released on 1962 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Conference on Isotopic Exchange Reactions and Chemical Kinetics written by Brookhaven National Laboratory and published by . This book was released on 1949 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Isotopic Studies of Ligand Exchange Reactions of Some Co ordination Compounds of Cobalt and Chronium written by Charmian J. O'Connor and published by . This book was released on 1958 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Isotopic Exchange in the Solid State and Thermal Annealing of Recoil Damage in Cobalt Complexes written by Amar Nath and published by . This book was released on 1965 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book A Study of V III V IV and Ti III Ti IV Isotopic Exchange Reactions in Acid Solutions written by Charles J. Orth and published by . This book was released on 1969 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ligand Exchange Reactions of Some Cobalt III Complexes written by Thomas Madison Vickrey and published by . This book was released on 1974 with total page 246 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Hot Atom Chemistry written by Jagdish Shankar and published by . This book was released on 1968 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Isotopic Exchange Reactions of Inorganic Complexes written by Manohar Shridhar Vaidya and published by . This book was released on 1958 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Isotope Separation and Isotope Exchange written by G. M. Begun and published by . This book was released on 1954 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1976 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1969 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.

Download or read book Physical Chemistry written by I︠A︡kov Ivanovich Gerasimov and published by . This book was released on 1974 with total page 642 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Chemistry Electrochemistry and Electron Transfer Induced Reactions of Cobalt Complexes with Fluorinated Ligands written by Kihanduwage N. Gunawardhana and published by . This book was released on 2007 with total page 213 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemical or electrochemical reduction of the trifluoroacetyl complex CF3COCo(CO)3PPh3 involves a single electron transfer yielding trifluoromethyl radical and an anionic cobalt carbonyl complex. The mechanism is proposed to involve electron transfer followed by initial dissociation of either a carbonyl or phosphine ligand from the 19-electron [CF3COCo(CO)3PPh3]- anion. The resulting 17-electron intermediate undergoes subsequent one-electron reductive elimination of trifluoromethyl radical by homolytic cleavage of the carbon-carbon bond of the trifluoroacetyl group. The CF3. radical can be trapped by either benzophenone anion, forming the anion of [alpha]-(trifluoromethyl)benzhydrol, or Bu3SnH, yielding CF3H. The final organometallic product is an 18-electron anion, either [Co(CO)4]- or [Co(CO)3(PPh3)]-, depending upon which ligand is initially lost. The chemical or electrochemical reduction CF3Co(CO)3PPh3 is a two-electron process involving heterolytic cobalt-carbon bond cleavage to yield trifluoromethyl anion and cobalt carbonyl anions. The trifluoromethyl anion rapidly decomposes to fluoride and difluorocarbene. This carbene may dimerize to form C2F4. The unstable fluoro carbene can also be trapped by cyclohexene. The mechanism proposed for the reduction of C6F5Co(CO)3PPh3 involves a homolytic cobalt-carbon bond cleavage to form C6F5. radical. The resultant C6F5. radical abstracts hydrogen or deuterium from the solvent or trace amounts of water to produce C6F5H or C6F5D. With an excess of reducing agent this C6F5. radical can be further reduced to C6F5- anion before forming pentafluorobenzene by protonation. The inorganic fragment, the 18-electron [Co(CO)3PPh3]- anion, may participate in a ligand exchange reaction to form [Co(CO)4]-. In addition, interesting reactivity was observed between C6F5Co(CO)3PPh3 and tin hydrides, deuterides and chlorides without any reducing agents. We have demonstrated that ligand replacement reactions can be used for the synthesis of new cobalt-NHC complexes with fluorinated alkyl, acyl and aryl ligands. In addition, the X-ray crystal structure of CF3COCo(CO)3PPh3 was obtained to compare the bond lengths and bond angles with other related compounds. An unusual Co-C(acyl) bond length was observed for CF3COCo(CO)3PPh3. Considering the bond lengths of other alkyl and acyl complexes, it can generally be argued that the position of the alkyl/acyl equilibrium varies with the Co-C(alkyl/acyl) bond length.

Download or read book Energy Research Abstracts written by and published by . This book was released on 1992-05 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Solution Behavior and Kinetics of Exchange Reactions of Penta coordinate Complexes of Cobalt II and Nickel II written by Philip Maury Enriquez and published by . This book was released on 1972 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Conference of the Academy of Sciences of the USSR on the Peaceful Uses of Atomic Energy July 1 5 1955 written by Akademii︠a︡ nauk SSSR. and published by . This book was released on 1956 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: