Download or read book Isotope Ratios of Uranium Using High Resolution Inductively Coupled Plasma Mass Spectrometry ICP MS written by R. Hearn and published by . This book was released on 1998 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: Actinide element isotope ratios have been determined in environmental samples using high resolution ICP-MS with ultrasonic nebulisation. Precisions as low as 0.1% RSD have been achieved using various methods of acquisition. The methodology has been used for environmental monitoring of uranium isotope ratios as an indicator of nuclear activity. Also, it has been applied to calcite dating studies as a measure of past geochemical disturbances.
Download or read book Uranium Isotope Measurements by Quadrupole ICP MS for Process Monitoring of Enrichment written by RN. Bolin and published by . This book was released on 1998 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: Historically, uranium isotopic ratio measurements in the nuclear industry have been performed using Thermal Ionization Mass Spectrometry (TIMS); primarily due to the high level of precision that can be achieved. TIMS analysis, however, requires sample purification and intricate sample loading. Quadrupole (low resolution, single detector) inductively coupled plasma -- mass spectrometry, Q-ICP-MS, overcomes these disadvantages and is a cost-effective alternative, i.e., in terms of initial capital, maintenance, and operating costs. This paper presents a simple, single standard approach for measuring uranium isotope content in various solid and liquid nuclear materials along with some comparison data of Q-ICP-MS and TIMS. Intensity ratios of 234U, 235U, 236U, and 238U to total U intensity are produced, providing the enrichment level or percent 235U. A detailed description of the instrument and data collection parameters is also provided. Optimal precision and accuracy are achieved through the use of a single standard which is closely matched to the enrichment and concentration of the samples. Depending upon the standard chosen, enrichments between depleted and 97% can be quantified. Standard deviations for the major uranium isotopes are typically within 0.02 absolute and at least an order of magnitude lower for the minor U isotope abundances.
Download or read book The Isotopic Ratio Measurement of Uranium in the Form of Hydrolyzed Uranium Hexafluoride by Inductively Coupled Plasma Multiple Collector Mass Spectrometry written by T. Hodgson and published by . This book was released on 1995 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: An inductively coupled plasma-multiple collector-mass spectrometer (ICP-MC-MS) has been used to measure the isotopic composition of uranium in three solutions of uranium hexafluoride. The 235U: 238U ratio of each sample solution ranged from approximately 0.007 to 0.03 to 1.0. The measurements are linear over this range and the precision and accuracy are comparable, if not superior, to that obtained by thermal ionization mass spectrometry (TIMS). However, acceptable isotopic ratio measurement of uranium hexafluoride solutions is not possible by TIMS because the presence of fluoride ions severely limits analytical precision. Hence, the fluoride must be removed prior to analysis. This necessitates a chemical purification stage which adds both time and expense to the measurement process. This study reports direct, high precision, accurate uranium isotope ratio measurements on solutions of uranium hexafluoride. The instrumental time required for the analysis of 15 uranium samples with the ICP-MC-MS totals 135 min. This compares with an estimated time requirement of 600 min by TIMS and a time of 900 min by UF6 gas mass spectrometry.
Download or read book Tools and Trends in Bioanalytical Chemistry written by Lauro Tatsuo Kubota and published by Springer Nature. This book was released on 2021-11-25 with total page 559 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook covers the main tools and techniques used in bioanalysis, provides an overview of their principles, and offers several examples of their application and future trends in diagnosis. Chapters from expert contributors explore the role of bioanalysis in different areas such as biochemistry, physiology, forensics, and clinical diagnosis, including topics from sampling/sample preparation, chemometrics in bioanalysis to the latest techniques used in the field. Particular attention is given to the recent advances in the application of mass spectrometry, NMR, electrochemical methods and separation techniques in bioanalysis. Readers will also find more about the application of microchip-based devices and analytical microarrays. This textbook will appeal to graduate/advanced undergraduate students in Chemistry, Biology, Biochemistry, Pharmacy, and Chemical Engineering. It is also a useful resource for researchers and professionals working in the fields of biomedicine and veterinary sciences, with clear explanations and examples of how the different bioanalytical devices are applied for clinical diagnosis.
Download or read book Determination of Total and Isotopic Uranium by Inductively Coupled Plasma mass Spectrometry at the Fernald Environmental Management Project written by and published by . This book was released on 1995 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the Fernald Environmental Management Project (FEMP) in southwestern Ohio, ICP-mass spectrometry (ICP-MS), with sample introduction by peristaltic pumping, is used to determine total and isotopic uranium (U-234, U-235, U-236 and U-238) in soil samples. These analyses are conducted in support of the environmental cleanup of the FEMP site. Various aspects of the sample preparation and instrumental analysis will be discussed. Initial sample preparation consists of oven drying to determine moisture content, and grinding and rolling to homogenize the sample. This is followed by a nitric/hydrofluoric acid digestion to bring the uranium in the sample into solution. Bismuth is added to the sample prior to digestion to monitor for losses. The total uranium (U-238) content of this solution and the U235/U238 ratio are measured on the first pass through the ICP-MS. To determine the concentration of the less abundant U234 and U236 isotopes, the digestate is further concentrated by using Eichrom TRU-Spec extraction columns before the second pass through the ICP-MS. Quality controls for both the sample preparation and instrumental protocols will also be discussed. Finally, an explanation of the calculations used to report the data in either weight percent or activity units will be given.
Download or read book Determination of Trace Elements written by Zeev B. Alfassi and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 622 pages. Available in PDF, EPUB and Kindle. Book excerpt: The best way to determine trace elements! This easy-to-use handbook guides the reader through the maze of all modern analytical operations. Each method is described by an expert in the field. The book highlights the advantages and disadvantages of individual techniques and enables pharmacologists, environmentalists, material scientists, and food industry to select a judicious procedure for their trace element analysis.
Download or read book Polyatomic Interferences on High Precision Uranium Isotope Ratio Measurements by MC ICP MS written by and published by . This book was released on 2015 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modern mass spectrometry and separation techniques have made measurement of major uranium isotope ratios a routine task; however accurate and precise measurement of the minor uranium isotopes remains a challenge as sample size decreases. One particular challenge is the presence of isobaric interferences and their impact on the accuracy of minor isotope 234U and 236U measurements. Furthermore, we present techniques used for routine U isotopic analysis of environmental nuclear safeguards samples and evaluate polyatomic interferences that negatively impact accuracy as well as methods to mitigate their impacts.
Download or read book Handbook of Radioactivity Analysis written by Michael F. L'Annunziata and published by Academic Press. This book was released on 2020-03-07 with total page 1076 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Radioactivity Analysis: Radiation Physics and Detectors, Volume One, and Radioanalytical Applications, Volume Two, Fourth Edition, constitute an authoritative reference on the principles, practical techniques and procedures for the accurate measurement of radioactivity - everything from the very low levels encountered in the environment, to higher levels measured in radioisotope research, clinical laboratories, biological sciences, radionuclide standardization, nuclear medicine, nuclear power, and fuel cycle facilities, and in the implementation of nuclear forensic analysis and nuclear safeguards. It includes sample preparation techniques for all types of matrices found in the environment, including soil, water, air, plant matter and animal tissue, and surface swipes.Users will find the latest advances in the applications of radioactivity analysis across various fields, including environmental monitoring, radiochemical standardization, high-resolution beta imaging, automated radiochemical separation, nuclear forensics, and more. - Spans two volumes, Radiation Physics and Detectors and Radioanalytical Applications - Includes a new chapter on the analysis of environmental radionuclides - Provides the latest advances in the applications of liquid and solid scintillation analysis, alpha- and gamma spectrometry, mass spectrometric analysis, Cherenkov counting, flow-cell radionuclide analysis, radionuclide standardization, aerosol analysis, high-resolution beta imaging techniques, analytical techniques in nuclear forensics, and nuclear safeguards - Describes the timesaving techniques of computer-controlled automatic separation and activity analysis of radionuclides - Provides an extensive table of the radiation characteristics of most radionuclides of interest for the radioanalytical chemist
Download or read book Introduction to Focused Ion Beams written by Lucille A. Giannuzzi and published by Springer Science & Business Media. This book was released on 2006-05-18 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction to Focused Ion Beams is geared towards techniques and applications. This is the only text that discusses and presents the theory directly related to applications and the only one that discusses the vast applications and techniques used in FIBs and dual platform instruments.
Download or read book Precise Isotope Ratio Measurements for Uranium Thorium and Plutonium by Quadrupole based Inductively Coupled Plasma Mass Spectrometry written by J. S. Becker and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inorganic Mass Spectrometry written by Sabine Becker and published by John Wiley & Sons. This book was released on 2008-02-28 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing an exhaustive review of this topic, Inorganic Mass Spectrometry: Principles and Applications provides details on all aspects of inorganic mass spectrometry, from a historical overview of the topic to the principles and functions of mass separation and ion detection systems. Offering a comprehensive treatment of inorganic mass spectrometry, topics covered include: Recent developments in instrumentation Developing analytical techniques for measurements of trace and ultratrace impurities in different materials This broad textbook in inorganic mass spectrometry, presents the most important mass spectrometric techniques used in all fields of analytical chemistry. By covering recent developments and advances in all fields of inorganic mass spectrometry, this text provides researchers and students with information to answer any questions on this topic as well as providing the basic fundamentals for understanding this potentially complex, but increasingly relevant subject.
Download or read book Inductively Coupled Plasma Mass Spectrometry written by Howard E. Taylor and published by Elsevier. This book was released on 2000-10-25 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inductively Coupled Plasma-Mass Spectrometry presents a concise A-Z description of inductively coupled plasma-mass spectrometry, written in layman's terms, for use in the solution of trace element analytical chemistry problems. Detailed discussion of sample introduction and data interpretation is provided. Practicing analytical chemists will be able to use this text to familiarize themselves with the principles, approaches, options, pitfalls, and advantages of ICP-MS technology. - Concise and straightforward descriptions of ICP-MS principles and instrumentation, ensuring rapid understanding of the technique and its advantages and limitations - Examples to clarify the operational characteristics of the technology - Drawings and illustrations to clarify principles, techniques, and methodology - Discussions of practical approaches to the solution of specific trace analysis problems with helpful tips on efficiently producing the most accurate and precise data - Easy-to-understand terms, so that new users of the technology will immediately benefit from the information provided - Comprehensive appendixes containing isotopic and interference data - An exhaustive compilation of literature citations for supplemental information
Download or read book Analysis of Environmental Radionuclides written by Pavel P. Povinec and published by Elsevier. This book was released on 2011-07-28 with total page 539 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to present a state of art summary of current knowledge of methods of assessment of radionuclides in the terrestrial and marine environments. It cover the traditional methods of radioactivity measurements such as radiometrics techniques, but also recent developments in the mass spectrometry sector. The book starts with a short preface introducing the subject of the book, summarising content and philosophy of the book, as well as the most important historical achievements. The scientific topics are introduced by description of sampling methods, optimisation of sampling sites and sampling frequency. The recent developments in radiochemical separation methods using chromatography resins for the treatment of actinides, transuranics and other groups of radioelements are also described. No other book is available covering all aspects of environmental radioactivity measurements, although remarkable progress has been made in detection techniques over the last ten years. At present the new methods enable to carry out investigations which were not possible before, either because of lack of sensitivity or because of the fact that they required too large samples.
Download or read book Karst Bauxites written by G. Bárdossy and published by Elsevier. This book was released on 2013-10-22 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Karst Bauxites: Bauxite Deposits on Carbonate Rocks presents a comparison of bauxite regions using mathematical statistics methods. This book is divided into eight chapters that highlight the quantitative processing and assessment of the information available for bauxites. The opening chapters present observational and analytical evidence concerning karst bauxite, with particular emphasis on Hungarian bauxite deposits. The typical features of bauxites are analyzed from a variety of aspects and results from different bauxite regions are compared. Other chapters consider the feature of metamorphosed karst bauxites. The remaining chapters discuss the conditions of formation of karst bauxites and with the factors controlling their geographic and stratigraphic distribution. This book will prove useful to geologists, mineralogists, and researchers.
Download or read book Isolation and Puification of Uranium Isotopes for Measurement by Mass Spectrometry 233 234 235 236 238U and Alpha Spectrometry 232U written by and published by . This book was released on 2006 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report describes a standardized methodology used by researchers from the Center for Accelerator Mass Spectrometry (CAMS) (Energy and Environment Directorate) and the Environmental Radiochemistry Group (Chemistry and Materials Science Directorate) at the Lawrence Livermore National Laboratory (LLNL) for the full isotopic analysis of uranium from solution. The methodology has largely been developed for use in characterizing the uranium composition of selected nuclear materials but may also be applicable to environmental studies and assessments of public, military or occupational exposures to uranium using in-vitro bioassay monitoring techniques. Uranium isotope concentrations and isotopic ratios are measured using a combination of Multi Collector Inductively Coupled Plasma Mass Spectrometry (MC ICP-MS), Accelerator Mass Spectrometry (AMS) and Alpha Spectrometry.
Download or read book Determination of Total and Isotopic Uranium and Total Thorium in Soils by Inductively Coupled Plasma Mass Spectrometry written by RN. Bolin and published by . This book was released on 1995 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inductively coupled plasma-mass spectrometry (ICP-MS), using standard sample introduction by peristaltic pumping, is presented as a method to determine total and isotopic uranium (234U, 235U, 236U, and 238U) and thorium (232Th) in soil samples. Initial sample preparation consists of oven drying to determine moisture content, and grinding and mixing the soil to make it homogenous. This is followed by a nitric/hydrofluoric acid digestion to bring the uranium into solution. Bismuth (209Bi) is added prior to digestion to monitor for losses due to sample preparation and analysis. An additional digestion, using nitric/perchloric acid is performed if the total thorium concentration is required on the sample. The uranium and thorium content of this solution and the 235U/238U ratio are measured on an initial pass through the ICP-MS. The total uranium measurement is based on the 238U isotope measurement with correction for the presence of the U isotopes. To determine the concentration of the less abundant 234U and 236U isotopes, the digestate is further concentrated by using a solid phase extraction column (TRUSpec by EiChrom Industries, Inc.) before a second pass through the ICP-MS.
Download or read book Fukushima Accident written by Pavel P. Povinec and published by Newnes. This book was released on 2013-07-09 with total page 397 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fukushima Accident presents up-to-date information on radioactivity released to the atmosphere and the ocean after the accident on the Fukushima Dai-ichi nuclear power plant, on the distribution of radionuclides in the world atmosphere and oceans, and their impact on the total environment (man, fauna, and flora). The book will evaluate and discuss the post-Fukushima situation, emphasizing radionuclide impacts on the terrestrial and marine environments, and compare it with the pre-Fukushima sources of radionuclides in the environment. The authors' results, as well as knowledge gathered from the literature, will provide up-to-date information on the present status of the topics. Fukushima Accident is based on the environmental and nuclear research; however, the presentation will be suitable for university-level readers. - 2013 PROSE Award winner in Environmental Science from the Association of American Publishers - Covers atmospheric and marine radioactivity, providing information on the global atmospheric dispersion of radionuclides in the atmosphere and world oceans - Examines radiation doses to the public and biota to understand the health risks to the public and ecosystems - Provides information on monitoring radionuclides in the environment – information on sources of radionuclides, their temporal and spatial variations, and radionuclide levels - Covers transport of radionuclides from different sources (e.g. nuclear power plants) as well as atmospheric simulations and modeling approaches
