Download or read book Iron Mineral Transformations and Electron Transfer Reactions in Redox Dynamic Environments written by Elizabeth J. Tomaszewski and published by . This book was released on 2017 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: Due to the abundance and redox potential of iron (Fe), the solubility and oxidation state of trace metals may be strongly influenced by redox reactions with Fe minerals. The ability of a Fe mineral to participate in electron transfer with trace metals, such as chromium (Cr), is dependent on a variety of properties and processes. These include, but are not limited to, surface area, mineral stoichiometry, and geochemical conditions, such as redox potential. This dissertation work examines Fe mineral transformations and electron transfer reactions with Cr(VI) under varying redox conditions. In the second chapter, the mineralogical transformations of ferrihydrite ((Fe10O14(OH)2)) are investigated during rapid, abiotic redox oscillations, at different concentrations of dissolved Fe(II). The stoichiometry of the secondary mineral magnetite (Fe3O4) increases overall throughout redox oscillations, despite repeated exposure to oxygen. This work demonstrates structural Fe(II) in Fe minerals may not be oxidized in the presence of oxygen and could be a source of electrons in redox dynamic environments. In the third chapter, goethite ([alpha]-FeOOH) is exposed to varying numbers of abiotic redox cycles (e.g., 1, 2, 3, or 4) and subsequently reacted with Cr(VI). The reduction of Cr(VI) to Cr(III) is observed, demonstrating that Fe(II) substituted within the goethite lattice during anoxic periods is not only preserved during oxic periods but also available for electron transfer. Regardless of the number of redox cycles to which goethite is exposed Cr consistently is associated with the (100) crystallographic face, a predicted site of electron conduction. Finally, the fourth chapter examines the electron transfer between Cr(VI) and the reduced quinone species, AH2DS in the presence and absence of goethite at three different ratios of AH2DS:Cr(VI). Goethite inhibits of the extent of Cr(VI) reduction to Cr(III) most significantly at the highest ratio of AH2DS:Cr(VI) investigated. Possible production of semi-quinone radical species may limit electron transfer and decrease the percent yields of Fe(II) and Cr(III). Additionally, solid phase characterization of Cr confirms the formation of Cr(OH)3 phases. Understanding abiotic electron transfer reactions that occur in systems with multiple redox active species is important to elucidate the contribution of abiotic redox reactions to biogeochemical cycling in natural soils.

Download or read book Investigations of Surface Redox Chemistry on Environmentally Relevant Iron Oxides and Sulfides written by Elizabeth B. Cerkez and published by . This book was released on 2016 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Important reactions in the environment often occur at the interface between a mineral surface and aqueous phase. Reactions occurring at this interface often control the uptake or release of harmful components resulting in the geochemical cycling of elements in the environment. Additionally, minerals are commonly used in the remediation of contaminated areas, where similar chemistry occurs at their interfaces. Thus, studies of the chemistry of these interfaces are essential to our understanding of complex environments. Many of these processes are controlled by electron transfer reactions between adsorbates and the mineral interface, and it is here where this research presented will concentrate. The studies in this thesis key in on redox chemistry on various environmentally relevant iron minerals, including ferrihydrite, pyrite, and amorphous iron sulfide. A large portion of this body of work is dedicated to the understanding of the surface mediated reaction between chromate (Cr(VI)) and arsenite (As(III)). Both of these species are present in the environment and are detrimental to human health. Using in- and ex-situ experiments we have monitored the coupled redox transformation of Cr(VI) and As(III) to chromite (Cr(III)) and arsenate (As(V)). Quantum mechanical modeling was used to support the experimental studies of this novel redox chemistry. The reaction was monitored in situ, using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), on the surface of the iron oxyhydroxide, ferrihydrite, at various solution pH values by following vibrational modes unique to Cr(VI), As(III), and As(V). At pH

Download or read book Redox written by J. Schüring and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt: Few processes are as important for environmental geochemistry as the interplay between the oxidation and reduction of dissolved and solid species. The knowledge of the redox conditions is most important to predict the geochemical behaviour of a great number of components, the mobilities of which are directly or indirectly controlled by redox processes. The understanding of the chemical mechanisms responsible for the establishment of measurable potentials is the major key for the evaluation and sensitive interpretation of data. This book is suitable for advanced undergraduates as well as for all scientists dealing with the measurement and interpretation of redox conditions in the natural environment.

Download or read book Environmental Soil Remediation and Rehabilitation written by Eric D. van Hullebusch and published by Springer Nature. This book was released on 2020-04-22 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive overview of innovative remediation techniques and strategies for soils contaminated by heavy metals or organic compounds (e.g. petroleum hydrocarbons, NAPLs and chlorinated organic compounds). It discusses various novel chemical remediation approaches (in-situ and ex-situ) used alone and in combination with physical and/or thermal treatment. Further, it addresses the recovery of NAPLs, reuse of leaching solutions, and in-situ chemical reduction and oxidation, and explores the chemical enhancement of physical NAPLs recovery from both practical and theoretical perspectives. Also presenting the state-of-the-art in waste-assisted bioremediation to improve soil quality and the remediation of petroleum hydrocarbons, the book is a valuable resource for students, researchers and R&D professionals in industry engaged in the treatment of contaminated soils.

Download or read book Aquatic Redox Chemistry written by Paul Tratnyek and published by OUP USA. This book was released on 2012-06-14 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides a comprehensive overview of aquatic redox chemistry through chapters contributed by many of the leading investigators in the field.

Download or read book Explaining Reaction Rates Between Iron Oxide Associated Ferrous Iron and Nitrobenzene written by Sydney Stewart and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Redox reactions have important implications for contaminant fate and transport in the environment, as they can lead to transformations that affect chemical mobility, toxicity, and bioavailability. Many classes of contaminants can be reduced by ferrous iron (Fe2+) associated with iron oxides in subsurface anoxic environments. These include contaminants containing nitroaromatic functional groups, which are common due to their widespread release into the environment as pesticides and explosives. Understanding the transformations of these chemicals is essential for determining how to remediate contaminated sites. Nitrobenzene is a useful proxy for nitroaromatic contaminants because it provides a relatively simple model system that can give insight into how more complex or less reactive chemicals are transformed in the environment.While the reduced products that form as a result of these reactions are often well characterized, the rates at which they occur are typically difficult to predict. Measured values from well-controlled laboratory studies frequently vary by orders of magnitude. In principle, these rates can be described and possibly estimated by the thermodynamic driving force of the reaction (e.g., reduction potential values for the reductant and oxidant), but demonstrating this has been difficult to test due to the difficulty in obtaining meaningful and reliable reduction potential values for iron redox couples. Recently, that limitation was overcome using mediated potentiometry, a technique that has led to a quantitative understanding of the thermodynamics of Fe2+-Fe oxy(hydr)oxide redox couples. Using mediated potentiometry, reduction potentials for these redox couples can be measured, predicted, and controlled.The ability to determine reduction potential of the Fe2+-Fe oxide couple introduces the opportunity to evaluate the relationship between reaction rates and thermodynamic parameters. In this study, I hypothesized that reduction potentials could be used to explain redox reaction rates between nitrobenzene and the Fe2+-goethite (-FeOOH) couple. This was tested by measuring nitrobenzene reduction rates as a function of solution pH, Fe2+ concentration, and goethite loading. With these results, the reduction potential of the Fe2+-goethite couple was correlated with the reaction rate constant over all solution conditions using a linear free energy relationship (LFER). The reduction of nitrobenzene was rate-limited by the first electron transfer and the first proton transfer steps, which appeared to be coupled. The best correlation for the data was achieved by normalizing the reaction rate constant to surface area of the oxide, implying nitrobenzene was reduced at the oxide surface by delocalized electrons within the solid, rather than directly by discrete oxide-associated Fe2+ sites.This LFER was further used to determine how changing the goethite particle size, and hence its thermodynamic properties, influence nitrobenzene reduction rates. From experiments with nanogoethite-associated Fe2+, it was found that the surface area normalized reaction rates for nitrobenzene with the Fe2+-nanogoethite couple were better described by the reduction potential of micron-sized goethite than that of nanogoethite. This data suggests that reduction rates by goethite-associated Fe2+ kinetically depend on the surface area of the oxide, but the thermodynamic driving force of the reaction only depends on the standard reduction potential of bulk goethite. These conclusions were further supported by comparisons to data in the literature for goethite and hematite-catalyzed reactions with substituted nitrobenzenes. Previously reported reaction rates correlated well with the LFER developed in this study.These results corroborate the hypothesis that redox reactions involving Fe2+-Fe oxy(hydr)oxide couples could be explained by growth of the oxy(hydr)oxide crystals. The reduction potential of this reaction describes the thermodynamic driving force of nitroaromatic reduction, and the reaction rate is related to the surface area of the oxides. Ultimately, this work provides insight into the mechanisms of important environmental transformations, and can lead to improved predictive models for contaminant reduction rates as a function of geochemical conditions.

Download or read book Mineral Surfaces written by D. Vaughan and published by Springer. This book was released on 1995 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: 30% discount for members of The Mineralogical Society of Britain and Ireland This text summarises the state-of-the-art in the study of mineral surfaces and some of the key applications of surface science in mineralogy and mineral chemistry. Each chapter covers a particular aspect of the subject and is written by an expert who raises the key issues involved for those requiring an introduction to the subject, whilst highlighting most recent developments. Advanced undergraduates, postgraduates and researchers alike will find this essential reading as it is the first book to review the fast developing field of mineral surfaces.

Download or read book Environmental and Low Temperature Geochemistry written by Peter Ryan and published by John Wiley & Sons. This book was released on 2019-11-01 with total page 890 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmental and Low-Temperature Geochemistry presents conceptual and quantitative principles of geochemistry in order to foster understanding of natural processes at and near the earth’s surface, as well as anthropogenic impacts and remediation strategies. It provides the reader with principles that allow prediction of concentration, speciation, mobility and reactivity of elements and compounds in soils, waters, sediments and air, drawing attention to both thermodynamic and kinetic controls. The scope includes atmosphere, terrestrial waters, marine waters, soils, sediments and rocks in the shallow crust; the temporal scale is present to Precambrian, and the spatial scale is nanometers to local, regional and global. This second edition of Environmental and Low-Temperature Geochemistry provides the most up-to-date status of the carbon cycle and global warming, including carbon sources, sinks, fluxes and consequences, as well as emerging evidence for (and effects of) ocean acidification. Understanding environmental problems like this requires knowledge based in fundamental principles of equilibrium, kinetics, basic laws of chemistry and physics, empirical evidence, examples from the geological record, and identification of system fluxes and reservoirs that allow us to conceptualize and understand. This edition aims to do that with clear explanations of fundamental principles of geochemistry as well as information and approaches that provide the student or researcher with knowledge to address pressing questions in environmental and geological sciences. New content in this edition includes: Focus Boxes – one every two or three pages – providing case study examples (e.g. methyl isocyanate in Bhopal, origins and health effects of asbestiform minerals), concise explanations of fundamental concepts (e.g. balancing chemical equations, isotopic fractionation, using the Keq to predict reactivity), and useful information (e.g. units of concentration, titrating to determine alkalinity, measuring redox potential of natural waters); Sections on emerging contaminants for which knowledge is rapidly increasing (e.g. perfluorinated compounds, pharmaceuticals and other domestic and industrial chemicals); Greater attention to interrelationships of inorganic, organic and biotic phases and processes; Descriptions, theoretical frameworks and examples of emerging methodologies in geochemistry research, e.g. clumped C-O isotopes to assess seawater temperature over geological time, metal stable isotopes to assess source and transport processes, X-ray absorption spectroscopy to study oxidation state and valence configuration of atoms and molecules; Additional end-of-chapter problems, including more quantitatively based questions. Two detailed case studies that examine fate and transport of organic contaminants (VOCs, PFCs), with data and interpretations presented separately. These examples consider the chemical and mineralogical composition of rocks, soils and waters in the affected system; microbial influence on the decomposition of organic compounds; the effect of reduction-oxidation on transport of Fe, As and Mn; stable isotopes and synthetic compounds as tracers of flow; geological factors that influence flow; and implications for remediation. The interdisciplinary approach and range of topics – including environmental contamination of air, water and soil as well as the processes that affect both natural and anthropogenic systems – make it well-suited for environmental geochemistry courses at universities as well as liberal arts colleges.

Download or read book Redox Reactions and Phase Transformation Processes at Iron Mineral Surfaces Studied by Compound Specific Isotope Analysis written by Anke Buchholz and published by . This book was released on 2009 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Impact of Small Organic Acids on Iron and Manganese Mineral Transformations and the Fate of Trace Metals written by Elaine Denise Flynn and published by . This book was released on 2018 with total page 143 pages. Available in PDF, EPUB and Kindle. Book excerpt: Iron and manganese oxides are ubiquitous in soils and sediments and play a critical role in the geochemical distribution of trace elements and heavy metals through adsorption and coprecipitation. At redox interfaces, biogeochemical processes generate conditions with coexisting dissolved Fe(II) and solid-phase Fe(III). In such systems, Fe(II) induces the recrystallization of iron oxides through coupled mineral growth and dissolution due to electron transfer as oxidative adsorption of Fe(II) and reductive dissolution of Fe(III) occur. Aqueous Mn(II) adsorption onto Mn(III/IV) oxides also likely involves oxidation although likely through different mechanisms than that of the Fe system because of the potential for Mn(II)-Mn(IV) comproportionation reactions. During reactions between reduced and oxidized forms of Fe and Mn, trace metals may be redistributed among the mineral bulk, mineral surface, and aqueous solution. Many metals, including Ni and Zn, are important micronutrients but are also toxic at higher concentrations. It is important to identify the processes controlling the fate and availability of trace metals in the environment and this requires understanding the behavior and stability of Fe and Mn oxides. Small organic acids, produced as root exudates or by decomposition of organic matter in aerated soils, may potentially alter reactions involving Fe and Mn oxide minerals and trace metals through a series of cooperative or competitive processes: solution complexation, ternary surface complexation, surface site competition, ligand-promoted dissolution, and reductive dissolution. The effects of organic acids on trace metal fate in such systems is unclear because these processes may involve both trace metals and Fe or Mn oxides, and multiple processes may co-occur. The main objective of this dissertation is to determine how organic acids interacting with Fe and Mn oxides affect structural transformations of these minerals, including dissolution and recrystallization, and the resulting impact on trace metals micronutrient and contaminant fate. Three main research projects were conducted to meet this objective. First, the cooperative and competitive interactions between oxalate and Ni during adsorption to Fe oxide minerals were identified. Next, the effects of oxalate on Ni incorporation into and release from Fe oxides at pH 4 and 7 was investigated during Fe(II)-promoted recrystallization of these minerals. Finally, reductive transformations of layered Mn oxides by oxalate, citrate, and 4-hydroxybenzoate at pH 4, 5.5, and 7 were characterized as well as the associated changes in Ni and Zn adsorption extent and mechanisms. The addition of oxalate in macroscopic adsorption studies suppresses Ni uptake by goethite and hematite at pH 7. Aqueous speciation modelling indicates that this is dominantly the result of oxalate complexing and solubilizing Ni. Comparison of the Ni surface coverage to the concentration of free (uncomplexed) Ni2+ in solution suggests that oxalate also alters Ni adsorption affinity. Extended X-ray absorption fine structure and attenuated total reflectance Fourier transform infrared spectroscopies indicate that these changes in binding affinity are due to the formation of Ni-oxalate ternary surface complexes. When Ni is initially structurally-incorporated into hematite and goethite, oxalate and dissolved Fe(II) each promote the release of Ni to aqueous solution at pH 4 and 7. With the co-addition of both species, the effects on Ni release are synergistic at pH 7 but inhibitory at pH 4. This suggests that cooperative and competitive interactions vary with pH. In contrast, oxalate suppresses Ni incorporation into goethite and hematite during Fe(II)-induced recrystallization. Mn oxides may undergo redox and structural changes which can weaken trace metal binding and promote metal mobility. The conditions studied to date involve Mn(II) and are most similar to those found at redox interfaces which are limited in spatial extent in nature. Aging e-MnO2 and hexagonal birnessite in the presence of small organic acids was investigated using powder X-ray diffraction and X-ray absorption fine structure spectroscopic measurements. Organic acids caused partial Mn reduction but did not substantially alter the phyllomanganates sheet structure nor result in transformations to Mn(III) oxyhydroxides or mixed-valent minerals. All organic acids were fully consumed, producing solid-phase Mn(II) and Mn(III) as well as dissolved Mn(II), the latter favored under acidic pH conditions. Citrate caused the greatest reduction, with its oxidation products continuing to react and near-complete mineralization observed at pH 4. These redox reactions improved stacking of the phyllomanganate sheets for e-MnO2 at pH 7 and enhanced capping of vacancy sites by cations occurred for both minerals under all conditions studied. As a result of this mineral alteration, Ni and Zn adsorption behaviors were also modified. Net metal uptake did not change substantially at pH 7 where nearly all of the Ni and Zn in the system were adsorbed to the mineral surface. However, at pH 4, adsorption of Ni and Zn decreased in the presence of the organic acids. Ni adsorption mechanisms transitioned from binding above vacancy sites to at sheet edges in the presence of citrate and 4-hydroxybenzoate, while oxalate increased binding above and in vacancy sites; citrate inhibited Ni incorporation into vacancies. Zn adsorption also transitioned to binding at weaker sites on the particle edges. The adsorption behaviors of Ni and Zn suggest that during reaction with organic acids, phyllomanganate mineral reactivities towards metals are altered by organic acids via a decrease in the vacancy content of Mn oxides. This work improves our understanding of the effect of Fe and Mn oxides in soils and aquatic systems on micronutrient availability and heavy metals sequestration. Oxalate largely enhances trace metal mobility through multiple processes occurring in solution and on Fe oxide surfaces. Similarly, phyllomanganates structural changes in the presence of oxalic, citric, and 4-hydroxybenzoate alter the reactivity of Mn oxides through Mn reduction and subtle structural changes. Overall, this dissertation demonstrates that complex interactions at Fe and Mn oxide surfaces with organic acids must be considered when evaluating micronutrient availability and contaminant sequestration in the environment.

Download or read book Iron Oxides written by Damien Faivre and published by John Wiley & Sons. This book was released on 2016-08-08 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt: Alle relevanten Informationen zu Eisenoxiden, von der Struktur und Transformation über Charakterisierungsverfahren bis hin zu den neuesten AnwendungEN. Ein Muss für alle, die in dem Fachgebiet arbeiten.

Download or read book 2015 Progress Report July 2016 written by and published by . This book was released on 2016 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt: Despite decades of research on the reactivity and stable isotope properties of Fe oxides, the ability to describe the redox behavior of Fe oxides in the environment is still quite limited. This is due, in large part, to the analytical and spatial complexities associated with studying microscopic processes at the Fe oxide-water interface. This project had the long-term vision of filling this gap by developing a detailed understanding of the relationship between interfacial ET processes, surface structure and charge, and mineral semiconducting properties. We focused on the Fe(III)-oxides and oxyhydroxides because of their geochemical preponderance, versatility in synthesis of compositionally, structurally, and morphologically tailored phases, and because they are amenable to a wide range of surface and bulk properties characterization. In particular, reductive transformation of phases such as hematite (?-Fe2O3) and goethite (?-FeOOH) in aqueous solution can serve as excellent model systems for studies of electron conduction processes, as well as provide valuable insights into effect of nanoscale conductive materials on contaminant fate at DOE sites. More specifically, the goal of the Iowa component of this project was to use stable Fe isotope measurements to simultaneously measure isotope specific oxidation states and concentrations of Fe at the hematite-water and goethite-water interface. This work builds on our previous work where we used an innovative combination of 57Fe Mössbauer spectroscopy and high precision isotope ratio measurements (MC-ICP-MS) to probe the dynamics of the reaction of aqueous Fe(II) with goethite. Mössbauer spectroscopy detects 57Fe only among all other Fe isotopes and we have capitalized on this to spectroscopically demonstrate Fe(II)-Fe(III) electron transfer between sorbed Fe(II) and Fe(III) oxides (Handler, and others, 2009; Gorski, and others 2010; Rosso and others, 2010). By combining the Mössbauer spectroscopy and stable isotopes measurements, we have been able to simultaneously track the oxidation state and isotope concentration of the bulk Fe oxide and aqueous Fe. One of our most compelling findings is that despite the apparent stability of the Fe(II)-goethite system, there is actually a tremendous amount of Fe atom cycling occurring between the aqueous phase and the bulk goethite as indicated by the isotopic composition of both phases approaching the mass balance average (Handler and others, 2009). How such extensive re-crystallization and Fe atom exchange can occur with no significant morphological change is a fascinating question. Based on previous work from PI Rosso’s group showing that a potential gradient across hematite crystal faces leads to conduction through hematite and growth and dissolution at separate crystal faces we proposed that a redox-driven recrystallization could be occurring that would explain the extensive mixing observed with the isotope data. From our previous studies utilizing Mössbauer spectroscopy, we know that sorption of Fe(II) onto goethite results in electron transfer between the sorbed Fe(II) and the structural Fe(III) in goethite. Oxidation of the sorbed Fe(II) produces growth of goethite on goethite (id est, homoepitaxy), as well as injection of an electron into goethite. It is possible that electron transfer from sorbed Fe(II) occurs across a potential gradient, and that Fe(II) atoms are dissolved at a different location on the goethite surface. These newly-reduced Fe(II) atoms could then dissolve into the aqueous phase, exposing fresh Fe(III) goethite to the aqueous phase. Through a repeated series of these five steps of sorption–electron transfer–crystal growth–conduction– dissolution, a redox-driven conveyor belt, could be established that would allow all of the goethite to be eventually exposed to the aqueous phase and exchanged. This surface-mediated recrystallization process would result in similar Fe isotope distributions i...

Download or read book Iron in Soils and Clay Minerals written by J.W. Stucki and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: Probably more than any other element, iron markedly influences the chemical and physical properties of soils and sediments in the earth. Considering its transition metal status, with potential variation in electronic configuration, ionic radius, and magnetic moment, combined with its abundance and relatively large mass, little wonder that one sees its unique influence on every hand. Pre sentations at the NATO Advanced Study Institute (NATO AS!) on Iron in Soils and Clay Minerals reviewed and discussed the occurrence, behavior, and properties of Fe-bearing minerals found in soils and in the clay mineral groups kaolinite, smectite, and mica. Also discussed at the NATO AS! were the basic chemical properties of Fe, methods for separating and identifying Fe in minerals, and the role of Fe minerals in weathering and other soil-forming processes. The present publication is the reviewed and edited proceedings of that Advanced Study Institute. The sequence of chapters follows the general pattern beginning with introductory chapters which overview the general occurrence of Fe in the earth and its chemistry, both generally and in mineral environments, followed by identification and characterization methods for Fe and Fe phases in minerals. The properties and behavior of Fe oxides, Fe-bearing clay minerals, and other Fe minerals in soils are then described, and the text ends with a summary of the role of Fe in soil-forming processes. A Table of Contents and subject index are provided to assist the reader in finding specific topics within the text.

Download or read book Iron Oxides written by Damien Faivre and published by John Wiley & Sons. This book was released on 2016-04-12 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compiling all the information available on the topic, this ready reference covers all important aspects of iron oxides. Following a preliminary overview chapter discussing iron oxide minerals along with their unique structures and properties, the text goes on to deal with the formation and transformation of iron oxides, covering geological, synthetic, and biological formation, as well as various physicochemical aspects. Subsequent chapters are devoted to characterization techniques, with a special focus on X-ray-based methods, magnetic measurements, and electron microscopy alongside such traditional methods as IR/Raman and Mössbauer spectroscopy. The final section mainly concerns exciting new applications of magnetic iron oxides, for example in medicine as microswimmers or as water filtration systems, while more conventional uses as pigments or in biology for magnetoreception illustrate the full potential. A must-read for anyone working in the field.

Download or read book Molecular Modeling of Geochemical Reactions written by James D. Kubicki and published by John Wiley & Sons. This book was released on 2016-07-12 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular processes in nature affect human health, the availability of resources and the Earth’s climate. Molecular modelling is a powerful and versatile toolbox that complements experimental data and provides insights where direct observation is not currently possible. Molecular Modeling of Geochemical Reactions: An Introduction applies computational chemistry to geochemical problems. Chapters focus on geochemical applications in aqueous, petroleum, organic, environmental, bio- and isotope geochemistry, covering the fundamental theory, practical guidance on applying techniques, and extensive literature reviews in numerous geochemical sub-disciplines. Topics covered include: • Theory and Methods of Computational Chemistry • Force Field Application and Development • Computational Spectroscopy • Thermodynamics • Structure Determination • Geochemical Kinetics This book will be of interest to graduate students and researchers looking to understand geochemical processes on a molecular level. Novice practitioners of molecular modelling, experienced computational chemists, and experimentalists seeking to understand this field will all find information and knowledge of use in their research.

Download or read book Selected Water Resources Abstracts written by and published by . This book was released on 1991 with total page 884 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1994 with total page 836 pages. Available in PDF, EPUB and Kindle. Book excerpt: