Download or read book Iron Compounds in Organic Synthesis written by Anthony J. Pearson and published by . This book was released on 1994 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Despite this, the use of organoiron complexes in organic synthesis has been somewhat restricted compared with, for example, palladium, rhodium and other metals that are mainly used in catalytic processes.
Download or read book The Organic Chemistry of Iron Pt 1 written by Ernst A. Koerner Von Gustorf and published by Elsevier. This book was released on 2012-12-02 with total page 686 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organic Chemistry of Iron, Volume 1 covers the structures and bonding and the applications of a variety of physical techniques to organo-iron compounds, optically active compounds, as well as chapters on ?-bonded, ?2-, ?3-, and ?4-organo-iron compounds. The book discusses the structure and bonding in organic iron compounds; NMR spectroscopy of organoiron compounds; and mass spectra. The text also describes Mössbauer spectroscopy; magnetic properties; electron paramagnetic resonance; and optical activity of iron. Compounds with iron-carbon?-bonds; monoolefin iron complexes; allyl iron complexes; and diene iron complexes are also considered. The stabilization of unstable species with carbonyliron is also encompassed.
Download or read book The Organic Chemistry Of iron Pt 2 written by Ernst A. Koerner Von Gustorf and published by Elsevier. This book was released on 2012-12-02 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organic Chemistry of Iron, Volume 2 covers a series of selected topics in organo-iron chemistry, including complexes with poly-olefins, arenes, and sulfur-containing ligands, as well as an account of iron-metal bonds. The book discusses the iron complexes of trienes, tetraenes, and polyenes; the arene complexes; the compounds with iron-metal bonds and clusters; and the complexes with sulfur-containing ligands.
Download or read book The Organic Chemistry of Iron written by Ernest A. Koerner von Gustorf and published by . This book was released on 1981 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Iron Catalysis in Organic Chemistry written by Bernd Plietker and published by John Wiley & Sons. This book was released on 2008-09-08 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first comprehensive book to cover this exciting field also deals with the biological aspects, such as enzymes with iron. Following an introduction, this handy reference and handbook goes on to deal with reductions, oxidations of C, H- and C=C bonds, oxidative allylic oxygenation and amination, the oxidation of heteroatoms, cross coupling reactions, aromatic and nucleophilic substitutions, addition to carbonyl compounds, and cyclisations as well as ring opening reactions. The chapters are clearly classified according to the reaction type, allowing readers to quickly locate the desired information.
Download or read book Iron Catalysis written by Bernd Plietker and published by Springer Science & Business Media. This book was released on 2011-01-05 with total page 227 pages. Available in PDF, EPUB and Kindle. Book excerpt: Juan I. Padrón and Víctor S. Martín: Catalysis by means of Fe-based Lewis acids; Hiroshi Nakazawa*, Masumi Itazaki: Fe–H Complexes in Catalysis; Kristin Schröder, Kathrin Junge, Bianca Bitterlich, and Matthias Beller: Fe-catalyzed Oxidation Reactions of Olefins, Alkanes and Alcohols: Involvement of Oxo- and Peroxo Complexes; Chi-Ming Che, Cong-Ying Zhou, Ella Lai-Ming Wong: Catalysis by Fe=X Complexes (X=NR, CR2); René Peters, Daniel F. Fischer and Sascha Jautze: Ferrocene and Half Sandwich Complexes as Catalysts with Iron Participation; Markus Jegelka, Bernd Plietker: Catalysis by Means of Complex Ferrates.
Download or read book The Chemistry of Organoiron Compounds written by Ilan Marek and published by Wiley. This book was released on 2014-05-19 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of Patai’s Chemistry of Functional Groups each volume in this series treats all aspects of functional groups. Each volume contains chapters on a wide range of topics. Starting with theoretical aspects, this volume moves to analytical methods, such as thermochemistry, mass spectrometry and Mössbauer spectroscopy. This is followed by some general organic chemistry contributions on different classes of iron compounds such as Ferrocenes. This culminates in a range of articles hightlighting the use of organoiron compounds as reagents and as catalysts.
Download or read book Chemistry of Iron written by J. Silver and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is designed to be of use to the reader in two different ways. First, it is intended to provide a general introduction to all aspects of iron chemistry for readers from a variety of different scientific backgrounds. It has been written at a level suitable for use by graduates and advanced undergraduates in chemistry and biochemistry, and graduates in physics, geology, materials science, metallurgy and biology. It is not designed to be a dictionary of iron compounds but rather to provide each user with the necessary tools and background to pursue their ,individual interests in the wide areas that are influenced by the chemistry of iron. To achieve this goal each chapter has been written by a contemporary expert active in the subject so that the reader will benefit from their individual insight. Although it is generally assumed that the reader will have an understanding of bonding theories and general chemistry, the book is well referenced so that any deficiencies in the reader's background can be addressed. The book was also designed as a general reference book for initial pointers into a scientific literature that is growing steadily as the understanding and uses of this astonishingly versatile element continue to develop. To meet this aim the book attempts some coverage of all aspects of the chemistry of iron, not only outlining what understanding has been achieved to date but also identifying targets to be aimed at in the future.
Download or read book Recent Advances in Iron Catalysis written by Hans-Joachim Knölker and published by . This book was released on 2020-09-28 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal-catalyzed reactions play a key role in many transformations of synthetic organic chemistry. For most of these reactions, noble metals, for example, palladium, have been used as catalysts. Over the last two decades, more and more first row transition metals have been applied as catalysts for organic reactions, with iron taking the center stage. The driving forces behind this development are not only the high costs for the noble metals but also their toxicity. Iron is the most abundant transition metal in the Earth's crust, and thus, it is considerably cheaper than the precious noble metals. Moreover, iron compounds are involved in many biological processes, and thus, iron exhibits a low toxicity. Because of this low toxicity, iron-catalyzed reactions are important for an environmentally benign sustainable chemistry. However, iron catalysts are not only investigated to replace noble metals; they offer many applications in synthesis beyond those of classical noble metal catalysts. Several articles of the present book emphasize the complementarity of iron-catalyzed reactions as compared to reactions catalyzed by noble metals. The book shows intriguing recent developments and the current standing of iron-catalyzed reactions as well as applications to organic synthesis.
Download or read book Iron Catalysis II written by Eike Bauer and published by Springer. This book was released on 2015-07-23 with total page 367 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Download or read book The Chemistry of Iron Cobalt and Nickel written by D. Nicholls and published by Elsevier. This book was released on 2013-10-02 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Iron, Cobalt and Nickel deals with the chemistry of iron, cobalt, and nickel and covers topics ranging from the occurrence and distribution of all three elements to their properties, allotropy, and analytical chemistry. Compounds of iron, cobalt, and nickel in both low and high oxidation states are also discussed. This book is divided into three sections and begins with the history of iron, along with its occurrence and distribution, allotropy, and preparation and industrial production. The nuclear, physical, and chemical properties of iron, as well as the biological importance of iron compounds, are also considered. Compounds of iron are discussed, including carbonyls and nitric oxide complexes. The next two sections deal with the history, occurrence and distribution, allotropy, analytical chemistry, and preparation and industrial production of cobalt and nickel, along with their nuclear, physical, and chemical properties. Compounds of cobalt and nickel are examined, from carbonyls and nitrosyls to cyanides and organometallic compounds. This monograph will be a useful resource for inorganic chemists.
Download or read book Iron Carbene Complexes written by Wolfgang Petz and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: E.O. Fischer received the Nobel prize in 1973 for the investigations of complexes with a formal metal atom-carbon double bond. Among these, the Iron-Carbene species is readily available and has proved to be a versatile reagent in organic syntheses. It is rather simple to tune the electronicproperties of this Fischer Carbene and to control reactivity and stereospecificity of the reagent in, e.g., cyclopropanation reactions. This first volume of the "Scripts in Inorganic and Organome- tallic Chemistry" addresses graduate students in the fields ofcoordination compounds and organic synthesis. It covers the chemistry and structural aspects of iron-carbon com- pounds with a iron-carbon double bond. The first part deals with the carbene moiety, the second with vinylidene ligands.
Download or read book Organotransition Metal Chemistry Applications to Organic Synthesis written by S. G. Davies and published by Elsevier. This book was released on 2013-10-22 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.
Download or read book Iron Catalyzed Synthesis of Fused Aromatic Compounds via C H Bond Activation written by Arimasa Matsumoto and published by Springer. This book was released on 2014-07-08 with total page 84 pages. Available in PDF, EPUB and Kindle. Book excerpt: Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.
Download or read book Iron III Phosphate written by Farahnaz K. Behbahani and published by . This book was released on 2019-04-17 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the synthesis, properties, uses, structure, and safety of iron (III) phosphate, as well as its use as an intercalation electrode in lithium-ion batteries, despite having low electronic conductivity. In the synthesis of organic compounds, iron (III) phosphate catalyzes the one-pot synthesis of dihydropyrimidinones and thiones, and 2, 4, 5triarylated imidazoles. It also results in the acetylation of alcohols and phenols, the tetrahydropyranylation and tetrahydrofuranylation of alcohols and phenols, as well as the synthesis of polyhydroquinoline derivatives, 2-substituted benzimidazoles, 1, 2-disubstituted benzimidazoles, 1,2,4,5-tetra-arylated imidazoles, and bis(indolyl)methanes. Furthermore, it catalyzes the one pot three-component mannich reaction, 2-substituted imidazolines, ß-amido carbonyl compounds, 1,4-dihydropyridines, 4,4-diaminotriaryl methanes-leucomalachite materials, N-substituted pyrroles, 7,10,11,12-tetrahydrobenzo[c] acridin-8(9h)-ones, and 4,6-disubstituted 2-aminopyridine-3-carbonitriles. It results in the one-pot synthesis of octahydroquinazolinones, the conversion of tetrahydropyranyl ethers to acetates, dihydropyrimidinones, thiones, as well as β-amino ketones. In the authors opinion, this book could be beneficial for researchers, graduates, and post graduate students, as well as for professionals in the chemical and medicinal industries in the preparation of raw materials using green methods.
Download or read book Organometallics in Synthesis written by Manfred Schlosser and published by John Wiley & Sons. This book was released on 2013-04-15 with total page 1028 pages. Available in PDF, EPUB and Kindle. Book excerpt: WINNER of the 2013 PROSE Award in Chemistry & Physics This latest edition enables readers to master new classes of organometallic compounds and syntheses A popular resource used by synthetic organic chemists around the world, this book enables readers to conduct seamless synthetic reactions involving key organometallics. Each reaction is set forth in the book's acclaimed recipe-style format so that readers can easily replicate the results in their own labs. Moreover, each chapter has been written by a world leader in the field of organometallics in organic synthesis. These authors offer hands-on guidance and practical examples illustrating the preparation of organometallics and its application in organic synthesis. This Third Manual of Organometallics in Synthesis features completely new content and topics, with an eye towards providing researchers with the most useful and practical reference on the synthesis of organometallics. Organized into chapters by type of organometallic compound, the book covers: Organoalkali chemistry Organomagnesium and organozinc chemistry Organosilicon and relating organotin chemistry Organoiron chemistry Organopalladium chemistry Within each chapter, readers will find background information to learn more about the class of organometallics as well as mechanistic considerations. The authors thoroughly discuss the various methods of preparing the organometallic compounds presented in the book and outline their uses in synthetic reactions. In addition to current applications, the authors explore future research opportunities for each organometallic class. References at the end of each chapter enable readers to explore all the topics in greater depth. More and more industrial processes rely on organometallic chemistry. As a result, readers will find this book's step-by-step instructions essential in such fields as natural product synthesis, pharmaceuticals, fine chemicals, biotechnology, polymers, and materials science.
Download or read book Iron Metalate Reactions with Carbonyl Containing Compounds and Use in Organic Synthesis written by Ronald Damian Theys and published by . This book was released on 1994 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt:
