Download or read book Iron Carbene Complexes written by Wolfgang Petz and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: E.O. Fischer received the Nobel prize in 1973 for the investigations of complexes with a formal metal atom-carbon double bond. Among these, the Iron-Carbene species is readily available and has proved to be a versatile reagent in organic syntheses. It is rather simple to tune the electronicproperties of this Fischer Carbene and to control reactivity and stereospecificity of the reagent in, e.g., cyclopropanation reactions. This first volume of the "Scripts in Inorganic and Organome- tallic Chemistry" addresses graduate students in the fields ofcoordination compounds and organic synthesis. It covers the chemistry and structural aspects of iron-carbon com- pounds with a iron-carbon double bond. The first part deals with the carbene moiety, the second with vinylidene ligands.
Download or read book Synthesis and Reactivity of Iron Carbene Complexes written by Fred Boyle McCormick and published by . This book was released on 1980 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemistry of Iron written by J. Silver and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is designed to be of use to the reader in two different ways. First, it is intended to provide a general introduction to all aspects of iron chemistry for readers from a variety of different scientific backgrounds. It has been written at a level suitable for use by graduates and advanced undergraduates in chemistry and biochemistry, and graduates in physics, geology, materials science, metallurgy and biology. It is not designed to be a dictionary of iron compounds but rather to provide each user with the necessary tools and background to pursue their ,individual interests in the wide areas that are influenced by the chemistry of iron. To achieve this goal each chapter has been written by a contemporary expert active in the subject so that the reader will benefit from their individual insight. Although it is generally assumed that the reader will have an understanding of bonding theories and general chemistry, the book is well referenced so that any deficiencies in the reader's background can be addressed. The book was also designed as a general reference book for initial pointers into a scientific literature that is growing steadily as the understanding and uses of this astonishingly versatile element continue to develop. To meet this aim the book attempts some coverage of all aspects of the chemistry of iron, not only outlining what understanding has been achieved to date but also identifying targets to be aimed at in the future.
Download or read book High and Low Valent tris N Heterocyclic Carbene Iron Complexes written by Carola S. Vogel and published by Springer Science & Business Media. This book was released on 2012-02-03 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.
Download or read book Synthesis and Reactions of Iron Carbene Complexes Synthesis and Reactions of Bridging Methylene Complexes written by William Herbert Miles and published by . This book was released on 1984 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organic Synthesis written by Belakatte Parameshwarappa Nandeshwarappa and published by BoD – Books on Demand. This book was released on 2020-05-27 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book ‘Organic Synthesis - A Nascent Relook’ is a compendium of the recent progress in all aspects of organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic, green chemistry and medicinal chemistry, polymer chemistry, as well as analytical methods in organic chemistry. The book presents the latest developments in these fields. The chapters are written by chosen experts who are internationally known for their eminent research contributions. Organic synthesis is the complete chemical synthesis of a target molecule. In this book, special emphasis is given to the synthesis of various bioactive heterocycles. Careful selection of various topics in this book will serve the rightful purpose for the chemistry community and the industrial houses at all levels.
Download or read book Preparation of Iron carbene Complexes and Their Applications in Organic Synthesis written by Jane Sohn and published by . This book was released on 2003 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Carbenes in Organic Synthesis written by K H Dtz and published by Springer Science & Business Media. This book was released on 2004-09-21 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts
Download or read book Photophysics and Photochemistry of Iron Carbene Complexes written by Linnea Lindh and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book N Heterocyclic Carbenes written by Silvia Diez-Gonzalez and published by Royal Society of Chemistry. This book was released on 2016-11-04 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.
Download or read book Synthesis Spectral Characterization and Reactions of Electrophilic Organo iron Carbene Complexes written by James Robinson Tucker and published by . This book was released on 1981 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Carbenes in Organic Synthesis written by Florencio Zaragoza Dörwald and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are hardly more versatile compounds in organic synthesis than carbene complexes. The rapid development of new synthetic methods involving carbene complexes - stereoselective cyclopropanation, carbonyl olefination, olefin metathesis, etc. - reveals the value and high potential of these compounds. Their application ranges from the synthesis of fine chemicals to polymer production. This comprehensive, well structured handbook presents the fundamental principles and the recent advances in carbene complex chemistry. Arranged according to structure and reactivity, all relevant classes of carbene complexes, their generation, and application in organic synthesis are discussed in detail. Critically selected, up-to-date references and valuable experimental procedures await the reader. Every chemist searching for a concise introduction and reference work for carbene complex chemistry will welcome this practical guide. "...this concise presentation of all the aspects of the use of carbene complexes in synthesis will help provide the impetus for even more rapid developments in this field of research." R. H. Grubbs (Caltech)
Download or read book Synthesis and Reactivity of Carbene Complexes of Iron Ruthenium and Osmium Porphyrins written by Yan Li and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Iron Catalysis written by Bernd Plietker and published by Springer. This book was released on 2011-01-03 with total page 227 pages. Available in PDF, EPUB and Kindle. Book excerpt: Juan I. Padrón and Víctor S. Martín: Catalysis by means of Fe-based Lewis acids; Hiroshi Nakazawa*, Masumi Itazaki: Fe–H Complexes in Catalysis; Kristin Schröder, Kathrin Junge, Bianca Bitterlich, and Matthias Beller: Fe-catalyzed Oxidation Reactions of Olefins, Alkanes and Alcohols: Involvement of Oxo- and Peroxo Complexes; Chi-Ming Che, Cong-Ying Zhou, Ella Lai-Ming Wong: Catalysis by Fe=X Complexes (X=NR, CR2); René Peters, Daniel F. Fischer and Sascha Jautze: Ferrocene and Half Sandwich Complexes as Catalysts with Iron Participation; Markus Jegelka, Bernd Plietker: Catalysis by Means of Complex Ferrates.
Download or read book Functionalised N Heterocyclic Carbene Complexes written by Olaf Kühl and published by John Wiley & Sons. This book was released on 2010-02-02 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can anchor free carbenes to the metal site, introduce hemilability, provide a means to immobilise transition metal carbene catalysts, introduce chirality, provide a chelate ligand or bridge two metal centres. NHC can be attached to carbohydrates and campher, derived from amino acids and purines, they can be used as organocatalysts mimicking vitamin B1 or as weak “solvent” donors in lanthanide chemistry. Functionalised N-Heterocyclic Carbene Complexes describes major trends in functionalised NHC ligands, aiming to assist readers in their attempts to develop and apply their own functionalised carbenes. After an introduction to the chemistry and behaviour of NHC, the book gives a detailed description of functionalised carbenes and their complexes according to a range of functional groups, each with a discussion of the synthetic route, structure, stability and performance. Functionalised N-Heterocyclic Carbene Complexes is an essential guide to fine-tuning this important class of compounds for practitioners, researchers and advanced students working in synthetic organometallic and organic chemistry and catalysis.
Download or read book Reactions of Electrophilic Iron Complexes with Organosilanes written by Eric Scharrer and published by . This book was released on 1993 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis Spectral Characterization and Alkylidene Transfer Reactions of Electrophilic Iron Carbene Complexes Cp CO L Fe written by M. Brookhart and published by . This book was released on 1982 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt:
