Download or read book Ionized and Excited States written by and published by . This book was released on 1976 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Analysis of Excitation and Ionization of Atoms and Molecules by Electron Impact written by Afzal Chaudhry and published by Springer Science & Business Media. This book was released on 2010-10-17 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: The content of this book describes in detail the results of the present measurements of the partial and total doubly differential cross sections for the multiple-ionization of rare gas atoms by electron impact. These measurements show, beside other trends, the role of Auger transitions in the production of multiply ionized atoms in the region where the incident electron energy is sufficient to produce inner shell ionization. Other processes like Coster-Kronig transitions and shake off also contribute towards increasing the charge of the ions. The incident electron having energy of 6 keV, for example, in a collision with xenon atom can remove up to nine electrons! (*) X-ray-ion coincidence spectroscopy of the electron xenon atom collisions is also described. The present measurements of doubly differential cross sections for the dissociative and non-dissociative ionization of hydrogen, sulfur dioxide and sulfur hexa fluoride molecular gases by electron impact are also described in the text of this book. The results of the measurements for sulfur dioxide molecule show how this major atmospheric pollutant can be removed from the atmosphere by electron impact dissociation of this molecule. The present results of the measurements for sulfur hexa fluoride give an insight into the dissociation properties of this molecular gas, which is being so widely used as a gaseous insulator in the electrical circuits. The book also describes the present measurements of the polarization parameters of the fluorescence radiation emitted by the electron-impact-excited atoms of sodium and potassium. In these investigations the target atoms are polarized, therefore, the measurements of the polarization parameters give information about the electron atom interaction in terms of the interference, direct and exchange interaction channels.
Download or read book Computational Methods in Chemistry written by Joachim Bargon and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: The papers collected in this volume were presented at an international symposium on Computational Methods in Chemistry. This symposium was sponsored by IBM Germany and was held September 17-19, 1979, in Bad Neuenahr, West Germany. According to Graham Richards [Nature 278, 507 (1979)] the "Third Age of Quantum Chemistry" has started-;-where the results of quantum chemical calculations have become so accurate and reliable that they can guide the experimentalists in their search for the unknown. The particular example highlighted by Richards was the suc cessful prediction and subsequent identification of the relative energies, transition probabilities and geometries of the lowest triplet states of acetylene. The theoretical predictions were based chiefly upon the work of three groups: Kammer [Chern. Phys. Lett. ~, 529 (1970)] had made qualitatively correct predictions; Demoulin [Chern. Phys. 11, 329 (1975)] had calculated the potential energy curves for the two lowest triplet states (3 and 3 ) of B A acetylene; and Wetmore and Schaefer III [J. Chern. Phys. ~~ 1648 (1978)] had determined the geometries of the cis (3B and ~A ) and the trans (3B and 3A ) isomers of these two sta~es. Inua 2 2 guided search, Wendt, Hunziker and Hippler [J. Chern. PHys. 70, 4044 (1979)] succeeded in finding the predicted near infrared absorption of the cis triplet acetylene (no corresponding absorp tion for the trans form was found, which is in agreement with theory), and the resolved structure of the spectrum confirmed the predicted geometries conclusively.
Download or read book Higher Excited States of Polyatomic Molecules written by Melvin Robin and published by Elsevier. This book was released on 2012-12-02 with total page 391 pages. Available in PDF, EPUB and Kindle. Book excerpt: Higher Excited States of Polyatomic Molecules, Volume I focuses on the spectra in the vacuum-ultraviolet region between 50,000 and 100,000 cm-1. This book explores the higher excitations in molecules beyond 50,000 cm-1. Organized into three chapters, this volume starts with an overview of the excited-state properties of a molecule and the excited-state ionization potential. This book then proceeds with a discussion of the original classification of the properties as well as the types of excitations observed in the vacuum-ultraviolet. Other chapters discuss photoelectron spectroscopy, which is an independent, self-sustaining branch of molecular spectroscopy. This text examines as well the distinction between valence shell and Rydberg excitations. The final chapter deals with several topics, including the saturated molecules that are classified as having all valence electrons, the alkene absorption spectra, and the spectroscopic data on boron compounds. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.
Download or read book Localization and Delocalization in Quantum Chemistry written by Odilon Chalvet and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second volume of the proceedings of the international seminar devoted to locali· zation and delocalization in quantum chemistry is divided into four parts. The first one is mainly concerned with the localizability of electrons in ionized and exited states. The second part shows how is it possible to take advantage of the localizability of electrons to compute molecular wave-functions. The third part of the book is an homogeneous analysis of the electronic collective excitation and of the motion of excitons in organic solids. The last section is devoted to the study of the role of electron localizability in the chemical reactivity of molecules. Concluding remarks are concerned with a careful analysis of the localizability concept itself in relation with a possible interpretation of the wave-mechanics. PART I ELECTRON LOCALIZATION IN IONIZED AND EXCITED STATES APPLICATIONS OF PAIR DENSITY ANALYSIS R. CONSTANCIEL and L. ESNAULT Centre de Mecanique Ondulatoire Appliquee, Paris, France Abstract. The method of pair density analysis is applied to various kinds of calculations. We examine the influence of the quality of the wavefunction and of the nuclear configuration; the problem of hybridization is discussed, as weIl as the relations between separability and excitation.
Download or read book Physics of Ionized Gases written by Boris M. Smirnov and published by John Wiley & Sons. This book was released on 2008-11-20 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive textbook and reference for the study of the physics of ionized gases The intent of this book is to provide deep physical insight into the behavior of gases containing atoms and molecules from which one or more electrons have been ionized. The study of these so-called plasmas begins with an overview of plasmas as they are found in nature and created in the laboratory. This serves as a prelude to a comprehensive study of plasmas, beginning with low temperature and "ideal" plasmas and extending to radiation and particle transport phenomena, the response of plasmas to external fields, and an insightful treatment of plasma waves, plasma instabilities, nonlinear phenomena in plasmas, and the study of plasma interactions with surfaces. In all cases, the emphasis is on a clear and unified understanding of the basic physics that underlies all plasma phenomena. Thus, there are chapters on plasma behavior from the viewpoint of atomic and molecular physics, as well as on the macroscopic phenomena involved in physical kinetics of plasmas and the transport of radiation and of charged particles within plasmas. With this grounding in the fundamental physics of plasmas, the notoriously difficult subjects of nonlinear phenomena and of instabilities in plasmas are then treated with comprehensive clarity.
Download or read book High Resolution Experiments on Strong Field Ionization of Atoms and Molecules written by Lutz Fechner and published by Springer. This book was released on 2016-04-26 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this thesis, the ionization of atoms and small molecules in strong laser fields is experimentally studied using a reaction microscope. The population of autoionizing doubly excited states in the laser fields is proven and a possible connection to the well-known dielectronic recombination processes is discussed. The fundamental process of tunnel ionization in strong laser fields is subject of investigation in a pump-probe experiment with ultrashort laser pulses. A coherent superposition of electronic states in singly charged argon ions is created within the first, and subsequently tunnel-ionized with the second pulse. This gives access to state-selective information about the tunneling process and allows to test common models. Moreover, the ionization of krypton and argon at different wavelengths is studied, from the multiphoton to the tunneling regime. The wavelength-dependent investigations are furthermore extended to molecular hydrogen. In addition to ionization, this system might undergo different dissociative processes. Channel-selective electron momentum distributions are presented and compared to each other.
Download or read book Nonequilibrium Processes in Partially Ionized Gases written by M. Capitelli and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt: The NATO . Advanced Research Insti tute on Nonequilibrium Processes in Partially Ionized Gases was held at Acquafredda di Maratea during 4-17 June 1989. The Institute considered the interconnections between scattering and transport theories and modeling of nonequilibrium systems generated by electrical discharges, emphasizing the importance of microscopic processes in affecting the bulk properties of plasmas. The book tries to reproduce these lines. In particular several contributions describe scattering cross sections involving electrons interacting with atoms and molecules in both ground and excited states (from theoretical and experimental point of view), of energy transfer processes as well as reactive ones involving excited molecules colliding with atoms and molecules as well as with metallic surfaces. Other contributions deal with the basis of transport theories (Boltzmann and Monte Carlo methods) for describing the bulk properties of non equilibrium plasmas as well as with the modeling of complicated systems emphasizing in particular the strong coupling between the Boltzmann equation and excited state kinetics. Finally the book contains several contributions describing applications in different fields such as Excimer Lasers, Negative Ion Production, RF Discharges, Plasma Chemistry, Atmospheric Processes and Physics of Lamps. The Organizing Committee gratefully acknowledges the generous financial support provided by the NATO Science Committee as well as by Azienda Autonoma di Soggiorno e Turismo of Maratea, by University of Bari, by C. N. R. (Centro di Studio per la Chimica dei Plasmi and Comitato per la Chimica), by ENEA, by Lawrence Livermore Laboratory and by US Army Research Office.
Download or read book Excited States in Quantum Chemistry written by Cleanthes A. Nicolaides and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is undoubtedly true that much of the progress in the quant~m theory of matter is due to the remarkable success of the independent particle model (IPM)--especially in describing ground states. However, the accurate experimental results of the last 10 years or so, on a variety of spectroscopic phenomena and chemical processes which involve the Excited State, and the related failure of the IPM to reproduce accurately--in many cases, even qualitatively--the observed data, have sent to theorists a clear message: There is need to create and/or apply general and useful approaches to the many-electron problem of the excited state which go beyond the IPM, treat electron correlation and relativity and explain or predict all relevant physical or chemical information with consistent accuracy. This book contains articles devoted mainly to some of the most important new developments in Quantum Chemistry concerning the theoretical foundations and the computational implementation of many-body approaches to the quantitative and detailed under standing of the electronic excited states of atoms, molecules and solids. Furthermore, it contains experimental and pheno menological articles on Photoelectron and Auger spectroscopy, Lifetime measurements and Organic Photochemistry. In combination or individually, these articles constitute a good description of some current theoretical and experimental work on the electronic structure and spectroscopy of atoms, molecules, polymers, surfaces, metal oxides and amorphous solids.
Download or read book Fundamentals of Ionized Gases written by Boris M. Smirnov and published by John Wiley & Sons. This book was released on 2012-09-19 with total page 447 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive and readily accessible work for studying the physics of ionized gases, based on "Physics of Ionized Gases". The focus remains on fundamentals rather than on the details required for interesting but difficult applications, such as magnetic confinement fusion, or the phenomena that occur with extremely high-intensity short-pulse lasers. However, this new work benefits from much rearranging of the subject matter within each topic, resulting in a more coherent structure. There are also some significant additions, many of which relate to clusters, while other enlarged sections include plasmas in the atmosphere and their applications. In each case, the emphasis is on a clear and unified understanding of the basic physics that underlies all plasma phenomena. Thus, there are chapters on plasma behavior from the viewpoint of atomic and molecular physics, as well as on the macroscopic phenomena involved in physical kinetics of plasmas and the transport of radiation and of charged particles within plasmas. With this grounding in the fundamental physics of plasmas, the notoriously difficult subjects of nonlinear phenomena and of instabilities in plasmas can then be treated with comprehensive clarity. The work is rounded off with appendices containing information and data of great importance and relevance that are not easily found in other books. Valuable reading for graduate and PhD physics students, and a reference for researchers in low-temperature ionized gases-plasma processing, edge region fusion plasma physics, and atmospheric plasmas.
Download or read book The Theory of Atomic Structure and Spectra written by Robert D. Cowan and published by Univ of California Press. This book was released on 2023-11-15 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt: Both the interpretation of atomic spectra and the application of atomic spectroscopy to current problems in astrophysics, laser physics, and thermonuclear plasmas require a thorough knowledge of the Slater-Condon theory of atomic structure and spectra. This book gathers together aspects of the theory that are widely scattered in the literature and augments them to produce a coherent set of closed-form equations suitable both for computer calculations on cases of arbitrary complexity and for hand calculations for very simple cases.
Download or read book Atomic Physics of Highly Ionized Atoms written by Richard Marrus and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 571 pages. Available in PDF, EPUB and Kindle. Book excerpt: The last decade has seen dramatic progress in the development of devices for producing mu1ticharged ions. Indeed it is now pos sible to produce any charge state of any ion right up through 92 fully-stripped uranium (U +). Equally dramatic progress has been achieved in the energy range of the available ions. As an example, fully-stripped neon ions have been produced in useable quantities with kinetic energies ranging from a few ev to more than 20 Gev. Interest in the atomic physics of multicharged ions has grown apace. In the fusion program, the spectra of these ions is an im portant diagnostic tool. Moreover the presence of mu1ticharged ions presents a serious energy loss mechanism in fusion devices. This fact has motivated a program to study the collision mech anisms involved. In another area, mu1ticharged ions are present in the solar corona and the interstellar medium and knowledge of their collision properties and spectra is essential to understand ing the astrophysics. Other possible applications are to x-ray lasers and heavy ion inertial fusion. On a more fundamental level, new possibilities for testing quantum electrodynamics with mu1ti charged ions have emerged.
Download or read book Updated Excitation and Ionization Cross Sections for Electron Impact on Atomic Oxygen written by Russ R. Laher and published by . This book was released on 1988 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Physics of Highly Ionized Atoms written by Richard Marrus and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt: The progress in the physics of highly-ionized atoms since the last NATO sponsored ASI on this subject in 1982 has been enormous. New accelerator facilities capable of extending the range of highly-ionized ions to very high-Z have come on line or are about to be completed. We note particularly the GANIL accelerator in Caen, France, the Michigan State Superconducting Cyclotrons in East Lansing both of which are currently operating and the SIS Accelerator in Darmstadt, FRG which is scheduled to accelerate beam in late 1989. Progress i~ low-energy ion production has been equally dramatic. The Lawrence Livermore Lab EBIT device has produced neon-like gold and there has been continued improvement in ECR and EBIS sources. The scientific developments in this field have kept pace with the technical developments. New theoretical methods for evaluating relativistic and QED effects have made possible highly-precise calcula tions of energy levels in one-and two-electron ions at high-Z. The calculations are based on the MCDF method and the variational method and will be subject to rigorous experimental tests. On the experimental side, precision x-ray and UV measurements have probed the Lamb shift in the one and two electron ions up to Z=36 with increasing precision.
Download or read book Laser Enhanced Ionization Spectroscopy written by John C. Travis and published by John Wiley & Sons. This book was released on 1996-04-19 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: Laser-enhanced ionization (LEI) is a type of optical spectrometrythat employs photoexcitation to ionize atoms selectively. Over thepast two decades, this method--originally known as the optogalvaniceffect--has been the object of extensive worldwide research and thesubject of numerous papers and published articles. Until now,however, no single volume has presented this wealth of theory anddata in a cohesive and accessible form. Laser-Enhanced Ionization Spectrometry fills this gap in theliterature. It synthesizes vast amounts of information previouslyavailable only through scattered research papers and covers everyaspect of the technology, from underlying principles and theory tomethodology and applications. This book examines the state of theart of LEI, compares it with other methods, and demonstrates howlaser-enhanced collisional ionization is especially well suited toanalytical atomic spectrometry. The contributors to this collaborative effort--from Russia,Australia, Europe, and the United States--clarify terminology,explain the inner workings of LEI, and offer derivations for bothidealized forms and realistic approximations. They also analyze thecapabilities and limitations of this technique as an analyticalmethod, including instrumentation, sources of noise, limits ofdetection, interferences, and applications. After concentrating largely on flame LEI as the most commonly usedmethod to derive LEI measurements, the discussion moves to thedevelopment of nonflame technologies for LEI. There is alsoextended coverage of the relationship between LEI and laser-inducedfluorescence, including an examination of the interplay oflaser-induced ionization and fluorescence techniques in differentatomic and molecular reservoirs. Laser-Enhanced Ionization Spectrometry places understanding,usefulness, and practical applications ahead of detailedderivations. For practicing analytical chemists andspectroscopists, it offers a clear and uncluttered approach to acomplex subject, as well as a fresh perspective on a still-emergingtechnology. This book sums up the present understanding and state of the art oflaser-enhanced ionization (LEI)-a unique but underutilized tool foranalytical atomic spectrometry. LEI possesses the special abilityto ionize atoms selectively. The text focuses on the role of thistechnology in analytical chemistry, and covers both theory andapplications in one complete, self-contained volume. Carefully crafted by leading experts from around the globe, withcontributions under six key headings, Laser-Enhanced IonizationSpectrometry * Draws on hundreds of research papers to create a comprehensivereference for LEI * Describes in depth how ions are produced, and how a signal isgenerated and detected * Provides an extensive and up-to-date compilation of published LEIdetection limits * Emphasizes basic understanding and practical applications ratherthan detailed derivations * Discusses terms and definitions and clears up sources ofconfusion in the field * Offers up-to-date coverage of instrumentation and applications * Evaluates the usefulness of LEI as an analytical tool * Deals with questions of limits of detection, interference, andnoise * Devotes an entire segment to nonflame technologies for LEI * Extends the discussion to fluorescence techniques and how theycan be interrelated with LEI in various atomic and molecularreservoirs
Download or read book Ionization and Ion Transport written by David B. Go and published by Morgan & Claypool Publishers. This book was released on 2018-05-03 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this text is to introduce engineering and science students to the basic underlying physics and chemistry concepts that form the foundation of plasma science and engineering. It is an accessible primer directed primarily at those students who, like the general public, simply do not understand exactly what a plasma or gas discharge is nor do they even necessarily have the fundamental background in statistical thermodynamics, gas dynamics, fluid dynamics, or solid state physics to effectively understand many plasma and gas discharge principles. At the conclusion of this text, the reader should understand what an ion is, how they move, the equations we use to describe these basic concepts, and how they link to the aforementioned topics of plasmas and gas discharges. This book is focused on specific concepts that are important to non-equilibrium, low temperature gas discharges. These discharges fi nd wide applicability today and are of significant interest to the scientifi c and engineering communities.
Download or read book The Effect of Partially Ionized Impurities on a DCX Device written by R. G. Alsmiller and published by . This book was released on 1958 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
