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Book Demonstration of Strontium Removal from Hanford N Area Well Water

Download or read book Demonstration of Strontium Removal from Hanford N Area Well Water written by and published by . This book was released on 1998 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt: As part of the Efficient Separations and Processing Crosscutting Program, the Pacific Northwest National Laboratory conducted this study to demonstrate the efficiency of several ion-exchange materials in removing strontium-90 from actual groundwater from the Hanford N-Springs Pump and Treat Demonstration Facility. The objective of this experiment was to determine the strontium-loading distribution coefficients (Kds) for some titanate ion-exchange materials, modified minerals, and organic ion-exchange resins. The equilibrium uptake data presented in this report are useful for identifying potential materials that are capable of removing strontium from N-area groundwaters. The data show the relative selectivities of the ion-exchange materials under similar operating conditions, and show that additional flow studies are needed to predict materials capacities and to develop complete ion-exchange process flow sheets. The materials investigated in this study include commercially available ion exchangers such as IONSIV IE-911 (manufactured by UOP) and SuperLig 644 (IBC Advanced Technologies, Inc.), and materials produced on an experimental basis by Allied Signal (nontitanates), Selion Inc. (titanates), and Pennsylvania State University (modified mica). In all, the performance of seven different ion-exchange materials was evaluated using actual N-Area groundwater. The evaluation consisted of the determining strontium batch distribution coefficients, loading, and decontamination factors. Tests were performed at two different solution-to-exchanger mass ratios (i.e., phase ratios) of 2000 and 4000 using actual N-Area groundwater samples from three different wells. Actual N-Area groundwater used in the present study was obtained from three monitoring wells in FY 1998. These samples were taken from wells with strontium-90 concentrations ranging from 0.25 to 3.9 pCi/L.

Book Performance Evaluation of 24 Ion Exchange Materials for Removing Cesium and Strontium from Actual and Simulated N reactor Storage Basin Water

Download or read book Performance Evaluation of 24 Ion Exchange Materials for Removing Cesium and Strontium from Actual and Simulated N reactor Storage Basin Water written by Garrett N. Brown and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Proceedings of the International Conference on Decommissioning and Decontamination and on Nuclear and Hazardous Waste Management

Download or read book Proceedings of the International Conference on Decommissioning and Decontamination and on Nuclear and Hazardous Waste Management written by and published by . This book was released on 1998 with total page 804 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Comparison of Organic and Inorganic Ion Exchangers for Removal of Cesium and Strontium from Simulated and Actual Hanford 241 AW 101 DSSF Tank Waste

Download or read book Comparison of Organic and Inorganic Ion Exchangers for Removal of Cesium and Strontium from Simulated and Actual Hanford 241 AW 101 DSSF Tank Waste written by and published by . This book was released on 1996 with total page 48 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Comparison of Organic and Inorganic Ion Exchangers for Removal of Cesium and Strontium from Simulated and Actual Hanford 241 AW 101 DSSF Tank

Download or read book Comparison of Organic and Inorganic Ion Exchangers for Removal of Cesium and Strontium from Simulated and Actual Hanford 241 AW 101 DSSF Tank written by and published by . This book was released on 1996 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Investigation of the Strontium 90 Contaminant Plume Along the Shoreline of the Columbia River at the 100 N Area of the Hanford Site

Download or read book Investigation of the Strontium 90 Contaminant Plume Along the Shoreline of the Columbia River at the 100 N Area of the Hanford Site written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Efforts are underway to remediate strontium-laden groundwater to the Columbia River at the 100-N Area of the Hanford Site. Past practices of the 100-N reactor liquid waste disposal sites has left strontium-90 sorbed onto sediments which is a continuing source of contaminant discharge to the river. The Remediation Task of the Science and Technology Project assessed the interaction of groundwater and river water at the hyporheic zone. Limited data have been obtained at this interface of contaminant concentrations, geology, groundwater chemistry, affects of river stage and other variables that may affect strontium-90 release. Efforts were also undertaken to determine the extent, both laterally and horizontally, of the strontium-90 plume along the shoreline and to potentially find an alternative constituent to monitor strontium-90 that would be more cost effective and could possibly be done under real time conditions. A baseline of strontium-90 concentrations along the shoreline was developed to help assess remediation technologies.

Book Exchange Adsorption of Strontium on Clay Minerals

Download or read book Exchange Adsorption of Strontium on Clay Minerals written by J. S. Wahlberg and published by . This book was released on 1965 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book 100 N Area Strontium 90 Treatability Demonstration Project

Download or read book 100 N Area Strontium 90 Treatability Demonstration Project written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Strontium-90 (90Sr) exceeds the U.S. Environmental Protection Agency's drinking water standards for groundwater (8 picocuries/L) by as much as a factor of 1000 at several locations within the Hanford 100-N Area and along the 100-N Area Columbia River shoreline). Phytoextraction, a managed remediation technology in which plants or integrated plant/rhizosphere systems are employed to phytoextract and/or sequester 90Sr, is being considered as a potential remediation system along the riparian zone of the Columbia River as part of a treatment train that includes an apatite barrier to immobilize groundwater transport of 90Sr. Phytoextraction would employ coyote willow (Salix exigua) to extract 90Sr from the vadose zone soil and aquifer sediments (phytoextraction) and filter 90Sr (rhizofiltration) from the shallow groundwater along the riparian zone of the Columbia River. The stem and foliage of coyote willows accumulating 90Sr may present not only a mechanism to remove the contaminant but also can be viewed as a source of nutrition for natural herbivores, therefore becoming a potential pathway for the isotope to enter the riparian food chain. Engineered barriers such as large and small animal fencing constructed around the field plot will control the intrusion of deer, rodents, birds, and humans. These efforts, however, will have limited effect on mobile phytophagous insects. Therefore, this study was undertaken to determine the potential for food chain transfer by insects prior to placement of the remediation technology at 100-N. Insect types include direct consumers of the sap or liquid content of the plants vascular system (xylem and phloem) by aphids as well as those that would directly consume the plant foliage such as the larvae (caterpillars) of Lepidoptera species. Heavy infestations of aphids feeding on the stems and leaves of willows growing in 90Sr-contaminated soil can accumulate a small amount (~0.15 ± 0.06%) of the total label removed from the soil by the plant over a 17-day exposure period. The 90Sr in the exuded honeydew during this period amounted to 1.17 ± 0.28% of this total label. The honeydew would eventually be deposited into the soil at the base of the plant, but the activity would be so dispersed as to be undetectable. Moth larvae will consume 90Sr contaminated leaves but retain very little of the label (~0.02%) and only that contained in their digestive tracts. As the moths pupated and became adults, they contained no detectable amounts of 90Sr. Over the 10-day exposure period, ~4% of the phytoextracted 90Sr was lost from the plant as moth feces. However, like the honeydew, feces dispersed into the soil were undetectable. As the plant diminishes the content of 90Sr in the soil, the activity of the label in the leaves and new stems would also diminish. The results of these studies indicate that the risk for detectable transfer of 90Sr from willow trees growing in the contaminated soil along the 100-N shoreline through the food chain of herbivorous insects would be very slight to non-existent.

Book Project Work Plan

    Book Details:
  • Author : Jim E. Szecsody
  • Publisher :
  • Release : 2006
  • ISBN :
  • Pages : pages

Download or read book Project Work Plan written by Jim E. Szecsody and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: We propose to develop an infiltration strategy that defines the precipitation rate of an apatite-forming solution and Sr-90 sequestration processes under variably saturated (low water content) conditions. We will develop this understanding through small-scale column studies, intermediate-scale two-dimensional (2-D) experiments, and numerical modeling to quantify individual and coupled processes associated with apatite formation and Sr-90 transport during and after infiltration of the Ca-citrate-PO4 solution. Development of capabilities to simulate these coupled biogeochemical processes during both injection and infiltration will be used to determine the most cost-effective means to emplace an in situ apatite barrier with a longevity of 300 years to permanently sequester Sr-90 until it decays. Biogeochemical processes that will be investigated are citrate biodegradation and apatite precipitation rates at varying water contents as a function of water content. Coupled processes that will be investigated include the influence of apatite precipitation (which occupies pore space) on the hydraulic and transport properties of the porous media during infiltration.

Book Project Work Plan 100 N Area Strontium 90 Treatability Demonstration Project

Download or read book Project Work Plan 100 N Area Strontium 90 Treatability Demonstration Project written by and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The 100-N Area Innovative Treatment and Remediation Demonstration (ITRD) identified phyto?remediation as a potential technology both for the removal of 90Sr from the soil of the riparian zone and as a filter for groundwater along the Columbia River. Recent greenhouse and growth chamber studies have demonstrated the viability of phytoextraction to remove 90Sr from this area's soil/water; in conjunction with monitored natural attenuation and an apatite barrier the process would make an effective treatment for remediation of the 100-N Area 90Sr plume. All activities associated with the 100-NR-1 and 100-NR-2 Operable Units of the Hanford 100-N Area have had, and continue to have, significant regulatory and stakeholder participation. Beginning in 1998 with the ITRD process, presentations to the ITRD TAG were heavily attended by EPA, Washington State Department of Ecology, and stakeholders. In addition, three workshops have been held to receive regulatory and stakeholder feedback on monitored natural attenuation, the apatite barrier, and phytoremediation; these were held in Richland in August 2003, December 2004, and August 2005. The apatite injection treatability test plan (DOE 2005) describes phytoremediation as a technology to be evaluated during the March 2008 evaluation milestone as described in the Tri-Party Agreement change request (M-16-06-01 Change Control Form). If, during this evaluation milestone, phytoremediation is favorably evaluated it would be incorporated into the treatability test plan. The phytoremediation treatability test described in this proposal is strongly supported by the Washington State Department of Ecology.

Book STRONTIUM 90 IN THE 100N AREA

Download or read book STRONTIUM 90 IN THE 100N AREA written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A number of photos and charts detailing the remediation of the Hanford Reservation and the cleanup of Strontium-90.

Book Removal of Strontium and Transuranics from Hanford Waste Via Hydrothermal Processing    FY 1994 95 Test Results

Download or read book Removal of Strontium and Transuranics from Hanford Waste Via Hydrothermal Processing FY 1994 95 Test Results written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Under the Tank Waste Remediation System (TWRS) Pretreatment Technology Development Project, Pacific Northwest Laboratory (PNL) is evaluating and developing organic destruction technologies that may be incorporated into the Initial Pretreatment Module (IPM) to treat Hanford tank waste. Organic (and ferrocyanide) destruction removes the compounds responsible for waste safety issues, and conditions the supernatant for low-level waste disposal by removing compounds that may be responsible for promoting strontium and transuranic (TRU) components solubility. Destruction or defunctionalization of complexing organics in tank wastes eliminates organic species that can reduce the efficiency of radionuclide (E.g., [sup 90]Sr) separation processes, such as ion exchange, solvent extraction, and precipitation. The technologies being evaluated and tested for organic destruction are low-temperature hydrothermal processing (HTP) and wet air oxidation (WAO). Four activities are described: Batch HTP/WAO testing with Actual Tank Waste (Section 3.0), Batch HTP Testing with Simulant (Section 4.0), Batch WAO testing with Simulant (Section 5.0), and Continuous Bench-scale WAO Testing with Simulant (Section 6.0). For each of these activities, the objectives, test approach, results, status, and direction of future investigations are discussed. The background and history of the HTP/WAO technology is summarized below. Conclusions and Recommendations are provided in Section 2.0. A continuous HTP off-gas safety evaluation conducted in FY 1994 is included as Appendix A.