Download or read book Investigation of Fuel Property and Biodiesel Effects in a Highly Dilute Low Temperature Combustion Regime with a Light duty Diesel Engine written by Huy Tran and published by . This book was released on 2010 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Investigation of Bio Diesel Fueled Engines Under Low Temperature Combustion Strategies written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In accordance with meeting DOE technical targets this research was aimed at developing and optimizing new fuel injection technologies and strategies for the combustion of clean burning renewable fuels in diesel engines. In addition a simultaneous minimum 20% improvement in fuel economy was targeted with the aid of this novel advanced combustion system. Biodiesel and other renewable fuels have unique properties that can be leveraged to reduce emissions and increase engine efficiency. This research is an investigation into the combustion characteristics of biodiesel and its impacts on the performance of a Low Temperature Combustion (LTC) engine, which is a novel engine configuration that incorporates technologies and strategies for simultaneously reducing NOx and particulate emissions while increasing engine efficiency. Generating fundamental knowledge about the properties of biodiesel and blends with petroleum-derived diesel and their impact on in-cylinder fuel atomization and combustion processes was an important initial step to being able to optimize fuel injection strategies as well as introduce new technologies. With the benefit of this knowledge experiments were performed on both optical and metal LTC engines in which combustion and emissions could be observed and measured under realistic conditions. With the aid these experiments and detailed combustion models strategies were identified and applied in order to improve fuel economy and simultaneously reduce emissions.

Download or read book Biodiesel Combustion Performance and Emissions Characteristics written by Semakula Maroa and published by Springer Nature. This book was released on 2020-07-10 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on biodiesel combustion, including biodiesel performance, emissions and control. It brings together a range of international research in combustion studies in order to offer a comprehensive resource for researchers, students and academics alike. The book begins with an introduction to biodiesel combustion, followed by a discussion of NOx formation routes. It then addresses biodiesel production processes and oil feedstocks in detail, discusses the physiochemical properties of biodiesel, and explores the benefits and drawbacks of these properties. Factors influencing the formation of emissions, including NOx emissions, are also dealt with thoroughly. Lastly, the book discusses the mechanisms of pollution and different approaches used to reduce pollutants in connection with biodiesel. Each approach is considered in detail, and diagrams are provided to illustrate the points in line with industry standard control mechanisms.

Download or read book Green Diesel Engines written by Breda Kegl and published by Springer Science & Business Media. This book was released on 2013-10-19 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: With a focus on ecology, economy and engine performance, diesel engines are explored in relation to current research and developments. The prevalent trends in this development are outlined with particular focus on the most frequently used alternative fuels in diesel engines; the properties of various type of biodiesel and the concurrent improvement of diesel engine characteristics using numeric optimization alongside current investigation and research work in the field. Following of a short overview of engine control, aftertreatment and alternative fuels, Green Diesel Engine explores the effects of biodiesel usage on injection, fuel spray, combustion, and tribology characteristics, and engine performance. Additionally, optimization procedures of diesel engine characteristics are discussed using practical examples and each topic is corroborated and supported by current research and detailed illustrations. This thorough discussion provides a solid foundation in the current research but also a starting point for fresh ideas for engineers involved in developing/adjusting diesel engines for usage of alternative fuels, researchers in renewable energy, as well as to engineers, advanced undergraduates, and postgraduates.

Download or read book Vehicle and Engine Investigations with Biodiesel written by A. Hasan and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Biodiesel is an environmentally friendly alternative diesel fuel consisting of the alkyl esters of fatty acids which are expected to play a significant role in reducing overall CO2 emissions. Biodiesel is produced commercially by a chemical reaction called transesterification which is a chemical process to lower the viscosity of the vegetable oils. Since Biodiesel is an oxygenated, sulfur free fuel, it typically reduces engine out emissions except for the oxides of nitrogen (NOX). The chemical and physical properties of the fatty acids, as well as the effect of molecular structure, determine the overall properties of biodiesel fuel. Investigations into the impact of FAME properties on diesel engines are highly topical, as higher blends of biodiesel are introduced. The aim of this work is to perform a comprehensive study on the use of biodiesel fuel in production diesel engines, and its impact on emissions, performance and fuel consumption. This thesis has shown that the use of biodiesel fuel reduces the engine out emissions of CO, HC and PM (except at sub-zero temperatures), and causes a slight increase in NOX emissions and fuel consumption compared to baseline diesel fuel. However, the lower exhaust gas temperatures seen when using biodiesel blends leads to reduced catalyst conversion efficiency and an adverse effect on tailpipe emissions. The cylinder pressure and rate of heat release profiles of biodiesel blends are very similar to those of baseline diesel fuel when similar torque is demanded from the engine with relatively similar start of combustion for the main charge. Biodiesel blends show a slightly quicker rise in the rate of heat release and higher peak values compared to baseline diesel fuel. In the case of matched pedal positions, the ignition delay time decreases slightly with biodiesel use at lower engine load conditions compared to baseline diesel fuel. The sensitivity of engine performance and emissions with B25 is more pronounced for EGR rate, rail pressure, and main injection timing variations than for baseline diesel fuel. Finally, an adverse thermal impact of using biodiesel fuel on the performance of diesel oxidation catalyst was observed compared to baseline diesel however, no solid evidence of exhaust gas HC speciation effects was found.

Download or read book Year round Biodiesel Use Strategy in Diesel Engines in Canadian Adverse Cold Weather Conditions written by Arvind Mangad and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The effects of climate change that have been seen at an unprecedented scale over last decade or so, have sparked intensive efforts toward the identification and development of clean, environmentally compatible, and renewable fuels. Biofuels such as alcohol and biodiesel have been identified as alternatives for powering internal combustion engines. When using vegetable oil as a feedstock for the production of biodiesel, major issues that arise include its poor low temperature properties. In this study, an experimental analysis was conducted to test the feasibility of biodiesel in cold climates specifically in Thunder Bay region and to suggest an appropriate solution for the biodiesel usage throughout the year. Weather reports from last decade were studied to compare with the cloud points of biodiesel blends. Biodiesel was produced from canola oil from transesterification and fractionation processes. Summer diesel and winter diesel have been used as reference fuels. Five different fuel series were used. The first series was summer diesel-biodiesel with ten blends (SB10, SB20, SB30, SB40, SB50, SB60, SB70, SB80, SB90 and B100). The second series was winter diesel-biodiesel with ten blends (WB10, WB20, WB30, WB40, WB50, WB60, WB70, WB80, WB90 and B100). The third series was winter diesel-biodiesel with 2 volume percent of (cold flow additive) Wintron Synergy series (WB20S2, WB50S2 and B100S2). The fourth series was winter diesel-fractionated biodiesel (FB20, FB50 and FB100). The final was winter diesel-fractionated biodiesel with 2 volume percent of Wintron Synergy series (FB20S2, FB50S2 and FB100S2). Except for winter diesel-biodiesel with 2 vol% synergy, all the fuel blend series were tested on two separate diesel engines; a four-cylinder heavy-duty diesel engine at constant speed of 800 rpm for emissions at idling condition followed by a two-cylinder light-duty diesel engine to investigate effects of fuel blends on performance and emission, under low, medium and high loads, at variable engine speeds of 1000 rpm, 2100 rpm and 3000 rpm. Results showed that normal biodiesel and fractionated biodiesel with 2 vol% synergy showed significant improvement in the cloud point. FB40S2 has the lowest cloud point compared to other fuel blends measuring -48.5°C. The effect of fuel blends on engine performance in light duty engine was investigated. The emissions of carbon monoxide (CO), hydrocarbon (HC), oxides of nitrogen (NOx) and smoke opacity from different fuel blends were measured and compared to summer and winter diesel fuels. In both the engines, fractionated biodiesel and synergy blends were found to be effective in reducing both CO and HC emissions. Smoke opacity emissions when compared from both the engines had a contrasting results. However, all biodiesel blends increased NOx emission. Results indicated that fractionated biodiesel with 2 vol% synergy had better engine performance, and lower emission compared with diesel fuel and normal biodiesel blends. Thus, fractionated biodiesel up to 80 vol% with 2 vol% synergy was found to be suitable for use in diesel engines in extreme winter conditions in Canada without the need for any engine modification.

Download or read book Investigations Into the Performance and EmissionCharacteristics of a Biodiesel Fuelled CI Engine Under Steady and Transient Operating Conditions written by Belachew Chekene Tesfa and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The stringent emission laws, the depletion of petroleum reserves and the relation of fuels with politics have forced the world to find alternatives to fossil fuels. Biodiesel is one of the biofuels which is renewable and environmentally friendly and can be used in diesel engines with little or no modifications. For the last two decades, many researchers have reported extensive work on the performance and emission characteristics of engines running with biodiesel during steady state operation. However, there are numbers of knowledge gaps that have been identified which include limited information on biodiesel physio-chemical properties and their effects on combustion behaviour and performance and emission characteristics of the engine. In this study after an exhaustive literature review, the following four research areas have been identified and investigated extensively using available numerical and experimental means. The initial focus was to investigate the most important properties of biodiesel such as density, viscosity and lower heating value using experimental and numerical techniques. The effects of biodiesel blend content on the physical properties were analysed. For each property, prediction models were developed and compared with current models available in literature. New density and viscosity prediction models were developed by considering the combined effect of biodiesel content and temperature. All the empirical models have showed a fair degree of accuracy in estimating the physical properties of biodiesel in comparison to the experimental results. Finally, the effects of density and viscosity on the fuel supply system were investigated. This system includes the fuel filter, fuel pump and the engine combustion chamber in which air-fuel mixing behaviour was studied numerically. These models can be used to understand the effects of changes in the physical properties of the fuel on the fuel supply system. In addition, the fuel supply system analysis can be carried out during the design stage of fuel pump, fuel filter and injection system. The second research objective was the investigation into a CI engine?s combustion characteristics as well as performance and emissions characteristics under both the steady and transient conditions when fuelled with biodiesel blends. The effects of biodiesel content on the CI engine?s in-cylinder pressure, brake specific fuel consumption, thermal efficiency and emissions (CO2, NOx, CO, THC) were evaluated based on experimental results. It has been seen that the CI engine running with the biodiesel resulted in acceptable engine performance as well as reduction in main emissions (except NOx). Following this study, a detailed analysis on the transient performance and emission output of the CI engine has been carried out. During this analysis, the emission changing rate is investigated during speed transient and torque transition stages. Further to this, a transient emission prediction model has been developed using associated steady and transient emission data. The model has been shown to predict the transient emission reasonably accurately. The third research objective was to develop a method for on-line measurement of NOx emission. For this purpose the in-cylinder pressure generated within a CI engine has been measured experimentally along with mass air flow and these parameters have been used in the development of a NOx prediction model. This model has been validated using experimental data obtained from a NOx emission analyzer. The predicted data obtained from NOx prediction model has been compared with measured data and has shown that the deviation is within acceptable range. The final research objective was to develop a simple, reliable and low-cost novel method to reduce the NOx emission of the CI engine when using biodiesel blends. A potential solution to this problem has been found to be in the form of direct water injection which has shown to be capable to reduce NOx emission. Using a water injection technique, the performance and emission(NOx and CO) characteristics of a CI engine fuelled with biodiesel has been investigated at varying water injection flow rates. Intake manifold water injection reduces NOx emission by up to 40% over the entire operating range without compromising the performance characteristics of the CI engine.

Download or read book The Characterization of Two Stage Ignition Effects on Late Injection Low Temperature Combustion Using Biodiesel and Biodiesel Blends written by Brandon Tirrell Tompkins and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The first stage of ignition in saturated hydrocarbon fuels (in diesel combustion) is characterized as low temperature heat release (LTHR) or cool flame combustion. LTHR takes place as a series of isomerization reactions at temperatures from 600K to 900K, and is often detectable in HCCI, rapid compression machines, and early injection low temperature combustion (LTC). The experimental investigation presented attempts to determine the existence of LTHR behavior in late injection low temperature combustion in a medium duty diesel engine with both petroleum diesel and biodiesel fuels and to determine the influence of such behavior on LTC torque and emissions. Three experiments were performed to meet these objectives: the first studies two operating modes (conventional combustion with -8° after top dead center injection timing and 0% EGR and low temperature combustion with 0° after top dead center injection timing and nominally 42% EGR level) with standard petroleum diesel, palm biodiesel, and soy biodiesel; the second studies a sweep of EGR level from 0% to nominally 45% with petroleum diesel and palm biodiesel with a constant injection timing of 0° after top dead center. The third and final experiment utilized petroleum diesel, soy biodiesel, and blends from the two fuels (20 and 50% soy biodiesel) to see the influence of viscosity and density on LTHR. LTHR is apparent in all fuels' rates of heat release profiles at the LTC operating conditions. Diesel fuel LTC displays a longer and more intense LTHR phase. Lower amounts of LTHR in the palm biodiesel causes less sensitivity to EGR, less instability, and produces better torque and emission characteristics. Density and viscosity only change the shape of the LTHR duration, while cetane number or ignition quality affects the length of the LTHR duration. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/155575

Download or read book A Computational Investigation of Diesel and Biodiesel Combustion and NOx Formation in a Light duty Compression Ignition Engine written by and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Diesel and biodiesel combustion in a multi-cylinder light duty diesel engine were simulated during a closed cycle (from IVC to EVO), using a commercial computational fluid dynamics (CFD) code, CONVERGE, coupled with detailed chemical kinetics. The computational domain was constructed based on engine geometry and compression ratio measurements. A skeletal n-heptane-based diesel mechanism developed by researchers at Chalmers University of Technology and a reduced biodiesel mechanism derived and validated by Luo and co-workers were applied to model the combustion chemistry. The biodiesel mechanism contains 89 species and 364 reactions and uses methyl decanoate, methyl-9- decenoate, and n-heptane as the surrogate fuel mixture. The Kelvin-Helmholtz and Rayleigh-Taylor (KH-RT) spray breakup model for diesel and biodiesel was calibrated to account for the differences in physical properties of the fuels which result in variations in atomization and spray development characteristics. The simulations were able to capture the experimentally observed pressure and apparent heat release rate trends for both the fuels over a range of engine loads (BMEPs from 2.5 to 10 bar) and fuel injection timings (from 0° BTDC to 10° BTDC), thus validating the overall modeling approach as well as the chemical kinetic models of diesel and biodiesel surrogates. Moreover, quantitative NOx predictions for diesel combustion and qualitative NOx predictions for biodiesel combustion were obtained with the CFD simulations and the in-cylinder temperature trends were correlated to the NOx trends.

Download or read book Biodiesel Handling and Use Guidelines written by Karin Shaine Tyson and published by . This book was released on 2006 with total page 72 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Petrodiesel Fuels written by Ozcan Konur and published by CRC Press. This book was released on 2021-05-05 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt: This third volume of the handbook presents a representative sample of the population papers in the field of petrodiesel fuels. Following the substantial public concerns on the adverse impact of the emissions from petrodiesel fuels on the environment and human health, the research has intensified in the areas related to the reduction of these adverse effects. Thus, bioremediation of spills from crude oils and petrodiesel fuels at sea and soils as well as desulfurization of petrodiesel fuels have emerged as publicly important research areas. Similarly, the emissions from diesel fuel exhausts, due to their adverse effects on both human health and environment, have been researched more in recent years. These emissions cover particulate emissions, aerosol emissions, and NOx emissions. Research on the adverse impact of petrodiesel fuel exhaust emissions on human health has primarily progressed along the lines of respiratory illnesses, cancer, and other illnesses, such as cardiovascular illnesses, brain illnesses, and reproductive system illnesses, through human, animal, and in vitro studies. It is clear that these illnesses caused by the petrodiesel fuel exhaust emissions have been one of the most significant reasons to develop alternative biodiesel fuels. Part IX presents a representative sample of the population papers in the field of crude oils covering major research fronts. It covers crude oil spills in general, crude oil spills and their cleanup, properties and removal of crude oils, biodegradation of crude oil-contaminated soils, and crude oil recovery besides an overview paper. Part X presents a representative sample of the population papers in the field of petrodiesel fuels in general covering major research fronts. It covers combustion of biodiesel fuels in diesel engines, bioremediation of biodiesel fuel-contaminated soils, biodiesel power generation, and desulfurization of diesel fuels besides an overview paper. Part XI presents a representative sample of the population papers in the field of emissions from petrodiesel fuels covering major research fronts. It covers diesel emission mitigation, diesel particulate emissions, and diesel NOx emissions, besides an overview paper. Part XII presents a representative sample of the population papers in the field of the health impact of the emissions from petrodiesel fuels covering major research fronts. It covers respiratory illnesses, cancer, cardiovascular, brain, and reproductive system illnesses, besides an overview paper. This book will be useful to academics and professionals in the fields of Energy Fuels, Public Environmental Occupational Health, Pharmacology, Pharmacy, Immunology, Respiratory System, Allergy, and Oncology. Ozcan Konur is both a materials scientist and social scientist by training. He has published around 200 journal papers, book chapters, and conference papers. He has focused on the bioenergy and biofuels in recent years. In 2018, he edited Bioenergy and Biofuels, which brought together the work of over 30 experts in their respective field. He also edited the Handbook of Algal Science, Technology, and Medicine with a strong section on the algal biofuels in 2020.

Download or read book Handbook of Diesel Engines written by Klaus Mollenhauer and published by Springer Science & Business Media. This book was released on 2010-06-22 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt: This machine is destined to completely revolutionize cylinder diesel engine up through large low speed t- engine engineering and replace everything that exists. stroke diesel engines. An appendix lists the most (From Rudolf Diesel’s letter of October 2, 1892 to the important standards and regulations for diesel engines. publisher Julius Springer. ) Further development of diesel engines as economiz- Although Diesel’s stated goal has never been fully ing, clean, powerful and convenient drives for road and achievable of course, the diesel engine indeed revolu- nonroad use has proceeded quite dynamically in the tionized drive systems. This handbook documents the last twenty years in particular. In light of limited oil current state of diesel engine engineering and technol- reserves and the discussion of predicted climate ogy. The impetus to publish a Handbook of Diesel change, development work continues to concentrate Engines grew out of ruminations on Rudolf Diesel’s on reducing fuel consumption and utilizing alternative transformation of his idea for a rational heat engine fuels while keeping exhaust as clean as possible as well into reality more than 100 years ago. Once the patent as further increasing diesel engine power density and was filed in 1892 and work on his engine commenced enhancing operating performance.

Download or read book Biodiesel Energy and Methane Hydrate Research written by United States. Congress. Senate. Committee on Energy and Natural Resources. Subcommittee on Energy Research, Development, Production, and Regulation and published by . This book was released on 1998 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Empirical Study of the Stability of Biodiesel and Biodiesel Blends written by R. L. McCormick and published by DIANE Publishing. This book was released on 2009-05 with total page 98 pages. Available in PDF, EPUB and Kindle. Book excerpt: In support of the U.S. Dept. of Energy (DOE) Fuels Technologies Program Multiyear Program Plan Goal of identifying fuels that can displace 5% of petroleum diesel by 2010, the Nat. Renewable Energy Lab. (NREL), in collaboration with the Nat. Biodiesel Board (NBB) and with subcontractor Southwest Research Institute, performed a study of biodiesel oxidation stability. The objective of this work was to develop a database to support specific proposals for a stability test and specification for biodiesel and biodiesel blends. B100 samples from 19 biodiesel producers were obtained during Dec. 2005 and Jan. 2006 and tested for stability. Eight of these samples were then selected for additional study, including long-term storage tests and blending at 5% and 20% with a number of ultra-low sulfur diesel (ULSD) fuels. These blends were also tested for stability. The study employed accelerated tests as well as tests intended to simulate three real-world aging scenarios: (1) storage and handling, (2) vehicle fuel tank, and (3) high-temperature engine fuel system. Results were analyzed to determine whether ensuring B100 stability was adequate to ensure the stability of B5 and B20 blends. Several tests were also performed with two commercial antioxidant additives to determine whether these additives might improve stability. This report documents completion of the NREL Fiscal Year 2007 Annual Operating Plan Milestone 10.1. Illus.

Download or read book Investigation of the Difference in Cool Flame Characteristics Between Petroleum Diesel and Soybean Biodiesel Operating in Low Temperature Combustion Mode written by Aditya Muthu Narayanan and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: One of the promising solutions to rising emission standards is the in-cylinder emission reduction, through low temperature combustion. Low temperature combustion defeats conventional soot-NOx trade off by simultaneous reduction of both emissions by controlling the in-cylinder temperature below the Soot and NOx forming temperature zones. The use of low temperature combustion strategy phases the combustion into the expansion stroke, making the entire combustion process highly sensitive to start of high temperature combustion. Early start of high temperature combustion results in the advancement of combustion, resulting in higher in-cylinder temperature and pressure promoting the formation of oxides of nitrogen. Delayed start of combustion results in the retardation of the high temperature combustion further into the expansion stroke the first stage combustion, in this case cool flame combustion, has an important role to play in the phasing of high temperature combustion, associated emissions and efficiency. The focus of this study is to investigate the difference in the cool flame combustion characteristics between petroleum diesel and soybean biodiesel, when operating in low temperature combustion mode. Previous studies have attributed the absence of the cool flame in biodiesel purely due to oxygen content of the biodiesel. Cycle-to-cycle variation, exhaust gas constituents, rail pressure and fuel penetration length were analyzed to determine the causes for difference in the cool flame characteristic between the two fuels. The result of the analysis was that cool flame combustion is present in all combustion processes and not a product of systematic error or due to the combustion of the partially combusted species in the recirculated exhaust gas. It does not entirely depend on the chemical composition of fuel and rather on the in-cylinder conditions in particular the ambient oxygen concentration. Lower ambient oxygen concentration causes the cool flame to advance with respect to the high temperature heat release, making it visible in the heat release profile. The appearance of the cool flame at increased rail pressure in biodiesel does not cause a change in the trend of ignition delay, unburned hydrocarbon or carbon monoxide with respect to rail pressure. It only results in the retardation of high temperature combustion, further into the expansion stroke. Low temperature combustion defeats conventional soot-NOx trade off by simultaneous reduction of both emissions by controlling the in-cylinder temperature below the Soot and NOx forming temperature zones. In this study, low temperature combustion is achieved with the use of high exhaust gas recirculation circulation and late injection timing, phasing the combustion in the expansion stroke. The use of low temperature combustion strategy phases the combustion into the expansion stroke, making the entire combustion process highly sensitive to start of high temperature combustion. Early start of high temperature combustion results in the advancement of combustion, resulting in higher in-cylinder temperature and pressure promoting the formation of oxides of nitrogen. Delayed start of combustion results in the retardation of the high temperature combustion further into the expansion stroke, increasing the concentration of unburned hydrocarbon in the exhaust. Hence the first stage combustion, in this case cool flame combustion, has an important role to play in the phasing of high temperature combustion, associated emissions and efficiency. The focus of this study is to investigate the difference in the cool flame combustion characteristics between petroleum diesel and soybean biodiesel, when operating in low temperature combustion mode. Previous studies have attributed the absence of the cool flame in biodiesel purely due to oxygen content of the biodiesel. Late injection timing along with EGR was used to achieve LTC combustion (verified by soot-NOx comparison with conventional combustion), to realize the difference in cool flame characteristics between the two fuels. Further, cycle-to-cycle variation, exhaust gas constituents, rail pressure and fuel penetration length were analyzed to determine the causes for difference in the cool flame characteristic between the two fuels. The result of the analysis was that cool flame combustion is present in all combustion processes and not a product of systematic error or due to the combustion of the partially combusted species in the recirculated exhaust gas. It does not entirely depend on the chemical composition of fuel and rather on the in-cylinder conditions in particular the ambient oxygen concentration. Lower ambient oxygen concentration causes the cool flame to advance with respect to the high temperature heat release, making it visible in the heat release profile. The appearance of the cool flame at increased rail pressure in biodiesel does not cause a change in the trend of ignition delay, unburned hydrocarbon or carbon monoxide with respect to rail pressure. It only results in the retardation of high temperature combustion, further into the expansion stroke. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/151940

Download or read book Laboratory Experiments on the Emissions from Different Biodiesel Blends in Comparison to B20 and Ultra Low Sulfur Diesel written by Pavan Kumar Penumalla Venkata and published by . This book was released on 2011 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biodiesel has been a promising clean alternative fuel to fossil fuels, which reduces the emissions that are released by fossil fuels and possibly reduces the energy crisis caused by the exhaustion of petroleum resources in the near future. Biodiesel is replacing diesel as an alternative fuel for internal combustion engines. Previous research studies have shown that biodiesel greatly reduces carbon monoxide (CO), hydrocarbon (HC) and particulate matter (PM) emissions compared to diesel fuels. At present, B20 (20% biodiesel in the total fuel mix) is being used commonly due to its material compatibility to changing weather conditions, emission benefits and costs. In this study biodiesel blends B5, B10 and B50 were combusted to investigate how the engine conditions influence the emission concentrations of H2, CO, CH4, CO2, N2 and morphological data of particulate matter. Different emission samples were collected for a certain range of temperatures and pressures. The samples were analyzed using Gas Chromatography and the particulate matter was analyzed using Scanning Electron Microscope images. The samples of different biodiesel blends were then compared with the emissions from B20 and Ultra Low Sulfur Diesel at the same temperature and pressure ranges. From the results under varied tested conditions it has been inferred that, for low H2 emissions, B5 combustion under low temperatures and high pressures is preferred. For low CO emissions, B20 combustion under high temperatures and pressures is preferred. For low N2 emissions, B5 combustion under low temperatures and high pressures is preferred. For low CH4 emissions, B5 combustion under low temperatures and high pressures is preferred. For low CO2 emissions, ULSD combustion under low temperatures and low pressures is preferred. H2 emissions have decreased as the biodiesel blend increased. CO was observed to increase with the blend. The emissions were comparatively lower under low temperatures. N2 showed an increasing trend with the blend. Low temperatures and high pressure reduced the emissions. Not much variation was observed for CH4 for the blends under the tested conditions. The CO2 emission from the results was observed to be on an increasing trend except for B20. Under higher pressures and temperatures CO2 emissions were lower for all the blends except for B20. ULSD showed lower emissions under low temperatures and varying pressures compared to biodiesel. B5 showed lower emissions under lower temperatures and higher pressures. B10 showed the least emissions under lower temperatures and lower pressures. B20 showed lower emissions under high pressures and varying temperatures. B50 showed the least emissions under lower temperatures and higher pressures except for CO2 which showed lower emissions under higher temperatures and pressures.

Download or read book The Effects of Oxidized Biodiesel Fuel on Fatty Acid Methyl Ester Composition and Particulate Matter Emissions From a Light Duty Diesel Engine written by Jack Elliot Reed and published by . This book was released on 2021 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Diesel particulate matter (PM) is classified by the EPA as carcinogenic, with the transportation sector largely responsible these emissions within the United States. Biodiesel (B100) is derived from renewable sources, providing similar chemical composition to diesel fuel and is in the current diesel supply up to 5% across the nation. However, biodiesel has an inherent oxidation issue due to the unique mixture of fatty acid methyl ester (FAME) molecules present in the biodiesel that are not in diesel. Biodiesel oxidation can only be delayed, and the inevitable process results in changes to the original fuel composition that may alter emissions profiles. There have been limited studies on the effect of oxidized biodiesel fuel on PM emissions, and with increasing biodiesel production volumes, it is important to assess due to possible adverse human health effects. In this study, it was hypothesized that the change in fuel composition due to oxidation would lead to lower PM emissions because the presence of more fuel oxygen molecules and secondary oxidation products would enhance self-combustion characteristics. In this study, PM mass generated from a light-duty diesel engine running on three different fuel types--pure ("neat") B100 biodiesel, pure B0 diesel, and B20 (20% v/v biodiesel blend with diesel)--was quantified and compared to the PM mass (and concentrations) from repeated emissions testing using artificially oxidized B100 and B20 biodiesel as the fuel source. B100 fuel was heated at 110oC for 5, 10, and 20 hours ("oxidation states" 3, 2, and 1, respectively), verifying the extent of fuel oxidation by building an apparatus (Biodiesel Oxidation Stability Surveyor, BOSS) that quantified the biodiesel fuel's oxidative stability using a method equivalent to standard methods for determining the biofuel's induction period. Induction period increased linearly with time spent under the artificial oxidation conditions. A custom, load-based steady-state modal drive cycle was specially developed for emissions testing each neat and oxidized B100 and B20 fuel type in a light-duty diesel engine dynamometer. Observed changes in PM mass with increased fuel oxidation time occurred only for B20 fuel with a 51 ±13% decrease. Fuel properties such as cetane number, biodiesel content, density, and total aromatics were compared between neat and oxidized B20 and B100 samples. Cetane number increased 7% from 66.8 to 71.7 from B100 neat to B100 OX1 (20hrs) and density increased from 0.709g/cm3 to 0.723g/cm3. Chemical analysis of the biodiesel fuels by gas chromatography mass spectrometry (GCMS) quantified individual FAME compounds to determine key species involved in fuel oxidation. B100 FAME concentration widely varied, however, the B20 fuel blend showed that 20 hour artificial oxidation treatment decreased concentrations of the unsaturated FAMEs for C18:3n3, C18:2 cis-9,12, C18:1 (both cis- and trans- isomers) by 41.7 ±3.5%, 33.25 ±8.8%, and 21.9 ±6.9% relative to their initial concentration in the unoxidized fuel, respectively, in general agreement with literature values. The findings of this study help contribute a better understanding of oxidation effects on biodiesel fuel and link together fuel properties, chemical composition, and particulate emissions whereas most literature excludes detailed analysis of biodiesel fuel composition and associated emissions effects.