Download or read book Interfacial Phenomena in Partially Compatible Polymers written by Jan Genzer and published by . This book was released on 1996 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Interfacial Phenomena written by J.T. Davies and published by Academic Press. This book was released on 2012-12-02 with total page 507 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interfacial Phenomena examines the fundamental properties of various liquid interfaces. This book discusses the physics of surfaces; electrostatic and electrokinetic phenomena; and adsorption at liquid interfaces. The properties of monolayers; reactions at liquid surfaces; diffusion through interfaces; and disperse systems and adhesion are also deliberated. Other topics include the vapor pressures over curved surfaces; electrical capacity of the double layer; applications of electrophoresis; and thermodynamics of adsorption and desorption. The experimental methods of spreading films at the oil-water interface; penetration into monolayers; experiments on dynamic systems; and spontaneous emulsification are likewise covered in this text. This book is beneficial to chemical engineers and students concerned with interfacial phenomena.
Download or read book Interdiffusion Phenomena at Partially Miscible Polymer Interfaces written by Erin Lynne Jablonski and published by . This book was released on 2002 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: This research is focused on understanding the effect of miscibility on interdiffusion phenomena in bilayers of polystyrene (PS) and the statistically random copolymer, poly (styrene-r-4-bromostyrene) (PBS). Miscibility in such systems can be quantified by N*[Subscript X], where N* is an effective degree of polymerization and [Subscript X] the Flory-Huggins interaction parameter. In the PS/PBS system, miscibility decreases as N*[Subscript X] increases. The extent of interdiffusion at a bilayer interface is ultimately determined by the miscibility of the system. A description of the effect of miscibility on interdiffusion phenomena, interfacial width, phase behavior, and fracture energy and a relationship between these properties has not been elucidated, thus limiting optimal design of polymer interfaces for technologically relevant applications. This work highlights the effect of miscibility on interdiffusion dynamics and interfacial behavior, employing both experimental and modeling tools. Rutherford backscattering spectroscopy (RBS) was used to quantify interdiffusion in the PS/PBS bilayers. PBS volume fraction versus depth profiles were obtained from the evolution of the bromine peak in the RBS spectra of these bilayers as a function of annealing time. From these profiles, mutual diffusion coefficients were calculated. In miscible PS/PBS systems, interdiffusion of the bilayers results in a single layer of constant composition. In bilayers with PS and PBS having a disparity in N, the interface is observed to move toward the faster diffusing (lower N) component, in agreement with the fast-mode theory of mobility. In partially miscible PS/PBS layers, interdiffusion is observed to occur until bimodal conditions that agree with predicted phase diagrams are reached. Interfacial widths (w[Subscript i]) in PS/PBS bilayers were measured with X-ray reflectivity (XR) and are in qualitative agreement with the results of RBS. It was observed in miscible systems that features corresponding to a bilayer configuration disappeared after short diffusion times, indicating complete interdiffusion, while partially miscible and immiscible systems retained bilayers features for even the longest annealing times, indicating interdiffusion to binodal conditions or minimal interdiffusion, respectively. Implications of the miscibility dependence of the mutual diffusion coefficient and interfacial width are discussed both in the context of theoretical arguments as well as for strengthening partially miscible polymer interfaces.
Download or read book Molecular Interfacial Phenomena of Polymers and Biopolymers written by P Chen and published by Taylor & Francis US. This book was released on 2005-07-22 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book combines three fundamental areas of interest to the science and engineering community, these being material science, nanotechnology and molecular engineering. Although there have been various results published in this field, there has yet to be a fully comprehensive review. This book covers key research on molecular mechanisms and thermodynamic behaviour of (bio)polymer surfaces and interfaces, from theoretical and experimental perspectives.
Download or read book Interfacial Phenomena in Composite Materials 91 written by Ignaas Verpoest and published by Elsevier. This book was released on 2017-05-04 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interfacial Phenomena in Composite Materials '91 is a collection of papers dealing with the science of composite interfaces, with emphasis on theoretical modeling, test methods, and characterization methods of polymer matrix, metal, or ceramic matrix composites. One paper reviews the micromechanical test methods used in evaluating mechanical properties of fiber-matrix interface. Another paper shows that the critical fiber length cannot always be considered a material constant in the framework of load transfer models based on the shear lag theory. Microwave plasma treatment is a quick technology to change fiber surface structure as the oxidation or the roughening of the fiber increases fiber-matrix adhesion. Another paper evaluates the effect of improved adhesion on mechanical performance under static, dynamic, and impact conditions. It also examines the role of fiber anisotropy on the performance of high performance polyethylene/epoxy composites. By using the Laser Raman Spectroscopy, the investigator can analyze the effects of the fiber surface treatment, the fiber modulus, the curing temperature on the Shear strength, and the fracture mechanics of the interface. The collection can be read profitably by chemists, biochemists, and academicians involved in material compound research.
Download or read book Polymer Interface and Adhesion written by Wu and published by Routledge. This book was released on 2017-11-22 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt: Poly mer Interface and Adhesion provides the critical basis for further advancement in thisfield. Combining the principles of interfacial science, rheology, stress analysis, and fracturemechanics, the book teaches a new approach to the analysis of long standing problemssuch as: how is the interface formed; what are its physical and mechanical properties;and how does the interface modify the stress field and fracture strength of the material.The book offers many outstanding features, including extensive listings of pertinent references,exhaustive tabulations of the interfacial properties of polymers, critical reviews ofthe many conflicting theories, and complete discussions of coupling agents, adhesion promotion,and surface modifications. Emphasis is placed on physical concepts and mechanisms,using clear, understandable mathematics.Polymer Interface and Adhesion promotes a more thorough understanding of the physical,mechanical, and adhesive properties of multiphase, polymer systems. Polymer scientistsand engineers, surface chemists, materials scientists, rheologists, as well as chemical andmechanical engineers interested in the research, development or industrial applications ofpolymers, plastics, fibers, coatings, adhesives, and composites need this important newsource book.
Download or read book Scientific Activities written by Mekhon Ṿaitsman le-madaʻ and published by . This book was released on 1991 with total page 976 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Interfaces Crystallization Viscoelasticity written by and published by Springer. This book was released on 2003-07-01 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Epoxy resins are regarded as thermosetting resins and have found various c- mercial applications after crosslinking with adequate curing agents [1–3]. H- ever, some epoxy resins have been used as thermoplastic resins without curing agents. Figure 1 shows the applications of epoxy resins that are classi?ed to three categories: thermosets in combination with curing agents, thermoplastics wi- out curing agents, and raw materials for modi?cation. The use in thermoplastics is not popular compared with the two other applications. Typical thermoplastic applications are found in stabilizers for vinyl resins, toners for copying - chines, ?re retardants for engineering plastics, and sizing material for glass or carbon ?bers. The epoxy resin most frequently used is the oligomer of the diglycidyl ether of bisphenol-A (DGEBA) whose chemical structure is shown below [1–3]. The DGEBA is composed of linear molecules with different molecular weights according to the variation of the repeated number (n) in the structural formula.
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 994 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Silanes and Other Coupling Agents Volume 2 written by Kash L. Mittal and published by CRC Press. This book was released on 2020-04-27 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book embodies the proceedings of the Second International Symposium on Silanes and other Adhesion Promoters held in Newark, New Jersey, October 21--23, 1998. Silanes are the most popular and widely used coupling agents (or adhesion promoters) to promote adhesion between dissimilar materials in a variety of situations, e.g. coating technology, adhesive bonding, reinforced composites, etc. Since the first symposium on this topic in 1991, there had been a tremendous R&D activity in developing new and more effective adhesion promoters and in understanding and optimising the performance of available coupling agents. The technical program for the symposium contained 36 papers and reflected both overviews and original research contributors and the presenters hailed from academia, industry and other research laboratories. Many different aspects of coupling agents were discussed, and both fundamental and applied aspects were accorded due coverage. In addition to formal presentations, there were brisk and lively discussions throughout the symposium, and this event provided an opportunity for cross-pollination of ideas in the broad arena of adhesion promoters. This present volume contains 18 papers by experts from academia, industry and other research laboratories. All manuscripts were subjected to rigorous peer review and were suitably revised before inclusion in this volume. The book is divided into two parts as follows: Part 1. Silane Coupling Agents; and Part 2: Non-silane Coupling Agents/Adhesion Promotors. The topics covered include: silane adhesion prompters for hydrosilylation cure systems; sterically hindered silanes; study of silanes hydrolysis; adsorption of silanes on different substrates; interaction of water with silane films studied by neutron reflection; characterization of glass fiber sizings; silanes as dispersion promoters; corrosion protection of metals by silanes; surface 'Intelligraft' as a new class of adhesion promoters; hydroxymethylated resorcinol, sol-gels, and -diketone functionalised polymers as adhesion promoters; and plasma deposition of silanes.
Download or read book Multicomponent Polymers written by Guojian Wang and published by Walter de Gruyter GmbH & Co KG. This book was released on 2020-10-26 with total page 405 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book introduces fundamental principles, phase structure, mechanism, mechanical properties, and different types of multicomponent polymers. Rheological properties, graft copolymers, block copolymers and interpenetrating polymer networks are discussed in detail as well. With abundant illustrations, it is an essential reference for polymer chemists, material scientists and graduate students.
Download or read book Biennial Report written by United States-Israel Binational Science Foundation and published by . This book was released on 1991 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermal Oxidation of Polymer Blends written by Lyudmila Shibryaeva and published by CRC Press. This book was released on 2006-06-08 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt: To identify the specific features of the kinetics of oxidation of polymer mixtures, determine the key structural elements, and create a model that can describe the mechanism of thermal oxidation of polymer mixtures, it is necessary to determine the relation between the initial structure of a polymer mixture, structural rearrangements associated with oxidation and the kinetics of the process. The aim of this book is to elucidate the complicated problem concerning the connection between the structure and mechanism of oxidation of heterogeneous and heterophase polymer systems. The material presented in this book concerns the specific features of the kinetics of oxidation and those of the structure of polymer systems. The book deals with an analysis of the key factors that can affect principally the mechanism of thermal oxidation of polymer mixtures, determines the role of the phase morphology, structure of components, and the interface layer (or boundary) in the kinetics of oxidation of heterophase system by an example of mixtures of polyolefines. Along with the kinetics of oxidation of heterophase systems, problems of investigation of their structural parameters in the oxidized state are considered. With this aim, the material presented in the book concerns not only the mechanism of oxidation of polymer mixtures but also homopolymers of diverse morphology and model systems.
Download or read book Metal Polymer Systems written by Jörg Florian Friedrich and published by John Wiley & Sons. This book was released on 2017-12-04 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: The result of decades of research by a pioneer in the field, this is the first book to deal exclusively with achieving high-performance metal-polymer composites by chemical bonding. Covering both the academic and practical aspects, the author focuses on the chemistry of interfaces between metals and polymers with a particular emphasis on the chemical bonding between the different materials. He elucidates the various approaches to obtaining a stable interface, including, but not limited to, thermodynamically driven redox reactions, bond protection to prevent hydrolysis, the introduction of barrier layers, and stabilization by spacer molecules. Throughout, chemical bonding is promoted as a simple and economically viable alternative to adhesion based on reversible weak physical interaction. Consequently, the text equips readers with the practical tools necessary for designing high-strength metal-polymer composites with such desired properties as resilience, flexibility, rigidity or degradation resistance.
Download or read book Biomaterials Interfacial Phenomena and Applications written by American Institute of Chemical Engineers. Annual Meeting and published by . This book was released on 1982 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Non equilibrium Phenomena in Confined Soft Matter written by Simone Napolitano and published by Springer. This book was released on 2015-08-28 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with those properties of non-equilibrium soft matter that deviate greatly from the bulk properties as a result of nanoscale confinement.The ultimate physical origin of these confinement effects is not yet fully understood. At the state of the art, the discussion on confinement effects focuses on equilibrium properties, finite size effects and interfacial interactions. However this is a limited vision which does not fully capture the peculiar behaviour of soft matter under confinement and some exotic phenomena that are displayed. This volume will be organized in the following three main themes. Equilibration and physical aging: treating non-equilibrium via the formal methodology of statistical physics in bulk, we analyse physical origin of the non-equilibrium character of thin polymer. We then focus on the impact of nanoconfinement on the equilibration of glasses of soft matter (a process of tremendous technological interest, commonly known as physical aging), comparing the latest trends of polymers in experiments, simulations with those of low-molecular weight glass formers. Irreversible adsorption: the formation of stable adsorbed layers occurs at timescales much larger than the time necessary to equilibrate soft matter in bulk. Recent experimental evidence show a strong correlation between the behaviour of polymers under confinement and the presence of a layer irreversibly adsorbed onto the substrate. This correlation hints at the possibility to tailor the properties of ultrathin films by controlling the adsorption kinetics. The book reports physical aspects of irreversible chain adsorption, such as the dynamics, structure, morphology, and crystallization of adsorbed layers. Glass transition and material properties: this section of the book focuses on the spread of absolute values in materials properties of confined systems, when measured by different experimental and computation techniques and a new method to quantify the effects of confinement in thin films and nanocomposites independently on the investigation procedure will be presented.
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2005 with total page 804 pages. Available in PDF, EPUB and Kindle. Book excerpt:
