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Book Initial Sulfate Solubility Study for Sludge Batch 4  SB4

Download or read book Initial Sulfate Solubility Study for Sludge Batch 4 SB4 written by T. Lorier and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this task is to provide the Defense Waste Processing Facility (DWPF) of the Savannah River Site (SRS) with an assessment of the viability of using the current 0.6 wt% SO{sub 4}{sup =} limit (in glass) and/or the possibility of increasing the SO{sub 4}{sup =} solubility limit to account for anticipated sulfur concentrations in Sludge Batch 4 (SB4). The 0.6 wt% SO{sub 4}{sup =} limit was implemented for processing of Frit 418-Sludge Batch 3 (SB3) to avoid the formation of sulfate inclusions in the glass and/or the formation of a molten sulfate-rich phase on the melt pool in the DWPF melter. The presence of such a phase on the surface of the melt pool increases corrosion rates of melter components, enhances the potential for steam excursions in a slurry-fed waste glass melter, and creates the potential for undesirable current paths that could deplete energy delivered to the melter due to the electrical conductivity of the molten salt layer. This suite of sulfate-solubility tests began by testing the 1200-canister, 2nd transfer case for SB4 (as defined by Lilliston and Shah, 2004)--based on this being the most conservative (having the highest predicted viscosity when coupled with specific frits, it could potentially have the greatest impact on SO{sub 4}{sup =} solubility) blending scenario of SB4 with the heel of SB3 for SO{sub 4}{sup =} solubility. Frits 320 and 418 were tested with SB4 and the tests indicated that at the current SO{sub 4}{sup =} limit (in glass) and the tested waste loadings (30% and 40%), neither Frit 320 nor Frit 418 could be utilized with SB4 (for the 1200-canister, 2nd transfer case composition originally provided). More specifically, SO{sub 4}{sup =} was observed on the surface with the SB4 composition and Frit 320 at 40% waste loading (WL) and 0.6 wt% SO{sub 4}{sup =}, and with Frit 418 at 30% and 40% WL and 0.5 wt% SO{sub 4}{sup =}. As alternative frits were being developed--Frits 447, 448, and 449, that contained CaO and/or V2O5 to enhance SO{sub 4}{sup =} solubility based on suggestions of previous studies--testing began of the 1100-canister, 1st transfer case for SB4 (from Lilliston, 2005), which is the baseline flowsheet for the DWPF. The results of the study with the revised compositions have indicated that the SO{sub 4}{sup =} solubility limit in the DWPF of 0.6 wt% can be applicable for the 1100-canister, 1st transfer case of SB4 for certain frits. Five frits were tested in closed-crucible studies--Frits 320, 418, 447, 448, and 449. Tests with Frit 418 showed that SO{sub 4}{sup =} was apparent on the glass surface of tests at 40% WL and 0.6 wt% SO{sub 4}{sup =}. No salt layer formation was evident in any test (30% or 40% WL) with Frits 320, 447, 448, or 449 until SO{sub 4}{sup =} concentrations of 0.8 wt% were targeted. The crucible tests of this study and model predictions (from Jantzen and Smith, 2004) indicated that the SO{sub 4}{sup =} solubility limit for SB4 with those four frits would be similar. However, even with the additions of CaO and V2O5, the solubility of SO{sub 4}{sup =} was not greatly enhanced by Frits 447, 448, and 449 over Frit 320 for the 1100-canister, 1st transfer case. The following recommendation is made regarding the SO{sub 4}{sup =} solubility limit for SB4 in the DWPF: Reinvestigate the solubility of SO{sub 4}{sup =} for SB4 once the final blending and/or washing strategies for SB4 are determined--based on the decisions for the inclusion of Tank 4 and the exact volume and composition of the Np stream--in order to determine if the current SO{sub 4}{sup =} solubility limit (0.6 wt% SO{sub 4}{sup =}) in the DWPF needs to be increased for the processing of SB4.

Book SLUDGE BATCH 4 SIMULANT FLOWSHEET STUDIES

Download or read book SLUDGE BATCH 4 SIMULANT FLOWSHEET STUDIES written by M. Stone and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Defense Waste Processing Facility (DWPF) will transition from Sludge Batch 3 (SB3) processing to Sludge Batch 4 (SB4) processing in early fiscal year 2007. Tests were conducted using non-radioactive simulants of the expected SB4 composition to determine the impact of varying the acid stoichiometry during the Sludge Receipt and Adjustment Tank (SRAT) process. The work was conducted to meet the Technical Task Request (TTR) HLW/DWPF/TTR-2004-0031 and followed the guidelines of a Task Technical and Quality Assurance Plan (TT & QAP). The flowsheet studies are performed to evaluate the potential chemical processing issues, hydrogen generation rates, and process slurry rheological properties as a function of acid stoichiometry. Initial SB4 flowsheet studies were conducted to guide decisions during the sludge batch preparation process. These studies were conducted with the estimated SB4 composition at the time of the study. The composition has changed slightly since these studies were completed due to changes in the sludges blended to prepare SB4 and the estimated SB3 heel mass. The following TTR requirements were addressed in this testing: (1) Hydrogen and nitrous oxide generation rates as a function of acid stoichiometry; (2) Acid quantities and processing times required for mercury removal; (3) Acid quantities and processing times required for nitrite destruction; and (4) Impact of SB4 composition (in particular, oxalate, manganese, nickel, mercury, and aluminum) on DWPF processing (i.e. acid addition strategy, foaming, hydrogen generation, REDOX control, rheology, etc.).

Book Wissenschaftliche Paperbacks  Literaturwissenschaft

Download or read book Wissenschaftliche Paperbacks Literaturwissenschaft written by and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Clostridia

    Book Details:
  • Author : Nigel P. Minton
  • Publisher : Springer Science & Business Media
  • Release : 2013-06-29
  • ISBN : 1475797184
  • Pages : 313 pages

Download or read book Clostridia written by Nigel P. Minton and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: To the uninitiated, the genus Clostridium is likely more to be associated with disease than biotechnology. In this volume, we have sought to remedy this misconception by compiling aseries of chapters which, together, provide a practically-oriented handbook of the biotechnologie potential of the genus. Clostridium is a broad grouping of organisms that together undertake a myriad of biocatalytic reactions. In the first two chapters, the reader is introduced to this diversity, both taxonomically and physiologically. In the following chapter, the current state of genetic analysis of members of the genus is reviewed. The remaining chapters concentrate on specific, exploit able aspects of individual Clostridium species-highlighting their range of unique capabilities (of potential or recognized industrial value), particu larly in the areas of biotransformation, enzymology, and the production of chemical fuels. Fittingly, the final chapter demonstrates that even the most toxic of the clostridia can be of therapeutic value. The contributors to this volume reflect the trans national interest in Clostridium, and we are indebted to each of them for making this volume possible. We particularly wish to acknowledge the contributions, both to this volume and to microbiology in general, of Dr. Elizabeth Cato, who, sadly, died shortly be fore publication ofthis volume. Finally, we would like to join the authors in recommending closer and wider consideration of the attributes and capabilities of this genus.

Book The Darkroom Cookbook

Download or read book The Darkroom Cookbook written by Steve Anchell and published by CRC Press. This book was released on 2012-09-10 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: The art of darkroom developing and printing will never go out of style. Master darkroom specialist Steve Anchell is back to prove it in this long-awaited third edition of his enormously successful Darkroom Cookbook. Packed with over 200 "recipes," some common and others rare gems, you'll discover something new every time you open this guide, whether you're new to the darkroom or have been making your own prints for years. In addition to the formulas, you'll find tons of useful information on developers, push-processing, where to get darkroom equipment, how to set up your own darkroom, how to work and play in your darkroom safely, and much more. This handy guide will become a constant companion for every darkroom enthusiast creating prints at home or in the studio. In addition to complete updates throughout to reflect changes in the availability of chemicals and equipment, this third edition contains all new information on: *Reversal processing *Enlarged negatives *Pyro formulas *Plus expanded sections on printing, pyro, and toning prints Also included for the first time are special technique contributions as well as stunning black and white imagery by Bruce Barnbaum, Rod Dresser, Jay Dusard, Patrick Gainer, Richard Garrod, Henry Gilpin, Gordon Hutchings, Sandy King, Les McLean, Saïd Nuseibeh, France Scully Osterman, Mark Osterman, Tim Rudman, Ryuijie, John Sexton, and John Wimberly. Be sure to visit www.darkroomcookbook.com to find useful links, an interactive user forum, and more! Steve Anchell is a photographer and author of The Variable Contrast Printing Manual, and co-author of The Film Developing Cookbook. He has been teaching darkroom and photography workshops since 1979. Steve is a member of the Freestyle Advisory Board of Photographic Professionals. "With its unrivalled collection of photographic formulae and easy to understand explanations of photographic processes, The Darkroom Cookbook has long been a favorite with darkroom workers everywhere. Now, with further additions to its formulary, more topics, and contributions by renowned darkroom experts, this new edition promises to be an indispensable Aladdin's Cave resource to darkroom enthusiasts of all levels. -Tim Rudman, photographer and author "The Darkroom Cookbook is an essential compendium of photographic information for anyone interested in high-quality darkroom work. -John Sexton, photographer

Book Materials Handbook

Download or read book Materials Handbook written by François Cardarelli and published by Springer Science & Business Media. This book was released on 2008-03-19 with total page 1365 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique and practical book provides quick and easy access to data on the physical and chemical properties of all classes of materials. The second edition has been much expanded to include whole new families of materials while many of the existing families are broadened and refined with new material and up-to-date information. Particular emphasis is placed on the properties of common industrial materials in each class. Detailed appendices provide additional information, and careful indexing and a tabular format make the data quickly accessible. This book is an essential tool for any practitioner or academic working in materials or in engineering.

Book Rules of Thumb for Chemical Engineers

Download or read book Rules of Thumb for Chemical Engineers written by Carl Branan and published by Gulf Professional Publishing. This book was released on 2002 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fractionators, separators and accumulators, cooling towers, gas treating, blending, troubleshooting field cases, gas solubility, and density of irregular solids * Hundreds of common sense techniques, shortcuts, and calculations.

Book Modern Glass Characterization

Download or read book Modern Glass Characterization written by Mario Affatigato and published by John Wiley & Sons. This book was released on 2015-10-05 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book consists of a series of edited chapters, each written by an expert in the field and focusing on a particular characterization technique as applied to glass. The book covers a variety of techniques ranging from the very common (like Raman and FTIR) to the most recent (and less well known) ones, like SEM for structural analysis and photoelastic measurements. The level of the chapters make it suitable for researchers and for graduate students about to start their research work. It will also: discuss the technique itself, background, nuances when it comes to looking at glassy materials, interpretation of results, case studies, and recent and near-future innovations Fill a widening gap in modern techniques for glass characterization Provide much needed updates on the multiple essential characterization techniques

Book Copper Leaching  Solvent Extraction  and Electrowinning Technology

Download or read book Copper Leaching Solvent Extraction and Electrowinning Technology written by Gerald V. Jergensen and published by SME. This book was released on 1999 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume recognizes the growing role of solvent extraction and electrowinning technology in the world copper business. This well-established, remarkable hydrometallurgical achievement fills an important role in our technical ability to extract copper in an efficient and cost-effective way. This proceedings documents the present status of the SX-EW business. It represents a substantial body of historical, scientific, engineering, and commercial information regarding the growth and application of the technology.

Book Chemical Process Design and Integration

Download or read book Chemical Process Design and Integration written by Robin Smith and published by John Wiley & Sons. This book was released on 2016-08-02 with total page 923 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a highly regarded author with industrial and academic experience, this new edition of an established bestselling book provides practical guidance for students, researchers, and those in chemical engineering. The book includes a new section on sustainable energy, with sections on carbon capture and sequestration, as a result of increasing environmental awareness; and a companion website that includes problems, worked solutions, and Excel spreadsheets to enable students to carry out complex calculations.

Book Microbial Interventions in Agriculture and Environment

Download or read book Microbial Interventions in Agriculture and Environment written by Dhananjaya Pratap Singh and published by Springer Nature. This book was released on 2019-11-27 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microbial communities and their functions play a crucial role in the management of ecological, environmental and agricultural health on the Earth. Microorganisms are the key identified players for plant growth promotion, plant immunization, disease suppression, induced resistance and tolerance against stresses as the indicative parameters of improved crop productivity and sustainable soil health. Beneficial belowground microbial interactions with the rhizosphere help plants mitigate drought and salinity stresses and alleviate water stresses under the unfavorable environmental conditions in the native soils. Microorganisms that are inhabitants of such environmental conditions have potential solutions for them. There are potential microbial communities that can degrade xenobiotic compounds, pesticides and toxic industrial chemicals and help remediate even heavy metals, and thus they find enormous applications in environmental remediation. Microbes have developed intrinsic metabolic capabilities with specific metabolic networks while inhabiting under specific conditions for many generations and, so play a crucial role. The book Microbial Interventions in Agriculture and Environment is an effort to compile and present a great volume of authentic, high-quality, socially-viable, practical and implementable research and technological work on microbial implications. The whole content of the volume covers protocols, methodologies, applications, interactions, role and impact of research and development aspects on microbial interventions and technological outcomes in prospects of agricultural and environmental domain including crop production, plan-soil health management, food & nutrition, nutrient recycling, land reclamation, clean water systems and agro-waste management, biodegradation & bioremediation, biomass to bioenergy, sanitation and rural livelihood security. The covered topics and sub-topics of the microbial domain have high implications for the targeted and wide readership of researchers, students, faculty and scientists working on these areas along with the agri-activists, policymakers, environmentalists, advisors etc. in the Government, industries and non-government level for reference and knowledge generation.

Book Phytobiont and Ecosystem Restitution

Download or read book Phytobiont and Ecosystem Restitution written by Vivek Kumar and published by Springer. This book was released on 2018-12-31 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers present-day retrospectives and future perspectives on ‘phytobiont’ studies in the context of phyto-micro restitution, filling some of the information gaps in this promising research field. It discusses several ecosystem restitution strategies using dissimilar groups of microbes alone or in association with plants, as well as advances in metagenomics technology for studying in situ micro and macro communities in contaminated soil. It addresses topics such as the status quo, and the perspectives of microbial researchers and scientists, foresters, students, environmentalists, agriculturists and professional engineers. The rising pollution levels caused by xenobiotics is one of the biggest problems of our times, and as such the book comprehensively elaborates the latest research in this field and describes how the issue can be tackled using micro-organisms. With detailed diagrams and illustrations, the book is a valuable resource for experts and novices in the field of microbial bioremediation, phyto-bioremediation and environmental microbiology

Book Energy Technology 2018

Download or read book Energy Technology 2018 written by Ziqi Sun and published by Springer. This book was released on 2018-01-30 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection focuses on energy efficient technologies including innovative ore beneficiation, smelting technologies, recycling and waste heat recovery. The volume also covers various technological aspects of sustainable energy ecosystems, processes that improve energy efficiency, reduce thermal emissions, and reduce carbon dioxide and other greenhouse emissions. Papers addressing renewable energy resources for metals and materials production, waste heat recovery and other industrial energy efficient technologies, new concepts or devices for energy generation and conversion, energy efficiency improvement in process engineering, sustainability and life cycle assessment of energy systems, as well as the thermodynamics and modeling for sustainable metallurgical processes are included. This volume also includes topics on CO2 sequestration and reduction in greenhouse gas emissions from process engineering, sustainable technologies in extractive metallurgy, as well as the materials processing and manufacturing industries with reduced energy consumption and CO2 emission. Contributions from all areas of non-nuclear and non-traditional energy sources, such as solar, wind, and biomass are also included in this volume.Papers from the following symposia are presented in the book:Energy Technologies and CO2 ManagementAdvanced Materials for Energy Conversion and Storage Deriving Value from Challenging Waste Streams: Recycling and Sustainability Joint SessionSolar Cell SiliconStored Renewable Energy in Coal

Book Photographic Chemicals and Solutions

    Book Details:
  • Author : John Ickeringill 1891- Crabtree
  • Publisher : Hassell Street Press
  • Release : 2021-09-09
  • ISBN : 9781014516336
  • Pages : 378 pages

Download or read book Photographic Chemicals and Solutions written by John Ickeringill 1891- Crabtree and published by Hassell Street Press. This book was released on 2021-09-09 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work has been selected by scholars as being culturally important and is part of the knowledge base of civilization as we know it. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. To ensure a quality reading experience, this work has been proofread and republished using a format that seamlessly blends the original graphical elements with text in an easy-to-read typeface. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.

Book Microbial Applications Vol 2

Download or read book Microbial Applications Vol 2 written by Vipin Chandra Kalia and published by Springer. This book was released on 2018-07-18 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: This contributed volume provides insights into multiple applications using microbes to promote productivity in agriculture, to produce biochemicals or to respond to challenges in biomedicine. It highlights the microbial production of nanocompounds with medical functionality alongside new anti-mycobacterial strategies, and introduces plant-growth-promoting Rhizobacteria as well as the correlation between biofilm formation and crop productivity. Further, the authors illustrate the green synthesis of biochemical compounds, such as hydroxamid acid or biosurfactants, using microbial and fungal enzymes. It inspires young researchers and experienced scientists in the field of microbiology to explore the combined use of green, white and red biotechnology for industrial purposes, which will be one of the central topics for future generations.

Book Microbial Electrochemical Technologies

Download or read book Microbial Electrochemical Technologies written by Sonia M. Tiquia-Arashiro and published by CRC Press. This book was released on 2020-01-06 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book encompasses the most updated and recent account of research and implementation of Microbial Electrochemical Technologies (METs) from pioneers and experienced researchers in the field who have been working on the interface between electrochemistry and microbiology/biotechnology for many years. It provides a holistic view of the METs, detailing the functional mechanisms, operational configurations, influencing factors governing the reaction process and integration strategies. The book not only provides historical perspectives of the technology and its evolution over the years but also the most recent examples of up-scaling and near future commercialization, making it a must-read for researchers, students, industry practitioners and science enthusiasts. Key Features: Introduces novel technologies that can impact the future infrastructure at the water-energy nexus. Outlines methodologies development and application of microbial electrochemical technologies and details out the illustrations of microbial and electrochemical concepts. Reviews applications across a wide variety of scales, from power generation in the laboratory to approaches. Discusses techniques such as molecular biology and mathematical modeling; the future development of this promising technology; and the role of the system components for the implementation of bioelectrochemical technologies for practical utility. Explores key challenges for implementing these systems and compares them to similar renewable energy technologies, including their efficiency, scalability, system lifetimes, and reliability.

Book Archaeometallurgy     Materials Science Aspects

Download or read book Archaeometallurgy Materials Science Aspects written by Andreas Hauptmann and published by Springer Nature. This book was released on 2020-11-21 with total page 595 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book successfully connects archaeology and archaeometallurgy with geoscience and metallurgy. It addresses topics concerning ore deposits, archaeological field evidence of early metal production, and basic chemical-physical principles, as well as experimental ethnographic works on a low handicraft base and artisanal metal production to help readers better understand what happened in antiquity. The book is chiefly intended for scholars and students engaged in interdisciplinary work.