Download or read book Influence of Dispersed Refractory Oxides in Retarding Catalyst Sintering written by D. Lynn Johnson and published by . This book was released on 1978 with total page 45 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1978 with total page 1018 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Sintering Mechanism as Applied to Refractory Oxides written by D. R. Wilder and published by . This book was released on 1952 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt: This annotated bibliography was prepared as a guide to the literature, 1937 to 1952, pertaining to sintering of refractory oxides. It includes the theories proposed for the mechanism of sintering and much of the work on which these theories are based. Due to the limited and scattered nature of the work reported, subject classification has not been made, but the abstracts are listed alphabetically by author.
Download or read book Fossil Energy Update written by and published by . This book was released on 1978 with total page 790 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1978 with total page 1194 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Proceedings of the Symposium on Molten Carbonate Fuel Cell Technology written by J. R. Selman and published by . This book was released on 1984 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Proceedings of the Second International Symposium on Molten Salts written by Jerry Braunstein and published by . This book was released on 1981 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inventory of energy research and development 1973 1975 written by Oak Ridge National Laboratory and published by . This book was released on 1976 with total page 1430 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book EPRI Guide written by and published by . This book was released on 1983 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book EPRI Journal written by Electric Power Research Institute and published by . This book was released on 1978 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Inventory of Energy Research and Development 1973 1975 Indexes and appendices written by Oak Ridge National Laboratory and published by . This book was released on 1976 with total page 1462 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Molten Salt Technology written by David G. Lovering and published by Springer. This book was released on 2014-11-14 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Proceedings of the Fourth International Symposium on Carbonate Fuel Cell Technology written by J. R. Selman and published by The Electrochemical Society. This book was released on 1997 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Current Awareness in Particle Technology written by and published by . This book was released on 1979 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Sintering and Catalysis written by G. Kuczynski and published by Springer. This book was released on 1975-12-01 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: The proceedings of the 4th International Conference on Sin tering and Related Phenomena, contained in this volume, have been broadened in scope to include the phenomena of sintering and coa lescence of catalytic materials dispersed upon refractory oxides. For it has long been recognized within the circles of chemists and chemical engineers working in the field of catalysis that one of the chief causes of the decline in heterogeneous catalytic activity and/or selectivity is, indeed sintering, or perhaps using a better term, coalescence of the supported catalytic metal and compounds thereof. Essentially catalytic deactivation by sintering is now weIl recognized as Ostwald ripening; which of course is a phenome non familiar to scientists grappling with the problem of sintering of powder compacts. The 4th Conference at Notre Dame marks the first occasion at which scientists and engineers of each discipline were assembled in the same room to exchange views on these phenome na of mutual concern. In the wake of the Conference at Notre Dame, all parties acknowledged the synergistic benefit which issued from this exchange, both at the formal and informal level. All were persuaded that signal benefits will be realized by a continuation of this collab oration in the form of future sintering conferences in which both powder metallurgists and catalytic scientists and engineers would participate.
Download or read book Adsorption of Transition Metal Complexes on Metal Oxide Supports written by Ahana Mukhopadhyay and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Widespread industrial applications and large impact of supported late transitionprecious metal catalysts on the global economy serves as the prime motivation for thededication of academic researchers towards focusing on the scalable and affordable design ofefficient catalysts. Catalyst design requires a fundamental understanding of how the differentsynthetic steps (adsorption, drying, pretreatment, etc) influence the properties of the finalcatalyst. Moreover, in current times, single-atom catalysts represent an exciting new class ofmaterials that have demonstrated high activity for chemical reactions relevant to energyproduction. Among the various stages involved in catalyst synthesis, the initial adsorptionstep between the support and the precursor is believed to be of most importance as thisinteraction influences the unit operations that follow and affects the final size distribution ofthe catalyst nanoparticles. The ability of metal oxide supports to enhance the dispersion ofthe active metal on their surface and control their morphology and sintering kinetics isfundamentally related to the nature and strength of the metalsupport interaction which isdetermined at the time of adsorption at the solid-liquid interface. Documented studies on theimportance of the adsorption step on the overall characteristics of the catalyst nanoparticleare limited in recent literature due to challenges associated with probing a buried solid-liquidinterface. In this work, we have examined the molecular level details of catalyst synthesiswith substantial emphasis on the adsorption thermodynamics occurring at the solid-liquidinterface during the initial adsorption of transition metal complexes (TMCs) on metal oxidesupports and its influence on nanoparticle size, growth and stability.Using a number of surface analytical tools, we have probed at the interface during theadsorption process to quantify metal uptake and measure the kinetics and enthalpy of binding in order to identify the effect of different precursors and their ligand chemistry on the electrostatic driving force. Isothermal Titration Calorimetry (ITC) is used to contact reducible and refractory supports like SiO2, -Al2O3 and CeO2 with pH adjusted TMC solutions of Pt, Pd, Rh, Ir and Ag at adjusted pH values, providing a strong electrostatic driving force for adsorption and measure equilibrium binding constants, stoichiometry and enthalpies of adsorption. This study is unique in context that it truly probes the interface during adsorption (in situ) of metal precursors on supports rather than as-synthesized nanoparticles. The trends in the estimated thermodynamic parameters as a function of pH for both the cationic and anionic Pt complexes on silica and alumina respectively captures the effect of ligand speciation and complex solvation at acidic and basic solution conditions. Equilibrium adsorption isotherms from bench top bulk uptake studies aid in quantifying the amount of metal adsorbed on the support surface and by varying choice and weight loading of the precursors, we are able to identify that chloride ligand speciation chemistry around main metal center and solvation strongly influenced metal uptake. Next, we compared bulk and interfacial adsorption mechanisms through ex-situ synthesis to determine how the particle size distribution and metal dispersion of the catalysts were influenced by the mode of adsorption. Thereafter, we looked at cerium oxide which is an important support for transition metal catalysts due to its high oxygen storage capacity; thus allowing it to successfully stabilize noble metals, inhibit sintering and maintain small sized nanoparticles on its surface compared to other oxide supports. The thermodynamic adsorption parameters of a comprehensive list of late transition metal complexes in Group 9-11 on shape controlled faceted cerium oxide nano-crystals demonstrated by ITC and DFT calculations showed a trend in the enthalpies of binding between support and metal precursors that correlates with the oxide formation tendency of the transition metal and the reducibility of the support. The ability of metals to form atomically dispersed metal nanoparticles on cerium oxide through formation of an M-O-Ce bond under strong oxidative conditions was examined using XPS and TEM. Several combinations of catalysts were synthesized using precursors having various ligand chemistries deposited on different facets of cerium oxide nano-crystals and surface analytical tools were used to evaluate the optimal conditions for stable, highly dispersed catalysts. From these design rules, a series of ceria supported low weight loading single atom Pd catalysts were synthesized and examined for low temperature methane combustion that is highly in demand to reduce methane slip from lean-burn natural gas vehicles. Here, we probed into the effect of the transition from nano-clusters to single atoms on the activity of the reaction. A possible mechanistic change in the Pd catalytic redox cycle is believed to enhance the catalytic turnover at low temperatures while maintaining reduced precious metal usage.
Download or read book Government Reports Announcements Index written by and published by . This book was released on 1978-10-13 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt:
