Download or read book Comprehensive Organic Synthesis written by Barry M. Trost and published by Elsevier. This book was released on 1991 with total page 1174 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 8.

Download or read book Hydrogenation and Hydrogenolysis in Synthetic Organic Chemistry written by A.P.G. Kieboom and published by Springer. This book was released on 1977-03-31 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: Numerous examples are known of the application of catalyzed hydrogenation and hydrogenolysis reactions in synthetic organic chemistry. However, catalyst and reaction conditions are often chosen on the analogy of literature data without a good knowledge of the influence of reaction variables and of the structure of the reactant on the various possible modes of reaction. In order to improve such an intuitive procedure it is essential to dispose of an understanding of the reaction mechanisms which are operative in hydrogena tion and hydrogenolysis reactions and which govern i.a. the selectivity of a given pathway with respect to consecutive and parallel reactions. Although organic chemistry and, in particular, hydrogenation and hydro genolysis reactions remain an experimental science this book has been written to give the organic chemist the insight and know-how necessary to apply these reactions successfully to synthetic problems. I warmly recommend it as a book which will enable the organic chemist to rationalize many of the phenomena of catalytic hydrogenation and hydrogenolysis reactions, whereby it surely helps the organic chemist to solve forthcoming synthetic problems in this field. In addition, it seems to me a useful book for physical and physical-organic chemists working in the field of homogeneous and heterogeneous catalysis. Finally, the ten years' experience of both authors in the field of catalysis and synthetic organic chemistry - as reflected by some forty publications guarantees a well-considered review containing many examples directly from the bench.

Download or read book Heterogeneous Catalysis in Organic Chemistry written by Gerard V. Smith and published by Academic Press. This book was released on 1999-06-30 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses. Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic organic chemistry. Many academic organic chemists are not aware of recent advances in heterogeneous enantioselective catalysis (Chapter 3) or in selective low temperature, liquid phase heterogeneous catalytic oxidations by hydrogen peroxide (Chapter 6). These specialty topics are timely and may be new to academic organic chemists and can be used to supplement their advanced courses. Several features of this book will also be of special interest to industrial chemists who are unfamiliar with heterogeneous catalysis. Many good organic chemists are hire by industry. They synthesize a new compound using standard organic synthetic techniques but are informed by their supervisor that they must convert some of their synthetic steps into heterogeneous catalytic steps. They may not have been exposed to heterogeneous catalysis and have few places to turn. This book offers them a crash course in heterogeneous catalysis as well as many examples of reactions and conditions with which they can start their search. Those industrial organic chemists already familiar with heterogeneous catalysis will find this book useful as a reference to many examples in the recent literature. They will find recent surface science discoveries correlated with heterogeneous catalysis or organic reactions and mechanistic suggestions designed to stimulate innovative nontraditional thinking about organic reactions on surfaces. - Written by organic chemists for organic chemists - Introduces heterogeneous catalysis concepts and language - Presents a comprehensive compilation of protecting group removal procedures - Covers liquid-phase hydrogenations, hydrogenolysis, and oxidations - Addresses heterogeneous methods for producing pure enantiomers of chiral products - Examines the emerging field of heterogenized homogeneous catalysts - Mixes practical applications with mechanistic interpretations

Download or read book Introduction to Surface Chemistry and Catalysis written by Gabor A. Somorjai and published by John Wiley & Sons. This book was released on 2010-06-08 with total page 804 pages. Available in PDF, EPUB and Kindle. Book excerpt: Now updated-the current state of development of modern surface science Since the publication of the first edition of this book, molecular surface chemistry and catalysis science have developed rapidly and expanded into fields where atomic scale and molecular information were previously not available. This revised edition of Introduction to Surface Chemistry and Catalysis reflects this increase of information in virtually every chapter. It emphasizes the modern concepts of surface chemistry and catalysis uncovered by breakthroughs in molecular-level studies of surfaces over the past three decades while serving as a reference source for data and concepts related to properties of surfaces and interfaces. The book opens with a brief history of the evolution of surface chemistry and reviews the nature of various surfaces and interfaces encountered in everyday life. New research in two crucial areas-nanomaterials and polymer and biopolymer interfaces-is emphasized, while important applications in tribology and catalysis, producing chemicals and fuels with high turnover and selectivity, are addressed. The basic concepts surrounding various properties of surfaces such as structure, thermodynamics, dynamics, electrical properties, and surface chemical bonds are presented. The techniques of atomic and molecular scale studies of surfaces are listed with references to up-to-date review papers. For advanced readers, this book covers recent developments in in-situ surface analysis such as high- pressure scanning tunneling microscopy, ambient pressure X-ray photoelectron spectroscopy, and sum frequency generation vibrational spectroscopy (SFG). Tables listing surface structures and data summarizing the kinetics of catalytic reactions over metal surfaces are also included. New to this edition: A discussion of new physical and chemical properties of nanoparticles Ways to utilize new surface science techniques to study properties of polymers, reaction intermediates, and mobility of atoms and molecules at surfaces Molecular-level studies on the origin of the selectivity for several catalytic reactions A microscopic understanding of mechanical properties of surfaces Updated tables of experimental data A new chapter on "soft" surfaces, polymers, and biointerfaces Introduction to Surface Chemistry and Catalysis serves as a textbook for undergraduate and graduate students taking advanced courses in physics, chemistry, engineering, and materials science, as well as researchers in surface science, catalysis science, and their applications.

Download or read book Handbook of Commercial Catalysts written by Howard F. Rase and published by CRC Press. This book was released on 2016-04-05 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: Despite the advances in understanding the phenomena that occur on a catalyst surface, much of the successful catalyst development and use continues to be half science and half art. The art resides in the practical knowledge of experts in the development and use of commercial catalysts-it comes with experience. Now the background needed to nurture t

Download or read book Transition Metal Reagents and Catalysts written by Jiro Tsuji and published by John Wiley & Sons. This book was released on 2002-08-16 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)

Download or read book Greene s Protective Groups in Organic Synthesis written by Peter G. M. Wuts and published by John Wiley & Sons. This book was released on 2006-11-10 with total page 1112 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Fourth Edition of Greene's Protective Groups in Organic Synthesis continues to be an indispensable reference for controlling the reactivity of the most common functional groups during a synthetic sequence. This new edition incorporates the significant developments in the field since publication of the third edition in 1998, including... New protective groups such as the fluorous family and the uniquely removable 2-methoxybenzenesulfonyl group for the protection of amines New techniques for the formation and cleavage of existing protective groups, with examples to illustrate each new technique Expanded coverage of the unexpected side reactions that occur with protective groups New chart covering the selective deprotection of silyl ethers 3,100 new references from the professional literature The content is organized around the functional group to be protected, and ranges from the simplest to the most complex and highly specialized protective groups.

Download or read book Metal Nanoclusters in Catalysis and Materials Science The Issue of Size Control written by Benedetto Corain and published by Elsevier. This book was released on 2011-08-11 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control deals with the synthesis of metal nanoclusters along all known methodologies. Physical and chemical properties of metal nanoclusters relevant to their applications in chemical processing and materials science are covered thoroughly. Special attention is given to the role of metal nanoclusters size and shape in catalytic processes and catalytic applications relevant to industrial chemical processing.An excellent text for expanding the knowledge on the chemistry and physics of metal nanoclusters. Divided in two parts; Part I deals with general aspects of the matter and Part II has to be considered a useful handbook dealing with the production of metal nanoclusters, especially from their size-control point of view.* Divided into two parts for ease of reference: general and operational * Separation of synthetic aspects, physical properties and applications* Specific attention is given to the task of metal nanoclusters size-control

Download or read book Lignin and Lignans as Renewable Raw Materials written by Francisco G. Calvo-Flores and published by John Wiley & Sons. This book was released on 2015-09-28 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: As naturally occurring and abundant sources of non-fossil carbon, lignin and lignans offer exciting possibilities as a source of commercially valuable products, moving away from petrochemical-based feedstocks in favour of renewable raw materials. Lignin can be used directly in fields such as agriculture, livestock, soil rehabilitation, bioremediation and the polymer industry, or it can be chemically modified for the fabrication of specialty and high-value chemicals such as resins, adhesives, fuels and greases. Lignin and Lignans as Renewable Raw Materials presents a multidisciplinary overview of the state-of-the-art and future prospects of lignin and lignans. The book discusses the origin, structure, function and applications of both types of compounds, describing the main resources and values of these products as carbon raw materials. Topics covered include: • Structure and physicochemical properties • Lignin detection methods • Biosynthesis of lignin • Isolation methods • Characterization and modification of lignins • Applications of modified and unmodified lignins • Lignans: structure, chemical and biological properties • Future perspectives This book is a comprehensive resource for researchers, scientists and engineers in academia and industry working on new possibilities for the application of renewable raw materials. For more information on the Wiley Series in Renewable Resources, visit www.wiley.com/go/rrs

Download or read book Chemisorption and Reactivity on Supported Clusters and Thin Films written by R.M. Lambert and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysis provides the backbone of the world's chemical and oil industries. The innate complexity of practical catalytic systems suggests that useful progress should be achievable by investigating key aspects of catalysis by experimental studies on idealised model systems. Thin films and supported clusters are two promising types of model system that can be used for this purpose, since they mimic important aspects of the properties of practical dispersed catalysts. Similarly, appropriate theoretical studies of chemisorption and surface reaction clusters or extended slab systems can provide valuable information on the factors that underlie bonding and catalytic activity. This volume describes such experimental and theoretical approaches to the surface chemistry and catalytic behaviour of metals, metal oxides and metal/metal oxide systems. An introduction to the principles and main themes of heterogeneous catalysis is followed by detailed accounts of the application of modern experimental and theoretical techniques to fundamental problems. The application of advanced experimental methods is complemented by a full description of theoretical procedures, including Hartree-Fock, density functional and similar techniques. The relative merits of the various approaches are considered and directions for future progress are indicated.

Download or read book Catalysis of Organic Reactions written by Dale W. Blackburn and published by CRC Press. This book was released on 1989-11-27 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is a collection of the papers presented at the Twelfth Conference on the Catalysis of Organic Reactions, where all phases of catalysis, including heterogeneous catalytic hydrogenation, catalytic oxidation, homogeneous catalysis, carbonylation, and amination have been discussed.

Download or read book Nanocatalysis written by Vivek Polshettiwar and published by John Wiley & Sons. This book was released on 2013-09-30 with total page 755 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations. Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors’ first-hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book’s nineteen chapters offer a broad perspective, covering: Nanocatalysis for carbon-carbon and carbon-heteroatom coupling reactions Nanocatalysis for various organic transformations in fine chemical synthesis Nanocatalysis for oxidation, hydrogenation, and other related reactions Nanomaterial-based photocatalysis and biocatalysis Nanocatalysts to produce non-conventional energy such as hydrogen and biofuels Nanocatalysts and nano-biocatalysts in the chemical industry Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance. Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing the information and guidance needed for designing green, sustainable catalytic processes.

Download or read book Jatropha Challenges for a New Energy Crop written by Sujatha Mulpuri and published by Springer. This book was released on 2019-03-29 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: Jatropha curcas, or physic nut, is a small tree that, in tropical climates, produces fruits with seeds containing ~38% oil. The physic nut has the potential to be highly productive and is amenable to subculture in vitro and to genetic modification. It also displays remarkable diversity and is relatively easy to cross hybridize within the genus. Thanks to these promising features, J. curcas is emerging as a promising oil crop and is gaining commercial interest among the biofuel research communities. However, as a crop, physic nut has been an economic flop since 2012, because the species was not fully domesticated and the average productivity was less than 2 t/ha, which is below the threshold of profitability.^7 t/ha could be reached and it is contributing to new markets in some countries. As such, it is important fro research to focus on the physiology and selective breeding of Jatropha . This book provides a positive global update on Jatropha, a crop that has suffered despite its promising agronomic and economic potential. The editors have used their collective expertise in agronomy, botany, selective breeding, biotechnology, genomics and bioinformatics to seek out high-quality contributions that address the bottleneck features in order to improve the economic trajectory of physic nut breeding.

Download or read book Hydrocarbon Chemistry written by George A. Olah and published by John Wiley & Sons. This book was released on 2017-08-29 with total page 1198 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an unparalleled contemporary assessment of hydrocarbon chemistry – presenting basic concepts, current research, and future applications. • Comprehensive and updated review and discussion of the field of hydrocarbon chemistry • Includes literature coverage since the publication of the previous edition • Expands or adds coverage of: carboxylation, sustainable hydrocarbons, extraterrestrial hydrocarbons • Addresses a topic of special relevance in contemporary science, since hydrocarbons play a role as a possible replacement for coal, petroleum oil, and natural gas as well as their environmentally safe use • Reviews of prior edition: “...literature coverage is comprehensive and ideal for quickly reviewing specific topics...of most value to industrial chemists...” (Angewandte Chemie) and “...useful for chemical engineers as well as engineers in the chemical and petrochemical industries.” (Petroleum Science and Technology)

Download or read book Nanoporous Catalysts for Biomass Conversion written by Feng-Shou Xiao and published by John Wiley & Sons. This book was released on 2017-09-05 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive introduction to the design, synthesis, characterization, and catalytic properties of nanoporous catalysts for the biomass conversion With the specter of peak oil demand looming on the horizon, and mounting concerns over the environmental impact of greenhouse gas emissions, biomass has taken on a prominent role as a sustainable alternative fuel source. One critical aspect of the biomass challenge is the development of novel catalytic materials for effective and controllable biomass conversion. Edited by two scientists recognized internationally for their pioneering work in the field, this book focuses on nanoporous catalysts, the most promising class of catalytic materials for the conversion of biomass into fuel and other products. Although various catalysts have been used in the conversion of biomass-derived feedstocks, nanoporous catalysts exhibit high catalytic activities and/or unique product selectivities due to their large surface area, open nanopores, and highly dispersed active sites. This book covers an array of nanoporous catalysts currently in use for biomass conversion, including resins, metal oxides, carbons, mesoporous silicates, polydivinylbenzene, and zeolites. The authors summarize the design, synthesis, characterization and catalytic properties of these nanoporous catalysts for biomass conversions, discussing the features of these catalysts and considering future opportunities for developing more efficient catalysts. Topics covered include: Resins for biomass conversion Supported metal oxides/sulfides for biomass oxidation and hydrogenation Nanoporous metal oxides Ordered mesoporous silica-based catalysts Sulfonated carbon catalysts Porous polydivinylbenzene Aluminosilicate zeolites for bio-oil upgrading Rice straw Hydrogenation for sugar conversion Lignin depolymerization Timely, authoritative, and comprehensive, Nanoporous Catalysts for Biomass Conversion is a valuable working resource for academic researchers, industrial scientists and graduate students working in the fields of biomass conversion, catalysis, materials science, green and sustainable chemistry, and chemical/process engineering.

Download or read book Glycerine Production and Transformation written by Marco Frediani and published by BoD – Books on Demand. This book was released on 2019-09-11 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: The increase in the amount of glycerin in the market is a burden for all producers, especially those operating in the biodiesel sector: reuse options are in fact limited for the management of this by-product. Glycerol enhancement has therefore become a priority to improve the sustainability of the biodiesel industry. Nevertheless, the multifunctionality of glycerol makes it a promising precursor for different types of production (fuel/biofuel, chemical products). This conversion has therefore become a subject of multifaceted research that requires an exchange of knowledge across many sectors. In this book, different disciplines (chemistry, biology, engineering, etc.) have been taken into consideration to propose an interdisciplinary point of view on different aspects.

Download or read book Process Chemistry in the Pharmaceutical Industry Volume 2 written by Kumar Gadamasetti and published by CRC Press. This book was released on 2007-12-10 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: As pharmaceutical companies strive to develop safer medicines at a lower cost, they must keep pace with the rapid growth of technology and research methodologies. Defying the misconception of process chemistry as mere scale-up work, Process Chemistry in the Pharmaceutical Industry, Vol. 2: Challenges in an Ever Changing Climate explor