Download or read book Hybrid Metal Organic Framework and Covalent Organic Framework Polymers written by Bo Wang and published by Royal Society of Chemistry. This book was released on 2021-11-12 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal–organic frameworks (MOFs) are crystalline porous materials constructed from metal ions/clusters and organic linkers, combining the merits of both organic and inorganic components. Due to high porosity, rich functionalities, well-defined open channels and diverse structures, MOFs show great potentials in field such as gas storage and separation, catalysis, and sensing. Combining them with polymers tunes their chemical, mechanical, electrical and optical properties, and endows MOFs with processability. Covalent organic frameworks (COFs) are crystalline porous materials built from organic molecular units with diverse structures and applications. Hybrid materials with intriguing properties can be achieved by appropriate preparation methods and careful selection of MOFs/COFs and polymers, broadening their potential applications. This book documents the latest research progress in MOF/COF-polymer hybrid materials and reviews and summarises hybridization strategies to achieve MOF/COF polymeric composites. It also introduces various applications and potential applicable scenarios of hybrid MOF/COF polymers. Hybrid Metal–Organic Framework and Covalent Organic Framework Polymers offers an overview to readers who are new to this field, and will appeal to graduate students and researchers working on porous materials, polymers, hybrid materials, and supramolecular chemistry.
Download or read book Hybrid Metal Organic Framework and Covalent Organic Framework Polymers written by Bo Wang and published by Royal Society of Chemistry. This book was released on 2021-11-26 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book documents the latest research progress in MOF/COF-polymer hybrid materials and reviews and summarises hybridization strategies to achieve MOF/COF polymeric composites.
Download or read book Coordination Polymers and Metal Organic Frameworks written by Oscar L. Ortiz and published by . This book was released on 2011-10 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, the authors present topical research in the study of coordination polymers and metal organic frameworks. Topics discussed include hybrid vanadates and metal organic frameworks; structure and magnetic properties of mono- and poly-nuclear complexes containing Re(IV)l; metal organic framework applications in the fields of hydrogen storage and catalysis; MOF-Based mixed-matrix-membranes for industrial applications; coordination polymers in heterogeneous catalysis; high pressure gas storage on porous solids; metal organic frameworks for CO2 capture and halogen bonding in the assembly of high-dimensional supramolecular coordination polymers.
Download or read book Metal Organic Framework Polymer Hybrid Materials for Chemical Warfare Agent Degradation written by Mark Kalaj and published by . This book was released on 2021 with total page 275 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since first discovered some two decades ago, metal-organic frameworks (MOFs) have shown interesting properties with regard to storage, separation, and catalysis applications. While MOFs have shown promise in these arenas over the years, a major shortcoming of these materials is their inherently crystalline form factor which hinders their applicational. To circumvent this issue, we have turned to the hybridization of MOFs with polymers in an effort to form a material that has the desired properties of the MOF and the flexibility of the polymer. In particular, we seek to develop novel textile based (nylon based or spray coated) MOF-polymer hybrid materials that are catalytically active against harmful organophosphorus chemical warfare agents (CWAs). Chapter 2 describes the synthesis of a MOF-nylon hybrid material through and interfacial postsynthetic polymerization (PSP) method. The hybrid material contains 29 weight percent MOF and shows catalytic activity against a CWA simulant. Importantly, the covalent MOF-nylon material displays about a seven-fold increase in activity compared to physically mixed controls. In Chapter 3, we screened a wide range of MOFs with varying organic functional groups to establish structure activity relationships (SAR) between MOF functional groups and CWA simulant degradation. The Zr-based MOF UiO-66 (UiO = University of Oslo) was synthesized with either mixed ligand functional groups or halogenated functional groups. We determined that the mixed ligand approach improves CWA activity by three-fold whereas the UiO-66-Iodine MOF displays a fourfold increase in activity. Through theoretical calculations, the increased activity in UiO-66-I was determined to be an artifact of halogen bonding with the CWA simulant. In Chapter 4, we combined the approaches from Chapter 2 and 3, by using the commonly known pseudohalogen isothiocyanate (NCS) functional group in UiO-66 to improve the catalytic activity against CWAs and covalent PSP sites. The UiO-66-NCS MOF was synthesized via postsynthetic modification (PSM) and displayed a ~20 fold increase in activity compared to the presynthetic MOF. More importantly, using amine terminated polypropylene oxides, MOF-polymer material was formed, and spray coated onto textile fibers. This material showed great durability and catalytic activity compared to physically mixed controls. Chapter 5 describes the room temperature synthesis of the commonly used UiO-66 MOF as well as a few functional groups derivatives. Starting from a UiO-66-F4 MOF with relatively labile ligands, postsynthetic exchange (PSE) with four different MOF ligands at room temperature in aqueous conditions was performed with almost complete ligand exchange. These MOFs were thoroughly characterized after PSE and maintained desired properties such as crystallinity and particle size or shape.
Download or read book Metal Organic Frameworks for Biomedical Applications written by Masoud Mozafari and published by Woodhead Publishing. This book was released on 2020-03-17 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks for Biomedical Applications is a comprehensive, authoritative reference that offers a substantial and complete treatment of published results that have yet to be critically reviewed. It offers a summary of current research and provides in-depth understanding of the role of metal-organic frameworks in biomedical engineering. The title consists of twenty-two chapters presented by leading international researchers in the field. Chapters are arranged by target-application in biomedical engineering, allowing medical and pharmaceutic specialists to translate current materials and engineering science on metal-organic frameworks into their work. Presents the state-of-the art in metal-organic frameworks for biomedical applications Offers comprehensive treatment of metal-organic frameworks that is useful to pharmaceutic and medical experts who are non-specialists in materials science Helps materials scientists and engineers understand the needs of biomedical engineering Critically-reviews published results and current research in the field
Download or read book Metal Organic Frameworks written by Bhawana Jain and published by Elsevier. This book was released on 2024-04-26 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Organic Frameworks: Fundamentals to Advanced offers a substantial and complete treatment of published results. The book includes a summary of current research, along with an in- depth explanation of Metal organic frameworks (MOFs) and applications in this versatile area. Metal organic frameworks (MOFs) are structured frameworks made up of metal ions and organic molecules. These materials are similar to sponges and can absorb, retain and remove molecules from their pores. As a result, metal-organic frameworks (MOFs) are the most rapidly evolving substances in chemistry with the highest surface areas due to their well-ordered pore structure.The exciting and vast surface area allows for more chemical reactions and molecule adsorption, hence this new resource provides the newest updates on the topics covered. - Covers the synthetic advantages and versatile applications of metal-organic frameworks (MOFs) due to their organic-inorganic hybrid nature and unique porous structure - Includes energy applications such as batteries, fuel storage, fuel cells, hydrogen evaluation reactions and super capacitors - Features information on using MOFs as a replacement to conventional engineering materials as they are lightweight, less costly, environmentally-friendly and sustainable
Download or read book Bio and Bioinspired Nanomaterials written by Daniel Ruiz-Molina and published by John Wiley & Sons. This book was released on 2014-12-03 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of nanomaterials that are inspired by or targeted at biology, including some of the latest breakthrough research. Throughout, valuable contributions from top-level scientists illustrate how bionanomaterials could lead to novel devices or structures with unique properties. The first and second part cover the most relevant synthetic and bioinspired nanomaterials, including surfaces with extreme wettability properties, functional materials with improved adhesion or structural and functional systems based on the complex and hierarchical organization of natural composites. These lessons from nature are explored in the last section where bioinspired materials are proposed for biomedical applications, showing their potential for future applications in drug delivery, theragnosis, and regenerative medicine. A navigational guide aimed at advanced and specialist readers, while equally relevant for readers in research, academia or private companies focused on high added-value contributions. Young researchers will also find this an indispensable guide in choosing or continuing to work in this stimulating area, which involves a wide range of disciplines, including chemistry, physics, materials science and engineering, biology, and medicine.
Download or read book Covalent Materials and Hybrids written by Bishnu P. Biswal and published by Royal Society of Chemistry. This book was released on 2023-08-11 with total page 507 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Applications of Porous Coordination Polymers and Metal Organic Frameworks MOFs written by Hemanta Kalita and published by GRIN Verlag. This book was released on 2022-08-09 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: Document from the year 2022 in the subject Chemistry - Macromolecular Chemistry, Polymer Chemistry, grade: 17, Gauhati University, language: English, abstract: Porous coordination polymers, also known as metal organic frameworks are a new type of hybrid material constructed via self-assembly of metal ions/metal clusters which function as nodes and organic ligands which act as bridges or linkers. They are one of the earliest developed classes of metal containing polymers. They extend infinitely one, two or three dimensional framework through coordination bonding, hydrogen bonding, π–π stacking, C-H-π interactions as well as van der Waal forces. These weaker non-covalent interactions, are important for the packing of the one dimensional chains, two-dimensional nets and three-dimensional frameworks. In view of the tunable structures and promising properties shown by these systems various complexities have been prepared and thoroughly investigated over last decade. MOFs are currently flourishing fields of research owing to their intriguing structural motifs and various potential applications, in the field of gas storage, gas separation, catalysis, ion exchange, microelectronics, non linear optics, sensors, medicine and molecular magnetism etc. They possess structural regularity, high porosity, high surface area resulting in greater potential applications than conventional zeolites or activated carbons and mesoporous silica. For the construction of porous coordination polymers with diverse structures and properties selection of the special inorganic and organic building blocks is one of the important factors. Multicarboxylate organic ligands have proved to be an excellent choice for the construction of MOFs of higher nuclearity due to their different coordination modes with the metals, molecular flexibilities and structural stabilities. Metal carboxylate linker in combination with cross linked or pillered polypyridine have generated many interesting coordination architecture. Making use of transition metal carboxylate and linear bridging auxiliary ligands it is possible to construct 1-D, 2-D and 3-D porous coordination polymer of different pore structures and porosities. Aside from coordination bonding interactions, various non-covalent bonding or some weak intra- or intermolecular interactions, such as hydrogen-bonding, π–π stacking and C–H–π interactions or van der Waals interactions also influence the formation of final architectures.
Download or read book Metal Organic Framework Materials written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2014-09-19 with total page 1210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc
Download or read book Functional Metal Organic Frameworks Gas Storage Separation and Catalysis written by Martin Schröder and published by Springer. This book was released on 2010-09-15 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: - Microporous Organic Polymers: Design, Synthesis, and Function By J.-X. Jiang and A. I. Cooper - Hydrogen, Methane and Carbon Dioxide Adsorption in Metal-Organic Framework Materials By X. Lin, N. R. Champness, and M. Schröder -Doping of Metal-Organic Frameworks with Functional Guest Molecules and Nanoparticles By F. Schröder and R. A. Fischer -Chiral Metal-Organic Porous Materials: Synthetic Strategies and Applications in Chiral Separation and Catalysis By K. Kim, M. Banerjee, M. Yoon, and S. Das -Controlled Polymerization by Incarceration of Monomers in Nanochannels By T. Uemura and S. Kitagawa -Designing Metal-Organic Frameworks for Catalytic Applications L. Ma and W. Lin -Magnetic and Porous Molecule-Based Materials By N. Roques, V. Mugnaini, and J. Veciana
Download or read book Metal Organic Frameworks written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2010-12-17 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Download or read book Hybrid Organic Inorganic Interfaces written by Marie Helene Delville and published by John Wiley & Sons. This book was released on 2018-04-09 with total page 1010 pages. Available in PDF, EPUB and Kindle. Book excerpt: Das erste Handbuch und gut zugängliche Referenzwerk zu diesem zunehmend wichtigen Thema erläutert in einem anwendungsorientierten Ansatz Synthese, Design, Charakterisierung und Simulation von Grenzflächen bei hybriden organisch-anorganischen Materialien.
Download or read book Lanthanide Metal Organic Frameworks written by Peng Cheng and published by Springer. This book was released on 2015-01-19 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students.
Download or read book Metal Organic Framework Composites written by Anish Khan and published by Materials Research Forum LLC. This book was released on 2019-10-25 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: Because of their nanoporous structures and ultra-high surface areas Metal-Organic Framework Composites (MOFs) are very interesting materials. The book focusses on the following applications: gas capture and storage, especially molecular hydrogen storage; performance enhancement of Li-ion batteries; gas separation, nano-filtration, ionic sieving, water treatment, and catalysis; sustainable renewable energy resources, electrochemical capacitors, including supercapacitors, asymmetric supercapacitors and hybrid supercapacitors; biomedical disciplines including drug delivery, theranostics; biological detection and imaging; nanoparticle photosensitizers for photodynamic therapy (PDT) and photothermal therapy (PTT). Keywords: MOF Materials, Hydrogen Storage, Renewable Energy Applications, Lithium Batteries, MOF-Quantum Dots, Clean Energy, Nanoporous MOFs, Supercapacitors, Therapeutic Applications, Biosensing, Bioimaging, Phototherapy of Cancer, Gas Separation, Nano-filtration, Ionic Sieving, Water Treatment, Drug Delivery, Theranostics; Nanoparticle Photosensitizers, Photodynamic Therapy (PDT), Photothermal Therapy (PTT).
Download or read book Elaboration And Applications Of Metal organic Frameworks written by Shengqian Ma and published by World Scientific. This book was released on 2018-01-31 with total page 730 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title takes researchers in as well as out of the field of metal-organic framework (MOF) and then guides them on a journey to rediscover and rethink how these designer coordination polymers will influence the realm of materials science. This book opens with a look at a deeply controversial issue, MOF stability, which has plagued many systems, but ultimately has led to better materials that proved to be more robust allowing them to be investigated for multiple applications. This book successfully highlights many of these useful applications that MOFs are well adapted for. Because MOF components, inorganic and organic, can combine the best of both chemical domains, MOFs will improve our environment by removing harmful contaminants from the air and water, reduce the energy required to perform chemical reactions, partition hard to separate molecular mixtures, and form the next-generation of magnetic and electronic materials. MOFs will eventually be used for everyday activities — for monitoring or reacting to changing conditions. Readers of this book can then take note and implement MOFs in their line of research.
Download or read book Introduction to Reticular Chemistry written by Omar M. Yaghi and published by John Wiley & Sons. This book was released on 2019-03-22 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.
