Download or read book High temperature Corrosion Study of Alloys in Molten MgCl2 KCl Eutectic Salt written by Yuxiang Peng and published by . This book was released on 2019 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: The MgCl2-KCl molten salt has been proposed as one of the heat transfer fluids (HTFs) in the solar energy system because of its potential thermal properties. This research investigates the corrosion behavior and protection strategies of Haynes 230 (H230), Incoloy 800H (800H), and Stainless Steel 316 (SS316) in MgCl2-KCl molten salt at high temperature. First of all, the corrosion rates of different alloys are determined by performing the long-term static corrosion experiments. The morphologies of the surface and corrosion depths are examined by scanning electron microscopy (SEM) equipped with an energy dispersive X-ray spectrometer (EDS). Secondly, the effect of Ni on the corrosion behavior of the alloys is studied in this research. When the alloy is connected with Ni, the corrosion rate is higher than that without connection in the same condition. Thirdly, the electrochemical tests of three alloys are also investigated in present research work. Tafel curves are plotted to calculate the corrosion potentials and corrosion rates of three alloys at different temperatures. Fourthly, two methods are proposed and studied to protect the alloys from severe corrosion in the MgCl2-KCl molten salt: 1) adding a sacrificial anode into the salt, and 2) coating a high-corrosion-resistance alloy. Mn, Zn, and Zr are chosen as the sacrificial anode materials to protect the alloys from further corrosion. The result showed that additions of inhibitor into the molten salts decrease the corrosion rates of the tested alloy. Pure Ni, Al2O3, Ni-Al alloy, and Cr-Fe-Al alloy are chosen to coat the tested alloy. Long-term corrosion experiments, as well as electrochemical tests of alloys with and without different coatings, are studied in present work. The results demonstrated that all these coatings decreased the corrosion rates of the tested alloys. Finally, the diffusion models are constructed to predict the distribution of the Cr in the different alloys after corrosion. And the results are comparable to the experimental data. In conclusion, H230 showed the highest corrosion resistance in the MgCl2-KCl salt proved by long-term corrosion test and electrochemical tests. Different inhibitors and coatings all improved the corrosion resistance of alloys in the molten salt.

Download or read book Liquid Salts as Media for Process Heat Transfer from VHTR s written by and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The goal of this NERI project was to perform research on high temperature fluoride and chloride molten salts towards the long-term goal of using these salts for transferring process heat from high temperature nuclear reactor to operation of hydrogen production and chemical plants. Specifically, the research focuses on corrosion of materials in molten salts, which continues to be one of the most significant challenges in molten salts systems. Based on the earlier work performed at ORNL on salt properties for heat transfer applications, a eutectic fluoride salt FLiNaK (46.5% LiF-11.5%NaF-42.0%KF, mol.%) and a eutectic chloride salt (32%MgCl2-68%KCl, mole %) were selected for this study. Several high temperature candidate Fe-Ni-Cr and Ni-Cr alloys: Hastelloy-N, Hastelloy-X, Haynes-230, Inconel-617, and Incoloy-800H, were exposed to molten FLiNaK with the goal of understanding corrosion mechanisms and ranking these alloys for their suitability for molten fluoride salt heat exchanger and thermal storage applications. The tests were performed at 850C for 500 h in sealed graphite crucibles under an argon cover gas. Corrosion was noted to occur predominantly from dealloying of Cr from the alloys, an effect that was particularly pronounced at the grain boundaries Alloy weight-loss due to molten fluoride salt exposure correlated with the initial Cr-content of the alloys, and was consistent with the Cr-content measured in the salts after corrosion tests. The alloys weight-loss was also found to correlate to the concentration of carbon present for the nominally 20% Cr containing alloys, due to the formation of chromium carbide phases at the grain boundaries. Experiments involving molten salt exposures of Incoloy-800H in Incoloy-800H crucibles under an argon cover gas showed a significantly lower corrosion for this alloy than when tested in a graphite crucible. Graphite significantly accelerated alloy corrosion due to the reduction of Cr from solution by graphite and formation on Cr-carbide on the graphite surface. Ni-electroplating dramatically reduced corrosion of alloys, although some diffusion of Fe and Cr were observed occur through the Ni plating. A pyrolytic carbon and SiC (PyC/SiC) CVD coating was also investigated and found to be effective in mitigating corrosion. The KCl-MgCl2 molten salt was less corrosive than FLiNaK fluoride salts for corrosion tests performed at 850oC. Cr dissolution in the molten chloride salt was still observed and consequently Ni-201 and Hastelloy N exhibited the least depth of attack. Grain-boundary engineering (GBE) of Incoloy 800H improved the corrosion resistance (as measured by weight loss and maximum depth of attack) by nearly 50% as compared to the as-received Incoloy 800H sample. Because Cr dissolution is an important mechanism of corrosion, molten salt electrochemistry experiments were initiated. These experiments were performed using anodic stripping voltammetry (ASV). Using this technique, the reduction potential of Cr was determined against a Pt quasi-reference electrode as well as against a Ni(II)-Ni reference electrode in molten FLiNaK at 650 oC. The integrated current increased linearly with Cr-content in the salt, providing for a direct assessment of the Cr concentration in a given salt of unknown Cr concentration. To study heat transfer mechanisms in these molten salts over the forced and mixed convection regimes, a forced convective loop was constructed to measure heat transfer coefficients, friction factors and corrosion rates in different diameter tubes in a vertical up flow configuration in the laminar flow regime. Equipment and instrumentation for the forced convective loop was designed, constructed, and tested. These include a high temperature centrifugal pump, mass flow meter, and differential pressure sensing capabilities to an uncertainty of

Download or read book Molten Salts Chemistry written by Frederic Lantelme and published by Newnes. This book was released on 2013-08-14 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molten salts and fused media provide the key properties and the theory of molten salts, as well as aspects of fused salts chemistry, helping you generate new ideas and applications for fused salts.Molten Salts Chemistry: From Lab to Applications examines how the electrical and thermal properties of molten salts, and generally low vapour pressure are well adapted to high temperature chemistry, enabling fast reaction rates. It also explains how their ability to dissolve many inorganic compounds such as oxides, nitrides, carbides and other salts make molten salts ideal as solvents in electrometallurgy, metal coating, treatment of by-products and energy conversion.This book also reviews newer applications of molten salts including materials for energy storage such as carbon nano-particles for efficient super capacitors, high capacity molten salt batteries and for heat transport and storage in solar plants. In addition, owing to their high thermal stability, they are considered as ideal candidates for the development of safer nuclear reactors and for the treatment of nuclear waste, especially to separate actinides from lanthanides by electrorefining. Explains the theory and properties of molten salts to help scientists understand these unique liquids Provides an ideal introduction to this expanding field Illustrated text with key real-life applications of molten salts in synthesis, energy, nuclear, and metal extraction

Download or read book Molten Salt Technology written by David G. Lovering and published by Springer. This book was released on 2014-11-14 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Nuclear Corrosion Science and Engineering written by Damien Feron and published by Elsevier. This book was released on 2012-02-21 with total page 1073 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion of nuclear materials, i.e. the interaction between these materials and their environments, is a major issue for plant safety as well as for operation and economic competitiveness. Understanding these corrosion mechanisms, the systems and materials they affect, and the methods to accurately measure their incidence is of critical importance to the nuclear industry. Combining assessment techniques and analytical models into this understanding allows operators to predict the service life of corrosion-affected nuclear plant materials, and to apply the most appropriate maintenance and mitigation options to ensure safe long term operation. This book critically reviews the fundamental corrosion mechanisms that affect nuclear power plants and facilities. Initial sections introduce the complex field of nuclear corrosion science, with detailed chapters on the different types of both aqueous and non aqueous corrosion mechanisms and the nuclear materials susceptible to attack from them. This is complemented by reviews of monitoring and control methodologies, as well as modelling and lifetime prediction approaches. Given that corrosion is an applied science, the final sections review corrosion issues across the range of current and next-generation nuclear reactors, and across such nuclear applications as fuel reprocessing facilities, radioactive waste storage and geological disposal systems. With its distinguished editor and international team of expert contributors, Nuclear corrosion science and engineering is an invaluable reference for nuclear metallurgists, materials scientists and engineers, as well as nuclear facility operators, regulators and consultants, and researchers and academics in this field. Comprehensively reviews the fundamental corrosion mechanisms that affect nuclear power plants and facilities Chapters assess different types of both aqueous and non aqueous corrosion mechanisms and the nuclear materials susceptible to attack from them Considers monitoring and control methodologies, as well as modelling and lifetime prediction approaches

Download or read book Nanoscale Materials and Devices for Electronics Photonics and Solar Energy written by Anatoli Korkin and published by Springer. This book was released on 2015-08-26 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents research dedicated to solving scientific and technological problems in many areas of electronics, photonics and renewable energy. Progress in information and renewable energy technologies requires miniaturization of devices and reduction of costs, energy and material consumption. The latest generation of electronic devices is now approaching nanometer scale dimensions; new materials are being introduced into electronics manufacturing at an unprecedented rate; and alternative technologies to mainstream CMOS are evolving. The low cost of natural energy sources have created economic barriers to the development of alternative and more efficient solar energy systems, fuel cells and batteries. Nanotechnology is widely accepted as a source of potential solutions in securing future progress for information and energy technologies. Nanoscale Materials and Devices for Electronics, Photonics and Solar Energy features chapters that cover the following areas: atomic scale materials design, bio- and molecular electronics, high frequency electronics, fabrication of nanodevices, magnetic materials and spintronics, materials and processes for integrated and subwave optoelectronics, nanoCMOS, new materials for FETs and other devices, nanoelectronics system architecture, nano optics and lasers, non-silicon materials and devices, chemical and biosensors,quantum effects in devices, nano science and technology applications in the development of novel solar energy devices, and fuel cells and batteries.

Download or read book TMS 2020 149th Annual Meeting Exhibition Supplemental Proceedings written by The Minerals, Metals & Materials Society and published by Springer Nature. This book was released on 2020-02-13 with total page 2046 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection presents papers from the 149th Annual Meeting & Exhibition of The Minerals, Metals & Materials Society.

Download or read book Applications of Process Engineering Principles in Materials Processing Energy and Environmental Technologies written by Shijie Wang and published by Springer. This book was released on 2017-02-07 with total page 549 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection offers new research findings, innovations, and industrial technological developments in extractive metallurgy, energy and environment, and materials processing. Technical topics included in the book are thermodynamics and kinetics of metallurgical reactions, electrochemical processing of materials, plasma processing of materials, composite materials, ionic liquids, thermal energy storage, energy efficient and environmental cleaner technologies and process modeling. These topics are of interest not only to traditional base ferrous and non-ferrous metal industrial processes but also to new and upcoming technologies, and they play important roles in industrial growth and economy worldwide.

Download or read book Differential Scanning Calorimetry written by G.W.H. Höhne and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 233 pages. Available in PDF, EPUB and Kindle. Book excerpt: Differential Scanning Calorimetry (DSC) is a well established measuring method which is used on a large scale in different areas of research, development, and quality inspection and testing. Over a large temperature range, thermal effects can be quickly identified and the relevant temperature and the characteristic caloric values determined using substance quantities in the mg range. Measurement values obtained by DSC allow heat capacity, heat of transition, kinetic data, purity and glass transition to be determined. DSC curves serve to identify substances, to set up phase diagrams and to determine degrees of crystallinity. This book provides, for the first time, an overall description of the most impor tant applications of Differential Scanning Calorimetry. Prerequisites for reliable measurement results, optimum evaluation of the measurement curves and esti mation of the uncertainties of measurement are, however, the knowledge of the theoretical bases of DSC, a precise calibration of the calorimeter and the correct analysis of the measurement curve. The largest part of this book deals with these basic aspects: The theory of DSC is discussed for both heat flux and power compensated instruments; temperature calibration and caloric calibration are described on the basis of thermodynamic principles. Desmearing of the measurement curve in different ways is presented as a method for evaluating the curves of fast transitions.

Download or read book Molten Salts Chemistry and Technology written by Marcelle Gaune-Escard and published by John Wiley & Sons. This book was released on 2014-05-12 with total page 902 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written to record and report on recent research progresses in the field of molten salts, Molten Salts Chemistry and Technology focuses on molten salts and ionic liquids for sustainable supply and application of materials. Including coverage of molten salt reactors, electrodeposition, aluminium electrolysis, electrochemistry, and electrowinning, the text provides researchers and postgraduate students with applications include energy conversion (solar cells and fuel cells), heat storage, green solvents, metallurgy, nuclear industry, pharmaceutics and biotechnology.

Download or read book Recent Advances in Solar driven Thermochemical Fuel Production and Thermal Energy Storage written by Alfonso J. Carrillo and published by Frontiers Media SA. This book was released on 2022-04-28 with total page 121 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Corrosion of Titanium written by J. D. Jackson and published by . This book was released on 1966 with total page 54 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book TMS 2019 148th Annual Meeting Exhibition Supplemental Proceedings written by The Minerals, Metals & Materials Series and published by Springer. This book was released on 2019-02-27 with total page 1731 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection features papers presented at the 147th Annual Meeting & Exhibition of The Minerals, Metals & Materials Society.

Download or read book Principles of Corrosion Engineering and Corrosion Control written by Zaki Ahmad and published by Elsevier. This book was released on 2006-09-18 with total page 673 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion is a huge issue for materials, mechanical, civil and petrochemical engineers. With comprehensive coverage of the principles of corrosion engineering, this book is a one-stop text and reference for students and practicing corrosion engineers. Highly illustrated, with worked examples and definitions, it covers basic corrosion principles, and more advanced information for postgraduate students and professionals. Basic principles of electrochemistry and chemical thermodynamics are incorporated to make the book accessible for students and engineers who do not have prior knowledge of this area. Each form of corrosion covered in the book has a definition, description, mechanism, examples and preventative methods. Case histories of failure are cited for each form. End of chapter questions are accompanied by an online solutions manual. * Comprehensively covers the principles of corrosion engineering, methods of corrosion protection and corrosion processes and control in selected engineering environments* Structured for corrosion science and engineering classes at senior undergraduate and graduate level, and is an ideal reference that readers will want to use in their professional work* Worked examples, extensive end of chapter exercises and accompanying online solutions and written by an expert from a key pretochemical university

Download or read book High Temperature Corrosion and Materials Applications written by George Y. Lai and published by ASM International. This book was released on 2007-01-01 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: George Lai's 1990 book, High-Temperature Corrosion of Engineering Alloys, is recognized as authoritative and is frequently consulted and often cited by those in the industry. His new book, almost double in size with seven more chapters, addresses the new concerns, new technologies, and new materials available for those engaged in high-temperature applications. As we strive for energy efficiency, the realm of high-temperature environments is expanding and the need for information on high temperature materials applications was never greater. In addition to extensive expansion on most of the content of the original book, new topics include erosion and erosion-corrosion, low NOx combustion in coal-fired boilers, fluidized bed combustion, and the special demands of waste-to-energy boilers, waste incinerators, and black liquor recovery boilers in the pulp and paper industry. The corrosion induced by liquid metals is discussed and protection options are presented.

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1973 with total page 2006 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Applied Metallurgy and Corrosion Control written by Amiya Kumar Lahiri and published by Springer. This book was released on 2017-08-23 with total page 558 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book serves as a comprehensive resource on metals and materials selection for the petrochemical industrial sector. The petrochemical industry involves large scale investments, and to maintain profitability the plants are to be operated with minimum downtime and failure of equipment, which can also cause safety hazards. To achieve this objective proper selection of materials, corrosion control, and good engineering practices must be followed in both the design and the operation of plants. Engineers and professional of different disciplines involved in these activities are required to have some basic understanding of metallurgy and corrosion. This book is written with the objective of servings as a one-stop shop for these engineering professionals. The book first covers different metallic materials and their properties, metal forming processes, welding, and corrosion and corrosion control measures. This is followed by considerations in material selection and corrosion control in three major industrial sectors, oil & gas production, oil refinery, and fertilizers. The importance of pressure vessel codes as well as inspection and maintenance repair practices have also been highlighted. The book will be useful for technicians and entry level engineers in these industrial sectors. Additionally, the book may also be used as primary or secondary reading for graduate and professional coursework.