Download or read book Heat of Vaporization and Species Evolution During Gasoline Evaporation Measured by DSC TGA MS for Blends of C1 to C4 Alcohols in Commercial Gasoline Blendstock written by Gina M. Fioroni and published by . This book was released on 2019 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Heat of Vaporization and Species Evolution During Gasoline Evaporation Measured by DSC TGA MS for Blends of C1 to C4 Alcohols in Commercial Gasoline Blendstocks written by and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Evaporative cooling of the fuel-air charge by fuel evaporation is an important feature of direct-injection spark-ignition engines that improves fuel knock resistance and reduces pumping losses at intermediate load but, in some cases, may increase fine particle emissions. We have reported on experimental approaches for measuring both total heat of vaporization and examination of the evaporative heat effect as a function of fraction evaporated for gasolines and ethanol blends. In this paper we extend this work to include other low-molecular-weight alcohols and additionally present results on species evolution during fuel evaporation by coupling of a mass spectrometer to our differential scanning calorimetry/thermogravimetric analysis instrument (DSC/TGA/MS). The alcohols examined were methanol, ethanol, 1-propanol (n-propanol), isopropanol, 2-butanol, and isobutanol at 10, 20, and 30 vol%. The results show that total HOV of the alcohol gasoline blends is in line with the decreasing HOV in kJ/kg with increasing alcohol carbon number, as expected. MS results show that methanol fully evaporates at significantly lower fraction evaporated relative to other alcohols even though it is present at higher molar concentration. Certain alcohols, especially methanol and ethanol can suppress the evaporation of aromatic compounds such as cumene during the evaporation process in some samples. While the use of mass spectrometry to analyze the composition of the evolving gas mixture provided useful results for a relatively simple research gasoline (FACE B), additional research is required to practically apply this methodology to more complex commercial gasolines.
Download or read book Heat of Vaporization by Measurement Using DSC TGA versus Estimation Using Detailed Hydrocarbon Analysis Preprint written by and published by . This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: One important property in assessing the knock resistance of ethanol-gasoline blends is heat of vaporization (HOV). Both estimation and direct measurement of the HOV have been problematic due to several factors. In this work, two different approaches were taken toward determination of the HOV. One was direct measurement by DSC/TGA. The other was by estimating the HOV by DHA.
Download or read book Heat of Vaporization Measurements for Ethanol Blends Up To 50 Volume Percent in Several Hydrocarbon Blendstocks and Implications for Knock in SI Engines written by and published by . This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of this work was to measure knock resistance metrics for ethanol-hydrocarbon blends with a primary focus on development of methods to measure the heat of vaporization (HOV). Blends of ethanol at 10 to 50 volume percent were prepared with three gasoline blendstocks and a natural gasoline. Performance properties and composition of the blendstocks and blends were measured.
Download or read book Differential Scanning Calorimetry written by G.W.H. Höhne and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 233 pages. Available in PDF, EPUB and Kindle. Book excerpt: Differential Scanning Calorimetry (DSC) is a well established measuring method which is used on a large scale in different areas of research, development, and quality inspection and testing. Over a large temperature range, thermal effects can be quickly identified and the relevant temperature and the characteristic caloric values determined using substance quantities in the mg range. Measurement values obtained by DSC allow heat capacity, heat of transition, kinetic data, purity and glass transition to be determined. DSC curves serve to identify substances, to set up phase diagrams and to determine degrees of crystallinity. This book provides, for the first time, an overall description of the most impor tant applications of Differential Scanning Calorimetry. Prerequisites for reliable measurement results, optimum evaluation of the measurement curves and esti mation of the uncertainties of measurement are, however, the knowledge of the theoretical bases of DSC, a precise calibration of the calorimeter and the correct analysis of the measurement curve. The largest part of this book deals with these basic aspects: The theory of DSC is discussed for both heat flux and power compensated instruments; temperature calibration and caloric calibration are described on the basis of thermodynamic principles. Desmearing of the measurement curve in different ways is presented as a method for evaluating the curves of fast transitions.
Download or read book Fuels and Lubricants Handbook written by and published by . This book was released on 2003 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Elastomers Second Edition written by Anil K. Bhowmick and published by CRC Press. This book was released on 2000-11-02 with total page 954 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Provides the latest authoritative research on the developments, technology, and applications of rubbery materials. Presents structures, manufacturing techniques, and processing details for natural and synthetic rubbers, rubber-blends, rubber composites, and thermoplastic elastomers. 80% revised and rewritten material covers major advances since publication of the previous edition."
Download or read book Natural Gas Conversion written by A. Holmen and published by Elsevier. This book was released on 1991-05-27 with total page 585 pages. Available in PDF, EPUB and Kindle. Book excerpt: These proceedings reflect the extensive fundamental and applied research efforts that are currently being made on the conversion of gas, in particular on the direct conversion of methane. The Symposium in Oslo focused on the following topics: Direct conversion of methane, Fischer-Tropsch chemistry, methanol conversion and natural gas conversion processes. The main aim was to present the state-of-the-art and progress currently being made within each of these areas. The book contains the papers presented and includes plenary lectures, short communications and posters. The papers will be of interest to scientists and engineers working in the field of gas conversion, transportation fuels, primary petrochemicals and catalysis.
Download or read book Advanced Direct Injection Combustion Engine Technologies and Development written by H Zhao and published by Elsevier. This book was released on 2014-01-23 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct injection enables precise control of the fuel/air mixture so that engines can be tuned for improved power and fuel economy, but ongoing research challenges remain in improving the technology for commercial applications. As fuel prices escalate DI engines are expected to gain in popularity for automotive applications. This important book, in two volumes, reviews the science and technology of different types of DI combustion engines and their fuels. Volume 1 deals with direct injection gasoline and CNG engines, including history and essential principles, approaches to improved fuel economy, design, optimisation, optical techniques and their applications. Reviews key technologies for enhancing direct injection (DI) gasoline engines Examines approaches to improved fuel economy and lower emissions Discusses DI compressed natural gas (CNG) engines and biofuels
Download or read book Recent Progress in Bioconversion of Lignocellulosics written by George T. Tsao and published by Springer Science & Business Media. This book was released on 1999-09-02 with total page 297 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume reports the latest advances in the science and technology related to the conversion of lignocellulosics. A portion of the volume is devoted to molecular biology of the enzymes and the microbes involved in the conversion. Hydrolysis of cellulose continues to be of prime importance in the overall conversion scheme. Reaction kinetics and mechanisms of cellulases as well as the state-of-the-art methods of cellulase production by submerged fermentation and also by solid state fermentation are included in the volume. The latest advances made in dilute acid hydrolysis of cellulose are described. Finally, some exciting methods and perspectives for bioconverion of lignocellulosics into ethanol, organic acids and other value-added products are described. This volume should be useful to researchers in this area. It should also be helpful to those who want a concise overview of lignocellulosics.
Download or read book Zeolite Catalysts written by Subhash Bhatia and published by CRC Press. This book was released on 2020-07-24 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presented in an easy-to-read form, this book on zeolite catalysis cover all aspects of the subject. It focuses on synthesis, structure, diffusion, deactivation, and industrial applications. This book is an ideal text for courses on catalysis or as a supplementary text for those studying applied or industrial chemistry. It is also a useful resource for anyone who works with zeolites as catalysts in the laboratory, pilot plants, or commercial installations.
Download or read book Advanced Combustion Techniques and Engine Technologies for the Automotive Sector written by Akhilendra Pratap Singh and published by Springer Nature. This book was released on 2019-10-10 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses the recent advances in combustion strategies and engine technologies, with specific reference to the automotive sector. Chapters discuss the advanced combustion technologies, such as gasoline direct ignition (GDI), spark assisted compression ignition (SACI), gasoline compression ignition (GCI), etc., which are the future of the automotive sector. Emphasis is given to technologies which have the potential for utilization of alternative fuels as well as emission reduction. One special section includes a few chapters for methanol utilization in two-wheelers and four wheelers. The book will serve as a valuable resource for academic researchers and professional automotive engineers alike.
Download or read book Engine Exhaust Particulates written by Avinash Kumar Agarwal and published by Springer. This book was released on 2018-11-01 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comparative analysis of both diesel and gasoline engine particulates, and also of the emissions resulting from the use of alternative fuels. Written by respected experts, it offers comprehensive insights into motor vehicle particulates, their formation, composition, location, measurement, characterisation and toxicology. It also addresses exhaust-gas treatment and legal, measurement-related and technological advancements concerning emissions. The book will serve as a valuable resource for academic researchers and professional automotive engineers alike.
Download or read book Distillation Studies written by John Collin Geniesse and published by . This book was released on 1926 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Automotive Spark Ignited Direct Injection Gasoline Engines written by F. Zhao and published by Elsevier. This book was released on 2000-02-08 with total page 129 pages. Available in PDF, EPUB and Kindle. Book excerpt: The process of fuel injection, spray atomization and vaporization, charge cooling, mixture preparation and the control of in-cylinder air motion are all being actively researched and this work is reviewed in detail and analyzed. The new technologies such as high-pressure, common-rail, gasoline injection systems and swirl-atomizing gasoline fuel injections are discussed in detail, as these technologies, along with computer control capabilities, have enabled the current new examination of an old objective; the direct-injection, stratified-charge (DISC), gasoline engine. The prior work on DISC engines that is relevant to current GDI engine development is also reviewed and discussed. The fuel economy and emission data for actual engine configurations have been obtained and assembled for all of the available GDI literature, and are reviewed and discussed in detail. The types of GDI engines are arranged in four classifications of decreasing complexity, and the advantages and disadvantages of each class are noted and explained. Emphasis is placed upon consensus trends and conclusions that are evident when taken as a whole; thus the GDI researcher is informed regarding the degree to which engine volumetric efficiency and compression ratio can be increased under optimized conditions, and as to the extent to which unburned hydrocarbon (UBHC), NOx and particulate emissions can be minimized for specific combustion strategies. The critical area of GDI fuel injector deposits and the associated effect on spray geometry and engine performance degradation are reviewed, and important system guidelines for minimizing deposition rates and deposit effects are presented. The capabilities and limitations of emission control techniques and after treatment hardware are reviewed in depth, and a compilation and discussion of areas of consensus on attaining European, Japanese and North American emission standards presented. All known research, prototype and production GDI engines worldwide are reviewed as to performance, emissions and fuel economy advantages, and for areas requiring further development. The engine schematics, control diagrams and specifications are compiled, and the emission control strategies are illustrated and discussed. The influence of lean-NOx catalysts on the development of late-injection, stratified-charge GDI engines is reviewed, and the relative merits of lean-burn, homogeneous, direct-injection engines as an option requiring less control complexity are analyzed.
Download or read book Lignocellulose Conversion written by Vincenza Faraco and published by Springer Science & Business Media. This book was released on 2013-06-12 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioethanol has been recognized as a potential alternative to petroleum-derived transportation fuels. Even if cellulosic biomass is less expensive than corn and sugarcane, the higher costs for its conversion make the near-term price of cellulosic ethanol higher than that of corn ethanol and even more than that of sugarcane ethanol. Conventional process for bioethanol production from lignocellulose includes a chemical/physical pre-treatment of lignocellulose for lignin removal, mostly based on auto hydrolysis and acid hydrolysis, followed by saccharification of the free accessible cellulose portions of the biomass. The highest yields of fermentable sugars from cellulose portion are achieved by means of enzymatic hydrolysis, currently carried out using a mix of cellulases from the fungus Trichoderma reesei. Reduction of (hemi)cellulases production costs is strongly required to increase competitiveness of second generation bioethanol production. The final step is the fermentation of sugars obtained from saccharification, typically performed by the yeast Saccharomyces cerevisiae. The current process is optimized for 6-carbon sugars fermentation, since most of yeasts cannot ferment 5-carbon sugars. Thus, research is aimed at exploring new engineered yeasts abilities to co-ferment 5- and 6-carbon sugars. Among the main routes to advance cellulosic ethanol, consolidate bio-processing, namely direct conversion of biomass into ethanol by a genetically modified microbes, holds tremendous potential to reduce ethanol production costs. Finally, the use of all the components of lignocellulose to produce a large spectra of biobased products is another challenge for further improving competitiveness of second generation bioethanol production, developing a biorefinery.
Download or read book Internal Combustion Engine Handbook written by Richard Van Basshuysen and published by SAE International. This book was released on 2016-03-07 with total page 1152 pages. Available in PDF, EPUB and Kindle. Book excerpt: More than 120 authors from science and industry have documented this essential resource for students, practitioners, and professionals. Comprehensively covering the development of the internal combustion engine (ICE), the information presented captures expert knowledge and serves as an essential resource that illustrates the latest level of knowledge about engine development. Particular attention is paid toward the most up-to-date theory and practice addressing thermodynamic principles, engine components, fuels, and emissions. Details and data cover classification and characteristics of reciprocating engines, along with fundamentals about diesel and spark ignition internal combustion engines, including insightful perspectives about the history, components, and complexities of the present-day and future IC engines. Chapter highlights include: • Classification of reciprocating engines • Friction and Lubrication • Power, efficiency, fuel consumption • Sensors, actuators, and electronics • Cooling and emissions • Hybrid drive systems Nearly 1,800 illustrations and more than 1,300 bibliographic references provide added value to this extensive study. “Although a large number of technical books deal with certain aspects of the internal combustion engine, there has been no publication until now that covers all of the major aspects of diesel and SI engines.” Dr.-Ing. E. h. Richard van Basshuysen and Professor Dr.-Ing. Fred Schäfer, the editors, “Internal Combustion Engines Handbook: Basics, Components, Systems, and Perpsectives”
