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Book Ground State Characteristics and Optical Spectra of Ce and Eu Octaethyl Bisporphyrinate Double Deckers

Download or read book Ground State Characteristics and Optical Spectra of Ce and Eu Octaethyl Bisporphyrinate Double Deckers written by and published by . This book was released on 1995 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt: The ground state electronic structure and optical spectra of Ce(III), Ce(IV) and Eu(III) octaethyl bisporphyrin dimers (double deckers) are examined using the Intermediate Neglect of Differential Overlap (INDO/S) model and multireference configuration interaction (MRCI). The low energy electronic excited states of the dimers are interpreted in terms of their monomer contributions, and the charge transfer and excitonic character of the transitions are analyzed. Particular attention is focused on the nature of the near infrared band (NIR) that characterizes the spectra of the electron deficient bisporphyrin dimers, justifying its shift to higher energy as the ionic radii of the central ion decreases, and relating its broadness to the contribution of closely spaced electronic transitions that become allowed through vibronic coupling. The influence of an electric perturbation on the dimeric Ce(IV) and Eu(III) structures is used to explain their conductivity. The results are compared to those derived from resonant Raman spectroscopy, which show the importance of the vibrational fine structure in the assignment of the NIR band. jg p4.

Book Government Reports Announcements   Index

Download or read book Government Reports Announcements Index written by and published by . This book was released on 1996 with total page 1104 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Analytical and Physical Electrochemistry

Download or read book Analytical and Physical Electrochemistry written by Hubert H. Girault and published by CRC Press. This book was released on 2004-10-25 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of electrochemistry is pertinent to a wide variety of fields, including bioenergetics, environmental sciences, and engineering sciences. In addition, electrochemistry plays a fundamental role in specific applications as diverse as the conversion and storage of energy and the sequencing of DNA. Intended both as a basic course for un

Book Functional Dyes

    Book Details:
  • Author : Sung-Hoon Kim
  • Publisher : Elsevier
  • Release : 2006-03-08
  • ISBN : 0080465625
  • Pages : 283 pages

Download or read book Functional Dyes written by Sung-Hoon Kim and published by Elsevier. This book was released on 2006-03-08 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last 10 years organic dyes, traditionally used for coloring textiles and other materials, have become increasingly important in the hi-tech industries of electronics and optoelectronics. They can be used in optical data storage, new solar cells and biomedical sensors.Functional Dyes discusses the synthesis of these new, high-value dyes and pigments as well as their applications and performance. The chapters are arranged so that the reader logically advances from the fundamental concepts to more practical aspects of the technology in which they are used.In providing the reader with current information on functional dye chemistry, as well as important developments within the field, Functional Dyes is a valuable information source for dye and material chemists, researchers and graduates, who want a summary of the key advances in the field over the last 10 years and an authoritative view on future developments. * Provides a broad introduction to the science technology of the functional dye application* Reviews recent advances on synthesis and characteristics of the functional dyes and their applications* Is a valuable information source for dye and material chemists and researchers

Book Macrocycles

Download or read book Macrocycles written by E. Weber and published by Springer. This book was released on 1992 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Combinatorial Chemistry

    Book Details:
  • Author : Stephen R. Wilson
  • Publisher : John Wiley & Sons
  • Release : 1997-03-28
  • ISBN : 9780471126874
  • Pages : 288 pages

Download or read book Combinatorial Chemistry written by Stephen R. Wilson and published by John Wiley & Sons. This book was released on 1997-03-28 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: The new time-saving revolution in drug discovery. Combinatorial chemistry, a method for synthesizing millions of chemical compounds much faster than usual, is becoming one of the most useful technical tools available to chemists and researchers working today. Using current advances in computer and laboratory techniques, combinatorial chemistry has freed professionals from the drudgery of piecemeal experimental work and opened new creative possibilities for experimentation. Combinatorial Chemistry: Synthesis and Application details critical aspects of the technique, featuring the work of some of the world's leading chemists, many of whom played a key role in its development. Including examples of both solution-phase and solid-phase approaches as well as the full complement of organic chemistry technologies currently available, the book describes: * Concepts and terms of combinatorial chemistry * Polymer-supported synthesis of organic compounds * Macro beads as microreactors * Solid-phase methods in combinatorial chemistry * Encoded combinatorial libraries, including Rf-encoding of synthesis beads * Strategies for combinatorial libraries of oligosaccharides * Combinatorial libraries of peptides, proteins, and antibodies using biological systems. While combinatorial chemistry originated in peptide chemistry, this volume has deliberately focused on nonpeptide organic applications, illustrating the technique's wide uses. Combinatorial Chemistry introduces organic, medicinal, and pharmaceutical chemists as well as biochemists to this exciting, cost-effective, and practical technique, which has unlocked creative potential for the next millennium.

Book Non Covalent Multi Porphyrin Assemblies

Download or read book Non Covalent Multi Porphyrin Assemblies written by Enzo Alessio and published by Structure and Bonding. This book was released on 2006-04-20 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts

Book Nanohybrids

Download or read book Nanohybrids written by Gaurav Sharma and published by Materials Research Forum LLC. This book was released on 2021-01-20 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book covers preparation, designing and utilization of nanohybrid materials for biomedical applications. These materials can improve the effectiveness of drugs, promote high cell growth in new scaffolds, and lead to biodegradable surgical sutures. The use of hybrid magneto-plasmonic nanoparticles may lead to non-invasive therapies. The most promising materials are based on silica nanostructures, polymers, bioresorbable metals, liposomes, biopolymeric electrospun nanofibers, graphene, and gelatin. Much research focuses on the development of biomaterials for cell regeneration and wound healing applications. Keywords: Biomedical Materials, Cell Growth, Cell Regeneration, Wound Healing, Surgical Sutures, Non-invasive Therapies , Drug Transport, Tissue Engineering, Cardiovascular Implants, Fracture Repair Implants, Biodegradable Materials, Hybrid Magneto-plasmonic Nanoparticles, Silica Nanostructures, Polymers, Bioresorbable Metals, Liposomes, Biopolymeric Electrospun Nanofibers, Graphene, Gelatin-based Hydrogels.