Download or read book Glycolic Formic Acid Flowsheet Sludge Matrix Study written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Testing was completed to demonstrate the viability of the newly developed glycolic acid/formic acid flowsheet on processing in the Defense Waste Processing Facility's (DWPF) Chemical Process Cell (CPC). The Savannah River National Laboratory (SRNL) initiated a sludge matrix study to evaluate the impact of changing insoluble solid composition on the processing characteristics of slurries in DWPF. Four sludge simulants were prepared to cover two compositional ranges in the waste. The first was high iron/low aluminum versus low iron/high aluminum (referred to as HiFe or LoFe in this report). The second was high calcium-manganese/low nickel, chromium, and magnesium versus low calcium-manganese/high nickel, chromium, and magnesium (referred to as HiMn or LoMn in this report). These two options can be combined to form four distinct sludge compositions. The sludge matrix study called for testing each of these four simulants near the minimum acid required for nitrite destruction (100% acid stoichiometry) and at a second acid level that produced significant hydrogen by noble metal catalyzed decomposition of formic acid (150% acid stoichiometry). Four simulants were prepared based on the four possible combinations of the Al/Fe and Mn-Ca/Mg-Ni-Cr options. Preliminary simulant preparation work has already been documented. The four simulants were used for high and low acid testing. Eight planned experiments (GF26 to GF33) were completed to demonstrate the viability of the glycolic-formic flowsheet. Composition and physical property measurements were made on the SRAT product. Composition measurements were made on the condensate from the Mercury Water Wash Tank (MWWT), Formic Acid Vent Condenser (FAVC), ammonia scrubber and on SRAT samples pulled throughout the SRAT cycle. Updated values for formate loss and nitrite-tonitrate conversion were found that can be used in the acid calculations for future sludge matrix process simulations with the glycolic acid/formic acid flowsheet. Preliminary results of the initial testing indicate: (1) Hydrogen generation rate was very low throughout all SRAT cycles. (2) The mercury concentration of the SRAT product was below the 0.8 wt% limit in all runs. (3) Nitrite in the SRAT product was

Download or read book GLYCOLIC NITRIC ACID FLOWSHEET DEMONSTRATION OF THE DWPF CHEMICAL PROCESSING CELL WITH MATRIX SIMULANTS AND SUPERNATE written by and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Savannah River Remediation (SRR) is evaluating changes to its current DWPF flowsheet to improve processing cycle times. This will enable the facility to support higher canister production while maximizing waste loading. Higher throughput is needed in the CPC since the installation of the bubblers into the melter has increased melt rate. Due to the significant maintenance required for the DWPF gas chromatographs (GC) and the potential for production of flammable quantities of hydrogen, reducing or eliminating the amount of formic acid used in the CPC is being developed. Earlier work at Savannah River National Laboratory has shown that replacing formic acid with an 80:20 molar blend of glycolic and formic acids has the potential to remove mercury in the SRAT without any significant catalytic hydrogen generation. This report summarizes the research completed to determine the feasibility of processing without formic acid. In earlier development of the glycolic-formic acid flowsheet, one run (GF8) was completed without formic acid. It is of particular interest that mercury was successfully removed in GF8, no formic acid at 125% stoichiometry. Glycolic acid did not show the ability to reduce mercury to elemental mercury in initial screening studies, which is why previous testing focused on using the formic/glycolic blend. The objective of the testing detailed in this document is to determine the viability of the nitric-glycolic acid flowsheet in processing sludge over a wide compositional range as requested by DWPF. This work was performed under the guidance of Task Technical and Quality Assurance Plan (TT and QAP). The details regarding the simulant preparation and analysis have been documented previously.

Download or read book GLYCOLIC FORMIC ACID FLOWSHEET DEVELOPMENT written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Flowsheet testing was performed to further develop the nitric/glycolic/formic acid flowsheet as an alternative to the nitric/formic flowsheet currently being processed at the DWPF. This new flowsheet has shown that mercury can be removed in the Sludge Receipt and Adjustment Tank (SRAT) with minimal hydrogen generation. All other processing objectives were also met, including greatly reducing the Slurry Mix Evaporator (SME) product yield stress as compared to the baseline nitric/formic flowsheet. Eight runs were performed in total, including the baseline run. The baseline nitric/formic flowsheet run was extremely difficult to process under existing DWPF acceptance criteria with this simulant at the HM levels of noble metals. While nitrite was destroyed and mercury was removed to near the DWPF limit, the rheology of the SRAT and SME products were well above design basis and hydrogen generation far exceeded the DWPF limit. In addition, mixing during the SME cycle was very poor. In this sense, the nitric/glycolic/formic acid flowsheet represents a significant upgrade over the current flowsheet. In the nitric/glycolic/formic flowsheet runs, mercury was successfully removed with almost no hydrogen generation and the SRAT and SME products yield stresses were within process limits or previously processed ranges. It is recommended that DWPF continue to support development of the nitric/glycolic/formic flowsheet. Although experience is limited at this time, this flowsheet meets or outperforms the current flowsheet in many regards, including off-gas generation, mercury removal, product rheology and general ease of processing. Additional flowsheet testing will allow for a more thorough understanding of the chemistry and effectiveness of the flowsheet over a range of sludge compositions and formic/glycolic ratios. This testing will also show whether the REDOX and metal solubility concerns with this change in the flowsheet can be addressed by just adjusting the volumes of glycolic acid added. The outstanding issues regarding the glycolic/formic flowsheet include increasing understanding of the impact on glass REDOX control and increased metal solubility, particularly iron, during processing. Additionally, evaluations of the utility of the flowsheet over varying sludge compositions should be completed to ensure flowsheet robustness. Work has already been initiated to further understand the REDOX and iron solubility areas.

Download or read book Actual Waste Demonstration of the Nitric Glycolic Flowsheet for Sludge Batch 9 Qualification written by and published by . This book was released on 2016 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: For each sludge batch that is processed in the Defense Waste Processing Facility (DWPF), the Savannah River National Laboratory (SRNL) performs qualification testing to demonstrate that the sludge batch is processable. Testing performed by the Savannah River National Laboratory has shown glycolic acid to be effective in replacing the function of formic acid in the DWPF chemical process. The nitric-glycolic flowsheet reduces mercury, significantly lowers the catalytic generation of hydrogen and ammonia which could allow purge reduction in the Sludge Receipt and Adjustment Tank (SRAT), stabilizes the pH and chemistry in the SRAT and the Slurry Mix Evaporator (SME), allows for effective rheology adjustment, and is favorable with respect to melter flammability. In order to implement the new flowsheet, SRAT and SME cycles, designated SC-18, were performed using a Sludge Batch (SB) 9 slurry blended from SB8 Tank 40H and Tank 51H samples. The SRAT cycle involved adding nitric and glycolic acids to the sludge, refluxing to steam strip mercury, and dewatering to a targeted solids concentration. Data collected during the SRAT cycle included offgas analyses, process temperatures, heat transfer, and pH measurements. The SME cycle demonstrated the addition of glass frit and the replication of six canister decontamination additions. The demonstration concluded with dewatering to a targeted solids concentration. Data collected during the SME cycle included offgas analyses, process temperatures, heat transfer, and pH measurements. Slurry and condensate samples were collected for subsequent analysis.

Download or read book Advanced Oxidation Processes for Water and Wastewater Treatment written by Simon Parsons and published by IWA Publishing. This book was released on 2004-03-01 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: The suitability of Advanced Oxidation Processes (AOPs) for pollutant degradation was recognised in the early 1970s and much research and development work has been undertaken to commercialise some of these processes. AOPs have shown great potential in treating pollutants at both low and high concentrations and have found applications as diverse as ground water treatment, municipal wastewater sludge destruction and VOCs control. Advanced Oxidation Processes for Water and Wastewater Treatment is an overview of the advanced oxidation processes currently used or proposed for the remediation of water, wastewater, odours and sludge. The book contains two opening chapters which present introductions to advanced oxidation processes and a background to UV photolysis, seven chapters focusing on individual advanced oxidation processes and, finally, three chapters concentrating on selected applications of advanced oxidation processes. Advanced Oxidation Processes for Water and Wastewater Treatment will be invaluable to readers interested in water and wastewater treatment processes, including professionals and suppliers, as well as students and academics studying in this area. Dr Simon Parsons is a Senior Lecturer in Water Sciences at Cranfield University with ten years' experience of industrial and academic research and development.

Download or read book Chemical Oxidation Applications for Industrial Wastewaters written by Olcay Tunay and published by IWA Publishing. This book was released on 2010-10-12 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the most recent scientific and technological developments (state-of-the-art) in the field of chemical oxidation processes applicable for the efficient treatment of biologically-difficult-to-degrade, toxic and/or recalcitrant effluents originating from different manufacturing processes. It is a comprehensive review of process and pollution profiles as well as conventional, advanced and emerging treatment processes & technologies developed for the most relevant and pollution (wet processing)-intensive industrial sectors. It addresses chemical/photochemical oxidative treatment processes, case-specific treatability problems of major industrial sectors, emerging (novel) as well as pilot/full-scale applications, process integration, treatment system design & sizing criteria (figure-of-merits), cost evaluation and success stories in the application of chemical oxidative treatment processes. Chemical Oxidation Applications for Industrial Wastewaters is an essential reference for lecturers, researchers, industrial and environmental engineers and practitioners working in the field of environmental science and engineering. Visit the IWA WaterWiki to read and share material related to this title: http://www.iwawaterwiki.org/xwiki/bin/view/Articles/CHEMICALOXIDATIONAPPLICATIONSFORINDUSTRIALWASTEWATERS Authors: Professor Olcay Tünay, Professor Isik Kabdasli, Associate Professor Idil Arslan-Alaton and Assistant Professor Tugba Ölmez-Hanci, Environmental Engineering Department, Istanbul Technical University, Turkey.

Download or read book Continuous Denitration written by M. J. Szulinski and published by . This book was released on 1955 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt: Design and technical specifications are outlined for equipment designed for the continuous calcination of UNH to UO2. (C.W.H.).

Download or read book Processing of Heavy Crude Oils written by Ramasamy Marappa Gounder and published by . This book was released on 2019-12-18 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Health Effects Assessment Summary Tables written by and published by . This book was released on 1997 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Energy Efficient Solvents for CO2 Capture by Gas Liquid Absorption written by Wojciech M. Budzianowski and published by Springer. This book was released on 2016-12-01 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.

Download or read book State of the art Report on the Progress of Nuclear Fuel Cycle Chemistry written by and published by . This book was released on 2018 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: The implementation of advanced nuclear systems requires that new technologies associated with the back end of the fuel cycle are developed. The separation of minor actinides from other fuel components is one of the advanced concepts being studied to help close the nuclear fuel cycle and to improve the long-term effects on the performance of geological repositories. Separating spent fuel elements and subsequently converting them through transmutation into short-lived nuclides should considerably reduce the longterm risks associated with nuclear power generation.

Download or read book Alternative Disinfectants and Oxidants Guidance Manual written by and published by . This book was released on 1999 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Petroleum Engineer s Guide to Oil Field Chemicals and Fluids written by Johannes Fink and published by Gulf Professional Publishing. This book was released on 2011-05-13 with total page 809 pages. Available in PDF, EPUB and Kindle. Book excerpt: Petroleum Engineer's Guide to Oil Field Chemicals and Fluids is a comprehensive manual that provides end users with information about oil field chemicals, such as drilling muds, corrosion and scale inhibitors, gelling agents and bacterial control. This book is an extension and update of Oil Field Chemicals published in 2003, and it presents a compilation of materials from literature and patents, arranged according to applications and the way a typical job is practiced. The text is composed of 23 chapters that cover oil field chemicals arranged according to their use. Each chapter follows a uniform template, starting with a brief overview of the chemical followed by reviews, monomers, polymerization, and fabrication. The different aspects of application, including safety and environmental impacts, for each chemical are also discussed throughout the chapters. The text also includes handy indices for trade names, acronyms and chemicals. Petroleum, production, drilling, completion, and operations engineers and managers will find this book invaluable for project management and production. Non-experts and students in petroleum engineering will also find this reference useful. Chemicals are ordered by use including drilling muds, corrosion inhibitors, and bacteria control Includes cutting edge chemicals and polymers such as water soluble polymers and viscosity control Handy index of chemical substances as well as a general chemical index

Download or read book Chemical Water and Wastewater Treatment V written by Hermann H. Hahn and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: It was intended to return with the International Gothenburg Symposia every other time to the birthplace of these events, Gothenburg in Sweden. But instead the 8th symposium has been invited to be organized and held in Prague, i. e. in the midst of Central and Eastern Europe a region now keen on intensified environmental control. This attests that the symposia have attained such standing in the interna tional world of operators, designers, officers and researchers in water treatment technology that their presence in various parts of the world has been requested. And this ever growing significance, in short the success of this conference series, stems form the fact that the symposia offer a unique platform for the exchange of ideas and experiences on all aspects of water and wastewater treatment between administrators, engineers and scientists. The content of this book, i. e. the schedule of the symposium lectures, results for the most part from a vast response to an international call for papers. Many excellent contributions are included in this volume but at the same time many outstanding ones could not be included for lack of time and space. The total sum of these contributions document again the development in the field, both in terms of new technological (and other) developments as well as public and administrative acceptance and approval of solutions offered.

Download or read book The Radiation Chemistry of Polysaccharides written by International Atomic Energy Agency and published by . This book was released on 2017-05 with total page 467 pages. Available in PDF, EPUB and Kindle. Book excerpt: This publication provides the background and compiles the most recent research findings as well as detailing development activities relating to the development of radiation processed products made of natural polymers. Successes clearly indicate that the radiation processing of natural polymers has emerged as an exciting area where the unique characteristics of these polymeric materials can be exploited for a variety of practical applications in agriculture, healthcare, industry and the environment.

Download or read book Biodiesel written by Meisam Tabatabaei and published by Springer. This book was released on 2018-11-02 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents in-depth information on the state of the art of global biodiesel production and investigates its impact on climate change. Subsequently, it comprehensively discusses biodiesel production in terms of production systems (reactor technologies) as well as biodiesel purification and upgrading technologies. Moreover, the book reviews essential parameters in biodiesel production systems as well as major principles of operation, process control, and trouble-shooting in these systems. Conventional and emerging applications of biodiesel by-products with a view to further economize biodiesel production are also scrutinized. Separate chapters are dedicated to economic risk analysis and critical comparison of biodiesel production systems as well as techno-economical aspects of biodiesel plants. The book also thoroughly investigates the important aspects of biodiesel production and combustion by taking advantage of advanced sustainability analysis tools including life cycle assessment (LCA) and exergy techniques. In closing, the application of Omics technologies in biodiesel production is presented and discussed. This book is relevant to anyone with an interest in renewable, more sustainable fuel and energy solutions.

Download or read book Production and Packaging of Non Carbonated Fruit Juices and Fruit Beverages written by Philip R. Ashurst and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the period of about five years since the first edition of this book appeared, many changes have occurred in the fruit juice and beverage markets. The growth of markets has continued, blunted to some extent, no doubt, by the recession that has featured prominently in the economies of the major consuming nations. But perhaps the most significant area that has affected juices in particular is the issue of authenticity. Commercial scandals of substantial proportions have been seen on both sides of the Atlantic because of fraudulent practice. Major strides have been made in the development of techniques to detect and measure adulterants in the major juices. A contri bution to Chapter 1 describes one of the more important scientific techniques to have been developed as a routine test method to detect the addition of carbohydrates to juices. Another, and perhaps more welcome, development in non-carbonated beverages during the past few years is the rapid growth of sports drinks. Beverages based on glucose syrup have been popular for many years, and in some parts of the world isotonic products have long featured in the sports arena. A combination of benefits is now available from a wide range of preparations formulated and marketed as sports drinks and featuring widely in beverage markets world-wide. A new chapter reviews their formulation and performance characteristics. Another major trend in the area of fruit-containing non-carbonated bever ages is the highly successful marketing of ready-to-drink products.