Download or read book Non Equilibrium Reacting Gas Flows written by Ekaterina Nagnibeda and published by Springer Science & Business Media. This book was released on 2009-07-09 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the present monograph, we develop the kinetic theory of transport phenomena and relaxation processes in the flows of reacting gas mixtures and discuss its applications to strongly non-equilibrium conditions. The main attention is focused on the influence of non-equilibrium kinetics on gas dynamics and transport properties. Closed systems of fluid dynamic equations are derived from the kinetic equations in different approaches. We consider the most accurate approach taking into account the state-to-state kinetics in a flow, as well as simplified multi-temperature and one-temperature models based on quasi-stationary distributions. Within these approaches, we propose the algorithms for the calculation of the transport coefficients and rate coefficients of chemical reactions and energy exchanges in non-equilibrium flows; the developed techniques are based on the fundamental kinetic theory principles. The theory is applied to the modeling of non-equilibrium flows behind strong shock waves, in the boundary layer, and in nozzles. The comparison of the results obtained within the frame of different approaches is presented, the advantages of the new state-to-state kinetic model are discussed, and the limits of validity for simplified models are established. The book can be interesting for scientists and graduate students working on physical gas dynamics, aerothermodynamics, heat and mass transfer, non-equilibrium physical-chemical kinetics, and kinetic theory of gases.
Download or read book Gas Phase Reactions written by V.N. Kondratiev and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.
Download or read book Plasma Kinetics in Atmospheric Gases written by M. Capitelli and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emphasis is placed on the analysis of translational, rotational, vibrational and electronically excited state kinetics, coupled to the electron Boltzmann equation.
Download or read book Gas Kinetics and Energy Transfer written by P G Ashmore and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Download or read book The Gas Kinetics of Very High Flight Speeds written by Eugen Sänger and published by . This book was released on 1950 with total page 58 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aerodynamic forces on bodies of arbitrary shape were investigated under conditions such that the mean free path of the air molecule is greater than the dimensions of the body. Air pressures and friction forces were calculated from gas kinetic theory for surfaces facing both toward and away from the air stream at any angle. Air forces for an atmosphere of definite composition (molecular hydrogen) were calculated as a function of the flight velocity. The results indicate that the friction stresses between the air and the body surface are of the same magnitude as the dynamic pressure and as the air pressures normal to the surface. The application of the general method to the specific cases such as thin airfoils and projectiles leads to high drag coefficients and poor glide ratios even for the theoretically best wing sections.
Download or read book Kinetics of Metal Gas Interactions at Low Temperatures written by Eckehard Fromm and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 219 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents experimental data and recent results of model calculations on the formation of natural oxide film on metal surfaces and of metal hydride formation. Such films are responsible for corrosion, friction, and wear of metallic materials. Describing mostly the authors own research, this monograph gives an overview of models suitable for metal-gas reactions and demonstrates how complex metal-gas interactions can be analyzed by standard procedures of chemical kinetics. The book, and the data and equations it contains, will be useful to researchers in surface science, condensed-matter physics, and materials science.
Download or read book Kinetics and Dynamics of Elementary Gas Reactions written by Ian W. M. Smith and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kinetics and Dynamics of Elementary Gas Reactions surveys the state of modern knowledge on elementary gas reactions to understand natural phenomena in terms of molecular behavior. Part 1 of this book describes the theoretical and conceptual background of elementary gas-phase reactions, emphasizing the assumptions and limitations of each theoretical approach, as well as its strengths. In Part 2, selected experimental results are considered to demonstrate the scope of present day techniques and illustrate the application of the theoretical ideas introduced in Part 1. This publication is intended primarily for working kineticists and chemists, but is also beneficial to graduate students.
Download or read book Kinetics of Chemical Gas Reactions written by Viktor Nikolaevich Kondrat£ev and published by . This book was released on 1962 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book An Introduction to the Kinetic Theory of Gases written by James Jeans and published by CUP Archive. This book was released on 1982-10-14 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book can be described as a student's edition of the author's Dynamical Theory of Gases. It is written, however, with the needs of the student of physics and physical chemistry in mind, and those parts of which the interest was mainly mathematical have been discarded. This does not mean that the book contains no serious mathematical discussion; the discussion in particular of the distribution law is quite detailed; but in the main the mathematics is concerned with the discussion of particular phenomena rather than with the discussion of fundamentals.
Download or read book Key Factors of Combustion written by Nikolai M. Rubtsov and published by Springer. This book was released on 2016-11-13 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarizes the main advances in the mechanisms of combustion processes. It focuses on the analysis of kinetic mechanisms of gas combustion processes and experimental investigation into the interrelation of kinetics and gas dynamics in gas combustion. The book is complimentary to the one previously published, The Modes of Gaseous Combustion.
Download or read book Chemical Kinetics of Gas Reactions written by V. N. Kondrat'Ev and published by Elsevier. This book was released on 2016-01-22 with total page 843 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics of Gas Reactions explores the advances in gas kinetics and thermal, photochemical, electrical discharge, and radiation chemical reactions. This book is composed of 10 chapters, and begins with the presentation of general kinetic rules for simple and complex chemical reactions. The next chapters deal with the experimental methods for evaluating chemical reaction mechanisms and some theories of elementary chemical processes. These topics are followed by discussions on certain class of chemical reactions, including unimolecular, bimolecular, and termolecular reactions. The remaining chapters examine gas reactions, such as molecular collisions, photochemical reactions, chemical reactions in electrical discharge, chain reactions, and combustion. This book will be of value to reaction kinetics engineers and researchers.
Download or read book LSENS a General Chemical Kinetics and Sensitivity Analysis Code for Homogeneous Gas phase Reactions 2 Code Description and Usage written by Krishnan Radhakrishnan and published by . This book was released on 1994 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics Of Gas Reaction VIB written by Willhelm Jost and published by Elsevier. This book was released on 2012-12-02 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical Chemistry: An Advanced Treatise: Kinetics of Gas Reactions, Volume VIB, is devoted to gas phase chemical reactions. The purpose of this treatise is to present a comprehensive treatment of physical chemistry for advanced students and investigators in a reasonably small number of volumes. An attempt has been made to include all important topics in physical chemistry together with borderline subjects which are of particular interest and importance. The book contains six chapters and begins with a study on the elastic and inelastic scattering of ions on molecules, including such topics as rainbow scattering, reactive scattering, and experimental procedures and results of high-resolution measurements. This is followed by separate chapters on collision processes and the theory of elastic scattering; and atom reactions, with a discussion of experimental techniques (static, flow, and pulse methods), among the selected examples being the reactions of H, O, C, and N atoms with alkanes, alkenes, acetylene, sulfur, and nitrogen compounds. Subsequent chapters deal with experimental methods and results obtained by several techniques of relaxation methods in gases; thermal unimolecular reactions; and the interactions between chemical reactions, transport processes, and flow phenomena.
Download or read book Gas Dynamics written by George Turrell and published by John Wiley & Sons. This book was released on 1997-09-09 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book consists of two parts, theory and applications. Part I introduces the kinetic theory of gases with relevance to molecular energies and intermolecular forces. Part II focuses on how these theories are used to explain real techniques and phenomena involving gases. By stressing the practical implications, the book explains the theory of gas dynamics in a highly readable and comprehensive manner.
Download or read book Kinetics and Mechanism written by John W. Moore and published by John Wiley & Sons. This book was released on 1981-09-30 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt: The third edition of a classic text originally by Frost and Pearson, that describes the fundamental principles and established practices that apply to the study and the rates and mechanisms of homogeneous chemical reactions in the gas phase and in solution. Incorporates new advances made during the past 20 years in the study of individual molecular collisions by molecular-beam, laser applications to experimental kinetics, theoretical treatments of reaction rates and our understanding of the principles that govern rates of reaction in solution. Presents numerous examples of the deduction of mechanism from experiment, including intimate details such as stereochemistry and the dependence of reaction pathway on the exact energy states of reacting particles.
Download or read book Generalized Boltzmann Physical Kinetics written by Boris V. Alexeev and published by Elsevier. This book was released on 2004-05-25 with total page 377 pages. Available in PDF, EPUB and Kindle. Book excerpt: The most important result obtained by Prof. B. Alexeev and reflected in the book is connected with new theory of transport processes in gases, plasma and liquids. It was shown by Prof. B. Alexeev that well-known Boltzmann equation, which is the basement of the classical kinetic theory, is wrong in the definite sense. Namely in the Boltzmann equation should be introduced the additional terms which generally speaking are of the same order of value as classical ones. It leads to dramatic changing in transport theory. The coincidence of experimental and theoretical data became much better. Particularly it leads to the strict theory of turbulence and possibility to calculate the turbulent flows from the first principles of physics. · Boltzmann equation (BE) is valid only for particles, which can be considered as material points, generalized Boltzmann equation (GBE) removes this restriction.· GBE contains additional terms in comparison with BE, which cannot be omitted· GBE leads to strict theory of turbulence· GBE gives all micro-scale turbulent fluctuations in tabulated closed analytical form for all flows · GBE leads to generalization of electro-dynamic Maxwell equations· GBE gives new generalized hydrodynamic equations (GHE) more effective than classic Navier-Stokes equations· GBE can be applied for description of flows for intermediate diapason of Knudsen numbers· Asymptotical solutions of GBE remove contradictions in the theory of Landau damping in plasma
Download or read book The Kinetic Theory of Gases written by Leonard B. Loeb and published by Courier Corporation. This book was released on 2004-01-01 with total page 746 pages. Available in PDF, EPUB and Kindle. Book excerpt: A pioneering text in its field, this comprehensive study is one of the most valuable texts and references available. The author explores the classical kinetic theory in the first four chapters, with discussions of the mechanical picture of a perfect gas, the mean free path, and the distribution of molecular velocities. Tbhe fifth chapter deals with the more accurate equations of state, or Van der Waals' equation, and later chapters examine viscosity, heat conduction, surface phenomena, and Browninan movements. The text surveys the application of quantum theory to the problem of specific heats and the contributions of kinetic theory to knowledge of electrical and magnetic properties of molecules, concluding with applications of the kinetic theory to the conduction of electricity in gases. 1934 edition.
