Download or read book Gain in Terahertz Quantum Cascade Lasers written by M. Houghton and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Mid Infrared and Terahertz Quantum Cascade Lasers written by Dan Botez and published by Cambridge University Press. This book was released on 2023-06-30 with total page 551 pages. Available in PDF, EPUB and Kindle. Book excerpt: A state-of-the-art overview of this rapidly expanding field, featuring fundamental theory, practical applications, and real-life examples.

Download or read book From High Power Terahertz Quantum Cascade Lasers to Terahertz Light Amplifiers written by Tsung-Yu Kao and published by . This book was released on 2014 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: The terahertz (THz) frequency range (300 GHz to 10 THz, wavelength 30-1000 [mu]m), despite having many potential applications, is technologically relatively underdeveloped mainly because of the lack of suitable coherent radiation sources when compared with nearby electromagnetic radiation spectrum. The invention of the THz quantum cascade laser, a electronically-pumped semiconductor heterostructure which emits photons from electronic intersubband transitions, provides the first solidstate fundamental oscillator at the frequency range from 1.2 to 5.1 THz. Due to the subwavelength confinement nature of the metal-metal waveguide used in most of the THz QC lasers, far-field beam patterns from lasers with simple Fabry-Perot waveguides are divergent and far from ideal Gaussian beams. The first part of this thesis describes the development of single-mode THz QC lasers on metal-metal waveguides. Starting with the corrugated third-order DFB laser-a clever laser structure which utilizes end-fire array effect to achieve low divergence beam patterns-several applications using densely-packed third-order DFB laser arrays, such as frequency agile sources for THz swept-source optical tomography and local oscillators for THz heterodyne receivers with precise frequency control, have been investigated. With the improved design rules and fabrication techniques, 830 GHz single-mode frequency coverage on a monolithic multicolor DFB laser array has been achieved. The origin of the deterioration in far-field beam patterns and power outputs in long third-order DFB lasers is then identified. This finding leads to a modified third-order DFB laser structure which can achieve perfect phase-matching (PM) condition, resulting in scalable power output and even lower beam divergence when compared with that of a conventional third-order DFB laser. Radiations from up to 151 laser sectors are phase-locked to form a single-lobe beam pattern with divergence ~ 6 x 11° and ~13 mW pulsed power at the end-fire direction. This approach substantially increases the usable length of a third-order DFB laser while keeping a high slope efficiency (140 mW/A). Later development applies the concept of microstrip antenna-a structure commonly used in microwave engineering-to THz photonics devices. By coupling the microstrip antenna to each grating aperture of a perfectly phase-matched DFB laser, the radiation impedance of the laser can now be tuned to enhance the overall emission efficiency. This novel genre of DFB laser achieves > 8 mW pulsed power (10% duty-cycle) at 12 K with beam divergence as low as 12.5 x 12.5' and maximum lasing temperature Tmax = 109 K (pulsed) and 77 K (c.w.) with the highest slope efficiency (~450 mW/A) and wall-plug efficiency (0.57%) of all THz DFB laser sources. The second part of the thesis then focuses on the development of the first light amplifier in THz frequency under Fabry-Perot amplifier (FPA) scheme. Although amplification at terahertz frequency in quantum cascade structures has been demonstrated under the transient state or in a integrated platform, none of them is suitable for amplifying continuous-wave free-space THz radiations. The proposed amplifier is consisted of an array of short-cavity surface-emitting second-order distributed feedback lasers arranged in a two-dimensional grid which are operated marginally beneath their lasing thresholds. A overall system power gain of ~5.6x = 7.5 dB at ~3 THz is obtained with ~1 GHz bandwidth. The free-space THz light amplifier can be used as the pre-amplifier for a THz heterodyne receiver system to reduce the receiver system noise, or be placed on the focal plane of a THz imaging system to enhance the signal-to-noise ratio of the image and reduce the acquisition time. A new locking mechanism for two-dimensional phase-locked laser arrays based on antenna mutual-coupling is also proposed and then successfully demonstrated in the THz frequency using short-cavity DFB THz lasers. Up to 37 lasers are phase-locked to deliver 6.5 mW single-mode pulsed power (4% duty-cycle) at 3 THz with symmetric beam pattern ( 10 x 10°). This new coupling scheme can be extended to other electromagnetic systems with sub-wavelength confined elements such as plasmonic lasers and nanolasers. This thesis also reports the development of fabrication techniques required to bring the aforementioned novel THz cavity designs from concepts to reality which include a high aspect ratio ( 1:10) anisotropic reactive-ion etch on GaAs which is compatible with the metal-metal waveguide platform and the procedure to create airbridge structures by selectively removing the dielectric materials beneath the metal contacts.

Download or read book Fundamentals of Terahertz Devices and Applications written by Dimitris Pavlidis and published by John Wiley & Sons. This book was released on 2021-08-02 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt: An authoritative and comprehensive guide to the devices and applications of Terahertz technology Terahertz (THz) technology relates to applications that span in frequency from a few hundred GHz to more than 1000 GHz. Fundamentals of Terahertz Devices and Applications offers a comprehensive review of the devices and applications of Terahertz technology. With contributions from a range of experts on the topic, this book contains in a single volume an inclusive review of THz devices for signal generation, detection and treatment. Fundamentals of Terahertz Devices and Applications offers an exploration and addresses key categories and aspects of Terahertz Technology such as: sources, detectors, transmission, electronic considerations and applications, optical (photonic) considerations and applications. Worked examplesbased on the contributors extensive experience highlight the chapter material presented. The text is designed for use by novices and professionals who want a better understanding of device operation and use, and is suitable for instructional purposes This important book: Offers the most relevant up-to-date research information and insight into the future developments in the technology Addresses a wide-range of categories and aspects of Terahertz technology Includes material to support courses on Terahertz Technology and more Contains illustrative worked examples Written for researchers, students, and professional engineers, Fundamentals of Terahertz Devices and Applications offers an in-depth exploration of the topic that is designed for both novices and professionals and can be adopted for instructional purposes.

Download or read book High Lying Confined Subbands in Terahertz Quantum Cascade Lasers written by Li Wang and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In designing the terahertz quantum cascade lasers, electron injection manner indeed plays a significant role to achieve the population inversion. The resonant tunneling process is commonly employed for this injection process but waste more than 50% fraction of populations out of the active region owing to resonance alignment, and the injection efficiency is obviously degraded due to thermal incoherence. An alternative approach is to consider the phonon-assisted injection process that basically contributes to most of the populations to the upper lasing level. However, this manner is still not realized in experiments if a short-period design only containing two quantum wells is used. In this work, it is found in this design that the population inversion is indeed well improved; however, the optical gain is inherently low even at a low temperature. Those two opposite trends are ascribed to a strong parasitic absorption overlapping the gain. The magnitude of this overlap is closely related to the lasing frequency, where frequencies below 3 THz suffer from fewer effects.

Download or read book Development of Terahertz QCLs written by Sushil Kumar (Ph. D.) and published by . This book was released on 2007 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: The terahertz or the far-infrared frequency range of the electromagnetic spectrum (...) has historically been technologically underdeveloped despite having many potential applications, primarily due to lack of suitable sources of coherent radiation. Following on the remarkable development of mid-infrared (...) quantum-cascade lasers (QCLs) in the past decade, this thesis describes the development of electrically-pumped terahertz quantum-cascade lasers in GaAs/AlsGal_. As heterostructures that span a spectral range of 1.59 - 5.0 THz (...). A quantum-cascade laser (QCL) emits photons due to electronic intersubband transitions in the quantum-wells of a semiconductor heterostructure. The operation of terahertz QCLs at frequencies below the Reststrahlen band in the semiconductor (...), is significantly more challenging as compared to that of the mid-infrared QCLs. Firstly, due to small energy separation between the laser levels various intersubband scattering mechanisms are activated, which make it difficult to selectively depopulate the lower laser level. Additionally, as electrons gain enough kinetic energy in the upper laser level thermally activated longitudinal-optical (LO) phonon scattering reduces the level lifetime and makes it difficult to sustain population inversion at higher temperatures. Secondly, waveguide design for terahertz mode confinement is also more challenging due to higher free-carrier losses in the semiconducting doped regions at the terahertz frequencies. For successful designs reported in this work, the lower radiative state depopulation is achieved by a combination of resonant-tunneling and fast LO phonon scattering, which allow robust operation even at relatively high temperatures. An equally important enabling mechanism for these lasers is the development of metal-metal waveguides, which provide low waveguides losses, and strong mode confinement due to subwavelength mode localization in the vertical dimension. With these techniques some record performances for terahertz QCLs are demonstrated including the highest pulsed operating temperature of 169 K, the highest continuous-wave (cw) operating temperature of 117 K, and the highest optical power output (248 mW in pulsed and 138 mW in cw at 5 K) for any terahertz QCL. Towards the bigger goal of realizing a 1-THz solid-state laser to ultimately bridge the gap between electronic and optical sources of electromagnetic radiation, QCLs with a unique one-well injection scheme, which minimizes intersubband absorption losses that occur at longer wavelengths, are developed. Based on this scheme a QCL operating at 1.59 THz (A - 189 ym) is realized, which is amongst the lowest frequency solid-state lasers that operate without the assistance of a magnetic field. This thesis also reports on the development of distributed-feedback lasers in metal-metal waveguides to obtain single-mode operation, with greater output power and better beam quality. The subwavelength vertical dimension in these waveguides leads to a strongly coupled DFB action and a large reflection from the end-facets, and thus conventional coupled-mode theory is not directly applicable to the DFB design. A design technique with precise control of phase of reflection at the end-facets is developed with the aid of finite-element analysis, and with some additional unique design and fabrication methods, robust DFB operation has been obtained. Single-mode surface-emitting terahertz QCLs operating up to - 150 K are demonstrated, with different grating devices spanning a range of approximately 0.35 THz around v - 3 THz using the same gain medium. A single-lobed far-field radiation pattern, higher output power due to surface-emission, and a relatively small degradation in temperature performance compared to the Fabry-Perot ridge lasers makes these DFB lasers well suited for practical applications that are being targeted by the terahertz quantum-cascade lasers.

Download or read book Towards Room temperature Terahertz Quantum Cascade Lasers written by Chun Wang Ivan Chan and published by . This book was released on 2015 with total page 251 pages. Available in PDF, EPUB and Kindle. Book excerpt: Terahertz Quantum Cascade Lasers (THz QCLs) are arguably the most promising technology today for the compact, efficient generation of THz radiation. Their main limitation is that they require cryogenic cooling, which dominates their ownership cost. Therefore, achieving room-temperature operation is essential for the widespread adoption of THz QCLs. This thesis analyzes the limitations of THz QCL maximum lasing temperature (Tmax) and proposes solutions. THz QCL Tmax is hypothesized to be limited by a fundamental trade-off between gain oscillator strength ful and upper-level lifetime [Tau]. This so-called "ful[Tau] tradeoff" is shown to explain the failure of designs which target [Tau] alone. A solution is proposed in the form of highly diagonal (low ful) active region design coupled with increased doping. Experimental results indicate the strategy to be promising, but heavily doped designs are shown to suffer band-bending effects which may deteriorate performance. In order to treat these band-bending effects, which are typically neglected in previous THz QCL designs, a fast transport simulation tool is developed. Scattering integrals are simplified using the assumption of thermalized sub bands. Results comparable to ensemble Monte Carlo are achieved at a fraction of the computational expense. Carrier leakages to continuum states are also investigated, although they are found to have little effect. Other work in this thesis includes the optimization of double-metal THz waveguides to enable Tmax ~ 200 K, a current world record. Furthermore, laser designs to investigate the leakages of carriers to high-energy subbands and continuum states were fabricated and tested; such parasitic leakages are suggested to be small. Finally, the design of gain media for applications is examined, notably the development of 4.7 THz gain media for OI line detection in astrophysics, and the development of broadband heterogeneous gain media for THz comb generation.

Download or read book Development of Terahertz Quantum cascade VECSELs written by Christopher Curwen and published by . This book was released on 2019 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: Terahertz (THz) quantum-cascade lasers (QCLs) are an emerging semiconductor source of compact, high-power THz radiation. Though first realized more than 15 years ago, THz QCLs continue to suffer from poor beam quality and outcoupling efficiency due to the subwavelength nature of the semiconductor ridge-waveguides typically used. In this thesis, a new technique is discussed for obtaining high power and good beam quality from THz QCLs, the THz quantum-cascade external cavity surface emitting laser (QC-VECSEL). The concept of the QC-VECSEL is to use THz QC-gain material to design a millimeter-scale reflective amplifying surface, or metasurface, for free space THz waves and incorporate it into a free-space THz resonant cavity to provide feedback to the amplification and form a laser. In this manner, the beam shape is determined by the external cavity, which supports fundamental Gaussian solutions. Further, the metasurface itself is composed of a subwavelength array (to prevent diffraction) of surface-coupled QC-elements whose properties, such as phase and polarization response, can be engineered on a unit cell basis allowing for a variety of unique experiments. The power output power of the QC-VECSEL can be scaled by either increasing the size of the metasurface, or increasing the density (or fill factor) of QC-elements across the surface. In this work, large area metasurfaces with high fill-factor have been studied and demonstrated up to 1.35 W of peak output power for a QC-VECSEL operating at 3.4 THz at a heat sink temperature of 4 K. A peak wall-plug efficiency of ~2% is demonstrated, but observation of self lasing from the metasurface at high bias (when no external cavity is provided) in combination with a simultaneous roll-off in VECSEL output power suggests even higher efficiency can be achieved with improved suppression of self-lasing modes. The output beam is well fit to a Gaussian distribution with a 4 degree full-width half-maximum divergence angle. In addition to power and beam quality, the QC-VECSEL opens the door to many interesting and unique studies via engineering of the metasurface properties and external cavity. Much of this thesis describes frequency tuning of QC-VECSELs based on broadband metasurfaces by varying the length of the external cavity. By making the external cavity extremely short (comparable to the operating wavelength), we are able to push all other external cavity modes outside of the gain bandwidth of the metasurface and demonstrate more than 20% fractional single-mode tuning around a center operating frequency of 3.5 THz. Because there are almost no diffraction losses at such a short cavity, the size of the metasurface could be reduced, allowing for continuous wave lasing with up to 20 milliwatts of output power at a heatsink temperature of 77 K, though the output power is highly variable as the reflectance of the output coupler has a strong frequency dependence. At the time of writing this, these are record performances in both frequency tuning and high-temperature continuous wave operation for lasers based on THz QC-gain material. The amount of tuning that be achieved with this approach is limited by the phase response of the metasurface, which squeezes the external cavity modes closer together in the spectral domain. Development of metasurfaces with lower electrical power consumption and higher conversion efficiency for the purpose of improving continuous wave performance. A sparse, patch-based metasurface with reduced power consumption is demonstrated, though the design was not optimal and only showed a 20% reduction in current draw compared to the previously demonstrated metasurfaces. Routes towards improving the performance are discussed. The last subject discussed is the design of a mid-infrared (IR) QC-VECSEL. Due to the large metal losses at mid-IR frequencies compared to THz, the technique used to develop THz QC-VECSELs cannot be directly extended to the mid-IR. We propose a scheme based on a diffraction grating to provide surface coupling of the QC-gain material. Progress on experimental realization is discussed, but lasing has not yet been observed.

Download or read book Toward High Performance Broad band Frequency Comb Operation of Terahertz Quantum Cascade Lasers written by Chao Xu and published by . This book was released on 2017 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent advances in Terahertz Quantum Cascade Laser (THz QCL) development are pushing this technology ever closer to practical application, particularly within the spectroscopic field. For this reason, optimizing the operation of THz QCL frequency combs, which can potentially provide unprecedented accuracy and stability to the optical spectra in a broad frequency band, is of particular interest to the research community. The THz QCLs frequency comb was only recently realized using two separate techniques: either a broad-gain active region or a group velocity dispersion controlled waveguide. However, due to residual optical dispersion from both the gain medium and the cold waveguide, comb formation in these reported THz QCLs can only sustain a limited current injection region and the observed comb frequency range is much narrower than the bandwidth of the designed gain medium. To overcome these limitations, this thesis targets a new THz QCL frequency comb device design that simultaneously exploits the broadband gain active region and a group velocity dispersion (GVD)-compensated waveguide over an octave frequency band of 2-4 THz. In designing a broadband gain active region, two heterogeneous structures are proposed and simulated, with one combining three different bound-to-continuum (BTC) active regions operating at a temperature of 25 K, and another one consisting of four different resonant-phonon (RP) active regions operating at the liquid nitrogen temperature (77 K) or higher. The simulation results show that both active region designs can provide a broadband and 'flat-top' gain profile covering the frequency range from 2 to 4 THz. To design a group velocity dispersion-compensated waveguide, strategies are explored for simulating chirped Distributed Bragg Reflectors (DBRs) that can serve as THz QCL metal-metal waveguides, and one-dimensional (1D) and three-dimensional (3D) modeling approaches are established and verified. A novel two-section chirped DBR is proposed, which provides substantially-improved group delay compensation over a broadband octave frequency range from 2 to 4 THz. Two THz QCL structures are grown using in-house molecular beam epitaxy and THz QCL devices equipped with a metal-metal waveguides are fabricated in the University of Waterloo Quantum-Nano-Centre clean-room fabrication lab. The experimental results demonstrate that the new THz QCL active region design can operate up to a maximum lasing temperature of 111 K, and with a broad lasing spectrum covering frequencies from 2.36 to 2.86 THz under pulse mode, at temperature of 13 K. The combined theoretical and experimental work would ultimately lead to the demonstration of improved THz QCL frequency comb operation over the broadband range from 2 to 4 THz.

Download or read book Spectroscopic Applications of Terahertz Quantum Cascade Lasers written by Tasmim Alam and published by Cuvillier Verlag. This book was released on 2020-10-29 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: Quantum cascade lasers (QCLs) are attractive for high-resolution spectroscopy because they can provide high power and a narrow linewidth. They are particularly promising in the terahertz (THz) range since they can be used as local oscillators for heterodyne detection as well as transmitters for direct detection. However, THz QCL-based technologies are still under development and are limited by the lack of frequency tunability as well as the frequency and output power stability for free-running operation. In this dissertation, frequency tuning and linewidth of THz QCLs are studied in detail by using rotational spectroscopic features of molecular species. In molecular spectroscopy, the Doppler eff ect broadens the spectral lines of molecules in the gas phase at thermal equilibrium. Saturated absorption spectroscopy has been performed that allows for sub-Doppler resolution of the spectral features. One possible application is QCL frequency stabilization based on the Lamb dip. Since the tunability of the emission frequency is an essential requirement to use THz QCL for high-resolution spectroscopy, a new method has been developed that relies on near-infrared (NIR) optical excitation of the QCL rear-facet. A wide tuning range has been achieved by using this approach. The scheme is straightforward to implement, and the approach can be readily applied to a large class of THz QCLs. The frequency and output stability of the local oscillator has a direct impact on the performance and consistency of the heterodyne spectroscopy. A technique has been developed for a simultaneous stabilization of the frequency and output power by taking advantage of the frequency and power regulation by NIR excitation. The results presented in this thesis will enable the routine use of THz QCLs for spectroscopic applications in the near future.

Download or read book Design and Simulation of Terahertz Surface Emitting Quantum Cascade Lasers written by Martin F. Schubert and published by . This book was released on 2005 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Magneto spectroscopy and Development of Terahertz Quantum Cascade Lasers written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work we concentrate our efforts on the generation of laser emission at low THz frequencies (3-1 THz range) employing the quantum cascade technology. Quantum cascade (QC) lasers are unipolar semiconductor lasers based on intersubband transitions in quantum wells that cover a large portion of the Mid and Far Infrared electromagnetic spectrum. Two main research lines have been followed: (i) the development of quantum cascade lasers based on population inversion between parabolic subbands and (ii) the development of low frequency QC lasers based on a three-dimensional electron confinement induced by an external magnetic field. (i) : Gain and laser action have been demonstrated in different systems at frequencies of 3.4 3.6 THz exploiting bound-to-bound and bound-to-continuum optical transition. A QC laser emitting at 3.6 THz and based on a vertical transition and resonant tunneling in a single quantum well has been demonstrated. To overcome the limitations in performance of such a system, an heterostructure laser based on a bound-to-continuum transition has been developed. The structure was the first one to operate above the technologically important temperature of liquid nitrogen. With a further development of the bound-to-continuum design that includes lower state lifetime reduction by optical phonon emission, laser action was successfully achieved at 115 K.A study of different waveguide mechanisms suitable for different THz frequencies has also been carried out. (ii) : THz quantum cascade lasers based on the in-plane confinement introduced by a strong magnetic field applied perpendiculary to the plane of the layers have been developed. A model system based on large single quantum wells (50-60 nm wide) has been exploited to study this gain mechanism. Such an approach led to the extension of the frequency range of operation of QC lasers, with the demonstration of laser action at 1.39 THz (220 mm) which is the lowest frequency observed to-date for this kind of.

Download or read book Efficient THz Lasers and Broadband Amplifiers Based on Quantum Cascade Gain Media written by Xiaowei Cai (S.M.) and published by . This book was released on 2014 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: One of the most important applications for Terahertz (THz) quantum cascade (QC) lasers is to provide compact and powerful frequency-stabilized solid-state sources as local oscillators in heterodyne receivers for astronomical studies. The first part of the thesis is dedicated to the device cavity design, fabrication and characterization of the microstrip antenna coupled third-order distributed feedback QC lasers aimed for 2.060 THz atomic oxygen line. THz travelling-wave QC amplifiers are highly desired to achieve broadband amplification of THz radiation in free space. The second part of the thesis focuses on the development of 4.3 THz travelling-wave QC amplifier by monolithically integrating horn antennas and attaching silicon lenses at the metal-metal waveguide facets.

Download or read book Quantum Cascade Lasers written by Jérôme Faist and published by Oxford University Press. This book was released on 2013-03-14 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the physics, fabrication technology, and applications of the quantum cascade laser.

Download or read book Physics and Applications of Terahertz Radiation written by Matteo Perenzoni and published by Springer. This book was released on 2013-10-16 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the latest advances in the techniques employed to manage the THz radiation and its potential uses. It has been subdivided in three sections: THz Detectors, THz Sources, Systems and Applications. These three sections will allow the reader to be introduced in a logical way to the physics problems of sensing and generation of the terahertz radiation, the implementation of these devices into systems including other components and finally the exploitation of the equipment for real applications in some different field. All of the sections and chapters can be individually addressed in order to deepen the understanding of a single topic without the need to read the whole book. The THz Detectors section will address the latest developments in detection devices based on three different physical principles: photodetection, thermal power detection, rectification. The THz Sources section will describe three completely different generation methods, operating in three separate scales: quantum cascade lasers, free electron lasers and non-linear optical generation. The Systems and Applications section will take care of introducing many of the aspects needed to move from a device to an equipment perspective: control of terahertz radiation, its use in imaging or in spectroscopy, potential uses in security, and will address also safety issues. The text book is at a level appropriate to graduate level courses up to researchers in the field who require a reference book covering all aspects of terahertz technology.

Download or read book Mid Infrared and Terahertz Quantum Cascade Lasers written by Dan Botez and published by Cambridge University Press. This book was released on 2023-09-14 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Learn how the rapidly expanding area of mid-infrared and terahertz photonics has been revolutionized in this comprehensive overview. State-of-the-art practical applications are supported by real-life examples and expert guidance. Also featuring fundamental theory enabling you to improve performance of both existing and future devices.

Download or read book DX Centers written by Elias Munoz Merino and published by Trans Tech Publications Ltd. This book was released on 1994-02-02 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last 25 years, the behavior of donors in III-V alloys has been the subject of a very extensive research effort. The research emphasis on AlGaAs compounds is motivated by the industrial importance of AlGaAs/GaAs heterojunction based devices. As seeing it now, "the DX center problem", the behavior of donors in III-V alloys, has shown to be unexpectedly difficult to understand. To determine the microscopic nature of the DX center is still a challenging problem.