Download or read book Functionalization of Oxidic Semiconductor Surfaces by Covalently Bound Molecular Thin Films written by Alexandra Ostapenko and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Aqueous derived Thin Films and Their Interfacial Interactions with Semiconductor Surfaces written by Milana Cherie Thomas and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal oxide systems are well known for their high dielectric constants, which are important for advanced microelectronics applications. The microelectronics industry currently employs vacuum-based techniques, such as chemical vapor deposition (CVD), to deposit metal oxide films. These vapor-phase deposition techniques suffer due to their slow deposition rates and their use of expensive equipment. Additionally, these processes sometimes require the use of harmful source gases and/or generate corrosive by-products. On the other hand, solution-processed thin films fabricated by spin-coating are advantageous because the process is simple, low cost, and scalable. Aqueous solution deposition is particularly attractive because it offers a green alternative to vapor-phase deposition and has been shown to produce uniform thin films by spin coating on hydrophilic silicon surfaces. However, it has been shown that silicon's native oxide can degrade device performance due to its electronic interfacial states. In addition, aqueousderived thin films suffer from poor electrical performance due to mobile water and hydroxyl protons, often requiring very high temperature anneals to mitigate. Such anneals compromise the interface between the film and the silicon substrate, hence the electrical performance. One effective method to control the interface, and thus improve device performance, is to functionalize the semiconductor surface using wet chemistry. Here, we address the concerns of aqueous thin film deposition and present a method for alleviating the issues associated with current silicon-silicon oxide devices. We use wet chemical functionalization to graft selfassembled monolayers (SAMs) onto oxide-free silicon, then spin-coat an aqueous thin film on top of the SAM layer. The chemical stability of the SAM and the changes that occur at the interfaces between the Si/SAM/film stack during film deposition and dehydration are monitored by in situ Fourier transform infrared spectroscopy (FTIR) and ex situ X-ray photoelectron spectroscopy (XPS). The modification of the Si/SAM interface is studied as a function of annealing temperature, with electrical measurements used as a metric to quantify the effectiveness of the SAM layer to alleviate issues of interfacial defects observed for films on silicon oxide. The results are presented in three parts: (1) a dehydration study of aqueous-derived thin films deposited on silicon oxide, (2) the synthesis of a novel SAM interfacial layer tailored to accommodate aqueous, Al-based precursors and (3) a study to quantify the effectiveness, if any, on the SAM interfacial layer through electrical characterization methods. In the first part, we investigate the mechanism for dehydration of aqueous thin films and present a method to enhance the removal of water from the films. Using in situ FTIR, we find that the addition of a protective capping layer can enhance the dehydration of the thin film and prevent water reabsorption for a period of up to 14 days. In the second part, we present hydrosilylation methods to graft SAMs onto oxide-free silicon surfaces. The results show that it is possible to covalently attach the SAMs to silicon, evidenced by the formation of Si-C (detected by XPS) at the interface between the Si and the SAM. Four phosphonic acid-terminated SAMs are prepared and contact angle measurements are used as a metric for evaluating which can best accommodate aqueous spin-coater solutions. To conclude, we investigate the interface between the SAM layer and an aluminum-based thin film derived from aqueous precursor solutions. Current-voltage and capacitance-voltage measurements are used to quantify the effectiveness of the SAM layer.
Download or read book Encyclopedia of Interfacial Chemistry written by and published by Elsevier. This book was released on 2018-03-29 with total page 5276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Seven Volume Set summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the field. As the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its important to highlight how these technologies enable the design and optimization of functional materials for heterogeneous and electro-catalysts in food production, pollution control, energy conversion and storage, medical applications requiring biocompatibility, drug delivery, and more. This book provides an interdisciplinary view that lies at the intersection of these fields. Presents fundamental knowledge of interfacial chemistry, surface science and electrochemistry and provides cutting-edge research from academics and practitioners across various fields and global regions
Download or read book Functionalization of Semiconductor Surfaces written by Franklin Tao and published by John Wiley & Sons. This book was released on 2012-04-10 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents both fundamental knowledge and latest achievements of this rapidly growing field in the last decade. It presents a complete and concise picture of the the state-of-the-art in the field, encompassing the most active international research groups in the world. Led by contributions from leading global research groups, the book discusses the functionalization of semiconductor surface. Dry organic reactions in vacuum and wet organic chemistry in solution are two major categories of strategies for functionalization that will be described. The growth of multilayer-molecular architectures on the formed organic monolayers will be documented. The immobilization of biomolecules such as DNA on organic layers chemically attached to semiconductor surfaces will be introduced. The patterning of complex structures of organic layers and metallic nanoclusters toward sensing techniques will be presented as well.
Download or read book Nanoporous Materials IV written by Abdel Sayari and published by Elsevier. This book was released on 2005-05-04 with total page 1006 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoporous Materials IV contains the invited lectures and peer-reviewed oral and poster contributions to be presented at the 4th International Symposium on Nanoporous Materials, which will be hosted in Niagara Falls, Ontario, Canada, June 7-10, 2005. This volume covers complementary approaches to and recent advances in the field of nanostructured materials with pore sizes larger than 1nm, such as periodic mesoporous molecular sieves (e.g., MCM-41 and SBA-15) and related materials including clays, ordered mesoporous carbons, colloidal crystal templated materials, porous polymers and sol gels. The broad range of topics covered in relation to the synthesis and characterization of ordered mesoporous materials are of great importance for advanced adsorption, catalytic, separation and environmental processes as well as for the development of nanotechnology. This volume contains over 120 contributions related to the synthesis of ordered mesoporous silicas, organosilicas, nonsiliceous inorganic materials, carbons, polymers and related materials, their characterization and applications in adsorption, catalysis and environmental clean up.* Unique contributions brings readers up-to-date on new research and application developments* Figures and tables supplement comprehensive topics * Extensive author and subject index
Download or read book Photochemistry written by Ian R. Dunkin and published by Royal Society of Chemistry. This book was released on 2009-10-09 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt: The breadth of scientific and technological interests in the general topic of photochemistry is truly enormous and includes, for example, such diverse areas as microelectronics, atmospheric chemistry, organic synthesis, non-conventional photoimaging, photosynthesis, solar energy conversion, polymer technologies, and spectroscopy. This Specialist Periodical Report on Photochemistry aims to provide an annual review of photo-induced processes that have relevance to the above wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology. In order to provide easy access to this vast and varied literature, each volume of Photochemistry comprises sections concerned with photophysical processes in condensed phases, organic aspects which are sub-divided by chromophore type, polymer photochemistry, and photochemical aspects of solar energy conversion. Volume 37 covers literature published from July 2004 to June 2007. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.
Download or read book Lateral Interactions in Organic Functionalization of Semiconductor Surfaces written by Bonggeun Shong and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: As the size scale of current electronic devices is reaching a fundamental physical limit, new and innovative materials solutions are required for continuous progress of semiconductor technologies. Moreover, the development of nanotechnologies comprised of nanoscale materials is burgeoning in various fields. Nanomaterials often show completely different properties compared to their bulk, dominated by surfaces or interfaces. Given the importance of these interfaces, organic functionalization of semiconductor surfaces, or direct attachment of organic molecules, is a topic of increasing interest. By creating interfaces between inorganic and organic functionalities, we may be able to tune the properties of the surface with the versatility and tailorability of organic molecules. In order to utilize organic functionalization in such applications, a deep understanding of the adsorption of the molecules on the surfaces is necessary. In this work, we focus on the fundamental aspects of the adsorption chemistry of organic molecules on a semiconductor surface, and on the lateral interactions between the adsorbed molecules. We explore several molecules' adsorption chemistry on the Ge(100)-2×1 surface. Experimental techniques such as infrared spectroscopy, X-ray photoelectron spectroscopy, and temperature programmed desorption, in addition to theoretical methods including density functional theory calculations and Monte Carlo simulations, are utilized. The strongest interaction that drives the adsorption of the molecules on the surface is local bond formation between the molecules and "dimers" of the Ge(100)-2×1 surface, such as C-dative bonding of isocyanides, dissociative adsorption of phenols, and cycloaddition of nitrobenzene. However, weaker lateral interactions between the adsorbates or between adsorbates and the surface are also present, and they significantly affect the adsorption of the molecules, especially at higher coverages of the adsorbates. In studies of adsorption of small molecules that interact with one dimer, we observe a coverage-dependant spectral shift of tert-butyl isocyanide, and explain self-assembly of methanol and ethylene that had been reported in the literature. Slightly larger molecules can interact with other neighboring dimers: we show that phenol undergoes a shift in molecular orientation due to non-covalent adsorbate-surface interactions, and we determine that coverage-dependent evolution of dual and single adsorption products of benzenediols originates from inter-adsorbate interactions. Overall, this dissertation provides new insights toward the organic functionalization of semiconductor surfaces.
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1992 with total page 1572 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Surfactants in Tribology written by Girma Biresaw and published by CRC Press. This book was released on 2014-11-21 with total page 538 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface science and tribology play very critical roles in many industries. Manufacture and use of almost all consumer and industrial products rely on the application of advanced surface and tribological knowledge. The fourth in a series, Surfactants in Tribology, Volume 4 provides an update on research and development activities connecting surfactants and tribological phenomena. Written by renowned subject matter experts, the book demonstrates how improved design of surfactants can be harnessed to control tribological phenomena. Profusely illustrated and copiously referenced, the chapters also discuss novel approaches to control tribological phenomena using surfactants including green surfactants. It also discusses the underlying tribological and surface science issues relevant to many situations in diverse industries. The information in this volume provides a cutting-edge reference connecting the fields of surfactants and tribology as a way forward to novel, enhanced methods of controlling lubrication, friction, and wear. It reflects the latest developments, highlighting the relevance of surfactants in tribological phenomena in a broad range of industries. As we learn more about the connection between surfactants and tribology, new and improved ways to control lubrication, friction, and wear utilizing surfactants will emerge. This book takes us farther on the path towards this goal.
Download or read book Biointerface Characterization by Advanced IR Spectroscopy written by C.-M. Pradier and published by Elsevier. This book was released on 2011-09-02 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: "There is an increasing interest in research and applications of biosensors and bio-compatability in relation to environmental protection, food and medical safety, implants, early detection of diseases and pollutant detection. This book describes how to characterise amino acids, protein or bacterial strain adsorption on metal and oxide surfaces by using infrared spectroscopy, in a vacuum, in the air or in an aqueous medium. Features description of the principles, experimental setups and parameter interpretation, and the theory for several advanced IR-based techniques for interface characterisation Contains examples which demonstrate the capacity, potential and limits of the IR techniques Helps finding the most adequate mode of analysis."--Publisher.
Download or read book Nanoporous Materials written by and published by . This book was released on 2005 with total page 1020 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Self Assembled Organic Inorganic Nanostructures written by Christian von Borczyskowski and published by CRC Press. This book was released on 2017-03-27 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt: The current state and perspectives in natural and life sciences are strongly linked to the development of novel complex organic-inorganic materials at various levels of organization, including semiconductor quantum dots (QDs) and QD-based nanostructures with unique optical and physico-chemical properties. This book provides a comprehensive description of the morphology and main physico-chemical properties of self-assembled inorganic-dye nanostructures as well as some applications in the field of nanotechnology. It crosses disciplines to examine essential nanoassembly principles of QD interaction with organic molecules, excited state dynamics in nanoobjects, theoretical models, and methodologies. Based on ensemble and single-nanoobject detection, the book quantitatively shows (for the first time on a series of nanoassemblies) that surface-mediated processes (formation of trap states) dictate the probability of several of the most interesting and potentially useful photophysical phenomena (FRET- or non-FRET-induced quenching of QD photoluminescence) observed for colloidal QDs and QD–dye nanoassemblies. Further, nanostructures can be generated by nanolithography and thereafter selectively decorated with dye molecules. A similar approach applies to natural nanosized surface heterogeneities.
Download or read book Handbook of Porous Silicon written by Leigh Canham and published by Springer. This book was released on 2021-01-14 with total page 1000 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Porous Silicon brings together the expertise of a large, international team of almost 100 academic researchers, engineers, and product developers from industry across electronics, medicine, nutrition and consumer care to summarize the field in its entirity with 150 chapters and 5000 references. The volume presents 5 parts which cover fabrication techniques, material properties, characterization techniques, processing and applications. Much attention was given in the the past to its luminescent properties, but increasingly it is the biodegradability, mechanical, thermal and sensing capabilities that are attracting attention. The volume is divided into focussed data reviews with, wherever possible, quantitative rather than qualitative descriptions of both properties and performance. The book is targeted at undergraduates, postgraduates, and experienced researchers.
Download or read book Electrochemistry written by Craig Banks and published by Royal Society of Chemistry. This book was released on 2023-07-12 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing the reader with an up-to-date digest of the most important current research carried out in the field, this volume is compiled and written by leading experts from across the globe. It reviews the trends in electrochemical sensing and its applications and touches on research areas from a diverse range, including microbial fuel cells, 3D printing electrodes for energy conversion and electrochemical and electrochromic colour switching in metal complexes and polymers. Coverage is extensive and will appeal to a broad readership from chemists and biochemists to engineers and materials scientists. The reviews of established and current interests in the field make this book a key reference for researchers in this exciting and developing area.
Download or read book Polymer Functionalized Graphene written by Arun Kumar Nandi and published by Royal Society of Chemistry. This book was released on 2021-06-18 with total page 457 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is an immense variety of research on polymer functionalized graphene (PFG). Functionalization of graphene is necessary for improvement of the compatibility with polymers. Applications of these graphene polymer hybrids include in chemical and biological sensing, photovoltaic devices, supercapacitors and batteries, dielectric materials and drug/gene delivery vehicles. This book will shed light on the synthesis, properties and applications of these new materials, covering two methods (covalent and noncovalent) for producing polymer functionalized graphene. Chapters cover physical, optical, mechanical and electronic properties, applications of polymer functionalized graphene in energy harvesting and storage, and uses in biomedicine and bioengineering. Written by an expert in the field, Polymer Functionalized Graphene will be of interest to graduate students and researchers in polymer chemistry and nanoscience.
Download or read book Nanocrystalline Materials written by Sie-Chin Tjong and published by Newnes. This book was released on 2013-09-02 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition of Nanocrystalline Materials provides updated information on the development and experimental work on the synthesis, properties, and applications of nanocrystalline materials. Nanocrystalline materials with new functionalities show great promise for use in industrial applications — such as reinforcing fillers in novel polymer composites — and substantial progress has been made in the past decade in their synthesis and processing. This book focuses primarily on 1D semiconducting oxides and carbon nanotubes, 2D graphene sheets and 0D nanoparticles (metals and inorganic semiconductors). These materials are synthesized under different compositions, shapes and structures, exhibiting different chemical, physical and mechanical properties from their bulk counterparts. This second edition presents new topics relevant to the fast-paced development of nanoscience and nanotechnology, including the synthesis and application of nanomaterials for drug delivery, energy, printed flash memory, and luminescent materials. With contributions from leading experts, this book describes the fundamental theories and concepts that illustrate the complexity of developing novel nanocrystalline materials, and reviews current knowledge in the synthesis, microstructural characterization, physical and mechanical behavior, and application of nanomaterials. - Investigates the synthesis, characterization, and properties of a large variety of nanocrystalline materials, and their applications in industry - Keeps the prominent challenges in nanomaterials fabrication at the forefront while offering the most up-to-date scientific findings - Written by experts in nanomaterials with academic backgrounds in chemistry, physics, and materials engineering
Download or read book Recent Advances in Thin Films written by Sushil Kumar and published by Springer Nature. This book was released on 2020-08-27 with total page 721 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume comprises the expert contributions from the invited speakers at the 17th International Conference on Thin Films (ICTF 2017), held at CSIR-NPL, New Delhi, India. Thin film research has become increasingly important over the last few decades owing to the applications in latest technologies and devices. The book focuses on current advances in thin film deposition processes and characterization including thin film measurements. The chapters cover different types of thin films like metal, dielectric, organic and inorganic, and their diverse applications across transistors, resistors, capacitors, memory elements for computers, optical filters and mirrors, sensors, solar cells, LED's, transparent conducting coatings for liquid crystal display, printed circuit board, and automobile headlamp covers. This book can be a useful reference for students, researchers as well as industry professionals by providing an up-to-date knowledge on thin films and coatings.
