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Book Extrapolation of Nuclear Waste Glass Aging

Download or read book Extrapolation of Nuclear Waste Glass Aging written by and published by . This book was released on 1984 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Increased confidence is provided to the extrapolation of long-term waste form behavior by comparing the alteration of experimentally aged natural basaltic glass to the condition of the same glass as it has been geologically aged. The similarity between the laboratory and geologic alterations indicates that important aging variables have been identified and incorporated into the laboratory experiments. This provides credibility to the long-term predictions made for waste form borosilicate glasses using similar experimental procedures. In addition, these experiments have demonstrated that the aging processes for natural basaltic glass are relevant to the alteration of nuclear waste glasses, as both appear to react via similar processes. The alteration of a synthetic basaltic glass was measured in MCC-1 tests done at 90°C, a SA/V of 0.1 cm−1 and time periods up to 182 days. Tests were also done using (1) MCC-2 procedures at 190°C, a SA/V of 0.1 cm−1 and time periods up to 91 days and (2) hydration tests in saturated water vapor at 240°C, a SA/V of approx. 106 cm−1, and time periods up to 63 days. These results are compared to alteration observed in natural basaltic glasses of great age. 6 references, 6 figures, 1 table.

Book Natural Glass Analogues to Alteration of Nuclear Waste Glass

Download or read book Natural Glass Analogues to Alteration of Nuclear Waste Glass written by and published by . This book was released on 1990 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this report is to review previous work on the weathering of natural glasses; and to make recommendations for further work with respect to studying the alteration of natural glasses as it relates quantifying rates of dissolution. the first task was greatly simplified by the published papers of Jercinovic and Ewing (1987) and Byers, Jercinovic, and Ewing (1987). The second task is obviously the more difficult of the two and the author makes no claim of completeness in this regard. Glasses weather in the natural environment by reacting with aqueous solutions producing a rind of secondary solid phases. It had been proposed by some workers that the thickness of this rind is a function of the age of the glass and thus could be used to estimate glass dissolution rates. However, Jercinovic and Ewing (1987) point out that in general the rind thickness does not correlate with the age of the glass owing to the differences in time of contact with the solution compared to the actual age of the sample. It should be noted that the rate of glass dissolution is also a function of the composition of both the glass and the solution, and the temperature. Quantification of the effects of these parameters (as well as time of contact with the aqueous phase and flow rates) would thus permit a prediction of the consequences of glass-fluid interactions under varying environmental conditions. Defense high- level nuclear waste (DHLW), consisting primarily of liquid and sludge, will be encapsulated by and dispersed in a borosilicate glass before permanent storage in a HLW repository. This glass containing the DHLW serves to dilute the radionuclides and to retard their dispersion into the environment. 318 refs.

Book Ageing Studies and Lifetime Extension of Materials

Download or read book Ageing Studies and Lifetime Extension of Materials written by Les Mallinson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 659 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first International Conference on Ageing Studies and Lifetime Extension of Materials was held on th July 12-14 , 1999 at St. Catherine's College, Oxford, United Kingdom. Over 230 delegates attended during the three days and heard nearly ninety papers, together with over thirty poster presentations. Sixteen of these papers were keynotes from invited speakers eminent in their field of research. The proceedings were organised into six separate sessions: observation and understanding of real-time and accelerated ageing; experimental techniques; modelling and theoretical studies; lifetime prediction and validation; lifetime extension; and material design for ageing. In doing this, it was hoped to cover most issues of scientific concern inthefield ofmaterials ageing. One important aspect was that the conference did not concentrateon any particular group or type ofmaterial; rather the aim was to attract contributions from workers engaged in ageing studies with as wide a range of materials as possible. In this way, it was hoped that delegates could interactwith and learnfrom those whom they perhapswould not normally come across and that metallurgists could learn from polymer scientists, ceramicists could talk to modellers, and so on, in this important field. A read through the diverse papers contained within these proceedings will confirm that this aim was happily satisfied. Why hold such a meeting? In the modem world, engineered systems are expected to last longer.

Book Natural Glass Analogues to Alteration of Nuclear Waste Glass

Download or read book Natural Glass Analogues to Alteration of Nuclear Waste Glass written by William F. McKenzie and published by . This book was released on 1990 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this report is to review previous work on the weathering of natural glasses; and to make recommendations for further work with respect to studying the alteration of natural glasses as it relates quantifying rates of dissolution. the first task was greatly simplified by the published papers of Jercinovic and Ewing (1987) and Byers, Jercinovic, and Ewing (1987). The second task is obviously the more difficult of the two and the author makes no claim of completeness in this regard. Glasses weather in the natural environment by reacting with aqueous solutions producing a rind of secondary solid phases. It had been proposed by some workers that the thickness of this rind is a function of the age of the glass and thus could be used to estimate glass dissolution rates. However, Jercinovic and Ewing (1987) point out that in general the rind thickness does not correlate with the age of the glass owing to the differences in time of contact with the solution compared to the actual age of the sample. It should be noted that the rate of glass dissolution is also a function of the composition of both the glass and the solution, and the temperature. Quantification of the effects of these parameters (as well as time of contact with the aqueous phase and flow rates) would thus permit a prediction of the consequences of glass-fluid interactions under varying environmental conditions. Defense high- level nuclear waste (DHLW), consisting primarily of liquid and sludge, will be encapsulated by and dispersed in a borosilicate glass before permanent storage in a HLW repository. This glass containing the DHLW serves to dilute the radionuclides and to retard their dispersion into the environment. 318 refs.

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1986 with total page 876 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Glass as a Waste Form and Vitrification Technology

Download or read book Glass as a Waste Form and Vitrification Technology written by National Research Council and published by National Academies Press. This book was released on 1997-03-02 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1985 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Final Program and Abstracts

Download or read book Final Program and Abstracts written by Materials Research Society. Fall Meeting and published by . This book was released on 1984 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Natural Analogues in Radioactive Waste Disposal

Download or read book Natural Analogues in Radioactive Waste Disposal written by B. Come and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 499 pages. Available in PDF, EPUB and Kindle. Book excerpt: In order to validate predictive models of the very long-term processes which affect the performance of radioactive waste repositories, there has been an increased interest in the information and understanding which can be obtained from studying similar mechanisms in natural systems. These "natural analogues", as they are known in the jargon of waste management, have been studied sporadically for many years, but there has been a considerable rejuvenation of interest in the last four years, possibly owing to the fact that performance assessment methodolo gy is gradually maturing to the point where it needs the kind of support which analogues can offer. Since 1982, the Commission of the European Communities has been involved in specific work on natural analogues in the framework of its activities on radioactive waste management, principally within the MIRAGE project which concerns migration of radionuclides in the geosphere. As a consequence, the Commission took the initiative, in 1985, of establish ing a Natural Analogue Working Group (NAWG) whose members can benefit from the overall expertise available for managing their own natural analogue research programmes. In this group, modeller' s requirements and the results of field research are exchanged at regular intervals. A number of wide-ranging investigation programmes, both on national and international scales. are currently underway or being initiated, and several of these have been discussed recently at the NAWG.

Book Waste Immobilization in Glass and Ceramic Based Hosts

Download or read book Waste Immobilization in Glass and Ceramic Based Hosts written by Ian W. Donald and published by John Wiley & Sons. This book was released on 2010-04-01 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: The safe storage in glass-based materials of both radioactiveand non-radioactive hazardous wastes is covered in a single book,making it unique Provides a comprehensive and timely reference source at thiscritical time in waste management, including an extensive andup-to-date bibliography in all areas outlined to waste conversionand related technologies, both radioactive and non-radioactive Brings together all aspects of waste vitrification, drawscomparisons between the different types of wastes and treatments,and outlines where lessons learnt in the radioactive waste fieldcan be of benefit in the treatment of non-radioactive wastes

Book Scientific Basis for Nuclear Waste Management

Download or read book Scientific Basis for Nuclear Waste Management written by and published by . This book was released on 1990 with total page 962 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Scientific Basis for Nuclear Waste Management VI

Download or read book Scientific Basis for Nuclear Waste Management VI written by Douglas G. Brookins and published by North Holland. This book was released on 1983 with total page 840 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Radioactive Waste Management

Download or read book Radioactive Waste Management written by and published by . This book was released on 1981 with total page 630 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Radioactive Waste Processing and Disposal

Download or read book Radioactive Waste Processing and Disposal written by U.S. Nuclear Regulatory Commission and published by . This book was released on 1980 with total page 908 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Radioactive Waste Forms for the Future

Download or read book Radioactive Waste Forms for the Future written by Werner Lutze and published by North Holland. This book was released on 1988 with total page 802 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents a compilation of important information on the full range of radioactive waste forms that have been developed, or at least suggested, for the incorporation of high-level nuclear waste. Many of the results were published in the ''gray literature'' of final reports of national laboratories or in various, generally less available, proceedings volumes. This is the first publication to draw information on nuclear waste forms for high-level wastes together into a single volume. Although borosilicate glass has become the standard waste form, additional research in this compound is still necessary. With improved technology (particularly processing technologies) and with a more detailed knowledge of repository conditions, glasses and second generation waste forms with improved performance properties can be developed. Sustained research programs on nuclear waste form development will yield results that can only add to public confidence and the final, safe disposal of nuclear waste. The aim of this volume is to provide a 'spring board' for these future research efforts. A detailed presentation is given on the properties and performance of non-crystalline waste forms (borosilicate glass, sintered glass, and lead-iron phosphate glass), and crystalline waste forms (Synroc, tailored ceramics, TiO 2 - ceramic matrix, glass-ceramics and FUETAP concrete). A chapter on Novel Waste Forms reviews a number of methods that warrant further development because of their potential superior performance and unique applications. The final chapter includes a tabulated comparison of important waste form properties and an extended discussion on the corrosion process and radiation damage effects for each waste form. Of particular interest is a performance assessment of nuclear waste borosilicate glass and the crystalline ceramic Synroc. This is the first detailed attempt to compare these two important waste forms on the basis of their materials properties. The discussion emphasizes the difficulties in making such a comparison and details the types of data that are required. Each chapter has been written by an expert and includes a current compilation of waste form properties with an extensive list of references. This volume will provide a stimulus for future research as well as useful reference material for scientists working in the field of nuclear waste disposal and materials science.

Book Government Reports Announcements   Index

Download or read book Government Reports Announcements Index written by and published by . This book was released on 1985 with total page 1060 pages. Available in PDF, EPUB and Kindle. Book excerpt: