Download or read book Exploring the Photophysics of Magnetically Doped Semiconductor Nanocrystals written by Christian Soren Erickson and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The inclusion of dopant ions in semiconductor materials provides a useful pathway to add optical, electronic, and magnetic functionality which in turn enable the creation of numerous real-world technologies. Magnetic dopants are of particular interest due to their potential impact in future spintronics and quantum computing applications. Recent advancement in the synthesis of magnetically doped colloidal nanocrystals (NC) have allowed researchers to begin studying the intersection of semiconductors and magnetism in the quantum confined limit where magnetic exchange interactions are dramatically enhanced. The most interesting phenomena resulting from these magnetic exchange interactions is photo-generated magnetic ordering, known as an excitonic magnetic polaron (EMP), observed in Mn2+ doped II-VI materials. This thesis focuses on the recent spectroscopic observation and analysis of (EMPs) at the single NC level. The unprecedent insight gained at the single particle level allows us to experimentally confirm a longstanding EMP hypothesis that crystal anisotropy is a significant factor in by the total EMP stabilization and its orientation. Overall, this work highlights the importance of understanding anisotropic distortions to magneto-optic properties and will help to identify synthetic pathways to take advantage of the relationship between NC anisotropy and magnetic behavior.

Download or read book Helping Observe and Tune Diffusion Using Mn2 Photophysics in Inorganic Nanocrystals After Growth written by Charles J. Barrows and published by . This book was released on 2017 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Doped inorganic crystals exhibit attractive optical, electrical, and magnetic properties that enabled the development of important modern technologies including ruby lasers and silicon microelectronics. The next frontier of doping chemistry is taking place on the nanoscale, where quantum confinement effects dramatically change the photophysical properties of semiconductors. This thesis describes recent advances in the doping of colloidal II-VI semiconductor nanocrystals known as "quantum dots." Interactions between excitonic excited states and Mn2+, a model magnetic dopant, are investigated, primarily by magnetic circular dichroism (MCD) spectroscopy. These data reveal a new mechanism of nanocrystal doping characterized by thermodynamic addition of cation + anion pairs, followed by diffusional mixing. A broad range of equilibrium compositions are achieved, from less than one to hundreds of impurities per quantum dot, and subsequent cation exchange reactions are utilized to develop a model for dopant diffusion in these nanocrystals. Unique spectroscopic signatures are demonstrated, including nonmonotonic magnetization in the low-doping regime and extraordinarily large (whopping) Zeeman splittings in more highly doped quantum dots. Collectively, these studies provide insight into the fundamental processes of diffusion and magnetic exchange on the nanoscale, and may be useful for future spintronics, spin-photonics, and solar energy conversion technologies.

Download or read book Photophysical and Redox Properties of Degenerately Doped Nanocrystals written by Jose Juan Araujo and published by . This book was released on 2020 with total page 83 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the past few decades, semiconductor nanocrystals (NCs) have been the subject of intense interdisciplinary research in both fundamental science and device engineering. Their size-tunable electronic and optical properties, solution processability, and diverse synthetic chemistries make them attractive candidates for applications such as photovoltaics, photocatalysis, and lighting technologies. Besides the well-known quantum confinement effect, the introduction of dopants introduces many more opportunities to tune the electronic, optical, and magnetic properties of NCs. This thesis focuses on NCs containing excess band-like electrons, their photophysical properties, and the redox chemistries associated with these dopants in relation to their charge-compensation mechanisms. Chapter 1 outlines the basic properties of degenerately doped NCs. Methods for preparing degenerately doped NCs are discussed, along with spectroscopic and electrochemical techniques for studying their optical and electronic properties. Chapter 2 describes a new method for preparing photodoped PbSe quantum dots with high electron densities. These high doping densities allow for a careful analysis of the changes in electronic absorption, which reveal conclusive evidence for the assignment of the electronic transitions in their absorption spectra. Chapter 3 employs spectroelectrochemical potentiometry to study the redox properties of excess electrons in Sn4+:In2O3 NCs. An important difference is observed between the redox properties of electrons added by photodoping compared to aliovalent doping. These differences reflect the impact of the charge-compensation motif on determining the stability of charges in degenerately doped NCs.

Download or read book Nanocrystal Quantum Dots Second Edition written by Victor I. Klimov and published by CRC Press. This book was released on 2010-04-21 with total page 485 pages. Available in PDF, EPUB and Kindle. Book excerpt: A review of recent advancements in colloidal nanocrystals and quantum-confined nanostructures, Nanocrystal Quantum Dots is the second edition of Semiconductor and Metal Nanocrystals: Synthesis and Electronic and Optical Properties, originally published in 2003. This new title reflects the book’s altered focus on semiconductor nanocrystals. Gathering contributions from leading researchers, this book contains new chapters on carrier multiplication (generation of multiexcitons by single photons), doping of semiconductor nanocrystals, and applications of nanocrystals in biology. Other updates include: New insights regarding the underlying mechanisms supporting colloidal nanocrystal growth A revised general overview of multiexciton phenomena, including spectral and dynamical signatures of multiexcitons in transient absorption and photoluminescence Analysis of nanocrystal-specific features of multiexciton recombination A review of the status of new field of carrier multiplication Expanded coverage of theory, covering the regime of high-charge densities New results on quantum dots of lead chalcogenides, with a focus studies of carrier multiplication and the latest results regarding Schottky junction solar cells Presents useful examples to illustrate applications of nanocrystals in biological labeling, imaging, and diagnostics The book also includes a review of recent progress made in biological applications of colloidal nanocrystals, as well as a comparative analysis of the advantages and limitations of techniques for preparing biocompatible quantum dots. The authors summarize the latest developments in the synthesis and understanding of magnetically doped semiconductor nanocrystals, and they present a detailed discussion of issues related to the synthesis, magneto-optics, and photoluminescence of doped colloidal nanocrystals as well. A valuable addition to the pantheon of literature in the field of nanoscience, this book presents pioneering research from experts whose work has led to the numerous advances of the past several years.

Download or read book Colloidal Semiconductor Nanocrystals Synthesis Properties and Applications written by Vladimir Lesnyak and published by Frontiers Media SA. This book was released on 2020-01-06 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Comprehensive Nanoscience and Technology written by and published by Academic Press. This book was released on 2010-10-29 with total page 2785 pages. Available in PDF, EPUB and Kindle. Book excerpt: From the Introduction: Nanotechnology and its underpinning sciences are progressing with unprecedented rapidity. With technical advances in a variety of nanoscale fabrication and manipulation technologies, the whole topical area is maturing into a vibrant field that is generating new scientific research and a burgeoning range of commercial applications, with an annual market already at the trillion dollar threshold. The means of fabricating and controlling matter on the nanoscale afford striking and unprecedented opportunities to exploit a variety of exotic phenomena such as quantum, nanophotonic and nanoelectromechanical effects. Moreover, researchers are elucidating new perspectives on the electronic and optical properties of matter because of the way that nanoscale materials bridge the disparate theories describing molecules and bulk matter. Surface phenomena also gain a greatly increased significance; even the well-known link between chemical reactivity and surface-to-volume ratio becomes a major determinant of physical properties, when it operates over nanoscale dimensions. Against this background, this comprehensive work is designed to address the need for a dynamic, authoritative and readily accessible source of information, capturing the full breadth of the subject. Its six volumes, covering a broad spectrum of disciplines including material sciences, chemistry, physics and life sciences, have been written and edited by an outstanding team of international experts. Addressing an extensive, cross-disciplinary audience, each chapter aims to cover key developments in a scholarly, readable and critical style, providing an indispensible first point of entry to the literature for scientists and technologists from interdisciplinary fields. The work focuses on the major classes of nanomaterials in terms of their synthesis, structure and applications, reviewing nanomaterials and their respective technologies in well-structured and comprehensive articles with extensive cross-references. It has been a constant surprise and delight to have found, amongst the rapidly escalating number who work in nanoscience and technology, so many highly esteemed authors willing to contribute. Sharing our anticipation of a major addition to the literature, they have also captured the excitement of the field itself in each carefully crafted chapter. Along with our painstaking and meticulous volume editors, full credit for the success of this enterprise must go to these individuals, together with our thanks for (largely) adhering to the given deadlines. Lastly, we record our sincere thanks and appreciation for the skills and professionalism of the numerous Elsevier staff who have been involved in this project, notably Fiona Geraghty, Megan Palmer and Greg Harris, and especially Donna De Weerd-Wilson who has steered it through from its inception. We have greatly enjoyed working with them all, as we have with each other.

Download or read book Halide Perovskites written by Tze-Chien Sum and published by John Wiley & Sons. This book was released on 2019-03-25 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Real insight from leading experts in the field into the causes of the unique photovoltaic performance of perovskite solar cells, describing the fundamentals of perovskite materials and device architectures. The authors cover materials research and development, device fabrication and engineering methodologies, as well as current knowledge extending beyond perovskite photovoltaics, such as the novel spin physics and multiferroic properties of this family of materials. Aimed at a better and clearer understanding of the latest developments in the hybrid perovskite field, this is a must-have for material scientists, chemists, physicists and engineers entering or already working in this booming field.

Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2692 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Comprehensive Nanoscience and Nanotechnology written by and published by Academic Press. This book was released on 2019-01-02 with total page 1881 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Nanoscience and Technology, Second Edition, Five Volume Set allows researchers to navigate a very diverse, interdisciplinary and rapidly-changing field with up-to-date, comprehensive and authoritative coverage of every aspect of modern nanoscience and nanotechnology. Presents new chapters on the latest developments in the field Covers topics not discussed to this degree of detail in other works, such as biological devices and applications of nanotechnology Compiled and written by top international authorities in the field

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 994 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Photophysics of Molecular Materials written by Guglielmo Lanzani and published by John Wiley & Sons. This book was released on 2006-05-12 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon based pi-conjugated materials offer a broad range of applications, going from molecular electronics and single molecule devices to nanotechnology, plastic electronics and optoelectronics. The proper physical description of such materials is in between that of molecular solids and that of low-dimensional covalent semiconductors. This book is a comprehensive review of their elementary excitations processes and dynamics, which merges the two viewpoints, sometimes very different if not contrasting. In each chapter, a broad tutorial introduction provides a solid physical background to the topic, which is further discussed based on recent experimental results obtained via state-of-the-art techniques. Both the molecular, intra-chain character and the solid state, inter-molecular physics is addressed. Reports on single molecule and single polymer chain spectroscopy introduce the on-site phenomena. Several chapters are dedicated to nano-probes, steady state and transient spectroscopies. The highly ordered state, occurring in single crystals, is also discussed thoroughly. Finally, less conventional tools such as THz spectroscopy are discussed in detail. The book provides a useful introduction to the field for newcomers, and a valid reference for experienced researchers in the field.

Download or read book Laser Ablation in Liquids written by Guowei Yang and published by CRC Press. This book was released on 2012-02-22 with total page 1166 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the fundamental concepts and physical and chemical aspects of pulsed laser ablation of solid targets in liquid environments and its applications in the preparation of nanomaterials and fabrication of nanostructures. The areas of focus include basic thermodynamic and kinetic processes of laser ablation in liquids, and its applic

Download or read book Semiconductor Nanocrystals written by Alexander L. Efros and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 277 pages. Available in PDF, EPUB and Kindle. Book excerpt: A physics book that covers the optical properties of quantum-confined semiconductor nanostructures from both the theoretical and experimental points of view together with technological applications. Topics to be reviewed include quantum confinement effects in semiconductors, optical adsorption and emission properties of group IV, III-V, II-VI semiconductors, deep-etched and self assembled quantum dots, nanoclusters, and laser applications in optoelectronics.

Download or read book Magnetic Resonance of Semiconductors and Their Nanostructures written by Pavel G. Baranov and published by Springer. This book was released on 2017-03-20 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explains different magnetic resonance (MR) techniques and uses different combinations of these techniques to analyze defects in semiconductors and nanostructures. It also introduces novelties such as single defects MR and electron-paramagnetic-resonance-based methods: electron spin echo, electrically detected magnetic resonance, optically detected magnetic resonance and electron-nuclear double resonance – the designated tools for investigating the structural and spin properties of condensed systems, living matter, nanostructures and nanobiotechnology objects. Further, the authors address problems existing in semiconductor and nanotechnology sciences that can be resolved using MR, and discuss past, current and future applications of MR, with a focus on advances in MR methods. The book is intended for researchers in MR studies of semiconductors and nanostructures wanting a comprehensive review of what has been done in their own and related fields of study, as well as future perspectives.

Download or read book Semiconductor Nanomaterials written by Challa S. S. R. Kumar and published by John Wiley & Sons. This book was released on 2010-04-05 with total page 499 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book series Nanomaterials for the Life Sciences, provides an in-depth overview of all nanomaterial types and their uses in the life sciences. Each volume is dedicated to a specific material class and covers fundamentals, synthesis and characterization strategies, structure-property relationships and biomedical applications. The series brings nanomaterials to the Life Scientists and life science to the Materials Scientists so that synergies are seen and developed to the fullest. Written by international experts of various facets of this exciting field of research, the series is aimed at scientists of the following disciplines: biology, chemistry, materials science, physics, bioengineering, and medicine, together with cell biology, biomedical engineering, pharmaceutical chemistry, and toxicology, both in academia and fundamental research as well as in pharmaceutical companies. VOLUME 6 - Semiconductor Nanomaterials

Download or read book Semiconductor Nanostructures written by Dieter Bimberg and published by Springer Science & Business Media. This book was released on 2008-06-03 with total page 369 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reducing the size of a coherently grown semiconductor cluster in all three directions of space to a value below the de Broglie wavelength of a charge carrier leads to complete quantization of the energy levels, density of states, etc. Such “quantum dots” are more similar to giant atoms in a dielectric cage than to classical solids or semiconductors showing a dispersion of energy as a function of wavevector. Their electronic and optical properties depend strongly on their size and shape, i.e. on their geometry. By designing the geometry by controlling the growth of QDs, absolutely novel possibilities for material design leading to novel devices are opened. This multiauthor book written by world-wide recognized leaders of their particular fields and edited by the recipient of the Max-Born Award and Medal 2006 Professor Dieter Bimberg reports on the state of the art of the growing of quantum dots, the theory of self-organised growth, the theory of electronic and excitonic states, optical properties and transport in a variety of materials. It covers the subject from the early work beginning of the 1990s up to 2006. The topics addressed in the book are the focus of research in all leading semiconductor and optoelectronic device laboratories of the world.

Download or read book Optical Properties of Semiconductor Nanocrystals written by S. V. Gaponenko and published by Cambridge University Press. This book was released on 1998-10-28 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examines the optical properties of low-dimensional semiconductor structures, a hot research area - for graduate students and researchers.