Download or read book Experimental Studies of Oxygen Isotope Fractionation in the Carbonic Acid System at 15 25 and 40 C written by William Cory Beck and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In light of recent studies that show oxygen isotope fractionation in carbonate minerals to be a function of HCO3 and CO32- concentrations, the oxygen isotope fractionation and exchange between water and components of the carbonic acid system (HCO3-, CO3 2-, and CO2(aq)) were investigated at 15°, 25°, and 40°C. To investigate oxygen isotope exchange between HCO3-, CO3 2-, and H2O, NaHCO3 solutions were prepared and the pH was adjusted over a range of 2 to 12 by the addition of small amounts of HCl or NaOH. After thermal, chemical, and isotopic equilibrium was attained, BaCl2 was added to the NaHCO3 solutions. This resulted in immediate BaCO3 precipitation; thus, recording the isotopic composition of the dissolved inorganic carbon. Data from experiments at 15°, 25°, and 40°C (1 atm) show that the oxygen isotope fractionation between HCO3- and H2O as a function of temperature is governed by the equation:1000 ;HCO3--H2O = 2.66 + 0.05(106T-2) + 1.18 + 0.52.where is the fractionation factor and T is in kelvins. The temperature dependence of oxygen isotope fractionation between CO32- and H2O is 1000 CO32--H2O = 2.28 + 0.03(106T-2) - 1.50 + 0.29. The oxygen isotope fractionation between CO2(aq) and H2O was investigated by acid stripping CO2(aq) from low pH solutions; these data yield the following equation:1000 CO2(aq)-H2O = 2.52 + 0.03(106T-2) + 12.12 + 0.33. The kinetics of oxygen isotope exchange were also investigated. The half-times for exchange between HCO3- and H2O were 3.6, 1.4, and 0.25 h at 15°, 25°, and 40°C, respectively. The half-times for exchange between CO2 and H2O were 1200, 170, and 41 h at 15, 25, and 40 (degrees) C, respectively. These results show that the 18O of the total dissolved inorganic carbon species can vary as much as 17% at a constant temperature. This could result in temperature independent variations in the 18O of precipitated carbonate minerals, especially in systems that are not chemically buffered.
Download or read book Stable Isotope Geochemistry written by Jochen Hoefs and published by Springer Science & Business Media. This book was released on 2009-01-13 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stable Isotope Geochemistry is an introduction to the use of stable isotopes in the geosciences. It is subdivided into three parts: theoretical and experimental principles; fractionation processes of light and heavy elements; the natural variations of geologically important reservoirs. Since the application of stable isotopes to earth sciences has grown in the last few years, a new edition appears necessary. Recent progress in analysing the rare isotopes of certain elements for instance allow the distinction between mass-dependent and mass-independent fractionations. Special emphasis has been given to the growing field of "heavy" elements. Many new references have been added, which will enable quick access to recent literature. For students and scientists alike the book will be a primary source of information with regard to how and where stable isotopes can be used to solve geological problems.
Download or read book Separating arsenic oxyanions from natural waters for oxygen isotope analysis written by Tang, Xiaohui and published by KIT Scientific Publishing. This book was released on 2014-08-14 with total page 246 pages. Available in PDF, EPUB and Kindle. Book excerpt: This study has developed a complete procedure for the measurement of oxygen isotopes in arsenic oxyanions in natural waters by using different adsorbents. The experimental results of kinetic exchange of oxygen between AsO43- and water show that the entire exchange procedure happens in a very short time at different pH conditions and temperatures.
Download or read book Triple Oxygen Isotope Geochemistry written by Ilya N. Bindeman and published by Walter de Gruyter GmbH & Co KG. This book was released on 2021-02-22 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 86 of Reviews in Mineralogy and Geochemistry concentrates on understanding the variations among ratios of the three isotopes of oxygen, with primary emphasis on terrestrial systems. Triple oxygen isotope variations may be related to large, mass-independent fractionation effects such observed in the Earth atmosphere or may be small and related to minute variations due to purely mass-dependent processes. Recent advancements in analytical resolution now allow for the identification of processes and distinct reservoirs that were formerly hidden in the paradigm of a "single terrestrial fractionation line". New, high-resolution measurements are accompanied by advances in theoretical calculations that dovetail with empirical calibrations and applications throughout this volume. 14 chapters span a wide range of subjects: from ab-initio theoretical approaches to observation of triple oxygen isotope variations in the Earth litho-, hydro- and atmosphere.
Download or read book Geomicrobiological Properties and Processes of Travertine written by Akihiro Kano and published by Springer. This book was released on 2018-09-20 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents basic knowledge and key objectives of research of geological, geochemical, and microbial properties and processes in travertines, carbonate deposits precipitated from calcareous hot springs. Much of the contents are based on the authors’ researches performed in Japan and Indonesia over the last decade. Travertine is one of the most active sedimentary systems, which have a potential impact on the Earth’s environment. It is also an accessible epitome of the Earth’s history, cultivating ancestral bacteria and representing a modern analog for ancient stromatolites. Readers can learn how integration of various scopes and methods unveils mysterious phenomena in travertine and can find clues for considering the early history of the Earth and life. This book includes a monographic chapter on Japanese onsens, or hot springs, which may help tourists to select the best places to enjoy the unique features of travertine.
Download or read book Wood Burned Monogram Creative Journal K written by Belle Journals and published by . This book was released on 2018-04-21 with total page 150 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dot grid journal - monogram letter K - faux wood grain look with a branded letter. Pages feature evenly spaced 5mm dotted matrix. This 150-page notebook - sketchbook - planner diary is perfect for bullet journal, hand lettering, calligraphy, zen tangles, doodling, planning daily activities, organizing shopping lists, strategic planning, note-taking, sketching, sketch notes, poetry, goal setting... whatever you can imagine. The possibilities are endless! Great for horizontal, vertical, diagonal and free-hand creativity. Includes name and contact page. The lovely soft cream color paper is easy on the eyes. Dots are light enough to move to the background once each page is filled in. Thicker than standard paperback paper means minimal ghosting. Bullet journal style dot grid notebook features: 7 x 10 inch paperback 168 Pages 5MM dot grid matrix 33 dots across 48 dots down - 6 dots per inch Name and contact page Easy wipe-clean glossy cover Printed on soft cream color paper which is easy on the eyes.The cream paper is thicker than standard paperback paper which means minimal ghosting. Each page is filled with light dots--dark enough to see, not too dark to cover. Dots are light enough to move to the background once each page is filled in. Perfect for bullet journal, hand lettering/calligraphy, zen tangles, doodling, planning daily activities, organizing shopping lists, strategic planning, note-taking, sketching, sketch notes, poetry, outlining your next book, social media post calendar, goal setting... whatever you can imagine. The possibilities are endless! The dot grid matrix is great for horizontal, vertical, diagonal and free-hand creativity. A great gift for coworker, husband, wife, mother, father, boyfriend, girlfriend, son, daughter, brother or sister.
Download or read book The Geologic Time Scale 2012 written by F M Gradstein and published by Elsevier. This book was released on 2012-08-14 with total page 1176 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Geologic Time Scale 2012, winner of a 2012 PROSE Award Honorable Mention for Best Multi-volume Reference in Science from the Association of American Publishers, is the framework for deciphering the history of our planet Earth. The authors have been at the forefront of chronostratigraphic research and initiatives to create an international geologic time scale for many years, and the charts in this book present the most up-to-date, international standard, as ratified by the International Commission on Stratigraphy and the International Union of Geological Sciences. This 2012 geologic time scale is an enhanced, improved and expanded version of the GTS2004, including chapters on planetary scales, the Cryogenian-Ediacaran periods/systems, a prehistory scale of human development, a survey of sequence stratigraphy, and an extensive compilation of stable-isotope chemostratigraphy. This book is an essential reference for all geoscientists, including researchers, students, and petroleum and mining professionals. The presentation is non-technical and illustrated with numerous colour charts, maps and photographs. The book also includes a detachable wall chart of the complete time scale for use as a handy reference in the office, laboratory or field. The most detailed international geologic time scale available that contextualizes information in one single reference for quick desktop access Gives insights in the construction, strengths, and limitations of the geological time scale that greatly enhances its function and its utility Aids understanding by combining with the mathematical and statistical methods to scaled composites of global succession of events Meets the needs of a range of users at various points in the workflow (researchers extracting linear time from rock records, students recognizing the geologic stage by their content)
Download or read book The Cnidaria Past Present and Future written by Stefano Goffredo and published by Springer. This book was released on 2016-09-07 with total page 842 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents a broad panorama of the current status of research of invertebrate animals considered belonging to the phylum Cnidaria, such as hydra, jellyfish, sea anemone, and coral. In this book the Cnidarians are traced from the Earth’s primordial oceans, to their response to the warming and acidifying oceans. Due to the role of corals in the carbon and calcium cycles, various aspects of cnidarian calcification are discussed. The relation of the Cnidaria with Mankind is approached, in accordance with the Editors’ philosophy of bridging the artificial schism between science, arts and Humanities. Cnidarians' encounters with humans result in a broad spectrum of medical emergencies that are reviewed. The final section of the volume is devoted to the role of Hydra and Medusa in mythology and art.
Download or read book Oxygen Isotope Fractionation Studies in Mineral Systems written by James R. O'Neil and published by . This book was released on 1963 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Master s Theses Directories written by and published by . This book was released on 2005 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Education, arts and social sciences, natural and technical sciences in the United States and Canada".
Download or read book CO2 in Seawater Equilibrium Kinetics Isotopes written by R.E. Zeebe and published by Elsevier. This book was released on 2001-10-15 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon dioxide is the most important greenhouse gas after water vapor in the atmosphere of the earth. More than 98% of the carbon of the atmosphere-ocean system is stored in the oceans as dissolved inorganic carbon. The key for understanding critical processes of the marine carbon cycle is a sound knowledge of the seawater carbonate chemistry, including equilibrium and nonequilibrium properties as well as stable isotope fractionation. Presenting the first coherent text describing equilibrium and nonequilibrium properties and stable isotope fractionation among the elements of the carbonate system. This volume presents an overview and a synthesis of these subjects which should be useful for graduate students and researchers in various fields such as biogeochemistry, chemical oceanography, paleoceanography, marine biology, marine chemistry, marine geology, and others. The volume includes an introduction to the equilibrium properties of the carbonate system in which basic concepts such as equilibrium constants, alkalinity, pH scales, and buffering are discussed. It also deals with the nonequilibrium properties of the seawater carbonate chemistry. Whereas principle of chemical kinetics are recapitulated, reaction rates and relaxation times of the carbonate system are considered in details. The book also provides a general introduction to stable isotope fractionation and describes the partitioning of carbon, oxygen, and boron isotopes between the species of the carbonate system. The appendix contains formulas for the equilibrium constants of the carbonate system, mathematical expressions to calculate carbonate system parameters, answers to exercises and more.
Download or read book Fractionation of the Carbon Isotopes During Photosynthesis written by J.C. Vogel and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 29 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Economic Geology written by and published by . This book was released on 2005 with total page 708 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Triple Oxygen Isotopes written by Huiming Bao and published by Cambridge University Press. This book was released on 2019-08-29 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The 'detective' power of stable isotopes for processes that occurred in the past, and for elucidating mechanisms at the molecular level, has impressed researchers over the past 100 years, since the time when isotopes of elements were first discovered. While most are interested in the normalized abundance ratios of two isotopes of an element, further power was unleashed when researchers investigated the relationship of three or more isotopes of the same element, e.g. 16O, 17O, and 18O for oxygen. This Element focuses on the history of discovery of triple isotope effects, the conceptual framework behind these effects, and major lines of development in the past few years of triple oxygen isotope research.
Download or read book Oxygen and Hydrogen Isotopic Fractionation Factors Determined in Experimental Clay water Systems written by Jean Bryna Kulla and published by . This book was released on 1984 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Stable Isotope Geochemistry written by Jochen Hoefs and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stable Isotope Geochemistry is an introduction to the use of stable isotopes in the fields of geoscience. It is subdivided into three parts: - theoretical and experimental principles; - fractionation mechanisms of light elements; - the natural variations of geologically important reservoirs. In this updated 4th edition many of the chapters have been expanded, especially those on techniques and environmental aspects. The main focus is on recent results and new developments. For students and scientists alike the book will be a primary reference with regard to how and where stable isotopes can be used to solve geological problems.
Download or read book Isotope Tracers in Catchment Hydrology written by C. Kendall and published by Elsevier. This book was released on 2012-12-02 with total page 870 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book represents a new "earth systems" approach to catchments that encompasses the physical and biogeochemical interactions that control the hydrology and biogeochemistry of the system. The text provides a comprehensive treatment of the fundamentals of catchment hydrology, principles of isotope geochemistry, and the isotope variability in the hydrologic cycle -- but the main focus of the book is on case studies in isotope hydrology and isotope geochemistry that explore the applications of isotope techniques for investigating modern environmental problems. Isotope Tracers in Catchment Hydrology is the first synthesis of physical hydrology and isotope geochemistry with catchment focus, and is a valuable reference for professionals and students alike in the fields of hydrology, hydrochemistry, and environmental science. This important interdisciplinary text provides extensive guidelines for the application of isotope techniques for all investigatores facing the challenge of protecting precious water, soil, and ecological resources from the ever-increasing problems associated with population growth and environmental change, including those from urban development and agricultural land uses.
