Download or read book Experimental Design Applications for Modeling and Assessing Carbon Dioxide Sequestration in Saline Aquifers written by and published by . This book was released on 2014 with total page 83 pages. Available in PDF, EPUB and Kindle. Book excerpt: This project was a computer modeling effort to couple reservoir simulation and ED/RSM using Sensitivity Analysis, Uncertainty Analysis, and Optimization Methods, to assess geologic, geochemical, geomechanical, and rock-fluid effects and factors on CO2 injectivity, capacity, and plume migration. The project objective was to develop proxy models to simplify the highly complex coupled geochemical and geomechanical models in the utilization and storage of CO2 in the subsurface. The goals were to investigate and prove the feasibility of the ED/RSM processes and engineering development, and bridge the gaps regarding the uncertainty and unknowns of the many geochemical and geomechanical interacting parameters in the development and operation of anthropogenic CO2 sequestration and storage sites. The bottleneck in this workflow is the high computational effort of reactive transport simulation models and large number of input variables to optimize with ED/RSM techniques. The project was not to develop the reactive transport, geomechanical, or ED/RSM software, but was to use what was commercially and/or publically available as a proof of concept to generate proxy or surrogate models. A detailed geologic and petrographic mineral assemblage and geologic structure of the doubly plunging anticline was defined using the USDOE RMOTC formations of interest data (e.g., Lower Sundance, Crow Mountain, Alcova Limestone, and Red Peak). The assemblage of 23 minerals was primarily developed from literature data and petrophysical (well log) analysis. The assemblage and structure was input into a commercial reactive transport simulator to predict the effects of CO2 injection and complex reactions with the reservoir rock. Significant impediments were encountered during the execution phase of the project. The only known commercial reactive transport simulator was incapable of simulating complex geochemistry modeled in this project. Significant effort and project funding was expended to determine the limitations of both the commercial simulator and the Lawrence Berkeley National Laboratory (LBNL) R & D simulator, TOUGHREACT available to the project. A simplified layer cake model approximating the volume of the RMOTC targeted reservoirs was defined with 1-3 minerals eventually modeled with limited success. Modeling reactive transport in porous media requires significant computational power. In this project, up to 24 processors were used to model a limited mineral set of 1-3 minerals. In addition, geomechanical aspects of injecting CO2 into closed, semi-open, and open systems in various well completion methods was simulated. Enhanced Oil Recovery (EOR) as a storage method was not modeled. A robust and stable simulation dataset or base case was developed and used to create a master dataset with embedded instructions for input to the ED/RSM software. Little success was achieved toward the objective of the project using the commercial simulator or the LBNL simulator versions available during the time of this project. Several hundred realizations were run with the commercial simulator and ED/RSM software, most having convergence problems and terminating prematurely. A proxy model for full field CO2 injection sequestration utilization and storage was not capable of being developed with software available for this project. Though the chemistry is reasonably known and understood, based on the amount of effort and huge computational time required, predicting CO2 sequestration storage capacity in geologic formations to within the program goals of ±30% proved unsuccessful.

Download or read book Experimental and Numarical Investigation of Carbon Dioxide Sequestration in Deep Saline Aquifers written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Started as an EOR technique to produce oil, injection of carbon dioxide which is essentially a greenhouse gas is becoming more and more important. Although there are a number of mathematical modeling studies, experimental studies are limited and most studies focus on injection into sandstone reservoirs as opposed to carbonate ones. This study presents the results of computerized tomography (CT) monitored laboratory experiments to characterize relevant chemical reactions associated with injection and storage of CO2 in carbonate formations. Porosity changes along the core plugs and the corresponding permeability changes are reported for varying CO2 injection rates, temperature and salt concentrations. CT monitored experiments are designed to model fast near well bore flow and slow reservoir flows. It was observed that either a permeability improvement or a permeability reduction can be obtained. The trend of change in rock properties is very case dependent because it is related to distribution of pores, brine composition and as well the thermodynamic conditions. As the salt concentration decreased the porosity and thus the permeability decrease was less pronounced. Calcite scaling is mainly influenced by orientation and horizontal flow resulted in larger calcite deposition compared to vertical flow. The duration of CO2 – rock contact and the amount of area contacted by CO2 seems to have a more pronounced effect compared to rate effect. The experiments were modeled using a multi-phase, non-isothermal commercial simulator where solution and deposition of calcite were considered by the means of chemical reactions. The calibrated model was then used to analyze field scale injections and to model the potential CO2 sequestration capacity of a hypothetical carbonate aquifer formation. It was observed that solubility and hydrodynamic storage of CO2 is larger compared to mineral trapping.

Download or read book Petrophysical Modeling and Simulation Study of Geological CO2 Sequestration written by Xianhui Kong and published by . This book was released on 2014 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Global warming and greenhouse gas (GHG) emissions have recently become the significant focus of engineering research. The geological sequestration of greenhouse gases such as carbon dioxide (CO2) is one approach that has been proposed to reduce the greenhouse gas emissions and slow down global warming. Geological sequestration involves the injection of produced CO2 into subsurface formations and trapping the gas through many geological mechanisms, such as structural trapping, capillary trapping, dissolution, and mineralization. While some progress in our understanding of fluid flow in porous media has been made, many petrophysical phenomena, such as multi-phase flow, capillarity, geochemical reactions, geomechanical effect, etc., that occur during geological CO2 sequestration remain inadequately studied and pose a challenge for continued study. It is critical to continue to research on these important issues. Numerical simulators are essential tools to develop a better understanding of the geologic characteristics of brine reservoirs and to build support for future CO2 storage projects. Modeling CO2 injection requires the implementation of multiphase flow model and an Equation of State (EOS) module to compute the dissolution of CO2 in brine and vice versa. In this study, we used the Integrated Parallel Accurate Reservoir Simulator (IPARS) developed at the Center for Subsurface Modeling at The University of Texas at Austin to model the injection process and storage of CO2 in saline aquifers. We developed and implemented new petrophysical models in IPARS, and applied these models to study the process of CO2 sequestration. The research presented in this dissertation is divided into three parts. The first part of the dissertation discusses petrophysical and computational models for the mechanical, geological, petrophysical phenomena occurring during CO2 injection and sequestration. The effectiveness of CO2 storage in saline aquifers is governed by the interplay of capillary, viscous, and buoyancy forces. Recent experimental data reveals the impact of pressure, temperature, and salinity on interfacial tension (IFT) between CO2 and brine. The dependence of CO2-brine relative permeability and capillary pressure on IFT is also clearly evident in published experimental results. Improved understanding of the mechanisms that control the migration and trapping of CO2 in the subsurface is crucial to design future storage projects for long-term, safe containment. We have developed numerical models for CO2 trapping and migration in aquifers, including a compositional flow model, a relative permeability model, a capillary model, an interfacial tension model, and others. The heterogeneities in porosity and permeability are also coupled to the petrophysical models. We have developed and implemented a general relative permeability model that combines the effects of pressure gradient, buoyancy, and capillary pressure in a compositional and parallel simulator. The significance of IFT variations on CO2 migration and trapping is assessed. The variation of residual saturation is modeled based on interfacial tension and trapping number, and a hysteretic trapping model is also presented. The second part of this dissertation is a model validation and sensitivity study using coreflood simulation data derived from laboratory study. The motivation of this study is to gain confidence in the results of the numerical simulator by validating the models and the numerical accuracies using laboratory and field pilot scale results. Published steady state, core-scale CO2/brine displacement results were selected as a reference basis for our numerical study. High-resolution compositional simulations of brine displacement with supercritical CO2 are presented using IPARS. A three-dimensional (3D) numerical model of the Berea sandstone core was constructed using heterogeneous permeability and porosity distributions based on geostatistical data. The measured capillary pressure curve was scaled using the Leverett J-function to include local heterogeneity in the sub-core scale. Simulation results indicate that accurate representation of capillary pressure at sub-core scales is critical. Water drying and the shift in relative permeability had a significant impact on the final CO2 distribution along the core. This study provided insights into the role of heterogeneity in the final CO2 distribution, where a slight variation in porosity gives rise to a large variation in the CO2 saturation distribution. The third part of this study is a simulation study using IPARS for Cranfield pilot CO2 sequestration field test, conducted by the Bureau of Economic Geology (BEG) at The University of Texas at Austin. In this CO2 sequestration project, a total of approximately 2.5 million tons supercritical CO2 was injected into a deep saline aquifer about ~10000 ft deep over 2 years, beginning December 1st 2009. In this chapter, we use the simulation capabilities of IPARS to numerically model the CO2 injection process in Cranfield. We conducted a corresponding history-matching study and got good agreement with field observation. Extensive sensitivity studies were also conducted for CO2 trapping, fluid phase behavior, relative permeability, wettability, gravity and buoyancy, and capillary effects on sequestration. Simulation results are consistent with the observed CO2 breakthrough time at the first observation well. Numerical results are also consistent with bottomhole injection flowing pressure for the first 350 days before the rate increase. The abnormal pressure response with rate increase on day 350 indicates possible geomechanical issues, which can be represented in simulation using an induced fracture near the injection well. The recorded injection well bottomhole pressure data were successfully matched after modeling the fracture in the simulation model. Results also illustrate the importance of using accurate trapping models to predict CO2 immobilization behavior. The impact of CO2/brine relative permeability curves and trapping model on bottom-hole injection pressure is also demonstrated.

Download or read book Investigation of Multiple Well Injections for Carbon Dioxide Sequestration in Aquifers written by Abhishek Joshi and published by . This book was released on 2014 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the amount of CO2 present in the atmospheres is increasing due to combustion emission, it is becoming more and more important to find ways to reduce greenhouse gas emissions. One of the ways to do that is through carbon sequestration. Saline formations (aquifers) provide viable destination for carbon sequestration. The storage potential in these reservoirs is estimated at several thousands of Giga Tonnes (Gt) of CO2. Even though the capacity is substantial, the process of filling this capacity has a lot of challenges. Injection of large volumes within short period of time increases the formation pressure (which should be below fracture pressure) very fast. For each particular reservoir, injection capacity should be identified based on which CO2 can be injected within a particular injection area and time. In order to achieve this, an in-depth sensitivity study needs to be done on the various reservoir parameters such as thickness, rock compressibility, permeability, porosity, reservoir temperature and pressure, aquifer fracture pressure, number and placement of injection's wells. The objective of my Master's thesis work is finding ways to increase the storage injection capacity based on reservoir parameters and optimizing the well placement by identifying and developing analytical and numerical tools to do so. The research also focuses on conducting a sensitivity analysis on these parameters in order to find out the optimal injection scenario to obtain the amount of maximum CO2 sequestration in a reservoir. This study can help in the CO2 sequestration capacity predictions and screening suitable reservoir based on technical and economic criteria. In order to derive the injection capacity of the reservoir based on the reservoir parameters, two analytical models of multiple well injections were studied: i) Single-phase (Brine injection in a brine reservoir and ii) Two phase model (CO2 injection in a brine reservoir). In both cases, the aim is to analyse the pressure build-up and the results are discussed in terms of comparison with numerical simulations. Although analytical modeling is less accurate (compare to numerical) and restricted to vertical well injection it allows large number of realizations for sensitivity analysis to find significant patterns of the process and reduces the number of numerical simulations needed at final stages of optimization. Analysis is done by considering infinite acting, homogenous, isotropic and isothermal reservoir condition. The Ei-function approximation method was used to simulate results on pressure profile across the reservoir. Once we have a validated model, we look into increasing the CO2 injection capacity of saline aquifers by applying the multiple wells injection strategy. This was done by looking at the well interferences based on superposition principle and mapping the pressure build-up profile in the reservoir. Various approaches were used to get maximum injection capacity.

Download or read book Geological Sequestration of Carbon Dioxide written by Luigi Marini and published by Elsevier. This book was released on 2006-10-12 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: The contents of this monograph are two-scope. First, it intends to provide a synthetic but complete account of the thermodynamic and kinetic foundations on which the reaction path modeling of geological CO2 sequestration is based. In particular, a great effort is devoted to review the thermodynamic properties of CO2 and of the CO2-H2O system and the interactions in the aqueous solution, the thermodynamic stability of solid product phases (by means of several stability plots and activity plots), the volumes of carbonation reactions, and especially the kinetics of dissolution/precipitation reactions of silicates, oxides, hydroxides, and carbonates. Second, it intends to show the reader how reaction path modeling of geological CO2 sequestration is carried out. To this purpose the well-known high-quality EQ3/6 software package is used. Setting up of computer simulations and obtained results are described in detail and used EQ3/6 input files are given to guide the reader step-by-step from the beginning to the end of these exercises. Finally, some examples of reaction-path- and reaction-transport-modeling taken from the available literature are presented. The results of these simulations are of fundamental importance to evaluate the amounts of potentially sequestered CO2, and their evolution with time, as well as the time changes of all the other relevant geochemical parameters (e.g., amounts of solid reactants and products, composition of the aqueous phase, pH, redox potential, effects on aquifer porosity). In other words, in this way we are able to predict what occurs when CO2 is injected into a deep aquifer.* Provides applications for investigating and predicting geological carbon dioxide sequestration* Reviews the geochemical literature in the field* Discusses the importance of geochemists in the multidisciplinary study of geological carbon dioxide sequestration

Download or read book Data Driven Analytics for the Geological Storage of CO2 written by Shahab Mohaghegh and published by CRC Press. This book was released on 2018-05-20 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: Data-driven analytics is enjoying unprecedented popularity among oil and gas professionals. Many reservoir engineering problems associated with geological storage of CO2 require the development of numerical reservoir simulation models. This book is the first to examine the contribution of artificial intelligence and machine learning in data-driven analytics of fluid flow in porous environments, including saline aquifers and depleted gas and oil reservoirs. Drawing from actual case studies, this book demonstrates how smart proxy models can be developed for complex numerical reservoir simulation models. Smart proxy incorporates pattern recognition capabilities of artificial intelligence and machine learning to build smart models that learn the intricacies of physical, mechanical and chemical interactions using precise numerical simulations. This ground breaking technology makes it possible and practical to use high fidelity, complex numerical reservoir simulation models in the design, analysis and optimization of carbon storage in geological formations projects.

Download or read book Geologic Carbon Sequestration written by V. Vishal and published by Springer. This book was released on 2016-05-11 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: This exclusive compilation written by eminent experts from more than ten countries, outlines the processes and methods for geologic sequestration in different sinks. It discusses and highlights the details of individual storage types, including recent advances in the science and technology of carbon storage. The topic is of immense interest to geoscientists, reservoir engineers, environmentalists and researchers from the scientific and industrial communities working on the methodologies for carbon dioxide storage. Increasing concentrations of anthropogenic carbon dioxide in the atmosphere are often held responsible for the rising temperature of the globe. Geologic sequestration prevents atmospheric release of the waste greenhouse gases by storing them underground for geologically significant periods of time. The book addresses the need for an understanding of carbon reservoir characteristics and behavior. Other book volumes on carbon capture, utilization and storage (CCUS) attempt to cover the entire process of CCUS, but the topic of geologic sequestration is not discussed in detail. This book focuses on the recent trends and up-to-date information on different storage rock types, ranging from deep saline aquifers to coal to basaltic formations.

Download or read book Development of Science Based Permitting Guidance for Geological Sequestration of CO2 in Deep Saline Aquifers Based on Modeling and Risk Assessment written by and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Underground carbon storage may become one of the solutions to address global warming. However, to have an impact, carbon storage must be done at a much larger scale than current CO2 injection operations for enhanced oil recovery. It must also include injection into saline aquifers. An important characteristic of CO2 is its strong buoyancy--storage must be guaranteed to be sufficiently permanent to satisfy the very reason that CO2 is injected. This long-term aspect (hundreds to thousands of years) is not currently captured in legislation, even if the U.S. has a relatively well-developed regulatory framework to handle carbon storage, especially in the operational short term. This report proposes a hierarchical approach to permitting in which the State/Federal Government is responsible for developing regional assessments, ranking potential sites (''General Permit'') and lessening the applicant's burden if the general area of the chosen site has been ranked more favorably. The general permit would involve determining in the regional sense structural (closed structures), stratigraphic (heterogeneity), and petrophysical (flow parameters such as residual saturation) controls on the long-term fate of geologically sequestered CO2. The state-sponsored regional studies and the subsequent local study performed by the applicant will address the long-term risk of the particular site. It is felt that a performance-based approach rather than a prescriptive approach is the most appropriate framework in which to address public concerns. However, operational issues for each well (equivalent to the current underground injection control-UIC-program) could follow regulations currently in place. Area ranking will include an understanding of trapping modes. Capillary (due to residual saturation) and structural (due to local geological configuration) trappings are two of the four mechanisms (the other two are solubility and mineral trappings), which are the most relevant to the time scale of interest. The most likely pathways for leakage, if any, are wells and faults. We favor a defense-in-depth approach, in which storage permanence does not rely upon a primary seal only but assumes that any leak can be contained by geologic processes before impacting mineral resources, fresh ground water, or ground surface. We examined the Texas Gulf Coast as an example of an attractive target for carbon storage. Stacked sand-shale layers provide large potential storage volumes and defense-in-depth leakage protection. In the Texas Gulf Coast, the best way to achieve this goal is to establish the primary injection level below the total depth of most wells (>2,400 m-8,000 ft). In addition, most faults, particularly growth faults, present at the primary injection level do not reach the surface. A potential methodology, which includes an integrated approach comprising the whole chain of potential events from leakage from the primary site to atmospheric impacts, is also presented. It could be followed by the State/Federal Government, as well as by the operators.

Download or read book MODELING OF CARBON DIOXIDE SEQUESTRATION IN A DEEP SALINE AQUIFER written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: ABSTRACT MODELING OF CARBON DIOXIDE SEQUESTRATION IN A DEEP SALINE AQUIFER BAÞBUÐ, Baþar M.S., Department of Petroleum and Natural Gas Engineering Supervisor : Prof. Dr. Fevzi Gümrah July 2005, 245 pages CO2 is one of the hazardous greenhouse gases causing significant changes in the environment. The sequestering CO2 in a suitable geological medium can be a feasible method to avoid the negative effects of CO2 emissions in the atmosphere. CO2 sequestration is the capture of, separation, and long-term storage of CO2 in underground geological environments. A case study was simulated regarding the CO2 sequestration in a deep saline aquifer. The compositional numerical model (GEM) of the CMG software was used to study the ability of the selected aquifer to accept and retain the large quantities of injected CO2 at supercritical state for long periods of time (200 years). A field-scale model with two injectors and six water producers and a single-well aquifer model cases were studied. In a single-well aquifer model, the effects of parameters such as vertical to horizontal permeability ratio, aquifer pressure, injection rate, and salinity on the sequestration process were examined and the sensitivity analyses were performed after simulating the field-scale model. The supercritical CO2, one-state fluid which exhibits both gas and liquid-like properties, and gaseous CO2 were sequestered in the forms of free CO2 bubble, dissolved CO2 in brine and precipitated CO2 with calcite mineral in a deep saline aquifer. The isothermal condition was assumed during injection and sequestration processes. The change in porosity and permeability values that might have occurred due to mineralization and CO2 adsorption on rock were not considered in this study. Vertical to horizontal permeability ratio and initial pressure conditions were the most dominating parameters affecting the CO2 saturation in each layer of the aquifer whereas CO2 injection rate influenced CO2 saturation in middle and bot.

Download or read book Negative Emissions Technologies and Reliable Sequestration written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2019-04-08 with total page 511 pages. Available in PDF, EPUB and Kindle. Book excerpt: To achieve goals for climate and economic growth, "negative emissions technologies" (NETs) that remove and sequester carbon dioxide from the air will need to play a significant role in mitigating climate change. Unlike carbon capture and storage technologies that remove carbon dioxide emissions directly from large point sources such as coal power plants, NETs remove carbon dioxide directly from the atmosphere or enhance natural carbon sinks. Storing the carbon dioxide from NETs has the same impact on the atmosphere and climate as simultaneously preventing an equal amount of carbon dioxide from being emitted. Recent analyses found that deploying NETs may be less expensive and less disruptive than reducing some emissions, such as a substantial portion of agricultural and land-use emissions and some transportation emissions. In 2015, the National Academies published Climate Intervention: Carbon Dioxide Removal and Reliable Sequestration, which described and initially assessed NETs and sequestration technologies. This report acknowledged the relative paucity of research on NETs and recommended development of a research agenda that covers all aspects of NETs from fundamental science to full-scale deployment. To address this need, Negative Emissions Technologies and Reliable Sequestration: A Research Agenda assesses the benefits, risks, and "sustainable scale potential" for NETs and sequestration. This report also defines the essential components of a research and development program, including its estimated costs and potential impact.

Download or read book Geochemistry of Geologic CO2 Sequestration written by Donald J. DePaolo and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-12-17 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 77 of Reviews in Mineralogy and Geochemistry focuses on important aspects of the geochemistry of geological CO2 sequestration. It is in large part an outgrowth of research conducted by members of the U.S. Department of Energy funded Energy Frontier Research Center (EFRC) known as the Center for Nanoscale Control of Geologic CO2 (NCGC). Eight out of the 15 chapters have been led by team members from the NCGC representing six of the eight partner institutions making up this center - Lawrence Berkeley National Laboratory (lead institution, D. DePaolo - PI), Oak Ridge National Laboratory, The Ohio State University, the University of California Davis, Pacific Northwest National Laboratory, and Washington University, St. Louis.

Download or read book Uncertainty Analysis of Carbon Sequestration in an Inclined Deep Saline Aquifer written by Guang Yang and published by . This book was released on 2012 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt: Geologic Carbon Sequestration (GCS) is a proposed means to reduce atmospheric carbon dioxide (CO2 ). In Wyoming, GCS is proposed for the Nugget Sandstone, an eolian sandstone exhibiting permeability heterogeneity. Using subsets of static site characterization data, this study builds a suite of increasingly complex geologic model families for the Nugget Sandstone in the Wyoming Overthrust Belt, which is an inclined deep saline aquifer. These models include: a homogeneous model (FAM1), a stationary geostatistical facies model with constant petrophyscial properties in each facies (FAM2a), a stationary geostatistical petrophysical model (FAM2b), a stationary facies model with sub-facies petrophysical variability (FAM3), and a non-stationary facies model (with sub-facies variability) conditioned to soft data (FAM4). These families, representing increasingly sophisticated conceptual models built with increasing amounts of site data, were simulated with the same CO2 injection test (50-year duration at ~1/3 Mt per year), followed by a 2000-year monitoring phase. Based on the Design of Experiment (DOE), an efficient sensitivity analysis (SA) is conducted for all model families, systematically varying uncertain input parameters, while assuming identical production scenario (i.e., well configuration, rate, BHP constraint) and boundary condition (i.e., model is part of a larger semi-infinite system where the injected gas can flow out). Results are compared among the families at different time scales to identify parameters that have first order impact on select simulation outcomes. For predicting CO2 storage ratio (SR) and brine leakage, at both time scales (i.e., end of injection and end of monitoring), more geologic factors are revealed to be important as model complexity is increased, while the importance of engineering factors is simultaneously diminished. In predicting each of the trapped and dissolved gases, when model is of greater complexity, more geologic factors are identified as important with increasing time. This effect, however, cannot be revealed by simpler models. Based on results of the SA, a response surface (RS) analysis is conducted next to generate prediction envelopes of the outcomes which are further compared among the model families. Results suggest a large uncertainty range in the SR given the uncertainties of the parameter and modeling choices. At the end of injection, SR ranges from 0.18 to 0.38; at the end of monitoring, SR ranges from 0.71 to 0.98. In predicting the SR, during the entire simulation time, uncertainty ranges of FAM2b, FAM3, and FAM4 are larger than those of FAM1 and FAM2a, since the former models incorporate more geological complexities. The uncertainty range also changes with time and with the model families. By the end of injection, prediction envelops of all families are more or less similar. Over this shorter time scale, where heterogeneities near the injection site are not significantly different among the different model representations, simpler models can capture the uncertainty in the predicted SR. During the monitoring phase, prediction envelope of each family deviates gradually from one another, reflecting the different (evolving) large scale heterogeneity experienced by each family as plume migrates and grows continuously. Compared to FAM4 (i.e., the most sophisticated model), all other families estimate higher mean SRs. The lesser the amount of site data are incorporated (i.e., lesser geological complexities), the greater the estimated mean SR. In terms of magnitude and range of the uncertainty, prediction envelop of FAM3 is the closest to that of FAM4, while FAM2b's uncertainty range is the largest and FAM1 and FAM2a's ranges are small. Finally, end-member gas plume footprint for each family is established from results of the RS designs (i.e., corresponding to SR minimum, median, and maximum). For FAM1 and FAM2a, at each time scale inspected, the end-member gas plume footprints are not as drastically different as in FAM2b, 3, and 4, since their SR uncertainty range is comparatively small. However, for families of greater geological complexity (i.e., FAM2b, FAM3, and FAM4), the differences are much more significant: gas plume of minimum SR sits around the wellbore and doesn't migrate far, while gas plume of maximum SR migrates a great distance from the wellbore. To summarize, geologic factors and associated conceptual model uncertainty can dominate the uncertainty in predicting SR, brine leakage, and plume footprint. At the study site, better characterization of geologic data such as porosity-permeability transform and facies correlation structure, can lead to significantly reduced uncertainty in predictions. Given the current uncertainty in parameters and modeling choices, CO2 plume predicted by the majority of the simulation runs is either trapped near the injection site (e.g., due to low formation permeability and its heterogeneity) or is gravity-stable under conditions of higher permeability and lower temperature gradient, suggesting a low leakage risk. The inclined Nugget Sandstone at the study site appears to be a viable candidate for safe GCS in this region.

Download or read book CO2 Sequestration in Saline Aquifer written by Biniam Zerai and published by . This book was released on 2005 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Geological Storage of CO2 in Deep Saline Formations written by Auli Niemi and published by Springer. This book was released on 2017-02-24 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers readers a comprehensive overview, and an in-depth understanding, of suitable methods for quantifying and characterizing saline aquifers for the geological storage of CO2. It begins with a general overview of the methodology and the processes that take place when CO2 is injected and stored in deep saline-water-containing formations. It subsequently presents mathematical and numerical models used for predicting the consequences of CO2 injection. This book provides descriptions of relevant experimental methods, from laboratory experiments to field scale site characterization and techniques for monitoring spreading of the injected CO2 within the formation. Experiences from a number of important field injection projects are reviewed, as are those from CO2 natural analog sites. Lastly, the book presents relevant risk management methods. Geological storage of CO2 is widely considered to be a key technology capable of substantially reducing the amount of CO2 released into the atmosphere, thereby reducing the negative impacts of such releases on the global climate. Around the world, projects are already in full swing, while others are now being initiated and executed to demonstrate the technology. Deep saline formations are the geological formations considered to hold the highest storage potential, due to their abundance worldwide. To date, however, these formations have been relatively poorly characterized, due to their low economic value. Accordingly, the processes involved in injecting and storing CO2 in such formations still need to be better quantified and methods for characterizing, modeling and monitoring this type of CO2 storage in such formations must be rapidly developed and refined.

Download or read book Thermochemical based Poroelastic Modelling of Salt Crystallization and a New Multiphase Flow Experiment written by Florian Osselin and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In a context of international reduction of greenhouse gases emissions, CCS (ce{CO2} Capture and Storage) appears as a particularly interesting midterm solution. Indeed, geological storage capacities may raise to several millions of tons of ce{CO2} injected per year, allowing to reduce substantially the atmospheric emissions of this gas. One of the most interesting targets for the development of this solution are the deep saline aquifers. These aquifers are geological formations containing brine whose salinity is often higher than sea water's, making it unsuitable for human consumption. However, this solution has to cope with numerous technical issues, and in particular, the precipitation of salt initially dissolved in the aquifer brine. Consequences of this precipitation are multiple, but the most important is the modification of the injectivity i.e. the injection capacity. Knowledge of the influence of the precipitation on the injectivity is particularly important for both the storage efficiency and the storage security and durability. The aim of this PhD work is to compare the relative importance of negative (clogging) and positive (fracturing) phenomena following ce{CO2} injection and salt precipitation. Because of the numerous simulations and modelling results in the literature describing the clogging of the porosity, it has been decided to focus on the mechanical effects of the salt crystallization and the possible deformation of the host rock. A macroscopic and microscopic modelling has then been developed, taking into account two possible modes of evaporation induced by the spatial distribution of residual water, in order to predict the behavior of a porous material subjected to the drying by carbon dioxide injection. Results show that crystallization pressure created by the growth of a crystal in a confined medium can reach values susceptible to locally exceed the mechanic resistance of the host rock, highlighting the importance of these phenomena in the global mechanical behavior of the aquifer. At the experimental level, the study of a rock core submitted to the injection of supercritical carbon dioxide has been proceeded on a new reactive percolation prototype in order to obtain the evolution of permeabilities in conditions similar to these of a deep saline aquifer.

Download or read book Site Specific Geochemical Modeling of Groundwater and CO2 Interactions written by Elizabeth Johns and published by . This book was released on 2014 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are concerns that anthropogenic emissions of carbon dioxide into the atmosphere are contributing to climate change and ocean acidification. Currently scientists are using geochemical modeling of groundwater, rock and carbon dioxide interactions for geologic carbon sequestration purposes, as possible methods to mitigate the problem. Geologic carbon sequestration is a process of mitigation that has the potential to reduce the impact of carbon dioxide emissions into the atmosphere through the injection of carbon dioxide into a saline aquifer. This study investigated the extent to which carbon dioxide can be sequestered in the Lamotte Formation, a Cambrian aged saline aquifer, due to solubility and mineral trapping, at three well sites. A comparison of the geochemical suitability of the three sites in North-Central Missouri was also conducted. Site specific data such as temperature, carbon dioxide fugacity, pH, mineral content and groundwater composition were the input parameters needed to simulate the sequestration of carbon dioxide in a saline aquifer (Geochemist's Workbench software). The simulation results showed more aqueous CO2 could be sequestered at the Luecke Site for both the injection period (91.4 g/kg) and post-injection period (81.5 g/kg), while more solid phase CO2 could be sequestered at the Thomas Hill Site for the injection period (5.06 g/kg) and the first 500 years of the post-injection period (16.32 g/kg).

Download or read book Carbon Dioxide Sequestration Into Deep Saline Aquifers written by Emre Özgür and published by LAP Lambert Academic Publishing. This book was released on 2010-05 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: The analytical and numerical modeling of CO2 sequestration in deep saline aquifers having different properties was studied with diffusion and convection mechanisms. The complete dissolution of CO2 in the aquifer by diffusion took thousands, even millions of years. In diffusion dominated system, an aquifer with 100 m thickness saturated with CO2 after 10,000,000 years. It was much earlier in convective dominant system. In diffusion process, the dissolution of CO2 in aquifer increased with porosity increase; however, in convection dominant process dissolution of CO2 in aquifer decreased with porosity increase. The increase in permeability accelerated the dissolution of CO2 in aquifer significantly, which was due to increasing velocity. The results of convective dominant mechanism in aquifers with 1md and 10 md permeability values were so close to that of diffusion dominated system. For the aquifer having permeability higher than 10 md, the convection mechanism began to dominate gradually and it became fully convection dominated system for 50 md and higher permeability values.