Download or read book Experimental and Kinetic Modeling Study of the Pyrolysis and Oxidation of 1 5 hexadiene The Reactivity of Allylic Radicals and Their Role in the Formation of Aromatics written by and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Aromatic radical Oxidation Kinetics written by and published by . This book was released on 1992 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research progress in three areas is described. Progress achieved in the extensive experimental investigation of the oxidation and pyrolysis of cyclopentadiene is summarized first. The mechanistic implications of the experimental work are also discussed. An overview is given of the successful research effort devoted to modelling flow reactor toluene and benzene oxidation data. As mentioned above, one of the ultimate goals of this research is to develop a comprehensive, detailed chemical kinetic model of aromatics oxidation. The success already achieved in this effort augurs well for reaching the broader goal. The toluene/benzene model, however, does have a number of shortcomings which suggest the need for further experiments. A description is given of attempts to predict the laminar flame speeds of toluene and benzene. The difficulties encountered and the solutions found highlight the need of an examination of certain chemical steps that impact most the energy release of a burning aromatic fuel.

Download or read book The Mechanisms of Pyrolysis Oxidation and Burning of Organic Materials written by Leo Aloysius Wall and published by . This book was released on 1972 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Aromatic radical Oxidation Kinetics Annual Report written by and published by . This book was released on 1992 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research progress in three areas is described. Progress achieved in the extensive experimental investigation of the oxidation and pyrolysis of cyclopentadiene is summarized first. The mechanistic implications of the experimental work are also discussed. An overview is given of the successful research effort devoted to modelling flow reactor toluene and benzene oxidation data. As mentioned above, one of the ultimate goals of this research is to develop a comprehensive, detailed chemical kinetic model of aromatics oxidation. The success already achieved in this effort augurs well for reaching the broader goal. The toluene/benzene model, however, does have a number of shortcomings which suggest the need for further experiments. A description is given of attempts to predict the laminar flame speeds of toluene and benzene. The difficulties encountered and the solutions found highlight the need of an examination of certain chemical steps that impact most the energy release of a burning aromatic fuel.

Download or read book Experimental and Kinetic Modeling Study of Cyclohexane and Its Mono alkylated Derivatives Combustion written by Zhandong Wang and published by Springer. This book was released on 2018-01-23 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes’ combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control.

Download or read book Flame Structure and Processes written by R. M. Fristrom and published by Oxford University Press on Demand. This book was released on 1995 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: Documents the numerous experimental techniques used to study flame microstructure, and provides an interdisciplinary overview of how such research is revealing exciting new information about combustion and high temperature processes.

Download or read book Unimolecular Reactions written by Kenneth A. Holbrook and published by John Wiley & Sons. This book was released on 1996-07-10 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Representing major advances in this area of gas kinetics in the last twenty-five years, Unimolecular Reactions has been considerably rewritten to include important recent progress in both theory and experiment. New chapters cover the treatment of reactions with 'loose' transition states, the Master equation, and the approximate forms of Statistical Adiabatic Channel Theory. Extensive illustrations highlight both established activation methods and newer techniques such as the use of infrared and UV lasers, overtone excitation, molecular beam experiments and mass spectrometric methods.

Download or read book Comprehensive Dissertation Index written by and published by . This book was released on 1989 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Orbital Interaction Theory of Organic Chemistry written by Arvi Rauk and published by John Wiley & Sons. This book was released on 2004-04-07 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: A practical introduction to orbital interaction theory and its applications in modern organic chemistry Orbital interaction theory is a conceptual construct that lies at the very heart of modern organic chemistry. Comprising a comprehensive set of principles for explaining chemical reactivity, orbital interaction theory originates in a rigorous theory of electronic structure that also provides the basis for the powerful computational models and techniques with which chemists seek to describe and exploit the structures and thermodynamic and kinetic stabilities of molecules. Orbital Interaction Theory of Organic Chemistry, Second Edition introduces students to the fascinating world of organic chemistry at the mechanistic level with a thoroughly self-contained, well-integrated exposition of orbital interaction theory and its applications in modern organic chemistry. Professor Rauk reviews the concepts of symmetry and orbital theory, and explains reactivity in common functional groups and reactive intermediates in terms of orbital interaction theory. Aided by numerous examples and worked problems, he guides readers through basic chemistry concepts, such as acid and base strength, nucleophilicity, electrophilicity, and thermal stability (in terms of orbital interactions), and describes various computational models for describing those interactions. Updated and expanded, this latest edition of Orbital Interaction Theory of Organic Chemistry includes a completely new chapter on organometallics, increased coverage of density functional theory, many new application examples, and worked problems. The text is complemented by an interactive computer program that displays orbitals graphically and is available through a link to a Web site. Orbital Interaction Theory of Organic Chemistry, Second Edition is an excellent text for advanced-level undergraduate and graduate students in organic chemistry. It is also a valuable working resource for professional chemists seeking guidance on interpreting the quantitative data produced by modern computational chemists.

Download or read book Thermal and Catalytic Processes in Petroleum Refining written by Serge Raseev and published by CRC Press. This book was released on 2003-02-26 with total page 1185 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text examines the thermal and catalytic processes involved in the refining of petroleum including visbreaking, coking, pyrolysis, catalytic cracking, oligomerization, alkylation, hydrofining, hydroisomerization, hydrocracking, and catalytic reforming. It analyzes the thermodynamics, reaction mechanisms, and kinetics of each process, as well as

Download or read book Frontier Orbitals and Organic Chemical Reactions written by Ian Fleming and published by John Wiley & Sons. This book was released on 1976-01-01 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a basic introduction to frontier orbital theory with a review of its applications in organic chemistry. Assuming the reader is familiar with the concept of molecular orbital as a linear combination of atomic orbitals the book is presented in a simple style, without mathematics making it accessible to readers of all levels.

Download or read book Organic Chemistry written by Pierre Vogel and published by John Wiley & Sons. This book was released on 2019-10-07 with total page 1382 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides the background, tools, and models required to understand organic synthesis and plan chemical reactions more efficiently Knowledge of physical chemistry is essential for achieving successful chemical reactions in organic chemistry. Chemists must be competent in a range of areas to understand organic synthesis. Organic Chemistry provides the methods, models, and tools necessary to fully comprehend organic reactions. Written by two internationally recognized experts in the field, this much-needed textbook fills a gap in current literature on physical organic chemistry. Rigorous yet straightforward chapters first examine chemical equilibria, thermodynamics, reaction rates and mechanisms, and molecular orbital theory, providing readers with a strong foundation in physical organic chemistry. Subsequent chapters demonstrate various reactions involving organic, organometallic, and biochemical reactants and catalysts. Throughout the text, numerous questions and exercises, over 800 in total, help readers strengthen their comprehension of the subject and highlight key points of learning. The companion Organic Chemistry Workbook contains complete references and answers to every question in this text. A much-needed resource for students and working chemists alike, this text: -Presents models that establish if a reaction is possible, estimate how long it will take, and determine its properties -Describes reactions with broad practical value in synthesis and biology, such as C-C-coupling reactions, pericyclic reactions, and catalytic reactions -Enables readers to plan chemical reactions more efficiently -Features clear illustrations, figures, and tables -With a Foreword by Nobel Prize Laureate Robert H. Grubbs Organic Chemistry: Theory, Reactivity, and Mechanisms in Modern Synthesis is an ideal textbook for students and instructors of chemistry, and a valuable work of reference for organic chemists, physical chemists, and chemical engineers.

Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 11845 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

Download or read book Reverse Engineering of Rubber Products written by Saikat Das Gupta and published by CRC Press. This book was released on 2013-09-19 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reverse engineering is widely practiced in the rubber industry. Companies routinely analyze competitors’ products to gather information about specifications or compositions. In a competitive market, introducing new products with better features and at a faster pace is critical for any manufacturer. Reverse Engineering of Rubber Products: Concepts, Tools, and Techniques explains the principles and science behind rubber formulation development by reverse engineering methods. The book describes the tools and analytical techniques used to discover which materials and processes were used to produce a particular vulcanized rubber compound from a combination of raw rubber, chemicals, and pigments. A Compendium of Chemical, Analytical, and Physical Test Methods Organized into five chapters, the book first reviews the construction of compounding ingredients and formulations, from elastomers, fillers, and protective agents to vulcanizing chemicals and processing aids. It then discusses chemical and analytical methods, including infrared spectroscopy, thermal analysis, chromatography, and microscopy. It also examines physical test methods for visco-elastic behavior, heat aging, hardness, and other features. A chapter presents important reverse engineering concepts. In addition, the book includes a wide variety of case studies of formula reconstruction, covering large products such as tires and belts as well as smaller products like seals and hoses. Get Practical Insights on Reverse Engineering from the Book’s Case Studies Combining scientific principles and practical advice, this book brings together helpful insights on reverse engineering in the rubber industry. It is an invaluable reference for scientists, engineers, and researchers who want to produce comparative benchmark information, discover formulations used throughout the industry, improve product performance, and shorten the product development cycle.

Download or read book Silicon in Polymer Synthesis written by H.R. Kricheldorf and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 507 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon in Polymer Synthesis gives the first concise overview of silicon used for the synthesis and modification of polymers. The first section gives an introduction to the topic. The subsequent chapters detail the current status both from the basic research as well as from the industrial application points of view.

Download or read book Organic Chemistry written by Robert V. Hoffman and published by John Wiley & Sons. This book was released on 2004-11-26 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ideal for those who have previously studies organic chemistry butnot in great depth and with little exposure to organic chemistry ina formal sense. This text aims to bridge the gap betweenintroductory-level instruction and more advanced graduate-leveltexts, reviewing the basics as well as presenting the more advancedideas that are currently of importance in organic chemistry. * Provides students with the organic chemistry background requiredto succeed in advanced courses. * Practice problems included at the end of each chapter.

Download or read book A Fragrant Introduction to Terpenoid Chemistry written by Charles S Sell and published by Royal Society of Chemistry. This book was released on 2019-05-16 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Terpenoids play an important part in all our lives, from Vitamin A and hormones to perfumes and pharmaceuticals. This book provides an introduction to terpenoid chemistry, concentrating on the lower terpenoids, but the basic principles taught are also the foundation for the chemistry of the higher terpenoids. Coverage includes: the biogenesis of terpenoids; some of the history of the field; the principles of structural determination; and the importance of stereochemistry and stereoselective synthesis. Carbocation chemistry is introduced, as are the principles of total and partial synthesis. Finally, industrial chemistry (both discovery chemistry and chemical process development) is discussed, using the volatile terpenoids of perfumery to illustrate basic concepts. Ideal as both an introduction to terpenoid chemistry and as a refresher course, A Fragrant Introduction to Terpenoid Chemistry, with its real-life problems and appreciation of the relevance of chemistry to everyday life, will prove invaluable to students, lecturers and industrialists alike.