Download or read book Photochemistry of Coordination Compounds written by Vincenzo Balzani and published by . This book was released on 1970 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Energetics of Stable Molecules and Reactive Intermediates written by M.E. Minas da Piedade and published by Springer. This book was released on 1999-05-31 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the major experimental and theoretical methods currently used to study the energetics of stable molecules and reactive intermediates. Reviews the ate of the art and shows the interplay of experimental and theoretical methods used to probe bonding energetics and reactivity and a wide range of chemical species. A modern and invaluable introduction to the study of molecular energetics. A reference for workers currently involved in the field.
Download or read book Electron Transfer Reactions written by Stephan S. Isied and published by . This book was released on 1997 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: Begins with a historical overview by Henry Taube. Overviews the advances pioneered by Taube, including mechanisms of electron transfer reactions, charge transfer complexes, and *p back bonding effects in metal-ligand interactions. Discusses applications of principles of electron transfer to diverse areas of chemistry and biology such as the selective and controlled oxidation of organic functional groups, polymerization catalysis, metal biological interactions with DNA, biological electron transfer reactions, and new imaging agents in diagnostic medicine.
Download or read book Inorganic Reactions and Methods Electron Transfer and Electrochemical Reactions Photochemical and Other Energized Reactions written by J. J. Zuckerman and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic Reactions and Methods systemizes the discipline of modern inorganic chemistry according to a plan constructed by a council of editorial advisors and consults that include three Nobel laureates (E.O. Fischer, H. Taube, and G. Wilkinson). Rather than producing a collection of unrelated review articles, this series creates a framework that reflects the creative potential of this scientific discipline. In a clear, concise, and highly organized manner, it provides an in-depth treatment of bond formation reactions categorized by element type. The series covers all areas of inorganic chemistry including chemistry of the elements, coordination compounds, donor-acceptor adducts, organometallic, polymer and solid-state material, and compounds relevant to bioinorganic chemistry. A unique index system provides users with several fast options for accessing information on forming any bond type, compound, or reaction. Coverage of both classical chemistry and the frontiers of today's research make this series a valuable reference for years to come.
Download or read book Energy Transfer and Organic Photochemistry written by Angelo A. Lamola and published by . This book was released on 1969 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Electron Transfer Reactions written by Roderick David Cannon and published by Butterworth-Heinemann. This book was released on 1980 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Transition Metals in Coordination Environments written by Ewa Broclawik and published by Springer. This book was released on 2019-03-16 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.
Download or read book NBS Special Publication written by and published by . This book was released on 1968 with total page 896 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1991 with total page 1460 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.
Download or read book Photochemistry 7 written by A. Reiser and published by Elsevier. This book was released on 2013-10-22 with total page 187 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photochemistry — 7 is a collection of plenary lectures presented at the Seventh Symposium on Photochemistry held in Leuven, Belgium, on July 24-28, 1978. Contributors explore a wide range of topics relating to photochemistry, including the chemistry of exciplexes and the photo-oxidation of polymers. Excited state electron-transfer reactions of transition metal complexes are also discussed, along with the photochemistry of diazocompounds and azides in argon. This volume is comprised of 12 chapters and begins with a review of the role of exciplex intermediates in photocycloadditions involving polyenes and excited anthracenes. The reader is then introduced to the use of photochemical conversion of one molecule into another as an approach to the synthesis of natural products. The following chapters focus on the use of the Linear Combination of Fragment Configurations approach to generate qualitative potential energy surfaces; reciprocal interactions of polymers with excited solutes or polymer-bound chromophores; photochemistry of some three-membered heterocycles; cis-trans photoisomerization of 4-nitrostilbenes; and electron transfer in monolayer assemblies. This monograph will be of value to chemists.
Download or read book Photophysics of Aromatic Molecules written by John Betteley Birks and published by John Wiley & Sons. This book was released on 1970-01-01 with total page 704 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1993-02 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Photochemistry and Photophysics of Metal Complexes written by D.M. Roundhill and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focusing on practical applications, the author provides a balanced introduction to the many possible technological uses of metal complexes. Coverage includes the transition metals, lanthanide and actinide complexes, metal porphyrins, and many other complexes. This volume meets the needs of students and scientists in inorganic chemistry, chemical physics, and solid-state physics.
Download or read book Photofunctional Transition Metal Complexes written by Vivian W. W. Yam and published by Springer. This book was released on 2007-05-30 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts
Download or read book Integrated Approach to Coordination Chemistry written by Rosemary A. Marusak and published by John Wiley & Sons. This book was released on 2007-03-30 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coordination chemistry is the study of compounds formed between metal ions and other neutral or negatively charged molecules. This book offers a series of investigative inorganic laboratories approached through systematic coordination chemistry. It not only highlights the key fundamental components of the coordination chemistry field, it also exemplifies the historical development of concepts in the field. In order to graduate as a chemistry major that fills the requirements of the American Chemical Society, a student needs to take a laboratory course in inorganic chemistry. Most professors who teach and inorganic chemistry laboratory prefer to emphasize coordination chemistry rather than attempting to cover all aspects of inorganic chemistry; because it keeps the students focused on a cohesive part of inorganic chemistry, which has applications in medicine, the environment, molecular biology, organic synthesis, and inorganic materials.
Download or read book Photophysics Photochemical and Substitution Reactions written by Satyen Saha and published by BoD – Books on Demand. This book was released on 2021-06-30 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book represents a unique blend of topics covering photon-initiated reactions to substitution reactions. Additionally, several fantastic chapters on the photophysics of popular dyes and their applications make the book interesting for researchers working on photon-initiated physical and chemical processes.
