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Book Evaluation of the Propensity for Microbiologically Influenced Corrosion of Steels in Fuel Grade Ethanol Environments

Download or read book Evaluation of the Propensity for Microbiologically Influenced Corrosion of Steels in Fuel Grade Ethanol Environments written by Luke A. Jain and published by . This book was released on 2011 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Stress Corrosion Cracking of X65 Pipeline Steel in Fuel Grade Ethanol Environments

Download or read book Stress Corrosion Cracking of X65 Pipeline Steel in Fuel Grade Ethanol Environments written by Lindsey R. Goodman and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years, the demand for alternatives to fossil fuels has risen dramatically, and ethanol fuel has become an important liquid fuel alternative globally. The most efficient mode of transportation of petroleum-based fuel is via pipelines, and due to the 300% increase in ethanol use in the U.S. in the past decade, a similar method of conveyance must be adopted for ethanol. Low-carbon, low-alloy pipeline steels like X52, X60, and X65 comprise the existing fuel transmission pipeline infrastructure. However, similar carbon steels, used in the ethanol processing and production industry, were found to exhibit stress corrosion cracking (SCC) in ethanol service. Prior work has shown that contaminants absorbed by the ethanol during distillation, processing or transport could be the possible determinants of SCC susceptibility; 200 proof ethanol alone was shown not to cause SCC in laboratory studies. To ensure the safety and integrity of the pipeline system, it was necessary to perform a mechanistic study of SCC of pipeline steel in fuel grade ethanol (FGE).\r : The objective of this work was to determine the environmental factors relating to SCC of X65 steel in fuel grade ethanol (FGE) environments. To accomplish this, a systematic study was done to test effects of FGE feedstock and common contaminants and constituents such as water, chloride, dissolved oxygen, and organic acids on SCC behavior of an X65 pipeline steel. Slow strain rate tests (SSRT) were employed to evaluate and compare specific constituents' effects on crack density, morphology, and severity of SCC of X65 in FGE. SCC did not occur in commercial FGE environments, regardless of the ethanol feedstock. In both FGE and simulated fuel grade ethanol (SFGE), SCC of carbon steel was found to occur at low water contents (below 5 vol%) when chloride was present above a specific threshold quantity. Cl- threshold for SCC varied from 10ppm in FGE to approximately 1 ppm in SFGE. SCC of carbon steel was inhibited when oxygen was removed from solution via N2 purge or pHe was increased by addition of NaOH. During SSRT, in-situƠ electrochemical measurements showed a significant role of film rupture in the SCC mechanism. Analysis of repassivation kinetics in mechanical scratch tests revealed a large initial anodic dissolution current spike in SCC-causing environments, followed by repassivation indicated by current transient decay. In the deaerated environments, repassivation did not occur, while in alkaline SFGE repassivation was significantly more rapid than in SCC-inducing SFGE. Composition and morphology of the passive film on X65 during static exposure tests was studied using X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). Results showed stability of an air-formed native oxide under static immersion in neutral (pHe = 5.4) SFGE, and dissolution of the film when pHe was decreased to 4.3. XPS spectra indicated changes in film composition at high pHe (near 13) and in environments lacking sufficient water. In light of all results, a film-rupture anodic-dissolution mechanism is proposed in which local plastic strains facilitates local breakdown of the air-formed oxide film, causing iron to dissolve anodically. During crack propagation anodic dissolution occurs at the crack tip while crack walls repassivate preserving crack geometry and local stress concentration at the tip. It is also proposed that SCC can be mitigated by use of alkaline inhibitors that speed repassivation and promotes formation of a more protective Fe(OH)3 film.

Book Microbiologically Induced Corrosion of Steel Structures in Port Environment

Download or read book Microbiologically Induced Corrosion of Steel Structures in Port Environment written by and published by . This book was released on 2013 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Effect of Microbiologically Influenced Corrosion on Coated Steel in Marine Environment

Download or read book Effect of Microbiologically Influenced Corrosion on Coated Steel in Marine Environment written by Ying Ci Wee and published by . This book was released on 2012 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Stress Corrosion Cracking and Corrosion of Carbon Steel in Simulated Fuel grade Ethanol

Download or read book Stress Corrosion Cracking and Corrosion of Carbon Steel in Simulated Fuel grade Ethanol written by Xiaoyuan Lou and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Today, ethanol, as well as other biofuels, has been increasingly gaining popularity as a major alternative liquid fuel to replace conventional gasoline for road transportation. One of the key challenges for the future use of bioethanol is to increase its availability in the market via an efficient and economic way. However, one major concern in using the existing gas-pipelines to transport fuel-grade ethanol or blended fuel is the potential corrosion and stress corrosion cracking (SCC) susceptibility of carbon steel pipelines in these environments. Both phenomenological and mechanistic investigations have been carried out in order to address the possible degradation phenomena of X-65 pipeline carbon steel in simulated fuel-grade ethanol (SFGE). Firstly, the susceptibilities of stress corrosion cracking of this steel in SFGE were studied. Ethanol chemistry of SFGE was shown to have great impact on the stress corrosion crack initiation/propagation and the corrosion mode transition. Inclusions in the steel can increase local plastic strain and act as crack initiation sites. Secondly, the anodic behavior of carbon steel electrode was investigated in detail under different ethanol chemistry conditions. General corrosion and pitting susceptibility under unstressed condition were found to be sensitive to the ethanol chemistry. Low tendency to passivate and the sensitivity to ethanol chemistry are the major reasons which drive corrosion process in this system. Oxygen plays a critical role in controlling the passivity of carbon steel in ethanol. Thirdly, the detailed study was carried out to understand the SCC mechanism of carbon steel in SFGE. A film related anodic dissolution process was identified to be a major driving force during the crack propagation. Fourthly, more detailed electrochemical impedance spectroscopy (EIS) studies using phase angle analysis and transmission line simulation reveal a clearer physical picture of the stress corrosion cracking process in this environment. Fifthly, the cathodic reactions of carbon steel in SFGE were also investigated to understand the oxygen and hydrogen reactions. Hydrogen uptake into the pipeline steel and the conditions of the fractures related to hydrogen embrittlement were identified and studied.

Book An Investigation of Microbial Diversity and Microbiologically Influenced Corrosion in Automotive Fuel Environments

Download or read book An Investigation of Microbial Diversity and Microbiologically Influenced Corrosion in Automotive Fuel Environments written by Charles H. D. Williamson and published by . This book was released on 2013 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Stress Corrosion Cracking of Carbon Steel in Fuel Grade Ethanol

Download or read book Stress Corrosion Cracking of Carbon Steel in Fuel Grade Ethanol written by R. D. Kane and published by . This book was released on 2003 with total page 46 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Microbiologically Influenced Corrosion

Download or read book Microbiologically Influenced Corrosion written by Reza Javaherdashti and published by Springer. This book was released on 2016-09-29 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: Significantly extended from the first edition, this book presents the basics of microbiologically influenced corrosion (MIC) in an accessible and concise manner. It explores strategies for recognizing, understanding, mitigating and preventing this type of corrosion, and investigates this topic from the point of view of an engineer. Chapters cover issues including stress corrosion cracking and microbial corrosion, the pros and cons of biocides, the involvement of magnetic bacteria in microbial corrosion, and cathodic protection based on recent research in microbial environments. The 2nd Edition provides new material examining the following topics: *The corrosion-related bacteria clostridia *Mathematical modelling of MIC, in particular fuzzy logic *A comparison of culture-independent methods with culture-dependent methods *Further practical strategies for dealing with MIC *Natural biocidesThis book has provided course material for the author’s microbial corrosion workshops around the world, and it presents an invaluable resource to corrosion and integrity professionals working in a wide range of industries including power generation, oil and gas, marine, and mining. It is also intended for students and academics of corrosion engineering, materials science, microbiology, chemical engineering and welding.

Book Techniques for Corrosion Monitoring

Download or read book Techniques for Corrosion Monitoring written by and published by Elsevier. This book was released on 2008-02-01 with total page 711 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion monitoring techniques play a key role in efforts to combat corrosion, which can have major economic and safety implications. This important book starts with a review of corrosion fundamentals and provides a four-part comprehensive analysis of a wide range of methods for corrosion monitoring, including practical applications and case studies. The first part of the book reviews electrochemical techniques for corrosion monitoring, such as polarization techniques, potentiometric methods, electrochemical noise and harmonic analyses, galvanic sensors, differential flow through cells and multielectrode systems. A second group of chapters analyses the physical or chemical methods of corrosion monitoring. These include gravimetric, radioactive tracer, hydrogen permeation, electrical resistance and rotating cage techniques. Part II also includes a chapter on the innovative nondestructive evaluation technologies that can be used to monitor corrosion. Part III examines corrosion monitoring in special environments such as microbial systems, concrete and soil, and remote monitoring and model predictions. A final group of chapters includes various case studies covering ways in which corrosion monitoring can be applied to engine exhaust systems, cooling water systems, pipelines, equipment in chemical plants, and other real world systems. With its distinguished editor and international team of contributors, Techniques for corrosion monitoring is a valuable reference guide for engineers and scientific and technical personnel who deal with corrosion in such areas as automotive engineering, power generation, water suppliers and the petrochemical industry. Provides a comprehensive analysis of the range of techniques for corrosion monitoring Specific case studies are included to highlight the main issues A valuable reference guide for engineers, scientific and technical personnel who deal with corrosion

Book Applied Metallurgy and Corrosion Control

Download or read book Applied Metallurgy and Corrosion Control written by Amiya Kumar Lahiri and published by Springer. This book was released on 2017-08-23 with total page 558 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book serves as a comprehensive resource on metals and materials selection for the petrochemical industrial sector. The petrochemical industry involves large scale investments, and to maintain profitability the plants are to be operated with minimum downtime and failure of equipment, which can also cause safety hazards. To achieve this objective proper selection of materials, corrosion control, and good engineering practices must be followed in both the design and the operation of plants. Engineers and professional of different disciplines involved in these activities are required to have some basic understanding of metallurgy and corrosion. This book is written with the objective of servings as a one-stop shop for these engineering professionals. The book first covers different metallic materials and their properties, metal forming processes, welding, and corrosion and corrosion control measures. This is followed by considerations in material selection and corrosion control in three major industrial sectors, oil & gas production, oil refinery, and fertilizers. The importance of pressure vessel codes as well as inspection and maintenance repair practices have also been highlighted. The book will be useful for technicians and entry level engineers in these industrial sectors. Additionally, the book may also be used as primary or secondary reading for graduate and professional coursework.

Book Corrosion Science and Technology

Download or read book Corrosion Science and Technology written by David E.J. Talbot and published by CRC Press. This book was released on 2018-01-29 with total page 699 pages. Available in PDF, EPUB and Kindle. Book excerpt: Twenty years after its first publication, Corrosion Science and Technology continues to be a relevant practical guide for students and professionals interested in material science. This Third Edition thoroughly covers the basic principles of corrosion science in the same reader-friendly manner that made the previous edition invaluable, and enlarges the scope of the content with expanded chapters on processes for various metals and new technologies for limiting costs and metal degradation in a variety of commercial enterprises not explored in previous editions. This book also presents expertly developed methods of corrosion testing and prediction.

Book Microbiologically Influenced Corrosion in the Upstream Oil and Gas Industry

Download or read book Microbiologically Influenced Corrosion in the Upstream Oil and Gas Industry written by Torben Lund Skovhus and published by CRC Press. This book was released on 2017-03-03 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microorganisms are ubiquitously present in petroleum reservoirs and the facilities that produce them. Pipelines, vessels, and other equipment used in upstream oil and gas operations provide a vast and predominantly anoxic environment for microorganisms to thrive. The biggest technical challenge resulting from microbial activity in these engineered environments is the impact on materials integrity. Oilfield microorganisms can affect materials integrity profoundly through a multitude of elusive (bio)chemical mechanisms, collectively referred to as microbiologically influenced corrosion (MIC). MIC is estimated to account for 20 to 30% of all corrosion-related costs in the oil and gas industry. This book is intended as a comprehensive reference for integrity engineers, production chemists, oilfield microbiologists, and scientists working in the field of petroleum microbiology or corrosion. Exhaustively researched by leaders from both industry and academia, this book discusses the latest technological and scientific advances as well as relevant case studies to convey to readers an understanding of MIC and its effective management.

Book Microbiologically Influenced Corrosion

Download or read book Microbiologically Influenced Corrosion written by Brenda J. Little and published by John Wiley & Sons. This book was released on 2007-04-13 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: A multi-disciplinary, multi-industry overview of microbiologically influenced corrosion, with strategies for diagnosis and control or prevention Microbiologically Influenced Corrosion helps engineers and scientists understand and combat the costly failures that occur due to microbiologically influenced corrosion (MIC). This book combines recent findings from diverse disciplines into one comprehensive reference. Complete with case histories from a variety of environments, it covers: Biofilm formation Causative organisms, relating bacteria and fungi to corrosion mechanisms for groups of metals Diagnosing and monitoring MIC Electrochemical techniques, with an overview of methods for detection of MIC The impact of alloying elements, including antimicrobial metals, and design features on MIC MIC of non-metallics Strategies for control or prevention of MIC, including engineering, chemical, and biological approaches This is a valuable, all-inclusive reference for corrosion scientists, engineers, and researchers, as well as designers, managers, and operators.

Book Stress Corrosion Cracking of Pipelines

Download or read book Stress Corrosion Cracking of Pipelines written by Y. Frank Cheng and published by John Wiley & Sons. This book was released on 2013-02-13 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explains why pipeline stress corrosion cracking happens and how it can be prevented Pipelines sit at the heart of the global economy. When they are in good working order, they deliver fuel to meet the ever-growing demand for energy around the world. When they fail due to stress corrosion cracking, they can wreak environmental havoc. This book skillfully explains the fundamental science and engineering of pipeline stress corrosion cracking based on the latest research findings and actual case histories. The author explains how and why pipelines fall prey to stress corrosion cracking and then offers tested and proven strategies for preventing, detecting, and monitoring it in order to prevent pipeline failure. Stress Corrosion Cracking of Pipelines begins with a brief introduction and then explores general principals of stress corrosion cracking, including two detailed case studies of pipeline failure. Next, the author covers: Near-neutral pH stress corrosion cracking of pipelines High pH stress corrosion cracking of pipelines Stress corrosion cracking of pipelines in acidic soil environments Stress corrosion cracking at pipeline welds Stress corrosion cracking of high-strength pipeline steels The final chapter is dedicated to effective management and mitigation of pipeline stress corrosion cracking. Throughout the book, the author develops a number of theoretical models and concepts based on advanced microscopic electrochemical measurements to help readers better understand the occurrence of stress corrosion cracking. By examining all aspects of pipeline stress corrosion cracking—the causes, mechanisms, and management strategies—this book enables engineers to construct better pipelines and then maintain and monitor them to ensure safe, reliable energy supplies for the world.

Book Corrosion for Everybody

Download or read book Corrosion for Everybody written by Alec Groysman and published by Springer Science & Business Media. This book was released on 2009-11-21 with total page 377 pages. Available in PDF, EPUB and Kindle. Book excerpt: People seldom enjoy corrosion. They usually perceive it as a nasty phenomenon with which they must cope. Yet many people, far from the corrosion field, come across it because of their professional duty. Lawyers, historians, doctors, architects, philosophers, artists, and archeologists, to name a few, may want or need to understand the principles of corrosion. This volume explains this important topic in a lucid, interesting, and popular form to everybody: to students and young engineers who are only beginning their studies, to scientists and engineers who have dealt with corrosion for many years, and to non-specialists involved in corrosion problems. The book uses a fresh writing style, with some new explanations relating to thermodynamics of oxidation of iron and mild steels in water, reversible and irreversible potential, solubility of oxygen in water and aqueous solutions of electrolytes, corrosion of metals in fuels, corrosion of storage tanks for fuels and their corrosion control, corrosion monitoring in practice, humanitarian aspects of corrosion science and technology (history of the evolution of knowledge about corrosion, relationships between corrosion and philosophy, corrosion and art). Many practical examples of various corrosion phenomena are given.