Download or read book Equilibrium and Non equilibrium Aspects of Gibbs Measures written by Younghak Kwon and published by . This book was released on 2021 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: We consider a one-dimensional lattice system of unbounded, real-valued spins with arbitrarystrong, quadratic, finite-range interaction. The first area of interest concerns the equivalence of the grand canonical ensemble and the canonical ensemble: on the level of thermodynamic functions, on the level of observables, and on the level of correlations. More precisely, in the thermodynamic limit (size N of the system goes to infinity), we show that the free energy, expectation of intensive observable, and correlation of two intensive functions are the same for the grand canonical ensemble and canonical ensemble. The second area of interest concerns the decay of correlations and uniqueness of infinite-volume Gibbs measure of the canonical ensemble. It is shown that the correlations of the canonical ensemble decay exponentially plus a volume correction term. As a consequence, we verify a conjecture that the infinite-volume Gibbs measure of the canonical ensemble is unique on the one-dimensional lattice, extending results that are known for the case of weak interaction. The third area of interest concerns the logarithmic Sobolev inequality (LSI). It is shown that the canonical ensemble satisfies a uniform LSI. The LSI constant is uniform in the boundary data, the external field and scales optimally in the system size. We deduce the LSI by combining two different methods, the two-scale approach and the Zegarlinski method. The last area of interest concerns the hydrodynamic limit. We deduce the hydrodynamic limit of Kawasaki dynamics. The main ingredients are uniform LSI and decay of correlations for the canonical ensemble. The proof is based on a method invented by Grunewald, Otto, Villani and Westdickenberg.
Download or read book Stochastic Dynamics Out of Equilibrium written by Giambattista Giacomin and published by Springer. This book was released on 2019-06-30 with total page 649 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stemming from the IHP trimester "Stochastic Dynamics Out of Equilibrium", this collection of contributions focuses on aspects of nonequilibrium dynamics and its ongoing developments. It is common practice in statistical mechanics to use models of large interacting assemblies governed by stochastic dynamics. In this context "equilibrium" is understood as stochastically (time) reversible dynamics with respect to a prescribed Gibbs measure. Nonequilibrium dynamics correspond on the other hand to irreversible evolutions, where fluxes appear in physical systems, and steady-state measures are unknown. The trimester, held at the Institut Henri Poincaré (IHP) in Paris from April to July 2017, comprised various events relating to three domains (i) transport in non-equilibrium statistical mechanics; (ii) the design of more efficient simulation methods; (iii) life sciences. It brought together physicists, mathematicians from many domains, computer scientists, as well as researchers working at the interface between biology, physics and mathematics. The present volume is indispensable reading for researchers and Ph.D. students working in such areas.
Download or read book Statistical Mechanics of Lattice Systems written by Sacha Friedli and published by Cambridge University Press. This book was released on 2017-11-23 with total page 643 pages. Available in PDF, EPUB and Kindle. Book excerpt: A self-contained, mathematical introduction to the driving ideas in equilibrium statistical mechanics, studying important models in detail.
Download or read book Equilibrium and Nonequilibrium Statistical Mechanics Principles and Concepts written by Avijit Lahiri and published by Avijit Lahiri. This book was released on 2023-10-14 with total page 1623 pages. Available in PDF, EPUB and Kindle. Book excerpt: Equilibrium and Non-equilibrium Statistical Mechanics is a source-book of great value to college and university students embarking upon a serious reading of Statistical Mechanics, and is likely to be of interest to teachers of the subject as well. Written in a lucid style, the book builds up the subject from basics, and goes on to quite advanced and modern developments, giving an overview of the entire framework of statistical mechanics. The equilibrium ensembles of quantum and classical statistical mechanics are introduced at length, indicating their relation to equilibrium states of thermodynamic systems, and the applications of these ensembles in the case of the ideal gas are worked out, pointing out the relevance of the ideal gas in respect of a number of real-life systems. The application to interacting systems is then taken up by way of explaining the virial expansion of a dilute gas. The book then deals with a number of foundational questions relating to the existence of the thermodynamic limit and to the equivalence of the various equilibrium ensembles. The relevance of the thermodynamic limit in explaining phase transitions is indicated with reference to the Yang-Lee theory and the Kirkwood-Salsburg equations for correlation functions. The statistical mechanics of interacting systems is then taken up again, with reference to the 1D and 2D Ising model and to the spin glass model of disordered systems. Applications of the Mean field theory are worked out, explaining the Landau-Ginzburg theory, which is then followed by the renormalization group approach to phase transitions. Interacting systems in the quantum context are referred to, addressing separately the cases of interacting bosons and fermions. The case of the weakly interacting bosons is explained in details, while the Landau theory for fermi liquids is also explained in outline. The book then goes on to a modern but readable account of non-equilibrium statistical mechanics, explaining the link with irreversible thermodynamcs. After an exposition of the Boltzmann equations and the linear response theory illustrated with reference to the hydrodynamic model, it explains the statistical mechanics of reduced systems, in the context of a number of reduction schemes. This is followed by an account of the relevance of dynamical chaos in laying down the foundations of classical statistical mechanics, where the SRB distributon is introduced in the context of non-equilibrium steady states, with reference to which the principle of minimum entropy production is explaned. A number of basic fluctuation relations are then worked out, pointing out their relation to irreversible thermodynamics. Finally, the book explains the relevance of quantum chaos in addressing foundational issues in quantum statistical mechanics, beginning with Berry’s conjecture and then going on to an exposition of the eigenstate thermalization (ETH) hypothesis, indicating how the latter is relevant in explaining the processes of equilibriation and thermalization in thermodynamic systems and their sub-systems.
Download or read book An Introduction to Chaos in Nonequilibrium Statistical Mechanics written by J. R. Dorfman and published by Cambridge University Press. This book was released on 1999-08-28 with total page 303 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction to applications and techniques in non-equilibrium statistical mechanics of chaotic dynamics.
Download or read book Non Equilibrium Entropy and Irreversibility written by C. Lindblad and published by Springer Science & Business Media. This book was released on 2001-11-30 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: The problem of deriving irreversible thermodynamics from the re versible microscopic dynamics has been on the agenda of theoreti cal physics for a century and has produced more papers than can be digested by any single scientist. Why add to this too long list with yet another work? The goal is definitely not to give a gen eral review of previous work in this field. My ambition is rather to present an approach differing in some key aspects from the stan dard treatments, and to develop it as far as possible using rather simple mathematical tools (mainly inequalities of various kinds). However, in the course of this work I have used a large number of results and ideas from the existing literature, and the reference list contains contributions from many different lines of research. As a consequence the reader may find the arguments a bit difficult to follow without some previous exposure to this set of problems.
Download or read book Non equilibrium Thermodynamics of Heterogeneous Systems written by Signe Kjelstrup and published by World Scientific. This book was released on 2008 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.
Download or read book A Non equilibrium Statistical Mechanics written by Tian-Quan Chen and published by World Scientific. This book was released on 2003 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work presents the construction of an asymptotic technique for solving the Liouville equation, which is an analogue of the Enskog-Chapman technique for the Boltzmann equation. Because the assumption of molecular chaos has not been introduced, the macroscopic variables defined by the arithmetic means of the corresponding microscopic variables are random in general. Therefore, it is convenient for describing the turbulence phenomena. The asymptotic technique for the Liouville equation reveals a term showing the interaction between the temperature and the velocity of the fluid flows, which will be lost under the assumption of molecular chaos.
Download or read book Fundamental Aspects of Turbulent Flows in Climate Dynamics written by Freddy Bouchet and published by Oxford University Press. This book was released on 2020-02-05 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume, number 109 of the Les Houches Summer School series, presents the lectures held in August 2017 on the subject of turbulent flows in climate dynamics. Leading scientists in the fields of climate dynamics, atmosphere and ocean dynamics, geophysical fluid dynamics, physics and non-linear sciences present their views on this fast growing and interdisciplinary field of research, by venturing upon fundamental problems of atmospheric convection, clouds, large scale circulation, and predictability. Climate is controlled by turbulent flows. Turbulent motions are responsible for the bulk of the transport of energy, momentum, and water vapor in the atmosphere, which determine the distribution of temperature, winds, and precipitation on Earth. The aim of this book is to survey what is known about how turbulent flows control climate, what role they may play in climate change, and to outline where progress in this important area can be expected, given today's computational and observational capabilities. This book reviews the state-of-the-art developments in this field and provides an essential background to future studies. All chapters are written from a pedagogical perspective, making the book accessible to masters and PhD students and all researchers wishing to enter this field.
Download or read book Gibbs Measures and Phase Transitions written by Hans-Otto Georgii and published by Walter de Gruyter. This book was released on 2011-05-31 with total page 561 pages. Available in PDF, EPUB and Kindle. Book excerpt: "This book is much more than an introduction to the subject of its title. It covers in depth a broad range of topics in the mathematical theory of phase transition in statistical mechanics and as an up to date reference in its chosen topics it is a work of outstanding scholarship. It is in fact one of the author's stated aims that this comprehensive monograph should serve both as an introductory text and as a reference for the expert. In its latter function it informs the reader about the state of the art in several directions. It is introductory in the sense that it does not assume any prior knowledge of statistical mechanics and is accessible to a general readership of mathematicians with a basic knowledge of measure theory and probability. As such it should contribute considerably to the further growth of the already lively interest in statistical mechanics on the part of probabilists and other mathematicians." Fredos Papangelou, Zentralblatt MATH The second edition has been extended by a new section on large deviations and some comments on the more recent developments in the area.
Download or read book Statistical Thermodynamics of Nonequilibrium Processes written by Joel Keizer and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.
Download or read book Non Equilibrium Statistical Mechanics written by Ilya Prigogine and published by Courier Dover Publications. This book was released on 2017-03-17 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: Groundbreaking monograph by Nobel Prize winner for researchers and graduate students covers Liouville equation, anharmonic solids, Brownian motion, weakly coupled gases, scattering theory and short-range forces, general kinetic equations, more. 1962 edition.
Download or read book Convexity in the Theory of Lattice Gases written by Robert B. Israel and published by Princeton University Press. This book was released on 2015-03-08 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, Robert Israel considers classical and quantum lattice systems in terms of equilibrium statistical mechanics. He is especially concerned with the characterization of translation-invariant equilibrium states by a variational principle and the use of convexity in studying these states. Arthur Wightman's Introduction gives a general and historical perspective on convexity in statistical mechanics and thermodynamics. Professor Israel then reviews the general framework of the theory of lattice gases. In addition to presenting new and more direct proofs of some known results, he uses a version of a theorem by Bishop and Phelps to obtain existence results for phase transitions. Furthermore, he shows how the Gibbs Phase Rule and the existence of a wide variety of phase transitions follow from the general framework and the theory of convex functions. While the behavior of some of these phase transitions is very "pathological," others exhibit more "reasonable" behavior. As an example, the author considers the isotropic Heisenberg model. Formulating a version of the Gibbs Phase Rule using Hausdorff dimension, he shows that the finite dimensional subspaces satisfying this phase rule are generic. Originally published in 1979. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.
Download or read book Introduction to Non equilibrium Physical Chemistry written by R. P. Rastogi and published by Elsevier. This book was released on 2007-10-16 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium Experimental studies have been reported which provide test of the theories and their limitations Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed
Download or read book Non equilibrium Statistical Mechanics A Without The Assumption Of Molecular Chaos written by Tian-quan Chen and published by World Scientific. This book was released on 2003-07-07 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the construction of an asymptotic technique for solving the Liouville equation, which is to some degree an analogue of the Enskog-Chapman technique for solving the Boltzmann equation. Because the assumption of molecular chaos has been given up at the outset, the macroscopic variables at a point, defined as arithmetic means of the corresponding microscopic variables inside a small neighborhood of the point, are random in general. They are the best candidates for the macroscopic variables for turbulent flows. The outcome of the asymptotic technique for the Liouville equation reveals some new terms showing the intricate interactions between the velocities and the internal energies of the turbulent fluid flows, which have been lost in the classical theory of BBGKY hierarchy.
Download or read book Elements of Nonequilibrium Statistical Mechanics written by V. Balakrishnan and published by Springer Nature. This book was released on 2020-12-04 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the basic principles and techniques of nonequilibrium statistical mechanics. The importance of this subject is growing rapidly in view of the advances being made, both experimentally and theoretically, in statistical physics, chemical physics, biological physics, complex systems and several other areas. The presentation of topics is quite self-contained, and the choice of topics enables the student to form a coherent picture of the subject. The approach is unique in that classical mechanical formulation takes center stage. The book is of particular interest to advanced undergraduate and graduate students in engineering departments.
Download or read book In and Out of Equilibrium written by Vladas Sidoravicius and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume consists of a collection of invited articles, written by some of the most distinguished probabilists, most of whom were personally responsible for advances in the various subfields of probability. Graduate students and researchers in probability theory and math physics will find this book a useful reference.
