Download or read book Environmental Fate Aquatic Toxicology and Risk Assessment of Polymeric Quaternary Ammonium Salts from Cosmetic Uses written by Janet L. Cumming and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The consumption of household and personal care products in Australia is similar to that of more highly regulated agricultural and veterinary chemicals. One class of chemical used in cosmetic applications, polymeric quaternary ammonium salts (polyquaterniums), is thought to have adverse effects on aquatic organisms. These polymers belong to a larger class of polymers, cationic polyelectrolytes, that are widely used in industry, largely for water treatment, and that have been extensively studied and regulated. The cosmetic polyquaterniums, however, have not been subject to the same scrutiny, even though differences in, or expectations of, their behaviour are known to exist. The aim of this study was to examine the fate and toxicity of some cosmetic polyquaterniums, and particularly to examine the impact of the presence of the anionic surfactant, sodium dodecyl sulphate, that is often complexed with the polyquaterniums in cosmetic formulations on fate and toxicity. The polyquaterniums studied consisted of six samples of Polyquaternium-10 of provided by Amerchol (The Dow Chemical Company, Midland, MI U.S.A.), five samples of three polyquaterniums (Polyquaternium-11, Polyquaternium-28, Polyquaternium-55) provided by International Specialty Products (ISP, Wayne, New Jersey, USA), and polydimethyldiallyl ammonium chloride (poly(DADMAC), Polyquaternium-6), widely used in water treatment but less commonly in cosmetic applications purchased from Sigma-Aldrich (Castle Hill, NSW, Australia). The four-step risk assessment paradigm (hazard identification, exposure assessment, hazard assessment, risk characterisation) provided the framework for this study. Metachromatic polyelectrolyte titration was used to analyse polyquaterniums in aqueous solution. Although the method is generally not viable in the presence of other ions due to interference, it was found to be viable in the presence of the anionic surfactant sodium dodecyl sulphate. Further, the method was found to work with the supernatant following a sorption experiment involving humic acid. It was not possible to titrate solutions following exposure to bentonite, or in solutions prepared for toxicity tests. Metachromatic Colloid Titration was found to be useful in determining the charge density of the polyquaterniums, and in measuring the concentration of polyquaterniums of known charge density. To establish the extent of exposure of vulnerable aquatic organisms to polyquaterniums released from cosmetic usage, it is necessary to estimate the concentration of polyquaterniums in the aquatic environment. The volume usage of polyquaterniums was estimated from available published data and standard emission scenarios used in the risk assessment of new and existing chemicals. The partitioning of the polyquaternium from the aqueous to the biosolid phase from wastewater treatment plants was estimated from the determination of the partition coefficient between water and humic acid. The latter was assumed to be a suitable surrogate for the biosolids. The fate of polyquaterniums in wastewater treatment plants was modelled using a fugacity approach based on a typical wastewater treatment plant. The import/manufacture volume of polyquaterniums for cosmetic uses was estimated to be between 20 and 60 tonnes per annum. The partition coefficient for polyquaterniums between the aqueous phase and humic acid was lower than expected, generally between 100 and 1000 for the polyquaterniums in this study. Fugacity modelling results suggested that the partitioning of polyquaterniums to the solid phase in wastewater treatment may be less than the default values normally assumed in regulatory risk assessment. Therefore, the estimate of the predicted environmental concentration (PEC) of polyquaterniums in Australian waters is between 0.7 æg/L and 40 æg/L depending on the assumptions and methodology used. Effects assessment, or hazard assessment, is concerned with determining the capacity of the cosmetic polyquaterniums to cause harm to aquatic organisms in the environment. In this study, the aim was to determine if the hazard of the polyquaternium from cosmetic usage is the same as that of the better studied water treatment polymers; and if the complexing of the polyquaternium with the anionic surfactant makes any difference to the toxicity. One species from each of three trophic levels, viz fish, crustacean and algae were selected. Using assessment factors developed for the risk assessment of new chemicals, the environmental concentration likely to be hazardous to the most sensitive species was estimated. The polyquaterniums studied were found to be just as hazardous to the most sensitive species for a typical cosmetic polyquaternium when complexed with the anionic surfactant. The lowest concentration at which a toxic effect occurred was for 50% growth inhibition for algae, 0.3 mg/L for the most toxic polyquaternium. With assessment factors, and using the concentration at which cosmetic polyquaterniums were likely to be hazardous to aquatic organisms, the predicted no effect concentration (PNEC) was estimated to be between 0.3 æg/L and 1.2 æg/L. The risk characterisation process combines the information obtained from the effects and exposure assessments to evaluate the nature of the potential risk. Commonly, the level of risk is estimated based on the PEC/PNEC ratio. In this study, using point estimates and probabilistic methods (Monte Carlo Simulation), the risk of polyquaterniums from cosmetic uses was estimated. Based on the behaviour and toxicity determined in this study, there may be some risk to aquatic organisms from individual polyquaterniums at even low import volumes. As a class of compounds, polyquaterniums from cosmetic uses may present a significant risk to environmental waters in Australia. Sensitivity analysis showed that the prediction of risk was most sensitive to those parameters for which the least amount of data was available, such as the import volume and dilution to receiving waters. A recently developed method of estimating potential risk based on the concept of an Environmental Threshold of No Concern (ETNC), was applied to the use of cosmetic polyquaterniums in Australia. Using the fugacity model approach, the usage volume at which the environmental concentration would exceed the critical threshold was estimated. The volume was found to be significantly lower than the estimated usage determined by either of the methods employed in estimating the current usage volume. While some problems remain in identifying the risk from polyquaterniums to the Australian environment, particularly those associated with the difficulties of quantifying polymers in environmental samples, this thesis has made substantial progress in the risk assessment. Particularly, it has been shown that the use of default assumptions that are largely unsubstantiated, and the sensitivity of the methodology to information that is often unavailable, may result in an estimation of risk that may not be able to protect vulnerable environments.
Download or read book Oilfield Chemistry and its Environmental Impact written by Henry A. Craddock and published by John Wiley & Sons. This book was released on 2018-05-11 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt: Consolidates the many different chemistries being employed to provide environmentally acceptable products through the upstream oil and gas industry This book discusses the development and application of green chemistry in the oil and gas exploration and production industry over the last 25 years — bringing together the various chemistries that are utilised for creating suitable environmental products. Written by a highly respected consultant to the oil and gas industry — it introduces readers to the principles and development of green chemistry in general, and the regulatory framework specific to the oil and gas sector in the North Sea area and elsewhere in the world. It also explores economic drivers pertaining to the application of green chemistry in the sector. Topics covered in Oilfield Chemistry and its Environmental Impact include polymer chemistry, surfactants and amphiphiles, phosphorus chemistry, inorganic salts, low molecular weight organics, silicon chemistry and green solvents. It also looks at sustainability in an extractive industry, examining the approaches used and the other methodologies that could be applied in the development of better chemistries, along with discussions about where the application of green chemistry is leading in this industry sector. Provides the reader with a ready source of reference when considering what chemistries are appropriate for application to oilfield problems and looking for green chemistry solutions Brings together the pertinent regulations which workers in the field will find useful, alongside the chemistries which meet the regulatory requirements Written by a well-known specialist with a combined knowledge of chemistry, manufacturing procedures and environmental issues Oilfield Chemistry and its Environmental Impact is an excellent book for oil and gas industry professionals as well as scientists, academic researchers, students and policy makers.
Download or read book Premanufacture Notification written by Stephen C. DeVito and published by John Wiley & Sons. This book was released on 1997-04-11 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first and only guidance document to help applicants from chemical manufacturers obtain approval to synthesize and manufacture a chemical compound. Written by two EPA scientists, it provides coverage of chemical information needed for risk assessment to satisfy the requirements of the PMN review process and comply with the Toxic Substance Control Act.
Download or read book Antimicrobial Resistance in the Environment written by Patricia L. Keen and published by John Wiley & Sons. This book was released on 2012-01-24 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examines effects of the environmental distribution of antimicrobial resistance genes on human health and the ecosystem Resistance genes are everywhere in nature—in pathogens, commensals, and environmental microorganisms. This contributed work shows how the environment plays a pivotal role in the development of antimicrobial resistance traits in bacteria and the distribution of resistant microbial species, resistant genetic material, and antibiotic compounds. Readers will discover the impact of the distribution in the environment of antimicrobial resistance genes and antibiotics on both the ecosystem and human and animal health. Antimicrobial Resistance in the Environment is divided into four parts: Part I, Sources, including ecological and clinical consequences of antibiotic resistance by environmental microbes Part II, Fate, including strategies to assess and minimize the biological risk of antibiotic resistance in the environment Part III, Antimicrobial Substances and Resistance, including antibiotics in the aquatic environment Part IV, Effects and Risks, including the effect of antimicrobials used for non-human purposes on human health Recognizing the intricate links among overlapping complex systems, this book examines antimicrobial resistance using a comprehensive ecosystem approach. Moreover, the book's multidisciplinary framework applies principles of microbiology, environmental toxicology, and chemistry to assess the human and ecological risks associated with exposure to antibiotics or antibiotic resistance genes that are environmental contaminants. Each chapter has been written by one or more leading researchers in such fields as microbiology, environmental science, ecology, and toxicology. Comprehensive reference lists at the end of all chapters serve as a gateway to the primary research in the field. Presenting and analyzing the latest findings in a field of growing importance to human and environmental health, this text offers readers new insights into the role of the environment in antimicrobial resistance development, the dissemination of antimicrobial resistant genetic elements, and the transport of antibiotic resistance genes and antibiotics.
Download or read book Toxicological Profile for Isophorone written by and published by . This book was released on 1989 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ecological Assessment of Polymers written by John Douglas Hamilton and published by Van Nostrand Reinhold Company. This book was released on 1997 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explores the ecological toxicity testing of polymers, the performance of degradable polymers, and credible regulatory control and environmental programs to reduce unreasonable effects of polymers on aquatic and terrestrial organisms. The specific topics include biodegradation testing in soil and in compost, polycarboxylates and polyacrylate superabsorbents, water-treatment and dispersion polymers, and life-cycle assessment. Regulations in the US, Canada, the Pacific region, Japan, and Europe are also reviewed. Annotation copyrighted by Book News, Inc., Portland, OR
Download or read book Toxicological Profile for Chloromethane written by and published by . This book was released on 1998 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Toxicological Profile for N nitrosodimethylamine written by and published by . This book was released on 1989 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Per and polyfluorinated substances in the Nordic Countries written by Stefan Posner and published by Nordic Council of Ministers. This book was released on 2013-06-19 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Tema Nord report presents a study based on open information and custom market research to review the most common perfluorinated substances (PFC) with less focus on PFOS and PFOA. The study includes three major parts:1) Identification of relevant per-and polyfluorinated substances and their use in various industrial sectors in the Nordic market by interviews with major players and database information; 2) Emissions to and occurence in the Nordic environment of the substances described in 1); 3) A summary of knowledge of the toxic effects on humans and the environment of substances prioritized in 2); There is a lack of physical chemical data, analystical reference substances, human and environmental occurrence and toxicology data, as well as market information regarding PFCs other than PFOA and PFOS and the current legislation cannot enforce disclosure of specific PFC substance information.
Download or read book Health Effects Assessment Summary Tables written by and published by . This book was released on 1997 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Biodegradability of Surfactants written by D.R. Karsa and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: The awareness and development of 'biodegradable' surfactants pre-dates current pressures by the environmental movement by nearly three decades, wherein a responsible industry mutually agreed to replace 'hard', non-biodegradable com ponents of household detergents by 'soft', biodegradable alternatives, without course to legislation. The only requirement at that time was for surfactants used in detergents to exhibit a 'primary biodegradability' in excess of 80%; this referring to the disap pearance or removal from solution of the intact surface active material as de tected by specified analytical techniques. This proved useful, as observed environmental impacts of surfactants, e.g. visible foam on rivers, are associated with the intact molecule. Test methods for 'primary biodegradability' were eventually enshrined in EU legislation for nonionic surfactants (Directive 821242/EEC, amended 73/404IEEC) and for anionic surfactants (Directive 8212431EEC, amended 73/405IEEC). No approved test methods and resultant legislation have been developed for cationic and amphoteric surfactants to date. The environmental classification of chemical substances, which of course includes surfactants, and associated risk assessment utilises a second criterion 'ready biodegradability'. This may be assessed by a number of methods which monitor oxygen uptake (BOD), carbon dioxide production or removal of dis solved organic carbon (DOC). Some surfactants which comply with the above Detergents Directive are borderline when it comes to 'ready biodegradability'.
Download or read book Handbook of Ecotoxicology written by Peter P. Calow and published by John Wiley & Sons. This book was released on 2009-06-05 with total page 901 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Ecotoxicology provides a readily accessible, yet critical collection of information on ecotoxicological testing. Now available in a single paperback volume, this handbook represents excellent value. Part A concentrates on techniques, especially those tests used for prediction. Thorough descriptions of the main tests are provided, followed by critical analyses in terms of ease of handling, repeatability and ecological relevance, and finally, an extensive bibliography citing key documents describing test methods and key papers evaluating them. Part B focuses on the toxicants themselves: summarising their ecological effects, describing ways of predicting effects from physico-chemical properties alone, and describing and discussing fate models. Now available as a single volume in paperback An invaluable reference resource
Download or read book Microbicides for the Protection of Materials written by W. Paulus and published by Springer Science & Business Media. This book was released on 1993-09-30 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is chiefly intended for those who are using microbicides for the protection of materials. Another purpose is to inform teachers and students working on biodeterioration and to show today's technical standard to those engaged in R&D activities in the microbicide field. When trying to classify, or to subclassify, material-protecting microbicides according to their mode of action, e.g. as membrane-active and electrophilic active ingredients, it turned out that a clear assignment was not always possible. For that reason the author has resorted to chemistry's principle of classifying according to groups of substances (e.g. alcohols, aldehydes, ketones, acids, esters, amides, etc.), thus providing the first necessary information about the micro bicides' properties. The description of the various groups of substances includes, whenever possible, an outline of the mode and mechanism of action of the active ingredients involved. The effective use of microbicides presupposes knowledge of their character istics. That is why the microbicides' chemico-physical properties, their toxicity, ecotoxicity, effectiveness, and effective spectrum are described in greater detail. As mentioned before, the characteristics of microbicides play an important role. They have to be suited to the intended application to avoid detrimental effects on the properties and the quality of the material to be protected; also production processes in which microbicides are used to avoid disturbances by microbial action must not be disturbed by the presence of those microbicides.
Download or read book Plastics and Environmental Sustainability written by Anthony L. Andrady and published by John Wiley & Sons. This book was released on 2015-03-23 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: Survey’s the issues typically raised in discussions of sustainability and plastics Discusses current issues not covered in detail previously such as ocean litter, migration of additives into food products and the recovery of plastics Covers post-consumer fate of plastics on land and in the oceans, highlighting the environmental impacts of disposal methods Details toxicity of plastics, particularly as it applies to human health Presents a clear analysis of the key plastic-related issues including numerous citations of the research base that supports and contradicts the popularly held notions
Download or read book Cumulated Index Medicus written by and published by . This book was released on 1997 with total page 1860 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Degradability Ecotoxicity and Bio accumulation written by Hendrik Jacobus Hueck and published by . This book was released on 1980 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Modern Shale Gas Development in the United States written by and published by . This book was released on 2009 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt:
