Download or read book Elementary step Modeling and Transient FTIR Studies of Carbon Monoxide and Ethylene Oxidation on Silica supported Platinum and Rhodium Catalysts written by Ravindra Sant and published by . This book was released on 1988 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Elementary step Modeling and Transient FTIR Studies of Carbon Monoxide and Ethylene Oxidation on Silicia supported Platinum and Rhodium Catalysts written by Ravindra Sant and published by . This book was released on 1988 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transient FTIR Studies and Elementary Step Modeling of Carbon Monoxide and Ethylene Oxidation on Silica Supported Pt and Pd Catalysts written by David John Kaul and published by . This book was released on 1985 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Comprehensive Dissertation Index written by and published by . This book was released on 1989 with total page 1116 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book American Doctoral Dissertations written by and published by . This book was released on 1988 with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book In situ FTIR Studies on Oxidation of Carbon Monoxide Over Silica Supported Palladium Catalysts written by Ekua Okoso-Amaa and published by . This book was released on 2005 with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Characterization and Reaction Studies of Silica Supported Platinum and Rhodium Model Catalysts written by Matthew James Lundwall and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The physical and catalytic properties of silica supported platinum or rhodium model catalysts are studied under both ultra high vacuum (UHV) and elevated pressure reaction conditions (>1torr). Platinum or rhodium nanoparticles are vapor deposited onto a SiO2/Mo(112) surface and characterized using various surface analytical methods. CO chemisorption is utilized as a surface probe to estimate the concentration of various sites on the nanoparticles through thermal desorption spectroscopy (TDS) and infrared reflection absorption spectroscopy (IRAS) along with microscopy techniques to estimate particle size. The results are compared with hard sphere models of face centered cubic metals described as truncated cubo-octahedron. Results demonstrate the excellent agreement between chemisorption and hard sphere models in estimating the concentration of undercoordinated atoms on the nanoparticle surface. Surfaces are then subjected to high pressure reaction conditions to test the efficacy of utilizing the rate of a chemical reaction to obtain structural information about the surface. The surfaces are translated in-situ to a high pressure reaction cell where both structure insensitive and sensitive reactions are performed. Structure insensitive reactions (e.g. CO oxidation) allow a method to calculate the total active area on a per atom basis for silica supported platinum and rhodium model catalysts under reaction conditions. While structure sensitive reactions allow an estimate of the types of reaction sites, such as step sites ([less than or equal to]C7) under reaction conditions (e.g. n-heptane dehydrocyclization). High pressure structure sensitive reactions (e.g. ethylene hydroformylation) are also shown to drastically alter the morphology of the surface by dispersing nanoparticles leading to inhibition of catalytic pathways. Moreover, the relationships between high index single crystals, oxide supported nanoparticles, and high surface area technical catalysts are established. Overall, the results demonstrate the utility of model catalysts in understanding the structure-activity relationships in heterogeneous catalytic reactions and the usefulness of high pressure reactions as an analytical probe of surface morphology.

Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2616 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Simultaneous Kinetic and Infrared Studies of Carbon Monoxide Oxidation on Supported Platinum Catalyst written by Kwang-Ho Park and published by . This book was released on 1987 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Metals Abstracts Index written by and published by . This book was released on 1983 with total page 894 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Carbon Monoxide Oxidation on Alpha alumina Supported Platinum Chromia and Platinum chromia Catalysts written by Philip Varghese and published by . This book was released on 1979 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book FTIR Studies of Surface Chemistry on Supported Rhodium Catalysts written by Ziyun Pei and published by . This book was released on 1997 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Characterization of Supported Platinum Catalysts written by Menno Johannes Kappers and published by . This book was released on 1993 with total page 115 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book An Infrared Study of the Oxidation of Carbon Monoxide Over Supported Rhodium Catalysts written by C. H. Dai and published by . This book was released on 1985 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: The reaction of carbon monoxide and oxygen over supported rhodium films has been studied using infrared spectroscopy. The focus of work was the reactivity of the various CO/Rh/X (X=Al2O3, SiO2, TiO2) surface states for supported catalysts having high and low Rh loading. Under the reaction conditions the 'linear CO' species was the most stable toward oxidation, but this could have been a result of an oxidized Rh surface. A new CO/Rh surface species has been proposed which exhibits an infrared band at 2000/cm for a 0.5% Rh/TiO2 film. This species is believed to be a bridged carbonyl between Rh+1 and the TiO2 support. Originator-supplied keywords include: Infrared spectroscopy, and Carbon dioxide.

Download or read book Kinetics of Carbon Monoxide Oxidation Over Supported Platinum Catalysts written by Maarten Antoon Jan Campman and published by . This book was released on 1996 with total page 131 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Characterisation of supported platinum catalysts written by Menno Johannes Kappers and published by . This book was released on 1993 with total page 115 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book X ray Absorption Studies of Silica supported Platinum Catalysts written by Azzam Nouman Mansour and published by . This book was released on 1983 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: