Download or read book Electron Transfer Reactions in Organic Chemistry written by Lennart Eberson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus' and Pross-Shaik's approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.
Download or read book Electron Transfer Reactions of Complex Ions in Solution written by Henry Taube and published by Elsevier. This book was released on 2012-12-02 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron Transfer Reactions of Complex Ions in Solution covers the significant development of some important area of electron transfer reactions of complex ions. This four-chapter book emerged from a series of lectures at the Polytechnic Institute of Brooklyn in November and December 1967. Chapter I presents research studies in cation hydration. This chapter describes principal methods for composition determination of the first coordination spheres of the aquo ions. Chapter II examines the distinction between reactions in which electron transfer takes place from one primary bond system to another. Chapter III discusses some aspects of ligand effects in electron-transfer reactions. This chapter demonstrates that differences in the behavior of systems can be expected at least in the extremes of mechanisms. Chapter IV deals with the history, principles and applications of the induced electron-transfer effect. This book is of great value to electrochemists, students, and researchers.
Download or read book Electron Transfer Reactions written by Roderick David Cannon and published by Butterworth-Heinemann. This book was released on 1980 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Introduction To Marcus Theory Of Electron Transfer Reactions written by Francesco Di Giacomo and published by World Scientific. This book was released on 2020-03-19 with total page 873 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, with a foreword from Nobel Laureate Rudolph A Marcus, aims at introducing the reader to the Marcus theory of electron transfer reactions from a reading of excerpts of Marcus' papers. Notes from the author may be of help to the student or the beginner. Marcus' notes at the end of each paper, with his comments and remarks, are an invaluable supplement to his articles for students and scholars in the field of electron transfer reactions.
Download or read book Catenanes Rotaxanes and Knots written by Gottfried Schill and published by Elsevier. This book was released on 2013-10-22 with total page 205 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, Volume 22: Catenanes, Rotaxanes, and Knots provides information pertinent to the synthesis of catenanes and rotaxanes. This book discusses the manner of interaction between the molecular subunits in catenanes in the solid, liquid, and gaseous states. Organized into 19 chapters, this volume begins with an overview of the idea of synthesizing molecules composed of separate entities that are mechanically connected to one another. This text then examines the stereochemistry and the other physical and chemical properties related to the mechanical connections in these compounds. Other chapters consider the determination of the absolute configuration of catenanes by extension of the Cahn–Ingold–Prelog rules. This book discusses as well the bond that mechanically connects the catenated rings. The final chapter deals with the model studies of the synthesis of knots, double wound rotaxanes, and higher linear catenanes. This book is a valuable resource for chemists, students, and research workers.
Download or read book Electron Transfer Reactions written by R. D. Cannon and published by Butterworth-Heinemann. This book was released on 2016-07-29 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electron Transfer Reactions deals with the mechanisms of electron transfer reactions between metal ions in solution, as well as the electron exchange between atoms or molecules in either the gaseous or solid state. The book is divided into three parts. Part 1 covers the electron transfer between atoms and molecules in the gas state. Part 2 tackles the reaction paths of oxidation states and binuclear intermediates, as well as the mechanisms of electron transfer. Part 3 discusses the theories and models of the electron transfer process; theories and experiments involving bridged electron transfer; optical electron transfer; and electron transfer in the solid state. The text is recommended for chemists who would like to know more about the principles and mechanisms behind electron transfer reactions.
Download or read book Semiconductor Photocatalysis written by Horst Kisch and published by John Wiley & Sons. This book was released on 2015-04-20 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focusing on the basic principles of semiconductor photocatalysis, this book also gives a brief introduction to photochemistry, photoelectrochemistry, and homogeneous photocatalysis. In addition, the author - one of the leading authorities in the field - presents important environmental and practical aspects. A valuable, one-stop source for all chemists, material scientists, and physicists working in this area, as well as novice researchers entering semiconductor photocatalysis.
Download or read book Advances in Electron Transfer Chemistry written by and published by . This book was released on 1991 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Electron Transfer Reactions written by Stephan S. Isied and published by . This book was released on 1997 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: Begins with a historical overview by Henry Taube. Overviews the advances pioneered by Taube, including mechanisms of electron transfer reactions, charge transfer complexes, and *p back bonding effects in metal-ligand interactions. Discusses applications of principles of electron transfer to diverse areas of chemistry and biology such as the selective and controlled oxidation of organic functional groups, polymerization catalysis, metal biological interactions with DNA, biological electron transfer reactions, and new imaging agents in diagnostic medicine.
Download or read book Electron Transfer written by Shunichi Fukuzumi and published by John Wiley & Sons. This book was released on 2020-01-29 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by one of the top scientists in this field, this is a systematic overview of the fundamental concepts and powerful applications. The author presents the central theories and mechanisms in electron transfer, followed by several systems in nature where this is important, while also covering modern green applications. An invaluable resource for graduate students and researchers working in this field in academia and industry.
Download or read book Proton coupled Electron Transfer written by Sebastião J. Formosinho and published by Royal Society of Chemistry. This book was released on 2012 with total page 169 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the most recent developments in the field of PCET reactions, from the theoretical and experimental points of view.
Download or read book Electron Transfer Reactions of Complex Ions in Solution written by Henry Taube and published by . This book was released on 2000 with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Interviews With Rudolph A Marcus On Electron Transfer Reactions written by Di Giacomo Francesco and published by World Scientific. This book was released on 2020-03-20 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt: In a preceding book titled 'Introduction to Marcus Theory of Electron Transfer Reactions' the reader was introduced to the Marcus Theory of Electron Transfer Reactions. There, Marcus' papers from 1956 to 1986 were considered. In the present book, oral interviews with Professor Marcus are reported on his papers published from 1987 to the present. These interviews with Marcus' notes, comments and remarks on his papers and those of his coworkers are an invaluable supplement to his articles for students and scholars in the field of electron transfer reactions.
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Hydrogen Transfer Reactions written by Gabriela Guillena and published by Springer. This book was released on 2016-09-27 with total page 387 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Download or read book Elements of Molecular and Biomolecular Electrochemistry written by Jean-Michel Savéant and published by John Wiley & Sons. This book was released on 2006-02-10 with total page 505 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is based on the George Fisher Baker Lecture given by Jean-Michel Savéant at Cornell University in Fall 2002. * The first book focusing on molecular electrochemistry * Relates to other fields, including photochemistry and biochemistry * Outlines clearly the connection between concepts, experimental illustrations, proofs and supporting methods * Appendixes to provide rigorous demonstrations to prevent an overload of algebra in the main text * Applications-oriented, focused on analyzing the results obtained rather than the methodology
Download or read book Protein Electron Transfer written by Dr Derek Bendall and published by Garland Science. This book was released on 2020-07-24 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is unique; the factual content and ideas it expounds are only just beginning to be touched upon in standard texts. Protein Electron Transfer is a major collaborative effort by leading experts and explores the molecular basis of the rapidly expan
